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By André Pomerleau, Michel Grégoire, René del Villar

"The operation of industrial flotation columns requires the control of at least two variables, the interface position and the bias rate, by manipulation of some appropriate operating variables. Problems arise due to the reliability of existing methods of measuring the bias (i.e bias = tailings water - feed water), a situation which has often forced the industry to disregard this control loop. Moreover, when using such a measuring approach, the identification of the process dynamics is impossible. A second problem arises from the possible interaction between both control loops that might call for the use of a more complex multivariable control strategy.Recent work done at Lava1 University has demonstrated the feasibility of an independent sensor for bias, which models the relation between the conductivity profile across the interface and the bias value using a neural network algorithm. A 250 cm height, 5.25 cm diameter Plexiglas laboratory column was equipped with a series of conductivity electrodes in its uppermost part (across the interface) to measure both interface position and bias rate. Using such equipment, the flotation column dynamics were identified. The results thus obtained permitted the design and implementation of a distributed PI control strategy, where bias was associated to wash water rate and froth depth to tails rate. Both PI controllers were tuned using a frequency-response tuning method. Results of both identification and process control are presented and discussed.INTRODUCTIONFlotation columns are used for the separation of valuable minerals from a carrier gangue. Typically, this device is a tall (9 to 14 m height) cylinder (1 to 3 m in diameter) although other cross sectional shapes are also used. Finely ground ore is fed as a pulp at about 2 m from the top of the column, and pressurized air is introduced through a sparger at the bottom. If the pulp has been properly conditioned with adequate chemical reagents (collectors and modifiers), the valuable mineral particles falling by gravity will attach themselves to the rising air bubbles, and the air-particle aggregates will rise to the top of the column where they overflow as a stream called the concentrate. The gangue particles,, that do not attach to the air bubbles, fall down the column being withdrawn at its bottom in a stream called the tails.A particular characteristic of flotation columns is the addition of a fine spray of water at the top. As the water flows down through the froth zone, it washes out the entrained gangue particles from the mineralized bubbles, thus improving the quality of the concentrate recovered at the top. As a result of its cleaning action, this water stream is called the wash water and the upper zone, the cleaning zone. In order to ensure a downward flow of wash water, a proper water balance must be kept in the froth zone, otherwise the water added at the top might shortcircuit to the concentrate without performing any cleaning action. This net downward flow of water inside the froth zone is called the bias and represents an important operating variable of a flotation column."

Jan 1, 1999

By Kevin O?Callaghan

Applying Legal Concepts - The Crown must consult, and where necessary accommodate, when: - Crown has knowledge, real or constructive, of the potential existence of Aboriginal rights or title and contemplates conduct that might adversely affect it - Duty to consult is triggered at a low threshold - How much consultation necessary? - Proportional to the strength of claim and potential impact - Spectrum: notice to direct involvement in decision making - Not duty to agree or to get consent (no veto) - Reciprocal: Duty requires good faith and sincere engagement on both sides Role of Proponents: Crown may delegate procedural aspects of its legal duty

May 1, 2010

By A. C. Elliott, A. J. Lafreniere

THE Hamilton Works of The Steel Company of Canada is a fully integrated steel plant with an annual capacity of three million tons. Located on the south shore of -Hamilton bay, it is in the centre of Hamilton's industrial belt. The heavy concentration of industrial activities found in this area, accompanied metallurgical well-known sources of pollution which are normal to urban areas is creating a pollution problem which concerns both industry and the general public. The Steel Company of Canada has recognized this problem and, accordingly, has adopted the policy of integrating suitable pollution control devices into its new installations. Much effort is also being expended to control the emissions of air contaminants from the existing equipment. At the Hamilton Works, there are two main sources of metallurgical dust emissions to the atmosphere -the Open Hearth furnaces and the Sinter Plant. Of these two, the Open Hearth furnaces are, undoubtedly, the largest single source of

Jan 1, 1962

By G. W. MacLeod

The iron ore question in this country has been widely discussed for many years, but only recently has its real significance becoming generally understood. The exhaustion of the old Helen mine, in 1918, marked the last phase of hematite production in Ontario, and with the closing of the Magpie mine in 1921 , Canada ceased to be a producer of iron ore. For the past three years every ton of ore used in Canadian blast furnaces has been imported. In a recent issue of the Engineering and Mining Journal-Press, Arthur B. Pearsons, Assistant Editor, makes the following statement : Iron dominates the world. Some contend that coal is more vital. be-cause heat is needed to make iron and steel. But there are other sources of energy, more convenient and less costly and it is only a question of time when progress in hydro-electric development will have reached the point where coal will be but an incidental source of power and heat. Even more direct means than the generation of electricity by hydro-power eventu-ally will be developed by making available the latent energy of the sun. But iron; Science gives not the vaguest suggestion that anything will dis-place iron and steel as the most essential material tool of modem civiliza-tion. ? Hardness, tenacity, malleability-it possesses all these in unique de-gree. These are some of the qualities that make steel and iron indispensable in modern industry. The domestic consumption per inhabitant of the United States has climbed uniformly from 0.18 tons in 1900, to 0.36 tons in 1922. New kinds of machines and new types of structures are being devised every year; and steel or iron is the basis of most of them." It is unlikely that the Ontario Government were actuated by this motive when they appointed the Iron Ore Committee to investigate and report on the iron ore situation, nevertheless, these facts must have influenced them in some degree.

Jan 1, 1924

By K. Janghorban

Multilayered ceramic-metal composites were produced by solid state diffusion bonding of polycrystalline alumina and three Al alloys containing 1 to 2%Sr, 2% Mg and Mg + Si (5057 Al alloy), The multilayered structures were fabricated at 610°C under a compressive stress of 3 MPa for 2 hours in He-5%H atmosphere, The ceramic-metal interfaces were studied by SEM and TEM equipped with energy dispersive spectrometer (EDS). Addition of 1 wt % Sr to Al promoted good adhesion, without producing any interfacial products, while the Al-2%Sr was poor in this regard due to the presence of dispersed A14Sr which is an intrinsic phase in the Al-Sr phase system, The Al-2%Mg alloy produced a continuous film at the interface, which was characterized to be MgAl2O4. Al alloys containing Mg and Si (5057 commercial alloy) produced not only the spinel structure (MgAl2O4), but another phase rich in Mg and Si (close to Mg2Si), These latter interfacial reaction products were not the intrinsic phases in Al-Mg alloys, and were reaction products at the Al2O3 ?Al alloy interfaces.

Jan 1, 2005

By C. C. Walden, A. Bruynesteyn

"Chemical and biological aspects of the formation of acidic effluents from sulfide waste materials are discussed. Test procedures to determine the acid producing potential of waste materials, as well as the characteristics of such acidic effluents, are presented. Practical applications of the test procedures are discussed with reference to predictior of environmentally unacceptable drainage and to estimation of metal recovery by dump leaching.INTRODUCTIONNatural leaching of sulfide minerals, exposed to the atmosphere, has been occurring for geological time. For centuries, man has been aware of the acid drainage originating from coal workings, copper mines and waste dumps. With the advent of the technical sciences, the processes involved in acid mine drainage production were considered to be solely chemical in nature. However, in 1947, it was shown (1) that a specific microorganism, called Thiobacillus ferrooxidans, was responsible for acid mine drainage from coal workings. It was demonstrated that under suitable conditions - this bacterium oxidized pyrite and marcosite in the coal to ferric sulfate and sulfuric acid. Numerous studies have subsequently demonstrated that - under suitable conditions - Thiobacillus ferrooxidans can attack most sulfide minerals, producing weak sulfuric acid, oxidizing ferrous to ferric iron and solubilizing other metals present (notably copper and zinc) as their sulfate salts."

Jan 1, 1980

By R. Webber, D. Averill, L. Whittle, D. Moffeti, G. Kassakhian

"This paper describes the recent pilot-plant work carried out on two alternative processes capable of producing an effluent containing less than 10 pCi/L total radium-226 activity and very close to 3 pCi/L dissolved radium-226. The processes incorporate coprecipitation of radium with barium sulphate by the addition of barium chloride in continuously stirred tank reactors followed by either chemical coagulation with ferric chloride, flocculation and clarification, or polymer-aided dual-media filtration. IntroductionUranium mines in Canada have practiced radium removal from tailings basin effluents since 1965. Treatment consists of addition of barium chloride to precipitate radium as barium- radium sulphate and provision of natural or constructed settling ponds for sedimentation. This process, however, has been identified as being deficient in that it allows particulate or suspended radium-226 releases which are higher than the regulated dissolved values». Also, the large size of some of the settling ponds is believed to represent a real limitation of the present technology because of inferred difficulty in recovery of barium-radium sulphate precipitates.The Federal Government Mining Task Force established a Radioactivity Sub-Group in 1974 to assist in the development of effluent regulations and guidelines for the uranium mining industry. Among the recommendations of the Sub-Group was the need to seek more effective methods of radium removal, including development of physical/chemical treatment systems as an alternative to settling ponds. In response to the SubGroup recommendations, a bench-scale study began in March 1976at the Wastewater Technology Centre (WTC) of Environment Canada . The results of this study indicated that coagulation and flocculation of the precipitate from barium chloride addition is a viable alternative to sedimentation in settling ponds(3). The bench work was expanded and accelerated in 1977, with financial assistance provided by the Atomic Energy Control Board. Subsequently, a research program with a larger scope was developed; this program is jointly managed and funded by government and industry, as shown in Table I.One of the goals of the joint program is to develop, at pilot scale, a physicalI chemical process to reduce the radium-226 content of uranium mining and milling effluents. Target radium-226 activities for treated tailings basin effluents were set: namely, 10 pCil L total and 3 pCil L dissolved radium 226. Extensive bench-scale and pilot-scale work was conducted through 1978 and 1979 and has culminated in the development of two physical/chemical processes. This paper describes work carried out at a pilot plant which led to the selection of the two physical I chemical processes for demonstration. In short-term tests, the processes produced effluents meeting the radium-226 target activities."

Jan 1, 1980

By F. L. Wu

Based on the analysis of a sealed coal mine resulting from a fire-triggered explosion, limitations were discovered in the re-entry procedures used to reduce the size of the sealed area that were being applied during the process of re-opening the mine. The analysis of two re-opening plans in a mine using mechanical ventilation showed that the estimation of the degree of damage of two air doors close to the working face with the fire was key to the identification of the optimum mine recovery plan. The operation points of airflow and air pressure of the main fan under either the doors? damaged or intact conditions can be estimated through the use of a ventilation network simulation program. Starting the main fan for a short time period and measuring its operation points of airflow and air pressure allowed their comparison with the simulated values. This procedure provided a reasonable estimation of the degree of damage of the ventilation structures and more confidence in choosing a recovery plan. Through this process, it was possible to conclude that the two doors were still intact. Consequently, the final plan of installing a new main fan in the main decline, sealing the initial upcast shaft and unsealing the auxiliary downcast shaft, was proven to be reasonable at the mine site.

Aug 1, 2013

By G. E. Veins

A three-phase, continuously-operated, 250 kv.a. electric smelting furnace has been installed at the Mines Branch, Department of Mines and Technical Surveys, Ottawa, for the experimental treatment of ores and by-products of interest to the Canadian mining, metallurgical, and chemical industries. In the operation of this furnace particular emphasis is placed on the accumulation of quantitative data which will be useful in determining the most suitable smelting technique and the nature of the products, and in arriving at preliminary conclusions regarding the cast of power and electrodes. The results obtained in the experimental smelting of iron, manganese-iron, titanium- iron, nickel, and chromiumiron ores, and of a number of industrial by-products, clearly show the value of such treatment for materials of this type.

Jan 1, 1957

By F. S. Hoseinian, M. Irannajad, M. Safari

In this study, the effect of chemical interactions of materials used in ion flotation on the removal of Ni(II) ions from low concentration synthetic wastewater was studied. Sodium dodecyl sulfate (SDS) and ethylhexadecyldimethylammonium bromide (EHDABr) as collectors and methyl isobutyl carbonyl (MIBC) and Dowfroth250 as frothers were used. To investigate the effective parameters and interactions of them, 16 experiments including 6 level variables were performed by supporting DX7 software and on the bases of 2-level factorial method. In the first step, the tests were conducted in a Hallimond tube. The result showed that collector of SDS and frother of Dowfroth 250 had appropriate interaction with each other at pH = 3. In the second step, optimal results from the first step were evaluated in a mechanical flotation cell. The removal of Ni(II) ions increased by increasing the time of flotation and they have a direct relation with the water removal. The kinetics study shows that the order and the rate of removal of the reaction do not follow any of the zero-order, first-order and second-order equations. The flotation rate curve on the removal of Ni(II) ions will divide the separation process to two stages, a fast flotation rate at the first stage and a slow flotation rate at the second stage. Ni(II) ions removal was obtained 88% at the best condition.This study showed that the use of ion flotation was a very effective method for Ni(II) ion removal from industrial wastewaters.

Jan 1, 2016

By M. Abouhamad

According to the Canadian Urban Transit Association (CUTA), 140 Billion CAD is required to maintain, rehabilitate, and replace subway infrastructure between 2010 and 2014. The current practice adopted by transit authorities for prioritizing subway stations for rehabilitation is based on the station structural needs. While this classification is reflective of station condition, other factors, such as station size, location and passenger capacity, play an important role. The criticality of a station is an index that represents the functional importance of a station depending upon a set of identified factors. The system criticality is based on several attributes, such as station location, size, and nature of use. This paper presents a novel method of clustering subway stations for rehabilitation priority based on their criticality level. The different stations in a subway network are rated according to their relative importance against predefined attributes. The weights and scores of the attributes are computed with the help of experts and current subway network data. The analysis is done using the Fuzzy Analytic Network Process (FANP) to accommodate the subjectivity of human judgment as being expressed in natural language which entails ?fuzziness? in real-life problems and account for the interdependency between the selected attributes. The output of the model is a criticality based clustering of subway stations. The proposed framework helps authorities prioritize stations for rehabilitation and highlight stations with more criticality for a more robust asset analysis.

Aug 1, 2013

Improved Process & Practices Result In: ? Reduction of undesirable downtime, & expensive secondary damage ? Improved equipment performance & health ? Extension of equipment life, & reduction of operating costs ? Safety and environmental performance improvement Equipment knowledge capture and consistently applied

May 1, 2010

By D. G. Klaren, E. F. de Boer

Self-cleaning fluidized bed heat exchangers have demonstrated unparalleled performance internationally for the implementation of indirect heat transfer in severely fouling fluid environments. The ingenious configuration of recirculated cleaning particles through the tubes of vertical shell and tube heat exchangers provides the ability to solve any problems that arise as a consequence of tube-side fouling during indirect heat transfer to process fluids or slurries. In most cases, the cleaning particles consist of chopped metal wire, however other process-specific materials have been used. In addition to the mitigation of fouling effects, a number of other significant benefits for slurry heating are afforded by the mode of operation of the self-cleaning fluidized bed heat exchangers. Increased turbulence at the slurry/tube interface is imparted by the action of the fluidised particles, resulting in very high heat transfers at relatively low liquid velocities. Furthermore, given the thixotropic nature of most process slurries, the action of the fluidised particles imparts additional shear to the process slurry, resulting in shear thinning effects with a consequent reduction in pressure drop and enhancement of heat transfer across the heat exchanger. The benefits provided by the self-cleaning fluidized bed heat exchanger make it the ideal option for the indirect heating of laterite nickel slurry for High-Pressure-Acid-Leach (HPAL) plants. This article explains the principle and application of the self-cleaning fluidized bed heat exchanger technology for the processing of laterite nickel and cobalt slurries in HPAL plants. It also presents an elegant method to revamp existing direct heated laterite nickel and cobalt processing plants into an indirect heated configuration employing self-cleaning fluidized bed heat exchangers.

Jan 1, 2004

By Euler De Souza

"The uninterrupted operation of a ventilation system is critical to ensure the mine meets its scheduled production and, as important, is vital to the health and safety of all personnel working underground. Those operating the mine ventilation system must have fundamental engineering training in the art of fluid dynamics and have a good comprehension and control of the mine ventilation network. Ventilation management by untrained and inexperienced personnel may result in serious consequences when the system becomes ineffective. This paper shares observations and experiences pertinent to the occurrence of upset conditions as a result of the improper design and operation of mine ventilation systems. A series of real life case studies are presented to describe disruptions to mine ventilation systems and the gradual deterioration of system operational efficiencies leading to eventual failure. Special focus is given to mistakes made and on the resulting serious consequences. The case studies also demonstrate how each upset condition was resolved, permitting the mines to safely resume production activities.INTRODUCTIONThe ventilation of operating mines is a continuously changing and evolving system; upset conditions will occasionally occur, but should be promptly resolved in order for the system to function properly, according to design, and in compliance.Those designing, managing or operating the mine ventilation system must have pertinent training and have a good understanding of fundamental ventilation concepts to be able to devise and implement engineering solutions to day-to-day challenges. Realistically, the operator must also have extensive practical experience and be able to effectively apply operating procedures, design criteria and ‘best practices’. They must be able to, on a daily basis, evaluate the mine ventilation system, determine and locate any problems, understand the causes of each problem, find a solution, and promptly and efficiently correct those problems.Ten case studies are presented to demonstrate how fundamental design or operational mistakes can lead to adverse conditions or to catastrophic consequences, how detailed on-site engineering assessments can be employed and how simple, low cost, engineering solutions can be implemented to successfully resolve the issues and return the ventilation system to compliance, permitting the mines to safely resume production activities."

Jan 1, 2019

By J. F. Vynne

ABSTRACT This paper examines several of the systems and processes that have been developed over the past few years and are now being utilized by major mining companies on draglines in North America, Australia and South Africa. These technologies include production monitors and reporting systems, GPS navigation systems, structural integrity monitoring systems, structural analysis studies to increase the dragline rated suspended loads (RSLs) and inspection and response strategies. The use of these technologies provides significant increases in dragline production and reduces maintenance costs, downtime and the chance of a catastrophic failure.

Jan 1, 2010

By Vladimir N. Rudashevsky, Louis J. Cabri, Nikolay S. Rudashevsky, Thomas Oberthür

"EPD (Electric Pulse disaggregation) and HS (hydroseparation) are exceptional technologies for research, concentration, evaluation, and mineral extraction of specific minerals such as precious metals (Au, Ag, PGM), kimberlites (extraction and concentration of indicator minerals), zircons and baddeleyite (recovery of objects for geochronology), and even gemstones (method of evaluation and production of the 100% gemstone concentrate of ideal crystals) etc. EPD is used for recovery of pristine undamaged crystals of diamond, emerald, ruby, sapphire etc, including large crystals. It was tested on various hard ores and was especially successful for recovery of “soft” minerals from “hard” matrix. EPD products are very convenient for HS processing, resulting in representative concentrates of all heavy minerals including the finest particles (5-10 µm). The combined EPD and HS method enables high sensitivity (20 ppb) for evaluation of precious metal ores providing objective information about original grain size, associations, and recovery using a very small amount of sample (1-3 kg). Latest developments of EPD and HS techniques at CNT Mineral Consulting Inc. include the HS-21 hydroseparator (50 kg/hr) and the Spark-21 EPD (5 t/hr), which enables use of both techniques for prospecting and mineral processing of industrial size samples of certain ores.INTRODUCTIONThe main task for mineral processors is to find a reliable technology for testing of mining feasibility and the efficiency of mineral extraction procedures. Among various mineral processing approaches of extraction and concentration there are two alternative cost-effective methods that can be described as the most environmentally benign and complementary: electric-pulse disaggregation and hydroseparation. These techniques were tested on many different ore types and process products with great success providing a precise and comprehensive mineralogical determination of different accessory precious metal and other useful minerals constituent in rocks, ores, and tailings.This article describes several examples of EPD and HS use: native gold from the Kostomuksha deposit (Karelia, Russia), a Ag-Au deposit in South America, zircons from ancient ultramafic igneous rocks of SW Greenland, bauxites of West Australia, PGM from the Driekop dunite pipe and gemstones (ruby, sapphire, emerald and demantoid) from different deposits."

Jan 1, 2008

By L. R. Fyffe, D. R. Lentz, S. H. Mcclenaghan

"Abstract - The Eel River area in the southwestern Miramichi terrane of New Brunswick contains a complete calc-alkaline suite of volcanic rocks that are interlayered with intervals of sedimentary and polylithic fragmental rocks, and are overlain by a thick sedimentary sequence. This package, collectively referred to as the Meductic Group, was deposited in a submerged volcanic arc setting interpreted to be part of the Popelogan arc. Rifting of this arc led to the development of the Tetagouche-Exploits back-arc basin, and formation of volcanogenic massive sulfide deposits in bimodal volcanic rocks of the Bathurst Mining Camp in the northeastern Miramichi Terrane. Unlike the Bathurst Mining Camp, volcanic rocks in the southeastern Miramichi Highlands form a continuous calc-alkaline suite characterized by increasing Zr/TiO2 with increasing SiO2, in part resulting from progressive coupled assimilation and fractional crystallization of nested magma systems. Slumping of semi-consolidated volcanic and sedimentary rocks in topographically unstable areas resulted in numerous slumps and debris flows that are preserved throughout the Eel River area. In the early 1990s, the discovery of a large sulfide clast in a road cut along the Benton road sparked interest in the volcanogenic massive sulfide potential of the Eel River area. Subsequent drilling intersected smaller fragments, one clast of which graded 16.7% Zn, 5.6% Pb, 90 ppm Ag, and 220 ppb Au. The intersection of thin lenses of stratiform sulfides in another drillhole indicates favorable conditions for the preservation of massive sulfides. Their subsequent incorporation into synvolcanic debris flows resulted in the transport and deposition of sulfide clasts from hydrothermal vents to more distal locations. Similar to the Buchans deposits of Newfoundland, tracing these debris flows back to their source would be beneficial from an exploration perspective. Approximately 15 km to the southwest of the Eel River area, gold-bearing base metal sulfide clasts (11.1% Zn, 6.13% Pb, 0.19% Cu, 108 ppm Ag, and 1100 ppb Au) occur within intermediate-composition volcanic rocks at Monument Brook in eastern Maine. Sommaire - Le secteur d’Eel River dans le sud-ouest de la terrane de Miramichi au Nouveau Brunswick contient une séquence complète de roches volcaniques calco-alcalines interstratifiées avec des roches sédimentaires et fragmentaires polylithologiques, sous une épaisse couverture sédimentaire. Cet assemblage constitue le Groupe de Meductic, et a été déposé dans un environnement d’arc insulaire interprété comme une partie de l’arc de Popelogan. Le rifting de cet arc à mené au développement du bassin d’arrière-arc de Tetagouche-Exploits, et à la formation de gisements de sulfures massifs volcanogènes dans les roches volcaniques bimodales du Camp Minier de Bathurst dans le nord-est de la terrane de Miramichi. Contrairement au Camp Minier de Bathurst, les roches volcaniques des hautes terres du sud-est de Miramichi constituent une suite calco-alcaline continue caractérisée par un accroissement du rapport Zr/TiO2 à des valeurs croissantes de SiO2, résultant en partie de l’assimilation progressive et de la cristallisation fractionnée de systèmes magmatiques superposés. L’effondrement de roches volcaniques et sédimentaires semi-consolidées dans des secteurs topographiquement instables est à l’origine des nombreux slumps et coulées de débris qui sont préservés dans le secteur d’Eel River. Au début des années 1990, la découverte d’un large claste de sulfures le long de la route Benton provoqué un intérêt pour le potentiel en gisements de sulfures massifs volcanogènes dans les secteur d’Eel River. Des forages ont par la suite recoupé des fragments plus petits, dont un claste qui a retourné des teneurs de 16.7% Zn, 5.6% Pb, 90 ppm Ag et 220 ppb Au. Le recoupement de minces lentilles de sulfures stratiformes dans un autre forage indique des conditions propices à la préservation des sulfures massifs."

Jan 1, 2006

By Barbara Hendrickson

Outline ? Canadian Regulatory Update ? Turning the Corner: Background & Status ? Implications of U.S. Waxman-Markey bill for Canada ? Federal-provincial considerations ? Current certainties and uncertainties ?Turning the Corner? as Originally Proposed ? April 26, 2007 - the Canadian federal government announced Turning the Corner: An Action Plan to Reduce Greenhouse Gases and Air Pollution (?Turning the Corner?)

May 1, 2009

By N. Parnian

"Carryover of caustic soda (NaOH) in the steam path caused catastrophic failure of superheater 304H stainless steel tubes in a steam generator and led to an unexpected shutdown after just five months of continuous service of petrochemical following the start of production. The cause of the failure was studied, with a focus on the formation of sigma phase in the weld joint and effect of caustic embrittlement on stress corrosion cracking (SCC). The cracks were examined at the seam weld, heat affected zone (HAZ), and Ubend areas. Hardness was measured for the base metal, HAZ, and weld metal, and microstructures were examined using optical microscopy and scanning electron microscopy (SEM). Crack initiation is attributed to gouging on the precipitated carbide at the HAZ and also the formation of sigma phase in the weld metal, as shown by energy dispersive X-ray (EDX) analysis. In addition, cracking was propagated by caustic embrittlement because of residual stresses and hammering. Finally, the characteristic feature of fracture was illustrated by SEM fractography, and consists mostly of intergranular SCC and some quasicleavage transgranular. INTRODUCTIONThree key factors are needed for the initiation and propagation of intergranular stress corrosion cracking (IGSCC): a susceptible material, a corrosive environment, and sufficient stress. Although austenitic stainless steels are susceptible to sensitization and IGSCC, they are widely used in boiler and superheater tubes because of their high corrosion resistance, high oxidation resistance, acceptable mechanical characteristics at elevated temperatures, and low cost.Sodium hydroxide is injected to neutralize acidic constituents in the steam path, but caustic can concentrate in boiler tubes and attack the surface metal (known as gouging) even traces of caustic in the steam can deposit on surfaces and cause local concentrations of several percent (ASM handbook, 1992). Not only sensitized grains but also sigma phase formed in the weld metal can initiate caustic cracking. In this research, the cause of the failure of 304H stainless steel superheater tubes in a methanol petrochemical plant in Iran was studied with a focus on the effects of caustic embrittlement on IGSCC."

Jan 1, 2012

By L. X. Li

Coking coal producers often encounter variations in clean coal quality when mining multiseam deposits containing coals with different washability and coking properties. This paper describes how, for a single coal property, an initial clean coal specification with an ash content of 8.5% on an air-dried basis (ADB) and a free swelling index (FSI) of 5.5 can be improved to a specification with 7.5% ash content ADB and an FSI of 6. This is accomplished by sorting coal seams into two groups for processing and blending. A preliminary economic model demonstrates how this improvement enhances economic returns through a beneficial factor.

Jan 1, 2014