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By Ram Song, Yohei Harada, Shinji Kumai, Kazuho Otsuka

"Recently, vertical-type high-speed twin-roll casting (HSTRC) has been developed. The HSTRC shows extremely high cooling rates over 1,000 K/s even at the mid-thickness area. The fabricated strip has many metallurgical characteristics; super-saturation of alloying elements, fine solidified structure, and homogeneous distribution of fine constituent particles. In Al-Mn based alloys, the Mn alloying element can be supersaturated in the a-Al matrix and also form Mn-containing constituent particles during solidification. The Mn supersaturation and the distribution of primary/secondary particles in cast products affect the metallurgical behavior in the down-stream processing and can improve mechanical properties of the final products. In this study, Al-Mn based alloy strips were fabricated by HSTRC with various Mn contents. The solidified microstructure, constituent particles and its distribution, and Mn solubility were investigated in the as-cast condition. Due to the high cooling rate of HSTRC, fine constituent particles were homogeneously distributed, and coarse intermetallics were not observed. Mn solid solubility was estimated by electrical conductivity. The estimated Mn solubility was equivalent between strip surface and mid-thickness area.INTRODUCTION Al-Mn based alloys, as non-heat treatable wrought aluminum alloys, are widely used in packaging and heat exchanger for automobile industry. Besides Mn, Al-Mn based alloys often contain Fe and/or Si as alloying elements or natural impurities. During solidification, Mn can be super-saturated in the Al matrix, and also form Mn-containing constituent particles. Additionally, in the subsequent thermal-mechanical processes such as homogenization, rolling, and intermediate annealing, Mn in solid solution precipitates out of the Al matrix as secondary particles. The size, distribution, type, and the amount of dispersoids including constituent particles affect to texture evolution, recrystallization behavior, and final mechanical properties of wrought Al-Mn based alloys (Huang et al., 2016; Huang & Marthinsen, 2015; Engler et al., 1995; Muggerud et al., 2013). Therefore, controlling the initial level of Mn super-saturation and the distribution of constituent particles are important in the cast Al-Mn based alloys."

Jan 1, 2018

By J. M. Harrison

"The Nor-Acme gold mine is near the shore of Snow lake, northern Manitoba, about 75 miles east of Flin Flon. The claims that form the nucleus of the present property were staked in 1927 by C. R. Parres, but it was not until 1941 that diamond drilling disclosed the potentialities of the deposit. In that year a large-scale drilling programme was begun under the direction of F. Ebbutt, of the Howe Sound Exploration and Development Company. Two orebodies were outlined containing about 5,000,000 tons of ore assaying $5.25 in gold per ton. In August, 1945, construction of the mining plant was begun.All information and interpretations contained in the following brief description of the deposit were obtained from surface mapping.GEOLOGYThe ore lies at the contact between a coarse, basic, pyroclastic rock, which is the hanging-wall, and grey, acidic lavas and sediments, which form the footwall. These rocks are cut by irregular basic intrusions that vary in composition from diorite to hornblendite, and by small acidic dykes . Tourmaline is locally common in the hanging-wall rock near the ore.The ore occurs in brecciated, silicified, and ·slightly carbonatized rock. Arsenopyrite is the main sulphide and the gold is associated with it. Pyrrhotite is locally abundant and minor pyrite, chalcopyrite, sphalerite, galena, and cubanite have been noted. Two orebodies are known, the Dick and the Toots. The Toots, which is much the smaller of the two, is about 1,000 feet west of the Dick."

Jan 1, 1954

By Yoginder P. Chugh

Beginning in 2010, a scientifically-founded water spray system for continuous miners (CMs) has been in development at Southern Illinois University that significantly reduces respirable dust exposure for workers in the face area (patent pending). It includes engineered sprays around the cutting drum, outer bitring sprays, chassis sprays and side cutter boom sprays. About 3.6?4.5 m behind these sprays are additional sprays that cover the area between the CM chassis and the mine roof and ribs. The innovative spray system uses approximately the same volume of water as spray systems currently used on CMs and with similar operating pressures. The innovative spray system design also takes into consideration coal dust wettability. An Illinois mine decided to implement these concepts on a CM during the rebuild stage. Dust control performance of the rebuilt CM was evaluated using gravimetric dust sampling and real-time monitoring with multiple personal dust monitors. The average results based on gravimetric sampling of about 105 cuts show about 30 and 20% reduction in dust exposure for the miner operator and the haulage unit operator, respectively. Visibility in the mining areas was also significantly improved. Since the initial demonstration, the coal company has implemented the system on all of their operating CMs.

Aug 1, 2013

By François Baillargeon

Two types of ore deposit provide the bulk of the world nickel production. They are the hypogene magmatic massive sulfide deposits and the supergene lateritic deposits. Platinum group elements (PGE) are also extracted from magmatic sulfide deposits. Recent sky-rocketing price of palladium has prompted the mineral industry to seek alternative resources. In such a manner has emerged the Lac-des-Iles type of target, a very low sulfide-bearing bulk tonnage type of deposit. Furthermore, unconventional (e.g. non-magmatic) types of deposit are now sought more intensively (Wilde et al., 2003). Considering both this trend of the PGE Industry, and that only a few magmatic deposits account significantly for the world nickel production, someone may wonder if a diversification of the hypogene nickel resources base would not be needed in the near future. Laterites are residual deposits developed on ultramafic rock under wet tropical climate. Are all ultramafic protoliths equal to generate high-grade lateritic deposit? Are some preweathering processes important to generate favourable ultramafic protoliths? The mineralogical heterogeneity of some ?dry? lateritic nickel deposits renders their ore beneficiation difficult. Is the type of nickel-bearing mineral found in the protolith a significant factor influencing the laterite heterogeneity? To contribute to answer all these questions, we have undertaken a research project on the nickel occurrences of the southern Quebec serpentinite belts. Why choosing this specific region for such a project? First because, due to continuous mining of asbestos ore since 1870, the serpentinite belts of this region are among the best exposed and studied in the world. Secondly, this region host a complete spectrum of nickel deposits that have been described before in the scientific literature. Furthermore, this region is slightly to moderately metamorphosed which make it perfectly suited to study the departure from magmatic nickeliferous paragenesis through various metamorphic conditions. As a matter of fact two orogenic events affected this region, the Taconian, in Ordovician time, and the Acadian during the Devonian. The magnitude and the timing of these dynamo-metamorphic events vary considerably through the region (Gauthier et al., 1994). These variations are now well constrained due to precise age dating.

May 1, 2003

By A. G. Pronk, D. M. Burton

"A regional till sampling program in the Upsalquitch Forks-Tetagouche Lakes area, centred some 70km west of the city of Bathurst, has proven an effective method for gold exploration in the heavily glaciated interior of northern New Brunswick. Prospecting activities within this area over the past three years, have led to the discovery of several gold occurences associated with quartz-carbonate alteration in a variety of intrusive rock types emplaced along major fault zonesQuaternary mapping shows that the glacial history is complex. However, the displacement of material is uniform in distance and direction, and the till is generally thin (0.5 m to 2.0 m) and locally derived, making the interpretation of till geochemical patterns relatively simple for the explorationist. Previous studies have shown the the fin e-grained gold is best detected in the -250 mesh (-0.063 mm) till fraction (clay plus silt) and that the C-horizon is the preferred medium for analyses.Samples were collected on a 2 km grid and analyzed f or Cu, Pb, Zn, Au, Ag, As, Sb, Mn, Fe, Ni, Co, and Cd. Results indicate that concentrations of 10 to 20 ppb Au can effectively delineate areas of anomalous gold in bedrock associated with fault structures, and that a good potential for discoveries exists to the west of the known occurrences, where up to 678 ppb A u has been detected in tills. IntroductionThis paper reports on the result s of surficial geological investigations conducted over the past two field seasons in north-central New Brunswick. The stud y area is located in the Upsalquitch Forks-Tetagouche Lakes map area s (N.T.S. 21 0 19 and 21 0 (10) 70 km west of the city of Bathurst (Fig. I). The area is situated on the margin of the New Brunswick Highlands and has a maximum elevation of 640 m (for a detailed description of the physiography, see Rampton et al. 1984).Historically, exploration in northern New Brunswick has concentrated on base metals within the Cambro-Ordovician Tetagouche Group, resulting in the discovery of man y significant massive sulphide deposits (Brunswick No.6 and No. 12, Heath Steele, Caribou, Armstrong Brook, Orvan Brook, McMaster, Murray Brook, and Restigouche). Auriferous base metal occurrences along the Rocky Brook-Millstream Fault have also been previously investigated."

Jan 1, 1988

By S. A. R. Keneti

Predicting the geomechanical response of the shale gas material during hydraulic fracturing operation in the field needs better understanding of their geomechanical behaviour under laboratory testing. Anisotropy is considered as a critical factor during investigation and analysis of deviated boreholes, borehole stability, stress-strain and strength behaviour, generation and propagation of fracture and fluid flow. In this study, compressive elastic modulus (Ec) of the Montney shale has been investigated in two perpendicular directions: unconfined compressive strengths test was conducted on the Montney sample to measure its Ec in the vertical direction. This value then was compared to the Ec value in the horizontal plane (i.e. foliation plane) which was previously measured throughout a Brazilian test by Keneti and Wong (2011). From the results, the representative values of Ec in the vertical and in the horizontal directions were found as 25 GPa and 40 GPa, respectively. Computer tomography technique was also employed for the experimental data interpretation.

Jun 1, 2012

By D. L. Griffith

THE realization by metallurgists of the important effect that traces of impurity may have upon the properties of a metal, and their steady demand for purer and still purer metals, have made the special cools for 'trace' analysis of increasing value. In the United States at least, spectrographic analysis is becoming the standard method for determining the impurities in zinc die-casting alloys. The Hudson Bay Mining and Smelting Company, as a producer of virtually pure zinc, uses the spectrograph to control the purity of its products, and-as the electrolytic method is employed here-to control both the impurities in the electrolyte and those 'trace' elements, which, while they do not contaminate the zinc, have a great effect on the plating efficiency. The general plan of the laboratory is shown in Figure l; the housing for air purification, which is on the roof, is indicated by broken lines. One of the chief factors affecting the layout was the easy way in which a spectrographic assay can be spoiled by contamination. To minimize the quantity of dust tracked in, the laboratory was made separate from the general research laboratories, and an office was placed between the two. This arrangement has its drawback because of the traffic through the office, but it has effectively cut down dust. For similar reasons, the available space was subdivided into a number of small rooms, and the air currents in the laboratory were so arranged that dust would be carried where it would do least harm. Air is drawn in at the roof over a 50-kilowatt bank of Calrod heaters, through Annis air filters, by a No. 4 Sirocco fan. Most of it is forced into the spectrograph room, but some goes to the office and darkroom. The air flow is from the spectrograph room, through the plate-measuring room, into the chemical laboratory, where it is exhausted by a No. 1% Sirocco fan on the fume hood. Air can also re-circulate from the plate-measuring room back to the heater. The arrangement is such that the air in the laboratory is maintained at higher pressure than the outside air; consequently, no dirt enters through cracks about the windows and doors. A thermo-regulator holds the temperature constant within one or two degrees; only on the hottest days in summer does the temperature rise enough to affect the focus of the instrument.

Jan 1, 1940

By Jeremy D. Glennon

A number of exciting challenges, opportunities and unanswered questions remain concerning the chemistry, geochemistry, medical, industrial and analytical applications of gold and its compounds.1 Among the challenges presented is the need for extraction methods for gold, at process and indeed analytical scales, that avoid the use of organic solvents or hazardous reagents. Extensive environmental contamination has occurred in the Brazilian Amazon from the mercury-gold amalgamation process. Major problems with the cyanidation process are the relatively slow dissolution kinetics and the health and environmental problems associated with it. With innovation and technical changes, a cleaner way for solubilising and extracting this versatile precious metal can be found. This cleaner future may lie in supercritical fluid science. Interestingly, geochemical studies of gold solubility and speciation in hydrothermal solutions have highlighted the importance of supercritical conditions and sulphur species in the deposition of gold in natural environments. Gold solubility in supercritical brines is far higher than previously supposed while interest in the high content of carbon dioxide in the mineralizing fluids is growing. 2,3 In recent years, also, there has been a tremendous amount of attention paid in analytical chemistry and in industry, to the area of supercritical fluid extraction (SFE) of organic and metallic species. 4 This interest has been fuelled by the introduction of more stringent environmental control and the subsequent need for cleaner solvents and processes to replace established ones. Carbon dioxide is the substance of choice for SFE because of its moderate critical parameters (Tc = 31oC, Pc = 73atm), inertness and availability in pure form. It is an excellent extraction medium for non-polar and moderately polar species, and with careful ligand design, it can be used for analytical and process scale metal extraction from solution and solid phases. In general, the dissolution of a metal in supercritical CO2 (sc-CO2) requires that the charge on the metal ion be neutralised on complexation by the ligand or through a form of ion pairing (analogous to the situation where metal ions are extracted into organic solvents, such as methyl isobutyl ketone or toluene). In this way, then, many chelating agents such as dithiocarbamates and hydroxamic acids have been utilised to extract metal ions such as Cu and Fe into sc- CO2, the process greatly enhanced by the use of fluorinated ligand derivatives. 5-7 In this review paper, we show that supercritical conditions and complexation with sulphur donor atoms, important in the natural deposition of gold, can form the basis of a clean, eco-friendly chemistry for gold extraction. Analytical scale extractions of gold from a variety of matrices can be conveniently used to assess the efficiency of any new proposed ligand.

Oct 1, 2003

By Royston Colbourne

Objectives Of Presentation - Identify specific risks - A fresh look at risk - Provide a moment reflection on risk - Open discussion on risk A route to solution and advanced thinking.

May 1, 2010

By P. Au, R. Kearsey, D. Y. Seo, Patnaik. P. C.

Three nickel based superalloys (7.5%Cr+5%Co+2%Mo+1%Ti+5%Al and Ni balance (wt%)) containing different amounts of W and Re were produced in the single crystal (SX) condition utilizing the Bridgman casting process. First, the effect of different levels of Re, and W on chemical microsegregation were investigated by EPMA quantitative analysis, and eutectic phase fraction analysis. Second, in order to investigate the effect of these refractory elements addition on oxidation behaviour, isothermal oxidation testing of the SX nickel based superalloys was conducted at 1000°C for 277 hours under 3 ppm moisture content of air in a thermogravimetric analyzer (TGA). All three SX nickel based superalloys revealed an excellent SX solidification structure with a common primary dendrite arm spacing of -250 µm and a large fraction of ?/?' eutectic located between the secondary dendrite arms. From the average EPMA compositional results, with the exception of Ni, elements such as Cr, Co, Re, Mo, and W all tended to segregate towards the dendrite core during solidification, while Al, Ti, and Ta were present in greater quantity in the last liquid phase to solidify, which resulted in large eutectic ?/? ' phases to form within the interdendritic regions. As the nominal level of Re increased, microsegreagation of Re, W, Cr and Mo increased, indicating that Re had a much greater influence on partitioning behavior compared to W. Figure la shows the specific mass gain as a function of exposure time for each alloy. An alloy with 2wt% of W and Re (Alloy B) exhibited less weight gain compared to two other alloys with either higher content of W or Re (Alloy A and C). Microstructural and compositional analyses of oxidized samples were conducted using SEM and EDS. Figure lb shows the typical surface morphologies of the oxidized Alloys A and B. It is evident that more oxide nodules (indicated by arrows in the figure) were presented in Alloy A. It is speculated that the amount of these nodules was responsible for more mass gain in Alloy A compared to the two other alloys. From the examination of the longitudinal section of the oxidized samples as shown in Figure 2, for Alloy A, nodules actually penetrated deep into the material. For Alloy B, however, a relatively uniform and continuous oxide layer was developed and deeply attacked areas were not observed. It was also found that preferential oxidized regions were located at the area between the ?/?' eutectic phase and the dendrite arms where the concentration of refractory elements was relatively high. Therefore, it is plausible that the oxidation kinetics of these alloys is related to the extent of microsegregation.

Jan 1, 2004

By S. Isaac

The networks of interdependencies between elements in building projects, referred to as the project topology, are often complex and difficult for project teams to comprehend. It is hypothesized that a graphbased model of the project topology can be based on existing data in Building Information Models (BIM), facilitating the application of graph-theoretic algorithms to analyze this topology. The objective of this study is to propose an outline for the synthesis of BIM and graph theory. This synthesis is expected to contribute to the development of new tools for representing, managing and analyzing the design of building projects.

Aug 1, 2013

By C. Denis Thibodeau

Outline Introduction 402 OB Mining Sequence Trial to Verify Sequence Change Monitoring Observations Numerical Modelling Conclusion

May 1, 2013

By Donald MacFadgen

Since 1950, a total of 164 miles of levels and rooms have been roof-bolted in the collieries of the Dominion Coal Company. Roof bolting is an efficient and economic method of sup-port where heavy timber sets or steel booms are necessary for temporary roof support, or where conventional methods of support interfere with the passage of mechanical mining equipment. This paper discusses present roof bolting practices and special bolting applications. THE practice of roof bolting in be collieries of the Dominion Coal Company dates from 1950, when preliminary studies and experiments were carried out in a mechanized room and pillar section of Dominion No. 20 Colliery. These studies were made in close liaison with members of the United States Bureau of Mines who were conducting similar studies. Following the successful application of roof bolting in No. 20 Colliery, this method of roof support was introduced into other collieries

Jan 1, 1963

By Ju-hyung Ha

New automated curing system for mass concrete has been developed to improve the quality of concrete structure and to save construction time and cost. The principle of this system is the automated water circulation system of heated curing water. Applied curing water on the surface of mass concrete keeps the temperature difference between center and surface of the structure below the threshold of specification. Mock-up test and field application have been conducted to investigate the performance of this system. In the results, new automated curing system reduced the chance of thermal crack occurrence and improved quality of the concrete structure as well.

Aug 1, 2013

By H. Helmstaedt, P. Thurston, R. Harrap

"Evolution of the continental lithosphere over Earth’s 4.6 billion year history is one of the fundamental questions of geoscience. Much of the Earth’s present-day continental crust formed during the first 2 billion years, the Archean eon, of the planet’s lifetime and thus, Archean processes of lithospheric formation must be studied in order to address this question. Until recently, the processes of Archean lithospheric evolution were thought to be fundamentally different from present-day plate tectonic processes. However, subsequent evidence suggests that the growth of Archean continents may be explained in terms of modern tectonic accretionary tectonics similar to those presently operating in the southwest Pacific region. The evidence supporting this hypothesis was compiled largely by Canadian geoscientists working in the Superior Province of the Canadian Shield in northwestern Ontario, over the past 15 years. Study of Archean rocks is also economically important because the Archean rocks of the world, although comprising only a relatively small fraction of the exposed continental crust, contain much of the world’s mineral wealth, including more than half of the world’s gold, as well as significant base metal reserves. Furthermore, the vast majority of primary economic diamond deposits are derived from the lithospheric roots beneath Archean cratons.The LITHOPROBE Western Superior Transect is located within the western part of the Superior Province in northwestern Ontario (Fig. 1). The Superior Province is the largest and best exposed Archean crustal block in the world and forms the nucleus of the North American continent. The internal structure of the Superior Province records a history of the processes that formed the earliest lithospheric elements of the Earth into cratons, thus providing an ideal laboratory for investigating early crustal evolution. The Western Superior Province is characterized by a regional pattern of alternating, 100 km to 200 km wide geological belts (Fig. 2). The observed geologic relationships between and within these subprovinces have been explained in terms of a modern tectonic model of terrane accretion. Oceanic floor, volcanic island arcs, oceanic sediments and continental fragments were accreted successively from north to south against the southern margin of a cratonic nucleus (North Caribou terrane, Fig. 2) which grew steadily in size with the arrival of new terranes through geologic time. If this model is correct, it suggests that the tectonic processes operating today have been active without major variation over the past 3 billion years."

Jan 1, 1998

By Rodney G. Orr, Phil Robertshaw, Roland Loewer, Klau Lehnert-Thiel

This paper documents the 1988 discovery and subsequent evaluation (to 1991) of diamond bearing kimberlites in the Fort à la Corne area, Saskatchewan, by Uranerz Exploration and Mining Limited. Cameco Corporation began participating as a joint venture partner (50%) in mid-1989. The first indications that kimberlite-type intrusions might exist in the area carne from Geological Survey of Canada aeromagnetic maps. Because of the overburden thickness (over 100 m), magnetometer surveys continue to be the main exploration tool in defining pipe locations and sizes. Magnetometer surveys in varying levels of detail have outlined one main cluster and two sub-clusters, the main group being some 10 km by 50 km in size. In excess of 70 individual targets have been interpreted from the magnetics as probably representing kimberlites. The size range of the individual magnetically-defined bodies is between 1 ha and 74 ha. Proof that the magnetic anomalies were kimberlite intrusions carne in 1989 when each of seven test holes, all drilled on different targets, intersected the potential diamond host rock. The majority of the targets tested were diamond-bearing, with the indicator mineral chemistries suggesting that both peridotitic and ecIogitic diamond parageneses could be expected. To date, 18 individual kimberlite bodies have been drill-tested. A total of 39 bulk samples, amounting to 186 t (representing 360 t of theoretical sample recoveries) were processed in 1990 and 1991. One hundred and sixty diamonds were recovered, averaging 0.04 carats in weight, the largest being 0.6 carats. Most of the bulk sample grades are less than 2 carats/loo t; only three bulk samples have higher grades, the best being approximately 10.5 carats/l00 1. The diamonds are predominantly gem-quality stones.

Jan 1, 1992

By J. C. Keenan

Company-community agreements are widely considered to be a practical mechanism for recognising the rights, needs and priorities of peoples impacted by mining, for managing impacts and ensuring that miningderived benefits are shared. The use and application of company?community agreements is increasing globally. Notwithstanding the utility of agreements, the gender dimensions of agreement processes in mining have rarely been studied. Prior research on women and mining, however, does show that women are often more adversely impacted by mining than men, and face greater challenges in accessing development opportunities that mining can bring, however there is currently little to no guidance for companies, government or communities in terms of bringing a gender perspective to the fore in mining and agreement processes. While it is undisputed in human development literature that investment in women and sensitivity to gender delivers long-term health, education and local development outcomes, a number of key factors remain unexplored in debates about mining and development. These include: women?s participation in agreement processes, the gendered distribution of agreement benefits, and the extent to which impacts and benefits influence (either positively or negatively) women?s development and economic inclusion. This paper presents the results of an applied research project undertaken by the Centre for Social Responsibility in Mining (CSRM) at The University of Queensland and funded by a partnership between the Minerals Council of Australia (MCA) and the Australian Agency for International Development (AusAID). The project sought to connect with practitioners who had been directly involved in agreement processes to hear grounded perspectives on the interaction of gender dynamics and agreements, and connect those experiences with the broader literature. Findings from this study have implications for the role of companies and governments in promoting gender equality and empowerment as part of their commitments to sustainable development. A key challenge for companies will be navigating the territory of cultural norms and gender equality. The authors argue that without consideration of the gender perspective, and appropriate responses, mining agreements may not be inclusive or representative and may exacerbate gender inequalities and fail to contribute to long-term sustainable development.

Aug 1, 2013

Operating and Social Considerations from a Contractor?s Perspective

May 1, 2013

By Hong Zhong, Shuai Wang, Gang Zhao, Lanqing Deng, Guangyi Liu

In this paper, three novel surfactants containing double reactive centers(-CONHOH and –CONH-), double hydrophobic groups were designed and synthesized as collector for separation of diaspore and aluminosilicate minerals, such as N-(4-(hydroxyamino)-4-oxobutyl)octanamide (HA-8), N-(4-(hydroxyamino)-4-oxobutyl)decanamide (HA-10) and N-(4-(hydroxyamino)- 4-oxobutyl) -dodecanamide (HA-12). The adsorption mechanism of N-(4-(hydroxyamino) -4-oxobutyl)alkylamides (HA) onto diaspore was also investigated by FTIR spectra, zeta potential measurement and DFT. The flotation results demonstrated that three collectors all exhibited superior collecting power to diaspore and selectivity against kaolinite and illite, and could effectively realize flotation recovery of diaspore from bauxite ores contained aluminosilicate minerals under neutral conditions. Moreover, HA-12 was a superior collector than other two collectors for bauxite separation. The results of XPS, FTIR spectra and zeta potential illustrated that at around pH 6.0, HA might chemisorb on diaspore surfaces through Al-O coordination bonds formed by binding its –C(=O)NHOH or –C(=O)NH– chelate groups with aluminum atoms on diaspore surfaces. HA’s unique properties, such as characteristic bond patterns onto diaspore surfaces, double hydrophobic groups, and intermolecular hydrogen bonds between neighboring HA molecules coated on diaspore surfaces, rendered it to be a superior flotation collector for diaspore.

Jan 1, 2016

By T. Kalliomäki, A. T. Aji, M. Lundström, J. Aromaa

The settling properties of anode slime in copper electrorefining have crucial effect on copper cathode quality. Anode slime settling is affected by electrolyte composition and temperature, electrolyte circulation, and the sizes and density of the slime particles and agglomerates. Typically, the industrial copper electrolytes contain 40–60 g/dm3 Cu2+, 130–220 g/dm3 H2SO4, 0.04–25 g/dm3 Ni2+, 0.005–30 g/dm3 As, and have operating temperature of 55–70°C. In optimal electrorefining process, the settling rate of anode slime is sufficiently high to avoid the risk of getting the slime entrapped in copper cathodes. In this research the settling properties of copper electrorefining bottom slimes, mainly consisting of Cu, Ni, Ag, Se, Pb, As, Bi, Sb and Ba compounds, were studied by settling rate tests. The tests were conducted in water and synthetic electrolytes with known viscosities and densities. In addition, the effect of agglomeration was taken into account – it was observed that breaking the agglomerates which existed in the as-received slimes decreased the particle sizes on average 56–73%, which decreased the settling rate. The results of this study provide detailed information of anode slime settling and thus clarify the conditions causing cathode contamination risks in copper electrorefining. INTRODUCTION Settling rates of Cu-ER anode slimes affect the purity of cathode copper and faster settling rate decreases the contamination risk (Davenport et al., 2002; Shi & Ye, 2013). The settling rates are affected by the properties of anode slime particles (Wills & Napier-Munn, 2011; Aaltonen, 2014; Kiviluoma, Aaltonen, Aromaa, Lundström & Forsén, 2016) as well as viscosity and density of the electrolyte (Davenport, King, Schlesinger, Biswas, & Robinson, 2002; Shi & Ye, 2013). Thus, it is crucial to find out how the viscosity and density affect the settling rates. Small spherical particles with diameter below approximately 50 µm obey Stokes’ law (Equation 1) (Wills & Napier-Munn, 2011). v = gd 2 (ρS – ρF) (18η) -1 (1) where v is terminal velocity (m/s), g acceleration due to gravity (m/s2), d diameter of particle (m), ρS density of particle (kg/m3), ρF density of fluid (kg/m3), and η dynamic viscosity (Pa∙s). The approximate effects of kinematic viscosity (ν = η / ρS), density (ρS) and particle sizes on settling rates defined for small anode slime particles based on Stokes’ law are presented in Figure 1. However, Stokes’ law does not take into account other than spherical shapes, and it is only applicable for small particles. Consequently, the real settling rates of the particles are lower than these (Wills & Napier-Munn, 2011). Moreover, some of the anode slime particles are larger than 50 µm (Aaltonen, 2014).

Jan 1, 2019