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By J. Cueto, M. Torres, J. Fernandez, J. Nuñez, C. Salgado, G. Zarate

Anglo American has used the extractant M 5640 in all the Divisions, which is an aldoxime modified with TXIB formulation, except in Los Bronces, where an aldoxime modified with tridecanol (TDA) formulation is used. It is a well-known fact that the aldoxime degrades while the modifier does not. With time the aldoxime/modifier ratio decreases significantly depending on the operating conditions of each plant. In order to evaluate the effect of this increasing modifier content in the organic of the plant, especially in the organic losses, a complete metallurgical test work program was started at laboratory and pilot plant scale. Results showed that the addition of aldoxime without modifier does not affect the chemical performance of the organic phase, but there is a significant decrease in the viscosity and density of the organic phase. Based on the results obtained in the metallurgical program, it was decided to run plant scale tests at both SX plants, Mantos Blancos and Mantoverde. In these tests, instead of adding the usual formulation of aldoxime modified with TXIB to maintain the organic inventory, CuPRO MEX™ 3406 which is an aldoxime without modifier is going to be added until the original aldoxime/modifier ratio is reached. The plant tests started in April 2013 at Mantos Blancos and in June 2013 at Mantoverde and will last 18 months. The results obtained at the laboratory and pilot plant scale, together with the preliminary plant test results, are discussed in this paper.

Jan 1, 2014

By R. P. Kofluk

The nickel-cobalt sulphides produced from limonitic laterite ores by Moa Nickel S.A. in Cuba are refined at the Corefco nickel-cobalt refinery in Canada. Significant economic implications are associated with the refining of precipitated sulphides containing elevated iron contents. The Moa Nickel S.A. operations encompass laterite mining, high pressure acid leaching (H PAL), and ultimately, precipitation of a mixed sulphide product. These processes are reviewed as they pertain to the control of iron and the formation of a mixed sulphide containing nominally 55% Ni, 5% Co and 1% Fe. The contributors to the iron content of the mixed sulphide product are reviewed; the major contributors are the HPAL operation and sulphide precipitation. The precipitation of iron during sulphide precipitation is influenced by the solution acidity, the iron and copper concentrations in the feed solution, and the presence of laterite leach solids. The significance of the copper concentration of the sulphide precipitation solutions is manifested by both physical and chemical modifications of the sulphide precipitates, presumably through the formation of fine copper sulfide seed particles.

Jan 1, 2006

By A. E. Lehmberg

"IT IS KNOWN that some ores of sulphide type, such as pyrite, chalcopyrite, and bornite have an electrical conductivity comparable to that of metals, and accordingly much higher than the conductivity of any unmineralized rock. This physical property has long been used for the detection of orebodies of this kind by means of electrical measurements made at the surface of the ground.The present paper will deal with a new electromagnetic instrument for the investigation of subsurface conductors, which has been recently introduced into field practice and has already led to successful results in Canada.The principle of the instrument will be described. How it operates, and how the observations made can be interpreted will be explained. Field examples will •be shown to illustrate its application.Description of Instrument and of Operating TechniqueThe equipment (1) includes a low-frequency alternating current generator. The a.c. is supplied to a transmitter coil and generates a primary field which induces eddy currents in the ground, the intensity of which is proportional to the ground conductivity."

Jan 1, 1952

By W. L. Ott, C. L. Lewis

"AbstractA technique is described for preparation of palladium sponge and for spectrochemical analysis of the metal in this form. The precision and accuracy of the method are discussed. Analyses are compared with previous spectrochemical analyses of palladium in the black form. Good agreement was found in the two sets •of results and it is concluded that they are more reliable than wet chemical .analyses of the same material.IntroductionFOR SEVERAL YEARS the problem of platinum metal analysis by spectrochemical methods has been under investigation at the Spedtrographic Laboratory, Department of Geological Sciences, Queen's University. The problem, briefly -stated, is as follows: Samples of platinum, palladium,-rhodium, ruthenium, and iridium are received as fine metal powders, called sponge. Direct spectrographic analysis of this material has not been found satisfactory due to its heterogeneity •as regards contaminant metals, which may be present up to a total of one per •cent or more. Further-more, spectrographic standards are difficult to obtain and difficult to prepare accurately by adding weighed portions of contaminant metals to the sponge. The fact that •contaminant metals in original samples are probably alloyed with the major constituent is a further difficulty since complete fusion of these refractory metals proved impractical in the present case as a means of standard preparation. It •has, therefore, been found most satisfactory to dissolve the metals, prepare standards by addition of solutions of contaminant metals, and to reduce both standards and samples to a homogeneous form. A previous paper, by Hawley, Wark, Lewis and Ott (2) dealt with a method for spectrochemical analysis of platinum and palladium in their black form. Since completion of research on the black technique, the possibility of analyzing palladium accurately in its sponge form has• been investigated."

Jan 1, 1953

By H. Westengen

The AE alloy family exhibits remarkable combinations of properties when utilized as high pressure die castings. This performance relies on the fact that the rapid cooling rate resulting from the direct contact between the molten alloy and the steel die walls effectively refines the structure through rapid solidification. Furthermore, the rare earth additions modify the solidification pattern, dramatically reducing the solidification interval. A solid shell forms at temperatures exceeding 500C, reducing the tendency for die sticking and inverse segregation. As a result, the die castability is excellent, giving parts with a smooth and shiny surface. Unlike other magnesium die casting alloys developed to improve elevated temperature creep properties, AE alloys do not suffer from the commonly observed tendency to introduce brittleness. This feature is attributed to the fact that the massive magnesium- aluminium intermetallic phase is substituted by a finely dispersed lamellar structure of Al-RE intermetallics. The resulting combination of excellent elevated temperature properties and good ductility, as well as excellent corrosion resistance, means superiority of these alloys for demanding automotive engine and chassis applications.

Jan 1, 2006

By J. Lu

The impact of acid treatment in agglomeration/acid curing on copper extraction and acid consumption was investigated with respect to acid dosage and moisture. Without the addition of water, no agglomeration occurred. At an acid dosage above 15 kg/t, the acid was not completely consumed during acid curing. With the addition of 6.2% water, the particles agglomerated together. Copper, iron, magnesium and manganese were dissolved as sulfates and enriched in the fine fraction of the ore. The copper extraction and net acid consumption increased with increasing acid dosage. The copper extraction for acid curing with the addition of 6.2% water was higher than that without the addition of water due to the improved permeability and the increase in the contact with acid-soluble copper. During acid curing, the reaction of sulfuric acid with muscovite, abite and nacrite mainly took place on the surface of the particles while the reaction of sulfuric acid with clinochlore occurred not only on the surface but also inside the particles.

Jan 1, 2007

By T. V. Lord

Minerals containing uranium have been successfully pre-concentrated by flotation at Queen's University, Kingston. In particular, uraninite, uranothorite, euxenite, and fergusonite, have responded to flotation to yield grades of 0.2 to 6.0 .per cent U .o. with recoveries of 85 to 98 per cent, from heads analysing approximately 0.10 per cent U3Os. Of the ten or so radioactive samples examined to date, two distinct groups were recognizable, firstly, those samples in which uranium was the sole constituent of economic interest, and, secondly, those in which Columbium (with minor amount of tantalum) was present in addition to uranium. For the purpose of this paper, the results of investigation on two samples of each of the above groups have been selected as typical.

Jan 1, 1945

By N. Ahern, D. B. Dreisinger, G. Van Weert

In the thiosulfate leaching of gold, degradation of the thiosulfate reagent is a major cost. One of the intermediary degradation products is trithionate, which also inhibits gold recovery from solution by ion exchange. Little attention has been given to this species in the context of gold leaching - the limited information on trithionate and its solution chemistry available in the literature is seldom directly related to gold leaching conditions. This review is a compilation of the published knowledge on trithionate, with a specific focus on identifying the relevance of this information to gold leaching and the shortcomings in the knowledge base.

Jan 1, 2005

By W. F. Baker

Location and History God's lake is in the northeastern part of Manitoba, about 400 miles northeast of Winnipeg, or about 250 miles due north of Red lake, Ontario. The lake is quite large, having an overall length of 54 miles and a maximum width of 18 miles. There are numerous islands in the lake, the largest of these, known as Elk island, being about 15 miles long and 3 miles wide in the widest part. The accompanying map (Figure 1) shows the location of God's lake and of the mine. The God's Lake area has long been regarded as promising country for the prospector, but, due to its inaccessibility, practically no prospecting was done prior to 1927. In the years 1927-1931, inclusive, a few prospectors visited the area, but no discoveries were made. In 1932, Bob Jowsey and Archie McDonald entered the area from Island lake. They first prospected in the vicinity of Knife lake, which is immediately south of the main part of God's lake, and then moved on to the latter lake, heading for the north shore of Elk island. The first afternoon on God's Lake, when looking for a place to camp on the north shore of what is now known as Jowsey island, Jowsey discovered a quartz porphyry dyke which was cut by a number of gold-bearing bluish quartz stringers. On the strength of this discovery, he and McDonald began at once to stake the Reno group of claims. Rumours of the discovery brought in other prospectors, and other groups of claims were staked to the east, along the north shore of Elk island. A second discovery was soon made by Dan McCrea on his Gold Standard claims, three and a half miles to the east of the original discovery. Staking still continued to the east, along the north shore of Elk island, and Bob Brown and Harvey McKenzie staked the Akers group on a discovery approximately two miles east of McCrea's discovery. Through the efforts of Jowsey, the Reno, Rand, Elk, and Cona groups, belonging to the original syndicate for which Jowsey and McDonald staked, were combined with the Gold Standard, Greenstone, and Akers groups, and the Company known as God's Lake Gold Mines, Limited, was formed. Several additional groups of claims were later taken over by the Company and a considerable area of adjoining ground was staked to round-out the property.

Jan 1, 1935

By L. Dorador

"In block caving projects, the rock mass fragmentation process plays a controlling role in the design and success of the operation. Poorly understood, however, is the secondary fragmentation that occurs as blocks of caved ore move through the draw column and interact with one another. The initial size of these blocks can be considerable, as can their strength and stiffness as the presence of non-persistent joints and veining will be variable. Intuitively, more planes of weakness within the blocks should facilitate early fragmentation, but this assumption could depend on additional factors such as contact type between adjacent blocks and loads imposed through varying heights of the draw column. This paper reports the findings from a laboratory investigation examining the role of block strength and planes of weakness on secondary fragmentation. Testing was carried out on small-scale concrete cubes of uniform size, with and without embedded planes of weakness. The results obtained demonstrate the significance of veining and other planes of weakness on secondary fragmentation under one-dimensional compression, and allow for the development and constraint of empirical guidelines.INTRODUCTIONThe fragmentation process during block caving involves the initial (primary) fragmentation of rock in the cave back through stress-induced fracturing, release and fall of individual blocks onto the broken ore muck pile. This is followed by secondary fragmentation involving splitting and rounding of blocks as they move downwards through the draw column towards the draw point. The degree of secondary fragmentation achieved involves many variables related to the mechanical properties of the rock blocks as well as different operational factors. With respect to the block properties, the presence of planes of weakness in the form of veining and non-persistent joints is a topic of special interest given the significant influence it potentially has on the overall fragmentation process. However, the inherent heterogeneity and variable size of individual blocks generated from the cave back makes it difficult to develop any empirical relationships relating secondary fragmentation to compressive loading based on insitu observations and mine data. More preferable would be to keep constant block parameters, such as shape (aspect ratio and angularity) and size, through controlled laboratory testing. This work presents an efficient technique to fabricate concrete cubes in order to keep constant different block properties. These are then tested under one-dimensional compressive loading. The objective of these tests is to emulate a tight packing condition of single blocks such as that which would occur when the air gap between the cave back and broken ore in the draw column is small. When the air gap is small, detached blocks are unable to fall and rotate but instead maintain a very tidy arrangement with minimal voids left between adjacent blocks."

Jan 1, 2015

By J. T. McGrath, R C. A Thruston

The structural changes which take place in polycrystalline copper under the action of alternating cycles of torsion stress were studied, using the optical microscope and the X-ray dif-fraction camera, and an attempt was made to correlate them with changes in the shape of the cyclic stress-strain curve. It was found that the period of work-hardening was less than one per cent of the fatigue life, and that persistent surface marking, which are assumed to be incipient or actual microcracks, occur upon completion of work-hardening. X-ray diffraction patterns revealed considerable grain distortion at the completion of work-hardening in specimens cycled at a high strain amplitude. This distortion became progressively less as the strain amplitude de-creased. Mechanisms for the completion of work-hardening and the formation of microcracks are discussed.

Jan 1, 1962

By E. Krause

The oxidation of Fe(II) with S(IV) and oxygen can be used advantageously in leaching systems requiring both Fe(III) and sulfuric acid; e.g., heap leaching of sulfide-containing ores or concentrates. The oxidation of Fe(II) with SO2/air is several orders of magnitude faster than with air alone; rates of up to ?20 g/L'h were observed at 25°C. The reaction proceeds via an intermediate orange-red mixed-valence Fe(II)/Fe(III) sulfite complex, which is present at an essentially constant concentration throughout most of the oxidation process. The oxidation rate of Fe(II) is approximated by the formula -d[Fe(II)]/dt = k [S(IV)] [02]0'3. The concentration of the mixed-valence complex, and thus the iron oxidation rate, decreases with increasing acidity. Certain impurities, such as SCN- and thiourea, negatively affect the rate. The oxidation reaction 2Fe2 + SO2 + 02 4 2Fe3+ + S042- is accompanied by the side reaction H20 + SO2 + 1/202 4 H2SO4. The side reaction becomes particularly important at low temperatures and whenever the oxygen mass transfer is insufficient with respect to the rate of addition of S(IV). Thus, effective oxygen mass transfer is essential for achieving high oxidation rates with minimal acid formation. The activation energy was estimated as 141 kJ/mol over the temperature range 10-35°C.

Jan 1, 2006

By H. Watari

In 1998, a voluntary agreement was reached between the European Commission and the European Car Manufacturers Association (ACEA) to reduce average carbon dioxide emissions of new cars to 25% below 1995 levels by 2008, Agreements have also been reached between the European Commission and the Japanese Automobile Manufacturers Association (JAMA) and the Korean Automobile Manufacturers Association (KAMA), However, the target average of carbon dioxide emissions of less than 140g/km in 2008 is a very challenging goal, Therefore, total product weight reduction is an objective for many manufacturers, This can be achieved utilizing materials possessing high strength and low weight, One material that has recently attracted interest is magnesium alloys, The magnesium alloys are expected to play an important role as next-generation materials, which have possibilities of contributing to lighten the total product weight when magnesium products can be used to replace aluminum and mild steel products.

Jan 1, 2005

By G. Avramovic-Cingara

Grain boundary characteristics and microstructural evolution are analyzed in a comparative study using orientation imaging microscopy (OIM/SEM) and transmission electron microscopy (TEM/SAD). The subgrain sizes and misorientations were determined by the OIM for aluminum deformed in torsion to equivalent strains between 0.2 and 4 over the temperature ranges of300-600°C and strain rates 0.01-1 s". The OIM gives clearer evidence of boundaries with high misorientation than does TEM, but it overestimates their frequency b y missing boundaries less than 1 0. T EM more clearly reveals low-angle arrays of widely spaced dislocations resulting in finer subgrain sizes than those indicated by OIM. The evidence supports a mechanism combining dynamic recovery (DRY), deformation band formation with permanent boundaries and geometric dynamic recrystallization (gDRX) in contrast to the hypothesis known as continuous dynamic recrystallization (cDRX).

Jan 1, 2004

By Kenneth Blower

This paper gives a detailed coverage of the ore flow through the primary crusher, cobbing plant and concentrator, including equipment sizes, recoveries, reagent consumptions and product descriptions. Special features, such as rubber chutes, rubber-lined mills, pebble-mill grinding, steam-hooded filters and process control instrumentation, are also discussed.

Jan 1, 1968

By Scott A. Trebilcock

Nautilus Minerals Inc the world?s leader in exploration and development of deep ocean mineral resources is today focused on the recovery of high grade copper-gold from in seafloor massive sulphide mineralization. These mineralized belts, analogous to land based volcanogenic massive sulphides (VMS) deposits are located near tectonic plate boundaries of the Western Pacific and around the world. Nautilus; first development project is Solwara 1 located in benign waters in Papua New Guinea. Since 2006 the company has completed detailed environmental and geological studies at Solwara 1, culminating in a number of world firsts, including the first Environmental Permit for a deep ocean mineral project and the first NI 43-101 compliant seafloor massive sulphide resource statement. Nautilus has relied heavily on proven deepwater technologies from the oil and gas industry in the design of the first mineral extraction system. Pipeline trenching units, workclass ROVs, deepwater production risers and drill cutting removal systems will all be adapted at Solwara 1. Key contractors to the project have all been selected for their deepwater experience, creativity and determination to launch this new industry. Innovation is at the forefront of Nautilus? success to date. This paper gives an overview of the Solwara 1 development and describes the exploration and production technologies adapted for seafloor mineral extraction.

May 1, 2010

By Thom Sedun

No sector of the mining industry is more closely tied to local communities than aggregates. Noise, dust, traffic, visuals aesthetics and environmental impacts all fall under the purview of neighbours, local governments and nongovernment organizations. It is no surprise that aggregate operations may not be welcome neighbors in many communities. In British Columbia (BC), the regulatory environment for aggregate operations includes a local component of municipal bylaws and land use-planning in addition to the usual suite of federal and provincial statutes that apply to its sister mining sectors. Additionally, under common law aggregate extraction is not considered to be a land use subject to land use zoning, and some aggregate processing activities can be regulated by zoning. Often traversing multiple local government jurisdictions, aggregate producers find themselves negotiating not only local traffic, but also a mosaic of regulatory environments. There is an opportunity in this present situation to facilitate the application of current technology and practices in the mitigation of many community and environmental concerns associated with aggregate operations. Moving a bulk commodity is a volume-based business, and operators often don?t have time for matters that don?t directly or obviously affect the bottom line. Regulatory agencies often play multiple and complex roles with respect to their industry, not the least of which is the fiduciary role. Balancing how and when to assist an industry is often a difficult decision. For the aggregate industry in BC, the Ministry of Energy and Mines saw an opportunity to assist not only aggregate operators, but also regulatory agencies, local governments, and the general public. Through investing in the Aggregate Operators Best Management Practices Handbook (handbook) project, the Ministry of Energy and Mines (MEM) believes that it will realize a return of upheld community values, enhanced environmental protection, improved regulatory compliance, reduce disputes and a stronger provincial aggregate industry. It is the intent to publish the handbook electronically through the MEM website later this year.

May 1, 2002

By F. Chiesa

The permanent mould process, which is a favoured process for producing premium quality aluminium casting, is rarely used to produce magnesium alloy parts. This may be attributed different factors such as: the reservation with which the automotive industry considers using magnesium in structural castings; also the relative hot shortness of most magnesium alloys when compared to aluminium A356/357 is another factor. A third reason stems from the fact that the "heat content" of magnesium is much less than that of aluminium, resulting in the difficulty, for a relatively slow process such as permanent mould (versus pressure die casting), to reach a mould dynamic equilibrium temperature sufficiently high to avoid premature freezing and misruns. The present work will address this problem by carrying out controlled cycling of a laboratory mould, poured with aluminium and magnesium alloys. The influence of insulation of the mould and artificial electric heating on the run-in mould temperature will be determined experimentally. A thermal model will be sought for these thermal devices that will allow to predict the thermal behaviour of moulds of different geometry before a single casting is poured. The model will be tested on an industrial casting in a workshop environment.

Jan 1, 2006

By Jan W. Merks

The objective of metrology in mineral exploration is to derive unbiased confidence limits for masses of metals contained in reserves and resources. Sets of test results for gold and silver determined in pairs of interleaved bulk samples give unbiased confidence limits for the central value of each metal. The same sets of test results show how to verify spatial dependence by applying Fisher?s F-test to the variance of a set and the first variance term of the ordered set. A significant degree of spatial dependence gives a higher degree of precision for the central values of gold and silver. Plotting variance terms of an ordered set against the variance of the set and its lower limits of asymmetric 99% and 95% confidence ranges gives a sampling variogram. Sampling variograms put in plain view where spatial dependence in sampling units or sample spaces dissipates into randomness. The application of statistical methods to test results for sets of ordered core samples within boreholes, and for sets of ordered ore volumes within profiles, plays an important role in defining reserves and resources.

Oct 1, 2009

By D. R. Reeves

This paper describes the geophysical Jogging of coal that is being carried out for the National Coal Board in the United Kingdom. An explanation of the technique is given and results are presented showing estimations of seam thickness to within ±0.5 in. and ash content to accuracies of ±2.5 per cent. The basic method of interpretation is outlined and some conclusions regarding the conditions of roof and floor material which may be deduced from the logs are explained. An indication of future developments in this field, including the identification of coal type and moisture content, is given.

Jan 1, 1971