Search Documents

By M. Askari, A. Ahmadi

"This study was conducted to establish the possible application of bioleaching in the pilot scale to recover valuable metals from the sulfidic tailings of Golgohar Iron Mine (Kerman, Iran). Using bioleaching processes, solvent extraction and sulfide precipitation recovery of valuable metals including, copper, cobalt and nickel from the tailing was investigated. The results showed that the optimum pH and temperature conditions relative to the bioleaching step was 1.5 and 45°C. The extraction of the metals from the low grade polymetal resource with complex mineralogy is very important from economic, environmental and technical point of views. Moreover, the proposed method has some advantages from energy saving, tailing management and creating added value from waste materials aspects.INTRODUCTION The growing demand for base metals and strategic such as: copper, nickel and cobalt as well as high-grade resource depletion has caused them, the mining industry to extract metals from low-grade resources and driven by complex mineralogy (Xie et al., 2005). Economic extraction of metals with low grade sources requires low-cost and efficient processing methods. A source with enormous potential for metals in future, secondary sources, such as: tailings mineral industries which the lack of appropriate technology and the high cost of processing weren't recoverable with previous procedures in the past. But it is possible that with develop new and efficient technologies have the economic exploitation ability. Recovery of metals from tailings resources is very important not only in terms of precious metals but also in terms of reducing environmental problems (due to heavy metals). The metals of copper, nickel and cobalt are mainly like sulfide compounds in the nature, usually for their recovery, first they make ore with flotation method to obtain the sulfide concentrate that containing valuable metals. then for the metal production, it will be melt and purification. Due to the environmental aspects, technical problems in the recovery of base metals from low grade ore and mixes, the presence of small reserves, in the past three decades they pay much attention to the use of hydrometallurgical processes for the recovery of base metals from these resources. These processes are classified according to the solver agent to leaching sulfates, chlorides, nitrates and amines (Hackl, 1995). Early, chloride leaching under oxidation condition in acidic or alkaline solutions was recognized the best process to produce sulfide concentrates. But then the basic processes sulfates was considered as the superior process because of being easier, a better understanding of the chemistry of leaching and recovery of base metals, especially copper from the environment easier sulfate solution with an organic solvent extraction and electro winning. The bioleaching is shown its ability on a commercial scale of low-grade sulfide minerals and ore that because of environmental reasons, the possibility of melting is not possible to them. The existing industrial base factories are based on primarily on the bioleaching and pressure leaching and recovery of cathode copper sulfate solution by extraction with organic solvents (SX) and electrowinning (EW) (Wang, 2005). Preliminary analysis has shown that valuable elements such as copper, nickel and cobalt are in the float flotation unit. Hence the plan to extract these metals from the wet tailing stream has been done."

Jan 1, 2017

By Q. J. Xu

In blasting sensitive areas, the use of traditional blasting for rock fracture is restricted. Soundless cracking technology has been presented to achieve rock fracture instead of blasting. However, when the diameter of a borehole is larger than 50 mm, it is very dangerous that the soundless cracking agent (SCA) will have a tendency to gush from the borehole, which also leads to cracking failure. In this paper, a new large scale borehole soundless cracking technology is presented, using a new enlarged drill bit and mechanical plugging, which could solve the hole gush problem. Experiments were made to measure the expansive pressure of the SCA working in boreholes of F40 mm and F100 mm. The difference between two sizes of cracking phenomenon was compared and analyzed to show that large scale borehole soundless cracking has larger expansion pressure and faster reaction speed than traditional soundless cracking. Based on the experimental data, finite element analysis was utilized to study the stress concentration and stress distribution between two neighboring large boreholes in several media during the cracking process. Using the data from experiments with finite element numerical simulation, the brittle material fracture condition was analyzed to design the parameters of the borehole mesh. With the theoretical analysis, the technological process and reference parameters of large scale borehole soundless cracking were proposed, including the borehole spacing, burden distance, depth of the borehole and so on. Then a single rock was cracked with the new enlarged drill bit and new plugging, and the results proved the feasibility of the new large scale borehole soundless cracking technology, which achieved the expected goal of improving the cracking ability and reducing the cracking time. This paper presents a new efficient rock cracking method for blasting sensitive areas, and which could apply to mining engineering, demolition engineering, excavation engineering and other engineering applications where there is a demand soundless and non-vibration fracturing of rock.

Aug 1, 2013

By A. D. Fisher

This paper describes the future position of metallurgical coal, particularly as applied to Canadian reserves. Quality coking coal is declining in availability, but preheating practices may alleviate this situation to some extent. Two new processes are discussed in the paper - formed coke and direct reduction - and their coal specifications are outlined.

Jan 1, 1972

By C. Bergstrand

"Precipitation of gypsum and the formation of scale may pose a serious challenge in the leaching of several minerals. As an example, precipitated gypsum may form scale in the machines increasing the need for maintenance. Alternatively, it may encapsulate precious elements, i.e. gold and lower the recovery during subsequent leach processes. In this work we explore how different biopolymers modify the rheology of gypsum at three different pH levels at ambient and elevated temperatures. The ability to disperse gypsum vary with temperature, pH and biopolymer. It is also inversely related to the scaling potential. Measurements of the zeta potential as a function of increasing amounts of biopolymer reveals that the magnitude of the zeta potential changes in the presence of biopolymer, and so does the ability to disperse the gypsum suspension. Similar results with hematite will also be discussed. The methodology and results may aid in the selection of additives used in mineral processing applications where scale pose a problem.INTRODUCTION Processing of refractory gold ores normally involve either atmospheric or oxidation under pressure in order to convert sulfides to oxides (Weir, King, & Robinson, 1986; Weir, Robinson, & King, 1986). This conversion facilitates leaching of gold (and silver) in normal CIL processes. During oxidation, sulfides are converted to sulfates. Normally, there is an abundance of calcium ions in the process water, either released from the ore or added as lime to adjust pH for the CIL process. Precipitation of calcium sulfate, or other compounds (calcium carbonate, jarosite, hematite) is a way to remove gangue minerals from the solution entering the CIL circuit (Ji, King, Fleming, & Ferron, 2010). Precipitation may also cause challenges in the process as gold (or other valuable elements) may become encapsulated in gangue. (Beauchamp, Choung, & Xu, 2006). In addition to precipitation, the precipitated gangue minerals may solidify and form scale in the processing equipment. Recently, Lauten and Kluck (2016) found that dispersants used as scale inhibitors to prevent encapsulation of gypsum did not modify the solubility of gypsum. In the utilised model system, similar amounts of gypsum precipitated with and without dispersants. Instead, it was found that the dispersants evaluated as scale inhibitors reduced the yield stress of gypsum suspensions. The reduced yield stress was associated with a reduced tendency for gypsum particles to agglomerate and form scale."

Jan 1, 2017

By R. A. Sullivan

I T IS one of the unwritten policies at Preston Mines that we examine closely any method or tool that will help us in our constant battle against rising costs. It is our personal conviction that most work methods can be improved. Therefore even though the job went well yesterday, it does not necessarily follow that it should be done by the same method today. With the arrival of the natural gas pipe line in the Porcupine area it was obvious that we would have to take a good look at the possibilities of using this source of fuel for plant heating. • Steam presently generated at Preston is for heating purposes only, no process steam being required. Prior to the fall of 1960, the heating plant consisted of two low pressure, coal-fired, fire-tube boilers, operating at an approximate pressure of 14 pounds per square inch. These boilers were underfed by stokers and could be operated either singly or together. ~o. 1 unit was a horizontal return tubular boiler, registered at 100 h.p. No. 2 unit was a fire-box boiler, registered at 75 h.p.

Jan 1, 1962

By Zygmunt Kowalczyk

"A theory permitting the determination of expected surface deformations for planned underground exploitation is proposed and discussed in this paper. The relations between surface subsidence and various methods of mining are analyzed, and allowable horizontal .deformations for protected objects, according to the degree of their significance, are reviewed."

Jan 1, 1966

By Jr. Arcand

Canadian Economy ? Getting Results ???? A stronger Canadian economy ???? National debt cut ???? Taxes reduced, tax-free savings account, support for manufacturing sector ???? Assisting with infrastructure Aboriginal issues affect all Canadians ???? Aboriginal prosperity is in everyone?s interest ???? Conditions for Aboriginal success include: - Indian residential school settlement - resolving outstanding specific claims

May 1, 2008

By F. M. Doyle, G. Sidhu, A. J. Dussault, A. Raygani

There is a growing demand for rare earth metals for use in high strength permanent magnets, most notably Nd2Fe14B. Rare earth metals are extremely reactive, with reduction potentials around -2.5V SHE, and are conventionally produced by molten salt electrolysis. The current work was done to investigate an earlier report of electrodeposition of a neodymium ferroalloy from aqueous solution, to determine whether this approach could be an environmentally and economically competitive commercial approach for producing feedstock for permanent magnets. Such a process would be analogous thermodynamically to the Castner- Kellner process, in which aqueous sodium chloride brine is electrolyzed in cells with mercury cathodes. Metallic sodium forms an alloy (amalgam) at the cathode, thereby lowering the activity of the metallic sodium significantly below unity and making the reduction potential of sodium significantly less negative than the standard reduction potential. Here we report the effects of Nd/Fe ratio in the electrolyte, current density, temperature and two different complexing agents, glycine and cysteine, on the composition and morphology of the electrodeposits, along with current efficiency. The energy needed to produce neodymium as Nd:Fe alloys by aqueous electrodeposition was compared with values estimated for production by molten salt electrolysis and the thermodynamic energy requirement.

Jan 1, 2014

In the last 30 years numerous mining plants have been developed in North America but only a handful of these have required freezing the area where the shaft was sunk. The most recent mine shaft to be sunk using this technique is located on an island off the coast of Louisiana. The project required the input and skills of numerous people in several companies, including the owner, engineers and contractors. The Cote Blanche installation is one of several mines in the area which extract salt from a dome which extends under the Gulf of Mexico. The geology of this area is, however, markedly different from others in the region because there is approximately 460 ft of water logged soil above the salt dome. Because it is not possible to sink a shaft in ground that is this soft, the overburden where the shaft is located must be frozen before excavation can take place. The Cote Blanche mine is a producing facility which was built in 1958 by the Carey Salt Company. The original facility included a 14 ft diameter production shaft and a 7 ft-8 in diameter service/ventilation/escape shaft. This system was installed by The Cementation Company. In 1996 the owner decided to improve both the mine ventilation and production hoisting system by installing a third shaft. This shaft would be designed to extract 650 tons per hour from a depth of 1600 ft and provide 500,000 cfm of ventilation to the mine at a maxium design pressure of 4 in WG. These parameters resulted in a requirement for a 16 ft finished inside diameter concrete lined shaft and a headframe designed as a pressure bulkhead. Because the mine would operate from one level only, the most efficient hoisting system for the application was determined to be a ground mounted koepe running on rope guides. With these criteria fixed Cote Blanche embarked on a program which would see construction start in June 1998 with the first salt produced in February 2001 at a cost of $US18M. The major players in the design and construction were G.L. Tiley & Associates Ltd., BLM Bharti Engineering, Freezewall Inc., Phillips Mining, Geotechnical and Grouting Inc., Don Hart Consulting and Dynatec International.

May 1, 2002

By M. E. Charles

The use of water flowing as a lower layer to reduce pressure gradients in petroleum pipelines was investigated using 17.5 deg. A.P.I. Lloydminster crude oil in a 1-inch laboratory pipe-line and a 21h-inch field pipeline. The method was found to be very effective in reducing the pressure gradient below that for the oil flowing alone. The factor by which the pres-sure gradient was reduced varied with the percentage of water added, and in general exceeded 10 for water contents ranging from 40 to 60 per cent. Within this range of water content the pressure gradient reduction factor was independent of the oil flow rate.

Jan 1, 1960

By R. J. Mitchell

"A lest apparatus has been developed for obtaining the relations among confining stress, porosity and percolation rate for hydraulic sand backfills. The apparatus can also be used to evaluate internal drainage characteristics and the effects of partial saturation on percolation rates. The test apparatus, test procedures and typical test data are presented in this paper.IntroductionAlthough the standard percolation test has become an accepted method of evaluating the drainage characteristics of hydraulically placed tailings backfill, it is recognized that the test results require considerable interpretation due to the following factors: (I) The results can be markedly influenced by varying sample preparation procedures, which vary the amount of material segregation in the sample . In particular, a thin layer of slimes on the top of a sample can control the flow of water into the sample. Wall edge effects can also affect the test results. (2) The in-place porosity of the backfill is not duplicated in the test sample and empirical formulae must be used to estimate the variation of percolation rate with porosity. (3) Internal drainage characteristics and the percolation rate of partly saturated fill cannot be evaluated in the standard percolation test.In addition to eliminating these problems, the compression percolation test apparatus also provides additional data on the mechanical properties of the backfill. Compressibility (or bulk modulus) is measured at different stress levels during the course of a test and this information can be used in evaluating the usefulness of the fill in providing ground control and in limiting ground subsidence. The engineering design of mine backfill is becoming an important part of the over all design of underground mine operations. The design problems are sufficently different from conventional civil engineering soil mechanics problems that new test methods and design procedures are required."

Jan 1, 1981

By R. Lapcevic, P. Lokin

"Among other components, ore body „T“ was discovered in the Bor pit copper mine at a depth of app. 500m. The ore body is relatively small: 60-65m long, 40-45m wide and up to 50m high, but with an extremely high content of copper and accompanying metals. The rock mass containing the ore body is composed of altered andesite of relatively poor physical-mechanical characteristics. The exploitation of this ore body by way of conventional mining methods was associated with high risk, cost, and potential losses of the rich ore. Due to everything specified hereinbefore, the adopted solution involved ore exploitation with complete ensuring of excavation stability, thus forming an extremely large underground opening. The excavation and supporting were performed according to the NATM principles along with applying shotcrete, 9-25 m long cables, and horizontal and vertical lattice girders. The excavation of the ore body was completed in app. 2.5 years, all the while ensuring complete stability and security of people and equipment; construction works were constantly monitored. The proposed solution for ore excavation enabled more than 95% exploitation of ore as requested by the Investor, while depletion due to waste-rock excavation was less than the allowed 5%. INTRODUCTIONThe Bor copper deposit is located in Eastern Serbia. Copper exploitation in Bor commenced as far back as 1902. A total of 26 ore bodies varying in size and valuable mineral content have been excavated so far. One of the most recent excavated ore bodies is ore body „T“, which is one of the smallest bodies by volume, but also a body with one of the largest content of copper and accompanying metals. An important fact regarding its exploitation is that it is located at a depth of app. 500 m; that its shape is irregular: 60-65 m long; 40-45 m wide and app. 50 m high; and that it lays within a rock mass of relatively poor physical-mechanical characteristics. In addition, above it, in its immediate vicinity, ore body „F“ was previously excavated and its room was refilled with backfill and water. Excavation methods common in mining practice (excavation with caving, excavation with backfilling, excavation with protective pillars) were inadequate in this case for various reasons:• The immediate vicinity of the previous ore body „F“ room could cause expansion of the caving zone also to that room, along with penetration of groundwater and flotation sludge;• Possibility of deformation expansion caused by caving as far up as the surface of the terrain, including the urban area;• Difficulties in maintaining the stability of excavation sidewalls having steep slopes and great height;• Significant loss of ore mass with a relatively high content of metals etc."

Jan 1, 2015

By Edgar Stanfield

Since April, 1923, the Scientific & Industrial Research Council of Alberta has had an analyst, Mr. W. P. Campbell, steadily employed analyzing coal samples taken by the provincial Mine Inspectors. Mr. Campbell has also analyzed a number of coal samples taken by one of the Council's Geological Survey parties. We have thus, at the time of writing, over four hundred analyses of Alberta coal, made by the same analyst, and strictly comparable. These samples come from widely distributed points, some 88 townships being represented. The stream of samples is still flowing in, and it is hoped by the end of this year that the number of townships represented will be increased at least fifty percent. The time has arrived to publish some of the data collected; but it must be clearly understood that this is merely a progress report, subject to revision as further information is obtained. Three hundred and fifty-three coal mines in the province were operated during 1923. The production per mine varied from 5 up to 500,000 tons. With this number of mines to examine (and fresh mines are being opened every year) it is a large task to make even a proximate analysis of representative samples from every mine. Any chemist will appreciate the fact that to make ultimate analyses representative of even the larger mines will be a long and tedious task. It has seemed better to make a comprehensive survey by proximate analysis and determination of calorific value before beginning the more thorough survey by ultimate analysis. This paper, therefore, deals only with proximate analyses and calorific values; and, owing to limitations of time and space, does not deal with other chemical and physical characteristics of coal, such as storage quality and fusibility of ash, important though these are.

Jan 1, 1925

By Qingxia Liu, Mingbo Zhang, Hongbo Zeng

The shortage of freshwater has been a major challenge for mineral flotation in arid areas. When using high salinity water, certain electrolytes are detrimental to flotation while others can improve the flotability of minerals. In this paper, the flotation behaviors and contact angles of pyrite in both Milli-Q water and high salinity water were investigated using different collectors at various pH levels. Results show that the thionocarbamate has a less affinity to pyrite in different solutions under mildly alkaline conditions as compared with potassium amyl xanthate (PAX) and N-isopropoxypropyl-N’-ethoxycarbonyl thiourea (iPOPECTU). At high pH levels, the slime coating on pyrite surfaces, which is caused by colloidal precipitates of magnesium and calcium ions in seawater, was confirmed by SEM, EDX and in-situ zeta potential measurement. The slime coating of colloidal precipitates on mineral surfaces led to low recovery of pyrite at high pH levels. The study of flotation behavior of pyrite in high salinity water improves our fundamental understanding of mineral flotation in seawater.

Jan 1, 2015

By Hyung Sup Choi

The preparation of high-purity zirconyl compounds was studied in order to develop an economical process for obtaining pure zirconium via the caustic fritting of zircon sand. The direct dissolution of caustic frits with concentrated hydrochloric or nitric acid at 80c. followed by the addition of a small amount of acidified gelatin, gave high-purity zirconyl chloride or nitrate. The addition of a small amount of gelatin caused a mutual flocculation between colloidal silica and gelatin. The precipitation of this silica floc markedly lowered the content of silica in the product. The silica content of the compounds (or solution) so produced, generally less than 100 ppm., was sufficiently low for tributyl phosphate extraction for nitrate solutions. It was found that the degree of purification de-pends not only on the procedures employed but also on the nature of the frit itself. Silica was more effectively eliminated from the fritted product produced at higher temperatures, and less silica was present in the com-pound prepared from the frit produced in a shorter heating time. In order to ascertain the nature of the

Jan 1, 1965

By Robert Lee

"International competition is presenting the Canadian steel industry with a major challenge. While Canadian companies have invested in new technology, research and development, activity by Canadian industry, in general, lags significantly behind that of its major competitors. While OECD countries increased their research and development spending during the 1980s, Canada's R&D funding levels have changed little since the early 1970s and have actually dropped since 1986, despite greater public discussion on the issue. This fact is reflected in the relatively slower pace of innovation in the Canadian steel industry, despite the efforts of both government and industry.In addition, there are a number of factors that undermine the competitiveness of the Canadian steel industry, in particular in relation to the United States. Among these are higher interest rates, labour costs and tax rates, as well as an overvalued Canadian dollar. Canadian steel companies are thus feeling the full impact of the current economic recession. This recession, combined with recent strikes, have, for example, caused serious losses for Algoma and Stelco.In spite of these objective difficulties, the Canadian steel industry has been able to survive and continues to strive for a leadership position in the world market. Since World War II, heavy investment in new technology has allowed the industry to upgrade its facilities and increase productivity, while at the same time improving quality and reducing pollution. This last point is particularly important in view of public insistence on improvements to the quality of the environment. Over the next decade, this technological innovation must be maintained and intensified if industry is to meet the challenge of international competition and attain a leadership position."

Jan 1, 1991

By J. P. Bennett, K. S. Kwong

Slagging gasifiers are used to produce chemicals and/or electricity from feedstocks such as coal and/or petroleum coke. A gasifier environment includes pressures from 400 to 1000 psi, temperatures from 1250-1550°C, are cyclic, reducing gases of CO and 112, and molten ash that interacts with the refractory liner materials. The high Cr2O3 refractory liners of gasifiers fail within 3 to 24 months. Gasifier users seek materials with increased reliability and service life. This paper discusses causes of refractory failure and efforts to increase refractory service life.

Jan 1, 2004

By K. B. Culver

"This paper provides background information on the expansion programs of Rio Algom Limited at Elliot Lake. Included are details on the Quirke expansion program, the Panel mine rehabilitation program, including the selection procedure for the tailings containment area, the Stanleigh mine rehabilitation program, housing, government regulations and the Environmental Assessment Board hearings. Introduction After 2Y2 years of public hearings, 4 years of arbritrating differences of opinion between our engineers and government licencing authorities, interspersed with research into radium removal and development of the LAMIX process and carrying out the work associated with some 24 control orders issued to us by the MOE, it is very difficult to compress all of the experiences and frustrations into a single paper. The highlights, as they relate to the expansion programs of Rio Algorn Limited and its affiliate, Preston Mines Limited, will be covered. Denison Mines Limited, of course, is the other uranium producer in Elliot Lake. They are currently in the process of expanding from 7,000 to 11,000 TPD by the second half of 1980 and then to 15,000 TPD by the mid 1980's. In giving this overview, the following seven items will be discussed: • The basis for Rio Algom's and Preston's expansion plans. • The Quirke Expansion. • The Panel Rehabilitation. • The Stanleigh Rehabilitation. • Housing Programs. • Government Licencing Requirements. • Environmental Assessment Board Hearings."

Jan 1, 1980

By A. K. Chetin, W. W. Fitkin

"The reservoirs of Mississippian Mi-dale beds and Frobisher beds found in the Weyburn field lie at the north-western termination of a broad productive belt extending 120 miles along the northeastern rim of the Williston basin. These carbonates, and inter-bedded evaporites, originated during cycles of marine transgression and regression, and were deposited as rock types characteristic of shoal, lagoon, and basinward shelf environments. The Frobisher-Alida Beds, which form a secondary reservoir to the main Midale Beds of producing zone are composed of oolit1c, fragmental-bioclastic, vugular limestone capped by an impervious dolomitic mudstone. Production is controlled by localized structural features resulting from de-positional build-up. Excellent reservoir conditions are accompanied by an active water drive. The Frobisher Evaporite, consisting of massive primary anhydrite with dolomitic veinlets, forms the floor seal for the Midale beds oil accumulation. A significant facies transition into an oolitic, bioclastic, vugular limestone characterizes this unit. Beyond the depositional margin of the evaporitic facies, marked increases in porosity and permeability of the en-tire reservoir are noted. Carbonate units overlying the areal extent of the Frobisher Evaporite exhibit a greater degree of metasomatism, dolomitization, and more abundant secondary anhydrite.Porous carbonates comprising the producing zone of the Midale beds are divided into an oolitic, fragmental bioclastic, vugular limestone, and an overlying granular marly lime-stone unit, capped, by the Midale Evaporite. Oil is accumulated in a stratigraphic trap bounded above and be-low by primary anhydrite and truncated by the post-Mississippian erosional surface. Mississippian strata dip basinward from this erosional surface in a broad homocline exhibiting only minor irregularities. Rapid lateral and vertical porosity and permeability variations are common. Localized, separated, porous lenticles contain interstitial water in areas where the Midale beds are underlain by the Frobisher Evaporite. The major portion of the field, however, is capable of water-free production. Bottom and edge waters are found in certain portions of the field. Productive limits are tentatively defined around most of the present field perimeter. A large area along foe southern edge of the field remains open to future development. Probable ultimate remaining recoverable crude oil reserves, as of September 30th, 1958, were estimated by Mc-Daniel Consultants Ltd. to be in excess of 330 million barrels."

Jan 1, 1959

By James R. Hein

Manganese nodules form at the sediment surface of abyssal plains throughout the global ocean at water depths of about 4000-6500 m. The nodules form a continuum from purely hydrogenetic (all metals from seawater) to purely diagenetic (all metals from sediment pore waters), which will determine which metals of potential economic interest are enriched in the nodules. Another important factor in metal enrichment is whether diagenesis in the bottom sediment is oxic or suboxic. There are several nodule fields in the deep ocean that have received much attention with regards to economic potential, the most important being the Clarion-Clipperton zone (CCZ) in the NE Pacific, where the International Seabed Authority (ISA) has signed 12 contracts for exploration areas, each spanning 75,000 square kilometers. Those nodules are rich in nickel (mean 1.3 wt. %), copper (mean 1.1 %), and manganese (28%), with moderate amounts of cobalt (mean 0.2%), molybdenum (587 g/t), and lithium (129 g/t). A conservative estimate is that there exists 21,100 million dry tonnes of nodules in the CCZ, yielding more manganese, twice the nickel, three times the cobalt, and four times the yttrium than the entire land-based reserve base (economic plus marginally economic plus subeconomic reserves) for each metal. Total rare-earth elements (REEs) as oxides average 0.09% in CCZ nodules, a potential byproduct even at that grade because the heavy REE complement averages 26%, compared to less than 1% for the large land-based carbonatite REE deposits. The price for HREEs is much greater than for the light REEs. For comparison, the REEs in deep-ocean ferromanganese crusts are 3 to 5 times greater than nodules and the HREE complement averages 18%. Of the 12 CCZ contracts, 7 are with States (China, France, Germany, Japan, Korea, Russia, and a group of States (IOM); and 5 are with companies: G-Tec Sea Mineral Resources NV, Nauru Ocean Resources Inc. (NORI); Tonga Offshore Mining Ltd (TOML), UK Seabed Resources Ltd (Lockheed UK), and Marawa Research and Exploration Ltd. Three other nodule fields that have received attention are in the Peru Basin, which has nodules very rich in manganese (34%) and lithium (mean 311 g/t), the Penrhyn Basin (Cook Islands Exclusive Economic Zone), with nodules very rich in cobalt (mean 0.4%); and the Central Indian Ocean Basin (CIOB), where India has an exploration contract with the ISA. CIPB nodules have mean nickel, copper, and manganese contents of 1.1%, 1.0%, and 24% respectively.

May 1, 2013