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By W. J. Farley

"The Sherritt Gordon mine is 100 miles north of The Pas in northern Manitoba. Copper-zinc ore was discovered on the property in 1922. Production began in 1931 and continued to June, 1932, when operations were suspended because of the low price of copper. Operations were resumed on August 1st, 1937, and have been carried on continuously from that time to the present (March 1947). The production of metals up to the end of 1945 was copper, 287,129,880 lb.; zinc concentrate (50 per cent) 104,419 tons ; gold, 79,388 oz.; silver, 2,529,974 oz.GENERALThe ore occurs in two deposits, the east and the west. Both are enclosed in gneisses that are highly metamorphosed sedimentary and volcanic derivatives. The rock beneath the deposits, and hence forming their footwall, is gneissoid quartzite; the hanging-wall rock is basic garnetiferous hornblende gneiss. Pegmatite commonly occurs along both foot- and hangingwall peripheries and as isolated blocks and fragments within the ore zone . These blocks and fragments are considered to be residuals of unreplaced host rock .The ore is relatively coarse grained and ranges from the massive to the disseminated type. The metallic sulphides composing these, named in the order of their abundance, are pyrite and pyrrhotite ( 2-1 ratio) , chalcopyrite, sphalerite (marmatite) , and minor chalmeriite; subordinate amounts of gold and silver are recovered . The insoluble content of the ore averages about 35 per cent.Another deposit known as the Bob Lake, much smaller and lower in grade but having very similar relationships, occurs about 3 ½ miles to the northeast of the main Sherritt Gordon ore masses.STRUCTUREThe Sherritt Gordon orebodies are of the replacement type, and lie within a pegmatite sill that has been intruded along a contact between quartzite and hornblende gneiss. The two main orebodies are intimately related, for the east deposit is an erosional remnant of the lower, easterly limit of an orebody once continuous with the west body. The ore lies along the southwest limb of an overturned syncline."

Jan 1, 1954

By Louise Corriveau

Exploration strategies have traditionally considered felsic gneiss complexes of the Canadian Shield sterile. This paradigm is challenged with the discovery of extensive granulite-facies Cu-Au, Fe oxides-bearing hydrothermal systems in the 1.4 Ga Bondy and 1.5 Ga La Romaine volcano-plutonic complexes of the Grenville Province. Early identification of magnetite-rich units in association with meta-exhalite and pelite-like units was key to targeting the search for mineralization, protolith information and indicators of pre-metamorphic hydrothermal activity during regional surveys of these frontier terrains. Textural evidences for a volcano-plutonic setting were found. There remained, however, numerous impediments to the recognition that the ubiquitous magnetite-laden units and associated aluminous gneiss were hydrothermal in origin. Many metamorphic reactions form magnetite at the amphibolite to granulite facies transition, and hydrothermally-leached rocks resemble metapelite or migmatitic restite, while carbonate alteration zones may look like marble or calc-silicate rock. Non-typical metamorphic mineral assemblages, modes and colours arise when hydrothermally-derived rock types are metamorphosed. These effective markers served as tools for reliable field identification of hydrothermally-altered rocks. In our case-studies, we traced pre-metamorphic hydrothermally-driven Fe-oxide precipitation in association with sericitization, albitization, pyrophyllite alteration, chloritization, and B enrichment by mapping unusually high contents of (1) magnetite or hematite, (2) biotite, (3) albite, (4) sillimanite, (5) orthopyroxene or phlogopite with cordierite, and (6) tourmaline or kornerupine. The unveiled garnetite, tourmalinite, and aluminous gneiss had assemblages that vary according to metamorphic grade and composition. To assess if high mode of Fe-Mg-Al phases resulted from partial melting (restitic residue) or metamorphism of hydrothermal rocks, we compared leucosome mineral assemblages, shape and amount with that expected of in situ partial melting reactions. In both areas there is no compelling evidence for these units to be restites. In contrast, the presence of lapilli in garnet-cordierite-sillimanite gneiss, though extremely rare, constitutes conclusive evidence for extreme pre-metamorphic high-sulphidation alteration of a volcanic protolith, while Fe-oxides or sillimanite-bearing nodules and veins record a less pervasive alteration. Geochemical research on element mobility and mass balance calculations further testified of an hydrothermal origin for these gneisses. The magnetite-rich units, together with calc-silicate rocks, garnetite, hornblendite, albitite among amphibolite, provided effective guides to sites of fluid discharge and led to the discovery of Cu and Cu-Au showings. With the presence of highsulphidation alteration, these features suggest early Cu-Au VHMS-type alteration halos within a predominantly felsic composite volcano-plutonic arc setting for both case-studies. Evidences for subsequent F-driven orthomagmatic fluid activity are also present.

May 1, 2003

By M. Okada

Consumption of refined copper in Asia, especially in China and India, has soared, and the copper price is at its historic height. New smelters and refineries have been built in the region with state-of-the-art technology to meet the unprecedented demands. Supply of copper concentrate, on the other hand, has fallen short of the growing demand for concentrate by the smelters and refineries with expanded production capacities. The shortage of copper concentrate is attributable to the delay in the mining development, caused by the prolonged price slump of before 2005. The mismatch between supply of concentrate and smelting and refining capacities may cause disorderly movement of copper price, and hamper the sound development of the industry. The recent high copper price may prompt substitution with alternate materials. With electrical and thermal conductivity and workability, copper is one of the most customer-friendly materials. It is regrettable for both customers and suppliers if the high copper price would become an impediment to promoting copper use. Some outdated and environmentally unfriendly facilities still operate. In view of recent lower-grade copper concentrate with higher sulfur content, these facilities must reform their equipment to environmental-responsive one. The current level of per capita consumption of refined copper in Asia shows that the demand of copper will further grow. It is necessary to realize stable supply of refined copper and stable copper price, to help developing countries including China and India to economically take off. Hence, it is essential that the development of the copper industry be accompanied by environmentally friendly facilities, and harmoniously increased capacities between mining and smelting and refining.

Jan 1, 2007

By André Piché

"Over the last ten years, several developments have been undertaken to conceive a machine capable of carrying out simultaneously all the mining tasks in hard rock deposits: cutting, mucking, hauling, ground support and dust control.The main advantages of continuous mining over conventional drill and blast is the elimination of the cyclical nature of the actual methods. Other advantages sought are improved stability of mine openings, higher productivity, lower costs, and a cleaner and safer mining environment. Noranda has con-tributed to these developments in a major way. As a member of HDRK, Noranda participated in the development of two mechanical continuous mining machines; the TM60 and the Wirth. Noranda also undertook a development of its own based on the utilization of electricity to break rock. This technology is called plasma blasting (PBT). The concept of plasma blasting is illustrated in Figure 1.When the operating voltage is reached (18kV), the energy is released through a high current switch (500k A) into a coaxial powercable. It is then delivered to the tip of an electrode inserted into a drill hole which is filled with an electrolyte (water). When the energy reaches the electrolyte, it is instantaneously transformed into a high temperature, high pres-sure plasma that produces a shock wave capable of breaking rock(1).After initial testing of the plasma blasting technology in the lab and in the feld, two experimental platforms were constructed. The first one, a test bench, was erected at the Noranda Technology Centre in Pointe Claire, Quebec.(2)The second one is a rock breaker prototype based on a standard diesel-powered carrier (Fig. 2). Each platform was equipped with a 300 kJ pulsed-power module.In 1993, the rock breaker prototype was used for an extensive series of tests in the field. During that campaign, over 700 oversized boulders were blasted. The results of the tests demonstrated that more durable components for PBT were needed. The test bench was then used to successfully develop and test long-lasting components (probe, switch, cable, connector) that can be adapted to industrial platforms leading to the commercialization of the technology."

Jan 1, 1996

By D. L. Churcher, R. J. Perry

"In recent years much work has been don e to examine alternate underground backfill support systems with the objectives of improving ground support and reducing mining costs. This report deals with the work conducted at Placer Dome Inc.’s Dome Mine to develop a high density backfill system, taking advantage of the unique properties of this fill material, to address a backlog of large open stopes to sustain stable minewide ground conditions for future generations of Dome miners.IntroductionDome Mine began its existence in 1909 with the discovery of visible gold on a dome shaped outcrop located west of Porcupine Lake in northern Ontario. The orebody beneath this outcrop has supported one of Canada’s premier gold mining operations for 80 years. Production during this time of over 46 000 000 tons of ore has resulted in the recovery of II 500 000 ounces of gold and 2 000 000 ounces of silver. Mining continues today at a production rate of 3500 tons per day, with ore coming from both underground and open pit operations.During the life of the mine, different underground mining methods have been used to extract the ore from a complex deposit consisting of single and multiple vein structures.Cut-and-fill mining was introduced in the 1930s using sand fill and later hydraulic fill for support and to provide a working platform. A total of 1 800 000 tons of sand fill and 7 300 000 tons of hydraulic fill have been placed underground in cut-and-fill stopes. Until the late 1960sshrinkage mining was used extensively, particularly in narrow, steeply dipping zones. Bulk mining with small diameter longholes was introduced about this time, to take advantage of low production costs. Longhole blasting has often been used to recover low grade ore from the walls or sills of old shrink stopes, resulting in large open stopes. Backfilling of these open holes has been restricted to smaller stopes and associated with local ground conditions.In the late 1970s it was recognized that the number of large open holes which were being generated presented serious regional and minewide stability problems for future operations. With higher gold prices, economic ore reserves were being tied up in areas adjacent to multi-level open stope complexes. To stabilize these stopes and allow access, backfilling would be required."

Jan 1, 1990

By P. R. A. Andrews, R. K. Collings

"In cooperation with le Ministère de l'Énergie et des ressources, Québec, le Centre de Recherches minérales, Sainte-Foy, Québec, and various silica producers, selected deposits of Quebec silica were identified in the southern region of the province and sampled to provide material for evaluation as glass and foundry sand by CANMET. The samples included both sandstone and quartz/quartzite. Head sample analyses ranged from 94.66% to 99.54% SiO2, 0.038% to 0.230% Fe2O3, and 0.16% to 4.51% Al2O3.Impurities included pyrite, iron oxides, and iron staining on quartz grains; carbonates as calcite; and alumino-silicates as clay and/or feldspar. Processing included size reduction to grain size, about 600 µm, by jaw, roll and cone crushers, and grinding in a muller-mixer. Removal of fines was achieved by attrition scrubbing and washing. Further removal of impurities was achieved by reverse flotation of iron oxide and alumino-silicate minerals employing both anionic and cationic collectors. Flotation resulted in a substantial improvement in the quality of most sands, the quartz concentrates analyzing 99.08% to 99.80% SiO2, 0.014% to 0.048% Fe2O3, and 0.06% to 0.49% Al2O3. Removal of iron oxide minerals was also investigated using the Sala HGMS. Iron oxide analyses of the non-magnetic fractions were comparable to the iron oxide analyses of the quartz concentrates obtained by flotation, 0.013% to 0.054% Fe2O3. On the basis of the samples submitted, silica from 5 of the 6 deposits studied has potential as source material for glass sand. Foundry tests showed that 3 of the 4 samples submitted for evaluation have potential as foundry sand."

Jan 1, 1987

By Dwayne D. Tannant

This paper presents a summary of results from a questionnaire sent to surface mines in western Canada seeking information on haul road design, construction, and maintenance. There has been a marked increase in the size of the trucks used over the last decade with some mines now using trucks with a payload capacity of 360mt. Consequentially, geometrical elements of haul roads, such as width, have been enlarged to accommodate larger trucks. Most haul roads are constructed on the basis of past experience without use of formal design procedures. With the introduction of larger haul trucks, problems related to rolling resistance, deterioration, and maintenance of the haul roads have become more important. This has lead to adoption of more rigorous design methods for roads at some mines, most notably for the oil sand mines operated by Syncrude Canada Ltd. A summary of the evolution of haul road designs implemented at Syncrude Canada Ltd. is presented.

May 1, 2001

By C. S. Touchard, F. Bourgeois, L. Cassayre, Julcour-Lebigue C.

Developing a hydrometallurgical process that can overcome the refractory nature of chalcopyrite (CuFeS2) to leaching still eludes the minerals industry, despite major research efforts spanning decades. The several leaching experiments of this ore in sulfuric acid tend toward the same conclusion that the precipitation of elemental sulfur or iron containing species are the main dissolution inhibitors. Describing both the electrolyte composition and the various solid phases in equilibrium for the Fe-H2SO4-H2O system is essential to overcome this issue and to find an operating window. According to the thermodynamic models and to the thermodynamic data, we demonstrate, in this study, the need to use the Specific ion Interactive Theory (SIT) model to describe complex electrolytic systems through a limited number of parameters. Hence, the binary interactions for our case study have to be defined and estimated. This work develops a methodology to determine these parameters of the SIT model up to 90°C and an acid concentration of 1 mol/kg from published data for H2SO4-H2O and Fe(II)-H2SO4-H2O sub-systems or from new experimental data for the Fe(III)-H2SO4-H2O one. This method will eventually be applied to copper systems to lead to a thermodynamic description of the complete CuFeS2-H2SO4-H2O system. INTRODUCTION A leaching process consists in the dissolution of a solid phase into an aqueous medium in order to extract compounds of interest. It is a key step in the hydrometallurgical processes used in the primary production and recycling of metal components. One of the main leaching issues is the formation of passivating layers on the surface of solid particles, whose consequence is a partial or total hindrance of the dissolution. The leaching of chalcopyrite (CuFeS2) in sulfuric acid is a prime example. No industrial solution for the atmospheric pressure leaching of this ore has been developed to date because of passivation phenomena caused by the formation of elemental sulfur or iron-containing precipitates on the surface of the particles (Li, Kawashima, Li, Chandra, & Gerson, 2013). In the 1970s, the Pourbaix diagrams established for the Cu-Fe-S-H2O system at 25°C for low concentrated solutions (Garrels & Christ, 1965; Peters, 1976) agreed that copper and iron are fully dissolved at high potential and in acidic medium (pH < 4). However, they neglected the many stable solid phases that can form in these conditions. In addition, the Pourbaix diagrams of chalcopyrite in water, calculated with two recent databases (FactPS and Thermoddem 2017) associated to FactSage and PhreeqC softwares respectively, show large discrepancies at 75°C (Figure 1). Indeed, at high potential, FactSage predicts the formation of goethite FeOOH at a pH value of 1, while PhreeqC predicts the formation of jarosite (H3O)[Fe3(SO4)2(OH)6] for pH greater than 2.5.

Jan 1, 2019

By M. Nagamori, A. J. Plumpton

"A low-grade concentrate from the Crevier Township, Quebec, containing 1.8% Ta205 and 13.7% Nb205 was reduced with carbon at 1600°C, and niobium and tantalum were selectively absorbed in liquid iron. To slag off the zirconia-rich gangue, some silica and lime were added as flux. Metallic iron was added in such a way that the combined contents of TaC and NbC did not exceed 20% in the ferroalloy . Up to 95% of the niobium, and up to 80% of the tantalum contained in the concentrate were recovered in the metal. The ferroalloy was ground finely and dissolved in 2 wt % sulphuric acid to leach out iron and silicon preferentially. The insoluble residue consisted principally of NbC and TaC, the calcination of which yielded an enriched concentrate comprising 80% Nb2O5 and 8% Ta2O5. The insoluble residue could also be chlorinated to obtain an impure liquid of Nb2Cl5 and TaCl5. Process variables and their effects are discussed in terms of higher metal recoveries in the smelting.IntroductionPresently, about one-third of the world production of tantalum comes from the pyrometallurgical reprocessing of tin slag, a by-product of tin smelting, containing sometimes 2 to 10% Ta205 and about the same amount of Nb205. Upon heating tin slags with carbon at about 1600°C in an electric furnace, tantalum and niobium oxides are converted to TaC and NbC, which are absorbed by the coexisting phase of molten metallic iron(1,2). The Fe-Nb-Ta-C melts cannot be decarburized by oxidation because of the preferential formation of Nb and Ta oxides over CO gas(3). So, the ferroalloys containing tantalum and niobium carbides are commercially treated by acid-leaching and I or chlorination to eliminate iron and thus permitting the eventual recovery of purified tantalum and niobium oxides(2).Absorbing Ta and Nb carbides in molten iron was first proposed and demonstrated by Zimmerley and Back(4) in 1957 in order to recover selectively tantalum and niobium from lowgrade concentrates. The process was successfully applied to the electric furnace smelting of tin slags by Hunter and Fursmant(5) over a period preceding 1965."

Jan 1, 1985

By M. Wittke

"In the course of the extension of the railway network in Israel, currently the two 4.6 km long tubes of the Gilon Tunnels on the line from Akko to Carmiel are being constructed. The tunnels run through the limestones of the Bina- and Yirka-formations, which locally are karstified. The maximum overburden amounts to 160 m.The limestones are mostly horizontally bedded and vertically jointed. Occasionally also inclined joints exist. The tunnels cross various fault zones, which mostly strike at an acute angle to the tunnel axis and are steeply inclined. The karstic cavities which were encountered during tunneling have partially been filled by clay. In the vicinity of the fault zones, the rock has often been strongly jointed and weathered respectively. The two single-track tubes have a cross section with vertical walls and an open invert. The tubes are connected by cross cuts with a spacing of approx. 250 m.During the tender phase, WBI has elaborated the tender design for a joint venture of a Chinese and an Israeli construction company. After the joint venture had been awarded the contract, the preliminary and the detailed design have been elaborated by WBI and the construction works have been guided. On the basis of the geological description, rock mechanical models have been elaborated, followed by stability analyses on the basis of the Finite Element method. The tunnels have been excavated according to the shotcrete method. The support in most areas only consisted of a very thin shotcrete lining and radial bolts in the area of the roof. Depending on the degree of jointing and weathering, locally advancing support by means of spiles has been applied.The internal lining of reinforced concrete has been constructed in parallel to the heading of the tubes. Mucking and delivery of materials was carried out through the cross cuts.The breakthrough was achieved in April 2014 and thus within schedule. The predicted distribution of the excavation and support classes along the tunnel has been in good agreement with reality."

Jan 1, 2015

By Jerry Handford

Investing in the Development of our Future Workforce ?Collaborative partnerships with educational institutions, industry associations, governments and other businesses. ?Programs: »Co-op / Discipline Student Program »Trades Development Initiatives »Operator Training Programs »General Student Program »Careers Next Generation / Community Careers Co-operative

May 1, 2006

By S. Onuki, T. Ando, M. Tejima, R. Enomoto, Y. Okada

"Al–Si–Cu–Mg die casting alloys are widely used in the automotive industry, and recent advancements in high pressure die casting technology enable heat treating products to achieve desirable properties. However, CO2emissions associated with die-casting production lines should be reduced to address the global warming issue. In this study, the relation between the microstructures and thermal stability of precipitates formed during isothermal aging at 423, 485, and 558 K of Al-11.0 mass%Si-1.8 mass%Cu-0.2 mass% Mg (JIS ADC12) was investigated using Vickers hardness tests and transmission electron microscopy (TEM). The hardness tests and TEM results showed that Si compounds and Al–Cu compounds enhanced the mechanical properties of the alloy and that the predominant compound affecting the mechanical properties differed between specimens treated at 423 K and those treated at 558 K. Moreover, additional aging at 423–458 K resulted in a material with a Vickers hardness higher than that of the isothermally single-aged material. Differential scanning calorimetry, differential elemental analysis, and selected-area diffraction analysis using TEM suggested that the combination of Al–Cu compounds precipitated at low aging temperatures and Si compounds precipitated during preliminary aging increased the mechanical strength, resulting in a maximum hardness of 130 HV.INTRODUCTIONAl–Si–Cu–Mg die casting alloys have well-balanced mechanical properties, machinability, and cast ability. These alloys are therefore widely used in the automotive industry because of their superior characteristics, accounting for>90% of the aluminum used in die casting production. As a substitute for iron-based materials, these alloys have contributed to the development of lightweight vehicles.Dong et al. (2014) reported that the heat treatment of die casting materials is effective for changing their dimensions under high temperatures as a result of the precipitation of solid-solution elements. Recent advancements in high pressure die casting technology have led to the application of heat treatments of Al–Si–Cu–Mg alloy products to reduce fuel consumption and satisfy customer needs. Although attempts to reduce CO2emissions have focused on fuel consumption in cars and fuel efficiency regulations have become increasingly strict in recent years, CO2discharged from production lines should also be reduced without adversely affecting the properties of the product. Heat treatments for artificial aging after solution treatment (T6 treatment) and after casting (T5 treatment) are CO2discharge sources, which together with a holding furnace account for >80 % of the CO2discharged during the casting process."

Jan 1, 2018

By H. Matsuoka, M. Kawata, K. Mitsuhashi, C. Tokoro, T. Kato

Copper sulfide minerals such as chalcocite, bornite, and chalcopyrite exhibit high floatability, thus they can be recovered as a froth product by adding only a collector in flotation process. However, when their surface is oxidized, the floatability decreases and the simple addition of collectors is no longer effective. In this case, flotation activators are required to improve the floatability. Sodium hydrosulfide (NaHS) acts as an activator for chalcocite and bornite by re-sulfurizing their oxidized surface portions. Nevertheless, the flotation conditions still require optimization in order to achieve a satisfactory recovery of copper minerals. This work addresses the study of the effect of pH and NaHS dosage on the flotation of a complex Chilean copper ore containing chalcocite, bornite, and chalcopyrite. Flotation experiments were conducted using a Denver-type flotation cell and by investigating the effect of two NaHS dosages (50, 100 g/t) and three pH values (8, 9, 10). Following this process, the surface interaction between the minerals and NaHS were analyzed using zeta potential measurements. INTRODUCTION In recent years in the mining area of metal resources, the complexity of ores and the fineness of grind required to liberate minerals have become serious problems. When ores are complex, several valuable minerals may interact with each other and reactions may become more complicated compared with an ore containing only one valuable mineral. Therefore, more processing steps may be required than for a simple ore. When the valuable minerals exist as fine grains, it is difficult to liberate them and more grinding time is required. Furthermore, the probability of collision of fine particles with bubbles in the flotation process declines and it takes much time to recover them. Flotation is one of the most applied methods to separate valuable minerals from unwanted ones using the difference of hydrophobicity (or hydrophilicity). In the flotation method, the air is fed to a cell filled with the pulp of the mineral of interest and agitation is implemented to introduce air and generate bubbles. The hydrophobic particles attach themselves to the bubbles and float along with the bubbles while the hydrophilic particles remain in the pulp. Copper sulfide minerals such as chalcocite (Cu2S), bornite (Cu5FeS4), chalcopyrite (CuFeS2) are widely known abundant copper resources. Generally, flotation is used to recover and concentrate these minerals. Copper sulfide minerals usually have high floatability. However when their surfaces are oxidized, their floatability becomes lower. When the sulfide surfaces are oxidized, activators are added before flotation to modify the surface property of the Copper sulfide minerals so that they can be floated. Sodium hydrosulfide, NaHS, is known as one of the activators. Zhao (2018) reported that NaHS is often used as a sulfurizer for oxidized sulfide minerals (Becker (2014), Clark (2000), Newell (2006), and Newell (2007)). In earlier work, the authors performed flotation tests on a sample of Chilean copper ore which contained chalcocite, bornite, and chalcopyrite using a Denver-type flotation apparatus. The sample was ground to P80 70 µm with a rod mill and ball mill. In these tests, the following conditions were used: natural pH (about pH 8.5), flotation time of 45 min, 60 g/t AP3477 (sodium diisobutyl dithiophosphate) as collector, and MIBC (methyl isobutyl carbinol) at appropriate dosage as frother. NaHS was applied at the dosage of 0, 67, and 120 g/t, respectively at the conditioning. The concentrates were collected at 6, 18, 30, and 45 min. The weights of the concentrates and tailing were measured and they were assayed for copper by ICP-AES (Optima 5300 DV, PerkinElmer Inc.). The flotation recoveries of the copper minerals were calculated from the results of MLA (mineral liberation analyser) (MLA 650, FEI) measurements.

Jan 1, 2019

By Ward G. Wilson

Best practice in the design and construction of soil cover systems for mine waste management has advanced extensively over the past two decades. While significant progress has been achieved, we still have little experience with respect to proven performance for cover systems that must last hundreds of years. Some cover designs appear to be functioning well, while at the same time the performance of many more are now being called into question. This presentation evaluates the integrity of cover systems from both a global and local perspective in relation to the uranium industry within Canada.

Aug 1, 2010

By Joey R. Kish, Shooka Mahboubi, Hatem S. Zurob, Gianluigi A. Botton

The kinetics of the Cr2O3-based scale oxidation and volatilization were studied in the presence of water vapour (H2O). A commercial Cr2O3-based scale forming Type 310S stainless steel was examined at the ambient pressure (0.1 MPa) and 550ºC in relatively low and high H2O containing environments of air- 10% H2O and air- 70% H2O, respectively. The increase in the partial pressure of H2O (pH2O) from 10% to 70% resulted in transition of the oxidation and volatilization kinetics from the parabolic rate law for air-10% H2O to the paralinear rate law for air-70% H2O. The kinetics transition was attributed to the increase in the Cr loss rate from the base scale after coupons exposure in air- 70% H2O. The significant role of the Mn alloying element in the base scale protectiveness was also discussed in the context of the Cr2O3-based scale stability.

Jan 1, 2017

By Eugene Sun, Qiang Xu

This presentation will review current applications of composite materials in aircraft design and discuss the challenges involved in maximizing the potential of the composites in aircraft applications.

Jan 1, 2010

By Wei Huang, Anh V. Nguyen

"Potash flotation is an industrially proven success of flotation of soluble salts, but its collector adsorption mechanism remains elusive. In this paper, specific ion effects in NaCl-KCl flotation with carboxylate collectors were investigated. Flotation recovery and contact angle were determined as a function of brine composition of NaCl and KCl. The experimental results have shown that wettability of KCl and flotation of the soluble salts with laurate collectors were dependent on brine ion composition. Specifically, adding Na+ to brines decreased hydrophobicity of KCl crystals and their flotation recovery. Both KCl and NaCl could be floated with laurate collectors. However, flotation of NaCl was greatly enhanced by adding K+ to brine whereas flotation of KCl was significantly suppressed by the presence of Na ions. The decrease in KCl recovery upon adding Na+ is attributed to the counter-ion binding in the pulp. The flotation recovery enhancement of NaCl in the presence of K+ is explained by two effects: 1) increasing K+ concentration leads to a better dispersion of collector colloids in the pulp and 2) K+ enhances the collector adsorption at NaCl crystal surfaces. The water affinity matching rule can explain the specific ion binding behaviors and supported by the SFG spectroscopic results.INTRODUCTIONPotassium is an important fertilizer. Its primary source comes from potash ores, which are a mixture of sylvite (KCl), halite (NaCl) and many other complex double salts such as carnallite (KCl·MgCl·6H2O), alkali nitrates such as KNO3 and NaNO3, and sulfates-langbeinite (2MgSO4·K2SO4) with water-insoluble minerals such as clay and carbonate minerals. Previously, these salts were recovered with a lengthy hot leaching method, with further crystallization of potassium salts from saturated saline solutions. Selective flotation has been preferred since 1940s. Various collector adsorption mechanisms have been proposed soon after the industrial introduction of potash flotation. These include the formation of the insoluble compound model (Halbich, 1933; Singewald, 1961), an ion exchange model (Fuerstenau and Fuerstenau, 1956), a heat of solution model (Rogers, 1957), the surface hydration model (Schubert, 1988), the surface charge model (Roman, 1966; Miller et al., 1992), the interfacial water structure model (Hancer and Miller, 2000) and the colloid adsorption model (Leja, 1983; Burdukova and Laskowski, 2009). Most of the early exercises attempting to propose a unified rule on collector adsorption mechanisms can be seen as heroic endeavors due to the consideration of a vast number of salts in the pulp including alkali halides, nitrates, and sulfates, even the practically insoluble heavy earth metals. Additionally, several types of surfactants with different polarization features and alkyl chain length have been employed. As for the recent models, due probably to the preferential application of long chain amines as collectors in industrial potash flotation, most researchers are only devoted to collectors with low polarization features like amines and sulfonates (Hancer and Miller, 2000; Du et al., 2014). Collector adsorption mechanisms are therefore proposed based largely on a neglect of carboxylates as collectors. However, carboxylates remain an important collector type in soluble salt flotation systems where both salt minerals can be floated using anionic collectors and cationic collectors. Fatty acid type collectors are still one of the widely used collectors for soluble salt flotation and also one of the first to be applied on an industrial scale for the separation of potash ore (Hernáinz et al., 2003; Titkov, 2004). Here we examine some recent models that are relevant to our study to reveal a long neglected specific ion binding effects in potash flotation."

Jan 1, 2016

By Louise Corriveau

A Targeted Geoscience Initiative transect in the eastern Grenville Province reveals an extensive VHMS-style cupriferous hydrothermal system among rhyolitic pyroclastic rocks of the Wakeham Group at La Romaine, Québec. The volcanic rocks outcrop sporadically along a < 10 km-wide by about 100 km-long belt correlated with the south-eastern extension of the Wakeham Group. This belt occurs among voluminous, magnetite-bearing, granitic gneiss. At Lake Musquaro, 1.51 Ga metarhyolitic to dacitic lapillistones and flows, locally with aluminous nodules and veins, are intruded by 1.49 Ga feldspar porphyries. This volcanic package was deposited on typical Wakeham Group arenite (< 1.52 Ga) interbedded with nodular, muscovite- and fibrolite-bearing gneiss, and minor marble hosting finely layered garnetiferous hornblendite, garnetite and magnetite-bearing coticule. The latter are interpreted as meta-exhalite and with the associated albitite (sodic alteration), aluminous veins (hydrothermal leaching) and magnetite-rich granitoids, they are key elements in the search for concealed mineral deposits in this area. At La Romaine, to the south, 1.5 Ga lapillistones outcrop structurally above metasediments and below a composite amphibolite unit of uncertain origin (lava or sills) with magnetite-rich (BIF?) units. An extensive zone of aluminous gneiss, with lapilli textures, provide evidences for severe hydrothermal leaching of the volcanic rocks prior to metamorphism. An adjacent siliceous vein-textured unit likely represent a zone of intense silicification (74 wt.% SiO2), while aluminous, hematite to magnetite-bearing veins in adjacent felsic gneiss (tuff?) preserve evidences for the sequence of alteration events. Despite granulite-facies metamorphism, the main characteristics of the amphibolite unit persist along the entire belt. This competent unit likely served as a cap rock; the garnetite, diopsidite and hornblendite it hosts provide effective guides to the sites of fluid discharge and mineralization. A number of Cu showings, modest in size, were discovered in this unit. Their systematic occurrence, in a structural-stratigraphic sense, indicates that this setting is attractive for mineral exploration despite high-grade metamorphism and deformation. Late-stage veins laden with fluorite crosscut these alteration zones, and are themselves metamorphosed, indicating that hydrothermal activity was polyphased. SHRIMP U-Pb ages obtained on detrital zircons (1 arenite) and on igneous zircons (5 volcanic rocks, 1 porphyry and 6 granitoids), pervasive arc-type geochemical signatures and presence of in situ rafts of barium-rich garnetite in the granitoids indicate that sedimentation and volcanism occurred between 1.52 and 1.49 Ga coevally with hydrothermal activity and emplacement of a sub-volcanic 1.5 Ga granitic batholith with early, 1.53 Ga tonalite intrusion. Such a geological context can sustain large-scale hydrothermal cells and development of VHMS, Cu-Fe oxides or SEDEX deposits.

May 1, 2003

By Pingchao Ke, Zhihong Liu

Fe(III)-As(V) precipitates were synthesized from the Fe(II)-As(V)-SO42--H2O system at 90°C in initial Fe(II)/As(V) molar ratios of 4.0 and 5.0, respectively. The synthesis were carried out by introducing oxygen gas into the system to oxidize Fe(II) ions into Fe (III) ions, and at the same time, adding aqueous sodium carbonate solution into the system to neutralize the acid released by the hydrolysis reactions, with the purpose of keeping the pH constant at 1.5±0.05. The precipitates obtained were characterized by XRD, chemical composition analysis, SEM, XPS, and Raman spectrum. The results indicated that the particles in the precipitates were in the morphology of irregular aggregation with their sizes in the range of about 1–4 µm. The precipitates consisted of scorodite, ferric arsenate and amorphous hydrated ferric oxide, of which amorphous hydrated ferric oxide formulated as Fe(OH)x(SO42-)y. The characteristic XPS peaks of Fe-AsO43- and Fe-O in the precipitates located at 711.8 and 713.3 eV, separately, and the existence of amorphous hydrated ferric oxide led to two series of shake off lines developed over the end of high binding energy of Fe2p XPS. The precipitates were stable in TCLP tests at pH 4.93 for 60 hours with the arsenic concentrations in the leaching solutions being 0.27 mg/L and 0.59 mg/L for the precipitates prepared in the initial Fe(II)/As(V) molar ratios of 4.0 and 5.0, respectively. The tests for the long-term stability of the precipitates were carried out by leaching them for 40 days at 25°C under various media in the pH range from 9.50 to 10.57, and the results showed that the precipitates synthesized in this study were much more stable than those by previous researchers.

Jan 1, 2017

By L. I. Kiss, S. Perron, D. Toulouse, S. Poncsák, A. Perron

Bubbles play an important role in many industrial processes. In a Hall-Heroult cell, used for aluminum production, bubbles contribute to induce flow in the cell. The induced flow is important for the thermal balance of the cell as well as for the distribution and dissolution of the alumina. The existence of the bubble layer does not have advantages only. It increases the voltage of the cell and causes deformation along the cryolite-molten aluminum interface. The role of the anode inclination in the behaviour of the bubble layer as well as in the hydrodynamics of the bath is not clearly understood. In this work, the effect of the anode inclination angle on the bubble driven flow is studied in an industrial scale air-water model. The inclination angle is varied up to 5° from the horizontal. The instantaneous flow field is captured by Particle Image Velocimetry (PIV) system. The mean velocity fields were calculated by ensembleaveraging the instantaneous velocity fields measured at different time. The existence of the counter-flow in the interpolar space and the vortex in the side channel has been confirmed. Furthermore it has been observed that the effect of anode slope on the velocity field is weak.

Jan 1, 2006