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By Robert Cluff

The Campo Morado precious-metal-bearing, volcanogenic massive sulphide district occurs in a Lower Cretaceous felsic volcanic sequence in a northerly trending belt in the Guerrero Terrane in northeastern Guerrero, Mexico. During upper Cretaceous to Early Tertiary greenschist-facies regional metamorphism, the rocks were deformed strongly into a northeast-verging fold-and-thrust belt. The deposits belong to a low-sulfidation, volcanogenic massive sulphide system formed in a subaqueous environment, and are of the siliciclastic type. Most are on the flanks of felsic domes or in adjacent basins and many are associated with heterolithic volcaniclastic rocks. The Reforma and possibly the El Rey massive sulphide deposits are interpreted to be overturned, and the Naranjo, El Largo, and Estrella de Oro deposits and the El Profundo occurrence to the south are upright. The G9 deposit and the La Lucha and San Rafael occurrences are in an over-thrust plate further to the southwest. In several of the deposits, zinc, lead, silver, and gold are concentrated near the stratigraphic top, and copper is concentrated near the stratigraphic base; copper also is concentrated in replacement bodies near the top of some domes. Major minerals are pyrite, quartz, ankerite, sphalerite, chalcopyrite, and galena. Gold and silver occur in argentian gold, and silver also occurs in tennantite/freibergite and galena. Underlying stockwork zones contain disseminated and vein quartz, pyrite, chlorite, and ankerite, with locally abundant chalcopyrite and/or sphalerite. Exploration since 2004 has enlarged greatly the El Largo and the high-grade G-9 deposits, and slightly enlarged the El Rey deposit. The cumulative in situ massive sulphides for the Reforma, Naranjo, El Rey, El Largo, and G9 deposits exceed 45 Mt.

May 1, 2006

By G. Couture, J. -F. Dubé, F. Letarte-Lavoie

"The Xstrata Nickel Raglan concentrator, located in Quebec’s Nunavik region, has been in operation since 1997. Originally designed to process 800,000 tonnes per year of high-grade nickel ore, the plant’s current capacity is 1.3 million tonnes per year due to various optimization projects. In 2011 and 2012, the Metallurgical group, with assistance from BBA, updated and optimized the variables affecting SAG throughput in order to optimize process stability while maintaining maximum plant throughput. This project consisted of reviewing the control strategy and completely updating the pre-existing Fuzzy Logic controller. This paper describes the successful update of the controller including a complete revision of control rules, a new process control strategy and the integration of new process variables, most notably mill rotational speed. It will also show how this new approach has provided a simple and robust way of delivering both an increase in throughput while reducing process variability.INTRODUCTIONThe Xstrata Nickel Raglan Mine concentrator is located in Northern Quebec along the 62th parallel. It has been in operation since 1997 and was originally designed to treat 800,000 tonnes of ore annually. The Raglan Agreement held with the Makivik Corporation and the Inuit communities limits the annual tonnage of ore that can be processed at 1.32 million tonnes.The ore is processed in a 24 foot variable speed, semi-autogenous grinding mill (SAG). The conversion from Autogenous Grinding (AG) to SAG was completed in 2006. Before the ore is processed by the SAG, its size is analyzed by a Wipfrag camera that provides a granulometry estimate. A cone crusher reduces the SAG’s discharge screen’s oversize material. A 14 foot diameter ball mill ensures final grinding before the flotation stage.Many control strategies were used at the SAG over the past few years. Fuzzy Logic was first used in 2007 in order to control tonnage feed to the SAG. This first version only measured the value of the variables without taking into account their rate of change. Revisions were made over the course of the last few years to improve controller performance. Other variables were added such as slurry density and crusher Closed Side Setting (CSS). The previous revision of the Fuzzy Logic was done in 2009 with a review of the rules only."

Jan 1, 2013

By S. Dicarlo

"In late 1985, B-zone ore was first processed through the Eldor Mines mill at Rabbit Lake. Extensive modifications had been completed in order to mill this ore. In-plant process development was initiated to tune up the new circuits and concentrated on leaching, solvent extraction, impurity and uranium precipitation and tailing and effluent treatment. This process development effort and the results are described.INTRODUCTIONEldor Mines, a division of Eldorado Resources Limited, operates the Rabbit lake mine-mill complex at Collins Bay on the western shore of Wollaston Lake in northeastern Saskatchewan.The first orebody was discovered in 1968 by Gulf Minerals Canada Limited below a small body of water named Rabbit Lake. Ore from the Rabbit Lake (RL) deposit was first processed through the new mill in June, 1975, with depletion scheduled over the next ten years. Continued exploration in the area led to the discovery of four orebodies in the vicinity of Collins Bay: A-zone (1971), B-zone (1977), D-zone (1978) and Eagle Point (1980). Collins Bay is about ten kilometres from the mill facility.In 1982, Gulf Minerals was acquired by Eldorado Nuclear Ltd., who continued the development effort to bring the B-zone deposit into production. The RL pit was mined out in May, 1984 with stockpiled ore providing mill feed until startup on B-zone ore, which was scheduled for November, 1985."

Jan 1, 1988

By Colin Hardie, Erik Bartsch, Guy Comeau

"The Xstrata Nickel Raglan Concentrator, located at the northern limit of Quebec’s Nunavik region has been in operation since 1997. Originally designed to process 800,000 tonnes per year of high grade nickel ore, plant capacity is currently approaching 1,200,000 tonnes per year due to an Optimization Project (FAG to SAG conversion) in 2005 and many recent processimprovements.In 2006, the Raglan Metallurgical Group with assistance from the Xstrata Process Support group decided to make SAG control one of its priorities in order to further increase throughput and improve stability. The original primary mill control logic delivered by the Optimisation Project in 2005 consisted of a simple PID loop controlling the mill charge (bearing pressure) through feed rate changes. Due to the multivariable, non-linear and disturbance dominated nature of the SAG circuit it was quickly found that this traditional PID control strategy was not able to adequately control the mill; resulting in poor stability, frequent operator interventions and less than optimum performance.This paper describes the successful integration of advanced field systems such as mill feed image analysis (Wipfrag) and crusher gap controller (ASRi), into a multi-variable fuzzy logic SAG mill controller. The process of how a strategy for control was developed and implemented directly in the existing control system (exploiting standard system capabilities) is discussed. It is also shown how this approach has provided mill automation which is simple, robust (despite erratic feed characteristics), and delivers both an increase in throughput and a reduction of variability.INTRODUCTIONOriginally commissioned as a Fully Autogenous Grinding (FAG) circuit in 1997, preparations to convert the Katinniq Concentrator Mill to SAG had in fact commenced as early as 1999, but were halted owing to alternative process improvements which achieved up to 1Mtpa as early as 2000. Up until this time, plant process controls had remained more or less static; modifications having been limited to those required by new equipment. Primary mill process controls and related measurements were at this stage limited to:"

Jan 1, 2008

By John Russell

"The South American mining community leads the world in recognition and adoption of the latest grinding mill relining technologies. Clearly this region has recognised the benefits of improved relining performance.Six of the seven RUSSELL TWIN 8 Mill Relining Systems, ordered to date, are either operating or being manufactured for South American mine sites.This paradigm shift, towards very short relining times, aims at displacing mill relining activities from the critical path of concentrator maintenance shutdown schedules.The first uses of the RUSSELL TWIN 8 Mill Relining System have seen some of the highest SAG mill new liner placement rates ever observed by RME, as would be expected with two, independent Machines working simultaneously in the one mill.The liner-replacement-rate, averaged over the whole reline, is good (27% improvement over single Machine System in the same mill) but short of full potential. This modest result can be attributed to reline crews unfamiliarity with RUSSELL TWIN 8 System operation.This paper compares a sample of conventional (single machine) RME Mill Relining System performance data with one ‘double head’ mill liner handler by others. Early performance of Escondida’s new RUSSELL TWIN 8 System performance is then compared with recent single Machine data from Escondida, immediately prior to RUSSELL TWIN 8 commissioning. RME and Escondida look to constantly improving RUSSELL TWIN 8 System performance as full operational familiarity is achieved.Also, the preparation of this paper revealed a need to develop a global industry standard for mill relining data collection. A web based platform, to develop and then distribute standardised data collection templates, is discussed in Annexure 1."

Jan 1, 2010

By W. F. McDermott

This paper covers the development, construction and operation of a 53-mile slurry pipeline operating in Tasmania, Australia. Special development techniques are discussed, as well as the operation of this line and its impact on transportation from remote areas.

Jan 1, 1970

By D. Stone, N. J. Aslin, W. Webb

In today's modem copper electro-refineries, increasingly higher average current densities are being employed. With these increases many refineries are approaching their limiting current density. The nearness of the average operating current density to the limiting current density has placed increasing emphasis on the need to maintain an even current distribution. This paper explores the importance of maintaining even current density and discusses the factors, processes and practices that are necessary to achieve and maintain high quality production at high operational intensity.

Jan 1, 2005

By A. Rodriguez-Prado

"Magnetic fields affect the growth of cultured cells and plants; however, limited information exists about their effects on vegetation performing environmental remediation. Constructed wetland mesocosms treating hexavalent chromium (Cr(VI)) wastewater exposed to low-intensity magnetic fields (60 Hz, 56.5 × 10-6 Tesla) produced 100% more biomass than the unexposed control. Nonetheless, they removed only 43 ± 27% of Cr(VI), compared to 60 ± 21% for the control. A Cr(VI) reduction expression was developed as a function of the magnetic field. The design and operation of constructed wetlands to treat mining wastewater can be corrected for magnetic field effects.RÉSUMÉ Les champs magnétiques affectent la croissance des cellules et des plantes cultivées; toutefois, il existe peu d’information quant à leurs effets sur la végétation utilisée à des fins d’assainissement environnementale. Les mésocosmes des marais artificiels traitant des eaux usées, contenant du chrome hexavalent (Cr(VI)), exposés à des champs magnétiques de faible intensité (60 Hz, 56,5 × 10-6 Tesla) ont produit 100 % plus de biomasse que le contrôle non exposé. Néanmoins, ils n’ont enlevé que 43 ± 27 % du Cr(VI), comparativement à 60 ± 21 % pour le contrôle. Une expression de réduction du Cr(VI) a été développée en tant que fonction du champ magnétique. La conception et l’exploitation de marais artificiels pour traiter les eaux usées des mines peuvent être adaptées pour tenir compte des effets des champs magnétiques."

Jan 1, 2015

By M. Maley, S. Burling, R. Ring

ABSTRACT The numerous global uranium deposits vary significantly in mineralogy, grade, and textural characteristics; therefore, information from traditional (or conventional) sources on the fundamentals of leaching uranium and gangue minerals is not always applicable when studying particular ores. Empirical studies can be effective in understanding leach systems and can lead to improvements in process design but there remains a lack of fundamental understanding necessary for ongoing process optimization as ore bodies continue to vary. ANSTO Minerals has undertaken a work program to address several fundamental questions about uranium leaching, including the unexpected impact for some ore types of leaching at high oxidation potential.

Jan 1, 2012

By D. E. Keeley

lntroduction Some years ago it was general practice in Canadian mines to use the best timber available, just as it was cut from the tree. Later, to prevent 'borers' from getting into the wood while stacked in the yard, the bark was peeled off, cleaned up carefully, and burned to eliminate a breeding ground for these and other destructive insects. This practice of good housekeeping also decreased the hazard from fire in scattered bark. A few years after damage by borers had been minimized, it became apparent that increased temperatures in the mines, occasioned by deepening operations, were being accompanied by rapid growth of fungus and by decay in timber underground, greatly shortening its life. In places on upper levels where the air temperature was below 50 deg. F., untreated timber retained a large proportion of its strength for ten or more years. In other places on these levels, however; its life was short and it developed much dry rot and merulius lacrymans. In these latter places and on lower levels in the mine where temperatures ranged from 50 to 60 deg. F., approximately, the wood became infested with extensive growths of this white fungus. This development was accompanied by the production of millions of spores. Spread of infection was due mainly to the transfer of spores from the warm lower levels to the cool upper horizons by upcasting ventilation currents. So serious did this become that about twenty years ago Lake Shore, Hollinger, and McIntyre Mines decided to investigate the use of wood preservatives and the plant necessary to treat timber.

Jan 1, 1949

By Trevor Yeomans

"NVI Mining’s Myra Falls Operation is a forty year old underground mining operation feeding a 4000 mtpd concentrator.The current Mill, built in 1985, was designed to process a large massive sulphide ore-body. This ore-body, known as the “HW”, contains about 50% pyrite. Value minerals are chalcopyrite, and sphalerite, with precious metals occurring in all mineral types.By 1997, mining of a new ore-body, known as “Battle-Gap” commenced. Mineralogically complex, the new orebody contains about 15% pyrite, copper minerals including primary chalcopyrite, secondary bornite, chalcocite and tennantite, combined with increased galena and sphalerite.Flotation performance generally decreased with increasing amounts of Battle-Gap ore types, with both copper concentrate quality (increased lead and zinc content) and copper recoveries being affected.Following significant metallurgical testwork, a new fully sequential copper-lead-zinc flotation flowsheet and reagent scheme was developed.This sequential flowsheet was progressively installed and commissioned during 2006.Copper concentrate lead and zinc smelter penalty contents have been reduced by some 40%, whilst increasing copper recovery by 10%.INTRODUCTIONNVI Mining operates the Myra Falls Operation near Campbell River on Vancouver Island, BC. The complex has been in operation since 1966 with mining being predominantly underground. One unique feature of Myra Falls is that the mine operates within a BC Provincial Park.In 1985, a new large massive sulphide ore-body (HW) had been defined, and metallurgically tested. A new concentrator was built based upon this massive pyrite, chalcopyrite, and sphalerite mineralization producing copper and zinc concentrates by conventional flotation methods."

Jan 1, 2008

By Tony Szwilski

Using Unity 3D as a collaborative multi-user virtual on-line environment, an interactive virtual underground mine platform (IVUMP) is being developed to provide on-line access to mine safety preparedness training with a focus on mine emergency response exercises (MEREs). Communication and information flow among MERE participants and their actions can be monitored, recorded and evaluated. A mine ventilation simulation utility VFIRE is being incorporated to enhance the realism and interactive nature of the ?in-world? exercises as well as extend its functionality to include training in real-time ventilation and fire control.

Aug 1, 2013

By Todd Smith, Brigitte Lacouture, Greg Anderson, David Lin

"The lead and zinc flotation circuits at Red Dog Mine are preceded by a preflotation circuit which recovers naturally-floating organic carbon contained in the ore. Organic carbon is a potential contaminant in the lead concentrate and is detrimental to lead-zinc selectivity. Prior to 2007, the Red Dog preflotation circuit consisted of a single stage bank of tank cells which floated the organic carbon. The preflotation concentrate was discarded directly to tailings, however, this stream contained significant amounts of lead and zinc. Zinc loss to preflotation ranged from 2% to 6%, relative to the zinc in the mill feed and was proportional to the amount of organic carbon in the ore. The main mechanism of the zinc loss was entrainment.Pilot plant and modeling testwork were conducted to examine the use of a Jameson Cell to clean the preflotation concentrate. Results indicated that up to 90% of the zinc deporting to preflotation concentrate could be returned to the flotation circuit for recovery. The installation of a 5.4 m Ø Jameson Cell with 18 downcomers was initiated in June 2006. The new preflotation cleaning circuit was commissioned in March 2007. Conservatively, preflotation cleaning has resulted in zinc and lead absolute recovery gains of 1.0% and 1.5%, respectively. The $9.1M project has a payback period of approximately 1 year at current metal prices.INTRODUCTIONRed Dog Preflotation CircuitRed Dog Mine is located above the Arctic Circle in northwest Alaska. It is the world’s largest zinc concentrate producer with a production rate of more than 1.0M t/yr. Red Dog is operated by Teck Cominco Alaska Incorporated under an operating agreement with the Northwest Alaska Native Association (NANA). Due to the remote location of the mine, it is accessible only by air, or seasonally, by ocean-going barges.The Red Dog deposit is a rich sedimentary exhalative (sedex) zinc-lead-silver deposit. The major sulphides, in decreasing order of abundance, are sphalerite, pyrite, galena and marcasite. Due to the complex nature of the ore body, run-of-mine ore is blended in stockpiles before being crushed and processed through the concentrator. The average mill feed grade for 2006 was 6.1% lead, 20.6% zinc, 8.0% iron and 0.67 % organic carbon."

Jan 1, 2008

By Andre L. De Vegt, Cees J. N. Buisman

"For the past eight years Paques has been engaged in the development and installation of treatment systems based on biotechnological processes to remove sulfur compounds from water, air and gaseous streams. Metal and sulfate can be removed from mine waters using two biological steps:1. Sulfate reducing bacteria convert sulfate to hydrogen sulfide (H2S). The H2S reacts with the dissolved metals to form insoluble metal sulfide precipitates.2. Sulfide oxidizing bacteria convert excess H2S to elemental sulfur.Paques has designed and installed a groundwater treatment system for the Budelco zinc refinery in the Netherlands to remove metals and sulfate as described above. The system has been operating since May 1992 treating a flow of 5000 m3/d. A test program, utilizing a large scale pilot plant, will commence in November 1995 at a copper mine in the U.S.A. to remediate groundwater contaminated with sulfate and heavy metals. Biological reactor performance and selective metal recovery will be studied. Sulfur dioxide (S02) can be removed from fluegas using a combination of scrubber technology and the two biological steps. The end product is elemental sulfur. A commercial size biological desulfurization plant has been in operation since July 1994 treating 50,000 Nm3/h of fluegas. Sulfide can be removed from mining waters or anaerobic wetlands using a THIOPAQ® Sulfide Oxidizing reactor.lntroductionSulfur can be present in various water and gaseous streams in a mining operation. In many cases the sulfur compounds have to be removed because of toxicity, corrosive properties and contribution to acid rain. Mine waters can contain dissolved heavy metals. An efficient way to remove dissolved metals removal is the precipitation as metal sulfides. Paques has developed and installed treatment systems based on biotechnological processes to remove sulfur compounds from water, air and gaseous streams. These treatment systems biologically convert sulfate to hydrogen sulfide (H2S) which can be used in heavy metal precipitation. Excess H2S is biologically converted to elemental sulfur. This paper provides an overview of these newly developed biotechnological treatment systems."

Jan 1, 1997

By G. S. Hume

Research thrives on ideas, and the theoretical considerations of today are either the discarded notions or the proven facts of tomorrow. The progress made in the past fifty years in the acquisition of knowledge of petroleum geology is no less astounding than is the tremendous increase in the production of oil on the North American continent from 61 million barrels in 1897 to 1,917 million barrels in 1947, an increase of 3,300 per cent, with production of natural gas expanding from less than 400,000 Mcf in 1897 to approximately 4,500,000,000 Mcf, or an increase of 11,000 fold in the same period. In the search for and discovery of the oil and gas fields that have yielded such prolific wealth, no idea has had a more profound effect than has the ?anticlinal? theory of oil accumulation, propounded in 1844 by Sir William Logan, the founder of the Geological Survey of Canada, after noting the position of oil seepages on the crests of anticlines in Gaspe peninsula. Sir William apparently was not much impressed with his own idea at this time, but after the Drake well discovery in 1859 and the publication by Henry D. Rogers, of Glasgow University, formerly of the Pennsylvania Geological Survey, of a paper in which he pointed out that the seepages in Pennsylvania were on anticlines, T. Sterry Hunt, an associate of Sir William Logan on the Geological Survey of Canada, published a reasonably comprehensive statement of the anticlina theory in the Montreal Gazette on March 1st, 1861. Hunt recognized the fact that the oil ?being lighter than the water which everywhere penetrates the rocks below the water level, naturally rises and accumulates along the crown of these anticlines". This was a recognition of the fact that gas, oil, and water in an anticlinal structure separate according to buoyancy or specific gravity. For some years the anticlinal theory does not seem to have attracted much attention, but when I. C. White in 1883 revived it and put it to practical use by prospecting for 'anticlinal' oil an gas structures in Pennsylvania, West Virginia, and Kentucky, its real value not as a theory but as a fact became widely recognized. Even today, the search for anticlines as oil and gas structures is being vigorously continued. In the past fifty years, however, it has become widely recognized that petroleum and natural gas collect in many different types of structures, and these have become known by the general name of 'traps'. About 1890, terrace structures were highly regarded because it was thought certain oil fields in Pennsylvania, New York, and Ohio were directly related to them. However, as Wilson (2, p. 437) has pointed out, it is recognized to day that ?'wherever the surface evidence is complete and dependable, other factors (than the terrace structure) are found to be in control'.

Jan 1, 1948

By Peter Dunn

London Mining Plc. is developing an iron ore project in Sierra Leone. The Marampa mine is a brownfield development effort, having been operated by others since the 1930?s until low iron ore prices forced closure. Peak production of the prior operations was approximately 2.5 Mt/a in the 1960?s. Following civil war In Sierra Leone, London Mining obtained the mining license in 2006 and commenced activity to redevelop the Marampa mining and processing operations. There are two ore deposits of interest for development as well as a resource comprised of tailings from previous operations. Phase 1 will be the mining of the tailings resource with a 1.8 Mt/a plant producing 66 per cent Fe sinter feed, expandable to 3.6 Mtpa. The first phase is currently under construction with start-up expected in the third quarter of 2011. Phase 2 will include development of the two ore deposits. These deposits are weathered secondary ore and the main primary ore resource. Phase 2 is currently under prefeasibility study and targets a final 16 Mt/a concentrate production in 2016. Outotec partnered with London Mining on testing efforts to develop the magnetic separation flowsheet using SLon VPHGMS machines to process the Marampa material. This paper explains the flowsheet development process for the weathered and primary ores commencing with sample characterization and detailed parametric investigations to evaluate SLon performance. The final flowsheet configuration is explained, including expected circuit recoveries and concentrate quality, clearly demonstrating the performance of the SLon VPHGMS circuit in iron ore tailings treatment applications.

May 1, 2011

By C. Larsen, E. Goodwin, E. Konigsmann

"This paper describes the development of an innovative effluent treatment process for cyanide and heavy metal removal from tailings wastewaters at Hemlo Gold Mines Inc. Golden Giant operation.The importance of minimizing dissolution of contaminants in the gold leaching circuit is discussed, as well as using recycled water in milling circuits to the fullest extent possible. Finally, a brief description of the role of natural cyanide degradation in the tailings pond is provided.Emphasis is placed on the need for overall water quality management to ensure minimum effluent treatment process costs and complexity while producing excellent quality effluents.1.0 INTRODUCTIONHemlo Gold Mines Inc. owns and operates its Golden Giant Mine located forty kilometres east of Marathon, Ontario. The Golden Giant mine is one of three gold operations exploiting the large gold orebody located in the Hemlo area. The milling facilities include two stage secondary crushing, three stage, closed circuit ball mill grinding with no reagents, thickening, cyanide leaching and carbon in pulp gold recovery unit operations. The average throughput is 3000 tonnes per day of 10 grammes per tonne gold ore. Figure 1.1 shows a schematic flowsheet of the operation."

Jan 1, 1989

By R. J. Chase, C. Davies

"Abstract- The Merelani graphite-tanzanite deposit is located in northeast Tanzania, 14 kilometers south of Kilirnajaro International Airport and in close proximity to the towns of Moshi and Arusha . The graphite mineralization is hosted by relatively undeformed linear Proterowic metasedimentary gneisses, several of which have been subjected to hydrothermal alteration resulting in tanzanite mineralization. Exploration work comprised detailed geological mapping coupled with pit and trench channel sampling and a subsequent 1500 meters of diamond drilling. In addition, metallurgical tests have shown the graphite to be of unusually coarse flake size, crystallinity and high purity.Feasibility studies have shown the economic viability of a major coarse flake graphite deposit with the measured resource to 50 meters in excess of 9 million tonnes assaying over 8o/o graphitic carbon . Production is due to start by the end of the first quarter of 1994 with the processing plant design capacity initially set at 15 000 tonnes per annum.ln addition to graphite production, tanzanite will be produced through selective mining within the graphite open pit in the upper horizon and from underground workings within the lower horizon.The Merelani graphite-tanzanite deposit will be the first major orebody to be exploited through means of private funding since Tanzania gained independence."

Jan 1, 1994

By S. R. Amos, N. O. Lotter, A. L. Hannaford, J. F. Oliveira, D. W. Broughton

"Ivanplats Ltd appointed Xstrata Process Support to perform the flowsheeting development work for their hypogene and supergene geomet units of the Kamoa Copper deposit, located in the Democratic Republic of the Congo. Through systematic flowsheet development using modern Process Mineralogy, the optimised milestone flowsheet delivered a saleable concentrate grade of 32.8% Cu at 85.4% recovery with hypogene ore, and a saleable concentrate grade of 45.1% Cu at a recovery of 83.4% for supergene ore. The significant value of this development is that a single flowsheet will treat both hypogene and supergene ores and produce saleable concentrates. Further work to advance the flowsheet performance has been identified for investigation in the near future.INTRODUCTIONLocation and Description of the Kamoa DepositThe Kamoa copper resource is located some 40 km west of the city of Kolwezi, in the south west of the Katanga Province of the Democratic Republic of the Congo, in the region of Central Africa. Drilling at Kamoa in 2008-2009 had discovered laterally continuous, sediment-hosted, high-grade stratiform copper mineralisation in a newly discovered copper district that forms a previously unrecognised western extension of the famous Central African Copperbelt – which hosts such world-class deposits as Kolwezi, Tenke-Fungurume, Konkola and Nchanga. This discovery showed that the western end of the Copperbelt in the Congo does not terminate at Kolwezi (Friedland & Broughton, 2009). The resource contains hypogene and supergene geomet units with a transitional zone located inbetween the (upper) supergene and the (lower) hypogene. In the hypogene unit, the major copper sulphides are bornite, chalcopyrite and chalcocite, whilst in the supergene, the sequence is led by chalcocite, then bornite, and finally chalcopyrite. Covellite is present in both units as a minor copper sulphide. Both geomet units will be mined and treated in one concentrator, either as blends or as campaigns."

Jan 1, 2013

By Peter Claus

In the last years, supported gold catalysts with particle sizes smaller than 10 nm have attracted a lot of attention. While gold bulk metal is rather inert in chemical reactions and, thus, is of low interest for catalysis, highly dispersed gold particles supported on oxides as TiO2 or ZrO2 show surprisingly high activities in some reactions important for the chemical industry. The oxidation of carbon monoxide at low temperatures is mainly used as model reaction to study the unusual properties of gold catalysts [1]. On the other hand, to evaluate the catalytic potential of gold, other chemical reactions which allow to control also the selectivity have to be considered. The selective hydrogenation of ???-unsaturated aldehydes to allylic alcohols is of both commercial relevance (e.g. in fine chemical and pharmaceutical intermediate production) and specific scientific interest [2]. Note that thermodynamics favors hydrogenation of the C=C over the C=O group (stronger negative free reaction enthalpy of 35 kJ/mol), and for kinetic reasons the C=C bond is more reactive than the C=O group. Thus, in the presence of most of the conventional hydrogenation catalysts, based on Pt, Rh or Pd, -unsaturated aldehydes such as acrolein and crotonaldehyde are hydrogenated predominantly to the saturated aldehydes and only to a minor extent to unsaturated alcohols. Therefore, it is desirable to find catalysts which are able to control the intramolecular selectivity by hydrogenation preferentially the C=O group while keeping the olefinic double bond intact (Fig. 1).

Oct 1, 2003