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By F. Qi, T. Frišcic, C. Mottillo

"One of the principal goals of modern industry is to minimize the environmental impact and increase the materials- and energy-efficiency of transforming raw materials into valuable products. This paper will highlight our latest laboratory-scale research in low-energy, low-solvent reactivity of metal oxides and their conversion into popular metal-organic frameworks (MOFs), zeolitic imidazolate frameworks (e.g. Basolite® Z1200 component ZIF-8), and metallodrugs (e.g. bismuth subsalicylate, active component of Pepto-Bismol®). Mechanochemical ion- and liquid-assisted grinding (ILAG) and ""accelerated aging"" techniques will be presented, along with novel low-energy and solvent-free approaches, inspired by geological weathering processes, for converting metal oxides into metal-organic materials. INTRODUCTIONThe development of environmentally-friendly processes, which would in the same time be more materials- and energy-efficient than the existing ones, is one of the central concerns of modern chemical research. In that sense, the focus of the chemist has been mainly on the preparation of carbon-based organic molecules and adaptation of traditional organic synthesis to the recently delineated ideals of Green Chemistry. However, there is a growing realization within the chemistry community that significant energy, materials, and ecology-related benefits can be achieved and, indeed, targeted in the transformations of materials that are typically associated with inorganic chemistry and minerals processing. The principal aim of this highlight contribution is to illustrate how, through the use of approaches associated with solventfree chemistry and mechanochemistry (James et al., 2012), one can develop a clean and efficient system of chemical and materials transformations involving oxide precursors that normally belong to the realm of inorganic chemistry and mineral processing. In particular, this contribution will provide an overview of the recently developed mechanochemical and solvent-free reactivity of metal oxides towards small organic molecules. These mechanochemical reactions, including the methods of liquid-assisted grinding (LAG, Frišcic & Jones, 2009) and ion- and liquid-assisted grinding (ILAG, Frišcic, 2010), have so far provided a radically different means to construct advanced metal-organic materials (e.g. porous metal-organic frameworks, [MOFs] or metallodrugs) by rehabilitating metal oxides as precursors, eliminating the use of bulk organic solvents, and avoiding the use of high temperatures."

Jan 1, 2012

By Manjeet Chowdhry, Qingxia Liu, Phillip Choi, Zhenghe Xu

Computational chemistry methods, such as density functional theory (DFT), are powerful tools to quantify reagent-mineral interactions encountered in sulphide mineral flotation. A quantitative relationship between theoretically calculated parameters based on chemical structure of collectors and their reactivity with different metals/minerals can provide valuable insights for design and development of more powerful and tailor-made reagents offering enhanced metal/mineral selectivity. DFT calculations at B3LYP/6-311++G(3df,3pd) level were employed to elucidate the reactivity of neutral sulphide collector reagents, including thionocarbamates (TC), thioureas (TU), xanthogen-formates (XF), dialkyldithiocarbamates (DTC) and dialkyltrithiocarbonates (TTC) with different heavy metal ions (Cu2+, Zn2+ and Pb2+) in solution. The extent of delocalization of lone pair electrons of heteroatoms (attached directly to C in C=S) over C=S group was found to be the dominant factor in determining the collector’s reactivity. Order of reactivity was established as: TU > TC > XF > DTC > TTC. All the collectors showed superior affinity towards copper followed by lead. Unidentate binding was observed through sulphur atom except for xanthogen-formate for which bidentate binding mode was observed. Effect of nature of substituent groups at N and/or O atom on reactivity of thionocarbamate and thiourea was also investigated. The results obtained through DFT calculations are consistent with the experimental data reported in literature.

Jan 1, 2015

By D. M. Bastidas

The reduction of copper sulfide and copper oxides originated during artificial tarnishing of copper was studied using potentiodynamic potential/current density experiments. Six copper surface treatments were considered: mechanical polishing; indoor exposure for 7 days; chemical etching in 1.6 M nitric acid; chemical etching and heating at 160°C; and chemical etching and dipping in a 9x10-4 M or 0.9 M potassium sulfide (1(25) solution at 70°C. Cuprite (Cu20) and chalcocite (Cu2S) were the main compounds formed. A linear relationship with the square root of the scan rate (v) was obtained by plotting the potentiodynamic potential/current density for the tarnish dissolution processes. A relationship between potential and current density cathodic peaks was not obtained, according to Müller's model, showing a proportionality factor with the dimensions of a resistance.

Jan 1, 2007

By T. P. Weldum, W. Conger

"These studies address the relationship between mill media sizing and its grinding efficiency. Starting with the results from a review of the literature, the issues of initial media sizing for a new ball milling circuit, and then optimal media sizing for an existing milling operation, were studied. The Functional Performance parameters “Mill Grinding Efficiency” and cumulative “Mill Grinding Rates” from both plant and test-scale equipment were used, and provide valuable new insight into this topic. A plant media sizing diagnostic tool is presented, as are newly developed testing equipment and evaluation methods, and recent case studies.REVIEW OF MEDIA SIZING LITERATURE For a plant metallurgist to answer the question “How can I maximize plant profit by manipulating this grinding circuit variable?” she must know what effect the variable has on grinding circuit efficiency. Despite the significant cost of grinding media and its potential effect on production capacity, the ‘best’ media sizing remains ill-defined for any given ball mill circuit in the industry today. The underlying reasons for this will be discussed. But the importance of this issue drove Metcom and its industrial partners to take on the challenge of how to engineer the ball charge for an existing grinding circuit. In the absence of any proven method, the first step was a review of the literature. Sponsored by Cleveland-Cliffs, Inc., a broad review of the literature was undertaken, producing “The Effect of Media Sizing on Ball Milling Efficiency” (McIvor, 1997). Among hundreds of publications that were reviewed that discuss the topics of media sizing or wear, forty-five were studied in detail. These were grouped into: plant experiences; laboratory and pilot plant investigations; media wear studies; population balance modeling studies; and general papers on ball milling which included the topic of media sizing. The reader is encouraged to refer to that review. The findings remain unchanged, although some relevant papers have been written since (e.g. Staples et al, 1997; Banasi et al, 1999; Orford et al, 2006; LaMarsh, 2015). The main findings of the review were as follows:"

Jan 1, 2018

As a bubble travels through the pulp region of a flotation cell, it will collect the most hydrophobic particles of an intermediate particle size range, this being the primary source of true flotation selectivity. Despite its role on bubble-particle attachment, however, particle hydrophobicity is still missing a mathematical definition that can be used for plant simulation. In this paper, particle hydrophobicity is defined in terms of the induction time necessary for attachment and then linked to the mass of collector adsorbed per particle. This allows particle hydrophobicity to be written as a function of density of collector adsorption as well as particle size and mineralogy. The model is calibrated from the experimental measurement of the flotation rate constant. Liberation data from an industrial flotation rougher is used for model validation. It is demonstrated that the model can describe a broad experimental dataset by means of a minimal number of parameters. Main industrial application is in simulating the effect of the chemical environment upon plant metallurgical performance.

Jan 1, 2006

By G. P. Gu

The in-service 90/10 cupro-nickel tubes in a water-chiller system suffered from severe corrosion damage during their relatively short service life causing unexpected down time. In addition to downtime, the environmental risk associated with losing refrigerant was also a concern that initiated this investigation, Microstructural investigation using SEM and electron microprobe indicated that pitting corrosion had resulted in local nickel depletion, During the corrosion process, copper appeared to have re-deposited around the corrosion pits accelerating the local corrosion.

Jan 1, 2005

By Ben R. Bjorkman

The future is here ? or at least that?s what Mine Planners predicted some 15 years ago ? that by 2004 we would have man-less mines running themselves using space-aged technology. Truthfully, though, there hasn?t been much change in mining methods in the past decade, but thankfully that?s all about to change. The benefits of autonomous ? even Tele-operated mining (especially in narrow-vein ore bodies) are wellknown: increased production hours by eliminating travel time to and from the face, continuous production at the face while crews screen and bolt behind the working equipment, less liability for workers? safety in certain areas, etc. But when plans are put in place to accomplish this vision, things stagnate and production carries on as before. This paper examines the components necessary to make that vision a reality. First we?ll detail the technology required to enable Tele-operation ? even autonomous operation of mining machinery, then we?ll look at what?s wrong with the current way we?re mining, and finally conclude with a critique of the machinery itself.

Oct 1, 2004

By M. Fujikawa

The Kamioka Zinc Smelter was converted from the jarosite process to the goethite process in the year 2000. The reasons for the conversion of the process were that the silica content of the raw material increased and the iron content decreased. The silica easily turns to a gel in sulfuric acid solutions and this causes the solid-liquid separation characteristics to deteriorate. The basic behavior of silica in sulfuric acid solution was investigated and it was found that the goethite process is the most suitable to effectively separate and remove silica from solution. Furthermore, Fe has the capability to remove elements such as Ge that have an adverse effect on zinc electrolysis. This means that, when the Fe content of the raw material decreased, the impurity removal capability also decreased and there was a risk of a build-up of impurities in the process. Iron precipitates in many forms in sulfuric acid solutions. The capability to remove elements such as Ge differs depending on the compound precipitated. Goethite has a higher capability than jarosite to remove elements such as Ge. In this report, the results of applying the process established by investigations of the basic behavior of Fe, silica and Ge in the zinc refining plant are presented.

Jan 1, 2006

By Jose Alberto Gonzalez, Said Sharif Mahboob, Jeffrey L. Shepherd

"During the industrial electrowinning of zinc, uneven growth can cause short-circuits and make the deposits more sensitive to the presence of impurities that can significantly impact current efficiency. To produce levelled zinc deposits, additives such as glue, licorice and sodium silicate are often added to the electrolyte. Even in the presence of additives, uneven zinc growth still takes place because of the combination of hydrodynamic and electrolysis conditions in the cell house. Recent advancements in imaging spectroscopy and scaling analysis have opened an avenue to further study the effects of additives on zinc growth morphology. In this study, Atomic Force Microscopy (AFM) and scaling analysis have been used to monitor zinc growth characteristics including roughness, periodicity, aspect ratios and growth mechanisms as a function of electrolyte composition as well as deposition time. Zinc was electrodeposited from an industrial electrolyte containing a host of additives onto an aluminum cathode with a platinum wire serving as the anode. AFM images of the samples were collected to obtain 3D topographical information on which scaling analysis was performed to extract details on root-mean-squared (rms) roughness, periodicity (grain size), aspect ratio of surface features and growth mechanism. This analysis provided information on the mechanism by which the previously mentioned variables can impact short term growth and also provided a prediction of expected growth at long deposition times.INTRODUCTIONElectrowinning is one of the final stages in the industrial production of zinc metal. It is during this process where dissolved zinc ions undergo electro-reduction from an acidic electrolyte onto an aluminum cathode and are later recovered by stripping the zinc metal from the substrate. However, due to the nature of zinc growth as well as the various operating conditions, zinc deposition may occur unevenly, sometimes causing short-circuits that can cause electrode damage and reduced zinc production."

Jan 1, 2016

By P. V. Barr, Y. -H. Li, A. P. Watkinson

Subsequent to a campaign of pilot-kiln trials of firing bio-oil and natural gas, scale-up to commercial lime kilns was made using an in-house mathematical kiln model. Both dry limestone and lime mud kilns of 3.5 m OD. by 100 m length were used for bio¬oil firing simulations. Comparisons were made against natural gas firing on the basis of specific firing rate, off-gas volume, energy consumption and overall lime quality. Model simulation results indicate that conversion from natural gas to bio-oil with no productivity loss will increase energy comsumption by about 7.5% and total off-gas volume by about 8%. Alternatively, a 6% decrease in productivity would be expected if off-gas volume is maintained constant. The calculations are sensitive to deviations in the lower heating value (LHV) used in the simulations. A 5% increase in the LHV of the bio-oil, which could result from a 3% decrease in the moisture content, reduces the energy penalty to 2% coupled with a slight reduction in off-gas volume.

Jan 1, 2004

By Jim Hazzard

A numerical investigation is presented to examine fluid flow in fractured rock slopes. In mining geomechanics, different numerical modelling approaches are used to estimate fluid pressures in open pit mines. The most common technique is the Equivalent Porous Medium (EPM) approach in which the fractured rock is assumed to behave as a porous continuum. Depending on the geometry and properties of the problem, this may not always be the best approach. The paper presents a parametric study to examine the effect of fracture spacing, fracture and matrix diffusivity and excavation rate on the fluid behaviour in rock slopes. Based on the model results, guidelines are provided as to when EPM models can be used and when different modelling approaches (e.g., discrete fracture flow) may be necessary.

Jun 1, 2012

By David Deglon, Martin Harris, Mehdi Safari

"This study investigates the effect of energy/power input on the flotation of a platinum ore in a pilot-scale oscillating grid flotation cell. Oscillating grids generate near ideal hydrodynamic environments, characterised by turbulence which is relatively homogeneous and isotropic. Secondary rougher feed and primary cleaner tail streams were floated in a pilot-scale oscillating grid flotation cell at power inputs from 0 to 2.5 W/kg, using 0.50 and 1.50 mm bubbles. From this study one may conclude that the effect of energy/power input on the flotation rate is strongly dependent on the particle and bubble size. Flotation rates generally increase with increasing particle size and decreasing bubble size. Increasing energy input generally leads to an increase in the flotation rate for finer particles and an optimum flotation rate for intermediate & coarse particles. Optimum conditions for intermediate/coarse platinum ore particles are using small bubbles at low energy inputs, or large bubbles at higher energy inputs. These results suggest that higher energy inputs are generally beneficial for the flotation of platinum ores as these consist predominantly of finer particles (-75 µm) and most industrial flotation applications operate with larger bubbles (1.0-2.0 mm).INTRODUCTIONThere is a considerable body of experimental and theoretical evidence to suggest that energy/power input plays an important role in flotation kinetics, particularly in the finer particle sizes where flotation efficiency is poor (Deglon, 2005). A number of excellent studies into the effect of energy on flotation kinetics have been carried out in impeller stirred cells (Ahmed and Jameson, 1985; Deglon, 2002; Pyke et al., 2003; Newell and Grano, 2006). Investigations using this type of cell have a number of limitations. The impeller influences particle suspension, bubble break-up and agitation in the cell. In addition, turbulence is highly inhomogeneous and anisotropic, with power intensities near the impeller orders of magnitude higher than those found elsewhere in the cell (Deglon, 1998; Koh and Schwarz, 2003; Schubert, 1999, 2008). These limitations have resulted in the development of novel cells for the investigation of energy input."

Jan 1, 2016

By Richard J. H. Barclay

The Lac Otelnuk iron property is located in the Province of Québec in the Northern Labrador Trough. The Labrador Trough is an extensive geosyncline of Proterozoic rocks, unconformably underlain by Archean gneisses. The Lac Otelnuk iron property hosts two significant magnetite iron-formation taconite deposits that outcrop, are sub-horizontal and are known to extend for at least 25 kilometres along strike. The host sedimentary rock package that includes a cherty iron formation is weakly metamorphosed to greenschist facies.

May 1, 2007

By A. S. Robb

SAMPLING of an ore-body is one of the fundamentals in its exploration, development, and exploitation. It is carried out to determine the gold value per ton of an ore-shoot and the probable gold output of the refinery. Sampling also places any broken ground in one of two classes, ore or waste. The value and importance of correct sampling has been shown repeatedly in the past. On the other hand, instances could be given where those in charge of mines have not believed in sampling, and the result has been the same in every case-disaster. This has in all probability been due to assuming that good-looking, well-mineralized rock was ore. Sampling in some form might have averted this misfortune. In this essay, only the method of sampling and the estimation of ore reserves is treated. All titles, figures, and values are fictitious. None of the illustrations can be directly applied to any portion of the Hollinger mine, except Figures 1 and 2, which are included with the special permission of the Canadian Mining Journal. METHODS OF SAMPLING Hollinger Consolidated Gold Mines, Limited, has, from the very beginning of operations, carried out an extensive system of sampling, and the results of this sampling have completely governed the whole mining programme. The Hollinger discovery was made in 1909 and prospecting and exploration of 'the surface began at once. Four men were given jobs as samplers and they sampled thoroughly all the outcrops and all bed-rock which could be exposed to view by removing the overburden. When shaft sinking began, samples were taken at two-foot intervals. In 1912, an underground gang of six samplers was organized, and the number was increased at a rate of about two men per year as the size and extent of the workings grew. No permanent record of sampling was kept until 1919, in which year an average of 11.6 men took 28,458 samples, cutting 113,894 feet of sample. From that time until the end of 1934, the average number of samplers varied, but the total number of samples cut, and the total footage sampled, increased.

Jan 1, 1937

By Derek V. Ellis

Coastal and marine mines affect the seabed?s biological resources, eg fisheries, when large volume wastes such as tailings are placed on the seabed, and by the extraction processes from marine mining. Worldwide monitoring of such effects for the past 30+ years now provides information to describe Best Practice design, construction and monitoring procedures. The critical environmental factors for submarine tailings placement (STP) are the selection of an appropriate deposition site and discharge depth, the deposition rate of the tailings, and the speed of biodiversity recovery to a sustainable ecological succession. These should be predictable at new sites using current modeling and experimental procedures. Prediction procedures are still needed to minimize potential destabilization of deposited tailings, and consequent biodiversity recovery setbacks. Comparable environmental information is needed from marine mining sites.

May 1, 2002

By V. A. Leão, M. L. M. Rodrigues, L. C. Sicupira, I. C. B. Rodrigues, T. C. Veloso

Brazilian sulphide ores can contain a significant content of chloride and fluoride, which are harmful to bacteria and thus bioleaching. This work summarizes a four-year research investigation on the effect of fluoride on both bacterial growth and sulphide bioleaching, supported by studies carried out with secondary copper ores. Firstly, the influence of fluoride on the kinetics of ferrous iron bio-oxidation with Sulfobacillus thermosulfidooxidans was addressed. Values as low as 10.0 mg/L F- fully inhibited bacterial growth, although fluoride toxicity could be overcome by the presence of aluminium, which reduced the concentration of hydrofluoric acid through the formation of aluminium-fluoride complexes. This required at least a 2:1 aluminium/fluoride molar ratio, which ensured bacterial growth rate values similar to that observed in the absence of fluoride ions. Subsequently, both batch and column bioleaching with mesofiles (30 ºC), moderate thermofile (50 ºC) or hyperthermophiles (67.5 ºC) of two secondary copper ore samples were analyzed with focus on the relevant effects of fluoride-containing minerals on the bioleaching of such sulphide ores.

Jan 1, 2014

Sustainable Development SAFETY ?Safety is the most important element of sustainability. ?One bad experience or incident can mar a company?s reputation for a long, long time. ?News travels faster than ever ?Internet, blogs, texting, peer-to-peer communication, etc. and unfortunately sometimes the information is not always accurate. ?Rarely do we hear in the news about the mining companies or projects that are done safely ?we always hear about the exceptions. ?Safety is just like TQI / TQM ?the process of improving can never stop.

May 1, 2010

By Barbara Kirby

Mining Industry Human Resource Council Who we are: National Sector Council for the Minerals and Metals Sector 18-person Board of Directors Over 100 Industry Volunteers PPP - Funded by HRSDC and industry What we do: Identify national HR challenges and opportunities for the Canadian mining industry Create national solutions through collaboration, partnerships and Synergy

Oct 1, 2010

By Larry M. Southwick

Extraction of gold and other metals from ores suspended in liquid slurries often involves gases (such as oxygen) as a participant in the reaction. An important factor then in setting the rate of extraction can be mass transfer of the gas into the liquid and/or solids. A number of recent studies have indicated that as solids loadings increase, mass transfer rates of gas into solid-liquid mixtures decreases. This would seem to imply that lower solids loadings would be beneficial to increased reaction rates. However, since it is the solids which are being reacted, a most intriguing paradox is created. More solids should lead to more surface area to react, but it seemingly also provides less gas to react. So is the reaction faster or slower as solids loadings increases? The creation of this paradox is imbedded in how mass transfer and reaction data is collected and measured, how it is analyzed and correlated, and finally on the rate controlling steps in the reaction. An alternative analysis of these studies is presented which clarifies and eliminates the paradox. The analysis applies to water slurries as used in gold or other metal leaching processes or in bio-hydrometallurgy, as well as to molten metal/solid/gas mixtures such as might be encountered in submerged gas injection.

Jan 1, 1999

By Mousa Mohammadi

Due to operational advantage of dragline in simultaneous excavation and back-filling, the equipment has gained vast importance in open-pit mining. Besides, absence of auxiliary haulage units and a myriad of other benefits are also credited in favor of excavation of muck piles by the draglines. However, the aspects of production, productivity and economics are of utmost significance in dragline operation and planning. In this light, the present paper is an endeavor to analyze availability and utilization of dragline operations. The paper presents a good amount of data for 4-draglines operating in one of the major opencast projects in India. The study reveals the trends of availability and utilization of these draglines during last 11-years. Furthermore, the study also highlights the salient reasons for loss of available hours and for idling of the draglines. Some startling information and facts have been illustrated in form of graphs and pie charts.

Aug 1, 2013