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By J M. Menacho, L Zhang, A Hoadley, L Verdugo, B Etschmann, W Bruckard

Since the introduction of Lithium-Ion Batteries (LIBs) in 1991, the market for lithium-ion cells has been driven by the high demand for portable electronic devices and more recently for batteries for the electric car industry. It is expected to grow rapidly to reach 2600 GWh globally by 2030 (US Government, Office of Energy Efficiency and Renewable Energy, 2021). However, there is a desperate need to recycle LIBs to recover valuable cathode materials and graphite. For this reason, several physical and chemical recycling technologies have been proposed to recover these materials from spent batteries. Amongst these, froth flotation technology is a potential cost-effective technology for separation of the graphite fraction from the lithium oxide components due to the natural hydrophobicity of graphite and density difference between graphite and cathode materials (Folayan et al, 2021).

Aug 24, 2022

Here, in what is partly a review and partly a personal viewpoint, I take stock of changes in emphasis and comprehension on the subject of basaltic volcanism in the decade that has passed since the completion of the landmark Basaltic Volcanism Study Project (1981). I concentrate attention on the relatively neglected physical-volcanology aspects (in 1988 it was still possible to publish a 340-page book on flood basalts with barely any mention of physical mechanisms).I adopt the useful unifying concept of "volcanic system" to embrace the invariably-present intrusions as well as the volcano; I consider controls exercised by magma-supply rate and modulator-mechanisms on the nature of the system;I emphasize that sheeted-intrusion complexes, consisting either of dikes or inclined sheets (depending on the ability of the system to expand laterally) occur in all eroded major systems and fuel geothermal systems; I show how constraints set by cooling of narrow intrusions cause such complexes to be wedge-like and produce considerable rotations; I consider the role of the level of neutral buoyancy in making magma chambers possible, causing lateral subsurface magma flow and localizing intrusions, while the LNB itself can be accentuated by intrusions; and I examine the possibility that underwater systems could have very different internal structures from systems on land.

Jan 1, 1990

Solar Salt, Lunar Ambitions I Bauerti The title of this paper is `Solar Salt, Lunar Ambitions'. It is largely the result of a lack of imagination and a tight deadline. I was seeking a catchy title to convey the image of being 'here' and wanting to get `there', with `there' being a long way away and our being held 'here' by powerful gravitational forces. I tried `Solar Salt, Lunar Landings', but that implied we had already reached `there' when, on reflection, we had not. A colleague suggested 'Solar Salt, Luna Park' which is a fun park in Sydney and, I must admit, there was appeal in the image of having embarked on a wild roller coaster ride with stomach-wrenching twists and turns and the only reward being a pair of sweaty palms, and a feeling of nausea. That's sometimes how it feels when you launch into change. In the end I settled for the more sedate `Lunar Ambitions'. It contained that suggestion of hope and continual striving which are central to the idea of best practice. I will discuss our experiences in this area shortly, but I would firstly like to provide some background to our business. The salt industry is steeped in history and tradition. As one learned commentator observed, common salt is 'a substance seemingly too ordinary to think about, yet it is the oldest of man's raw materials and the basis of some of his newest inventions' (Multhauf, 1978). From ancient times, salt was recognised as a key necessity of life and it has played a role in the rise and fall of governments throughout history. The Romans recognised its importance when they gave their soldiers money regularly to purchase salt, hence our modern word 'salary'. Today, while culinary use remains important, the main consumer of salt is the chemical industry (Figure 1).

Jan 1, 1995

By Hargraves A. J

At 4 MPa gas pres ure and 30°C the sorptive capacity of 10 selected Australian dried coal ranges from 17 to 23 m3/tonne of CH4 and 27 to 36 m3/tonne of CO2. Values for moist coals are about 25 per cent less. At 20°C, sorptive capacities are about 18 per cent greater. No clear relationship between coal rank and sorptive capacity was established.The permeability of coal to gas is dramatically reduced by progressive hydrostatic confinement. No single 'permeability' for a coal can be established because of relative affinities of coals and the gases (Ar, CH4 and CO2) used in experiments. Bedding plane permeability is significantly greater than permeability normal to bedding. Dependent on gas/coal combinations, permeabilities without confinement ranged from 150 to 0.05 millidarcies, and with 8 MPa hydrostatic confinement from 1.0 to 0.001 md. Generally, permeability is increased by reduction in temperature, and reduced by increase in moisture as one changes from Ar through CH4 to CO2. In retrospect, it is preferable to ubject permeability sample to 8 MPa hydrostatic stress only once, because changes occur in the samples and it is difficult to use other gases successively.The initial rate of desorption, DP, does not appear to be a reliable index of proneness to instantaneou outbursts for Australian coals.The methods used for determining quantitative gas-coal properties appear suitable and reliable for testing other coals.

Jan 1, 1985

I offer some comments which might complement the valuable recent paper by De Angelis et al (1987), on the newly discovered nickel-copper deposit at Radio Hill.The authors have accepted subdivisions and correlations by Hickman (1977, 1983) although they are disputed (Fitton, Horwitz and Sylvester, 1975; Horwitz, 1979; Horwitz and Guj, 1986).Also, in my opinion, more plausible correlations of the Sholl Belt with Whim Creek Belt have been shown, but not discussed, in Hudson and Horwitz (1986, Figure 1). Our suggested correlations and subdivisions have appeared in publications and reports which are not readily available, but it is gratifying to note that many of the observations and conclusions of De Angelis et al are consistent with our conclusions of the Whim Creek Belt.The units of the Sholl Belt (of Hickman, 1983), between the Sholl Fault (Shear Zone) and the overlying Mt Bruce Supergroup to the south, equate well with units of the Whim Creek Belt. A basalt, characterised by an abundance of vesicles and similar in many ways to the Wararnbi Basalt of Fitton, Horwitz and Sylvester (I975), is well developed at the base of the succession, particularly in the southern part of the area (Figure 1). It is overlain by acid tuffs (locally metamorphosed, such as at Whundoo Mine) and associated acid and mafic lavas, similar to those of the Mons Cupri area. The mafics in the succession are marked by the absence of the numerous cherty sedimentary intercalations, such as the Marble Bar Chert, which occur in the Warrawoona Group; and they also lack the intense chertification that is prevalent in all parts of the proven areas of Warrawoona Group rocks.The Whim Creek Group is overlain, locally unconformably (two to three km east of Mount Negri), by the Negri Volcanics which include here the Louden Volcanics (unit Abu of Hickman, 1977), (Horwitz, 1979). The negri volcanics are an alternating sequence of variolitic and quench textured lavas not dissimilar to the highest units of the Sholl Belt (Figure 1). They range from high-Mg basalt to tholeitic andesites (Glikson et al, 1986, pp 79 and 84). The whole succession of the Sholl Belt is estimated to be of the order of four km in thickness, more consistent with the two km thick (Horwitz, 1979, Figure 1) Whim Creek area sequence than with the much thicker Warrawoona Group sequences. The Whim Creek Group (including the Negri Volcanics) is considered to be a widespread grouping (Fitton, Horwitz and Sylvester, 1976; Horwitz, 1979; Horwitz and Guj, 1986) which is prevalent in the northern part of the Pilbara Craton. It is considered by these authors to include the Mallina Formation turbidites of the trough area of Ryan (1965). One component, the Mons Cupri Volcanic, is about 2.95 Ga (Richards and Blockley, 1984). Between the Sholl Fault and Egina, the Whim Creek Group is intruded by large ultrarnafic to granophyric ills of the Millindinna Complex (Fitton, Horwitz and Sylvester, 1975), dated at 2.860 ± 002 Ga by Gulson and Korsh (1983) near the Sherlock River (south side of Caines Well Granite area). The Millindinna Complex has been equated to the same magmatic episode as the layered complexes of the Sholl Belt by Fitton, Horwitz and Sylvester (1975, p 20).

Jan 1, 1988

By Blom MS

Two well-developed styles of mineralization occur in the Nevados del Famatina mining district, Famatina ranges, La Rioja province, Argentina. Porphyry molybdenum- copper-gold mineralization and high level acid sulphate alteration/mineralization (Nevados del Famatina) are related to intrusion of the Pliocene Mogote rhyodacite porphyry complex. High sulphidation epithermal mineralization (La Mejicana) is developed peripheral to the Nevados del Famatina deposit. Both are hosted mainly by the Ordovician Negro Peinado metapelites.At Nevados del Famatina, five mineralized fracture events have been identified and correlated with four distinct alteration assemblages. Stage I (barren quartz) and stage II (molybdenite¦sphalerite¦pyrite) mineralization are associated with a K-silicate alteration assemblage of K-feldspar+biotite+quartz+magneti te¦ilmenite¦anhydrite. Stage III (bornite+pyrite+sphalerite+molybdenite ¦chalcopyrite¦idaite) and stage IV (chalcopyrite+pyrite +sphalerite+gold¦tennantite-tetrahedrite) mineralization are related to a quartz-sericite assemblage of quartz +phengite+illite+pyrite+rutile. Stage V mineralization is divided into two substages. Stage Va (chalcopyrite +pyrite+sphalerite¦ tennantite-tetrahedrite ¦ tellurides ¦ gold ¦enargite¦famatinite¦stibnite¦molybdenite) is related to a sericite-clay assemblage of quartz+illite+kaolinite ¦montmorillonite¦alunite. Alunite-kaolinite alteration (alunite+pyrophyllite+kaolinite+ aluminum - phosphate -sulphate minerals ¦illite¦fluorite¦corundum¦anhydrite) occurs in the upper part of Nevados del Famatina associated with the later stage Vb (quartz+famatinite +chalcopyrite+covellite + chalcocite ¦ marcasite ¦ enargite ¦ luzonite¦sphalerite¦melnikovite) mineralization.

Jan 1, 1990

Major exploration companies can have a problem with what to do with small precious metal ore bodies located through exploration programmes. Low tonnage, but high grade, ore bodies too small to justify in-house development.1.2 Ban Ban Mining is a Sunshine Coast based partnership with considerable expertise in mining and earthmoving which specializes in the mining of small/medium size ore bodies on behalf of the tenement holder on a profit sharing or royalty basis.1.3 The partnership's first successful venture has been the mining and vat leaching of a small 40,000 tonne ore body with a head grade of 5 gm/tonne gold and 32 gms/tonne silver, situated near Ban Ban Springs in southeast Queensland.1.4 This paper looks at the low cost vat leaching method of treatment, as an alternative to CIP and CIL in the processing of low tonnage/high grade precious metal ore bodies.

Jan 1, 1990

By J Czerwinski, M Kasper, M Wyser, N Heeb

The VERT project 1993 - 1998 laid the technical foundation for curtailing the emission of fine particles from diesel engines at Swiss underground workplaces. The targeted maximum was 100 ¦g/m3 EC. Extensive laboratory and field investigations demonstrated that this specification is only attainable with modern diesel particulate filter (DPF) systems that almost eliminate particles in the entire lung penetrating size range from 20 nm to 2.5 ¦m. In January 2000, Switzerland mandated compulsory particle filters in underground workplaces, particularly in tunnelling, irrespective of engine age, size and type. After the implementation, the particle concentration in the respiratory air was below 40 ¦g/m3 EC, compared to earlier values of up to 750 ¦g/m3 EC. Deployed DPFs have proven filtration rates of 99 per cent in the entire size range of alveoli intruding particles. The DPFs are as durable as the engine, suffer no ageing and require minimal maintenance. The failure rate is below three per cent annually. Of the 6000 retrofitted construction machines in Switzerland, about 400 are deployed underground. Prerequisites for this quality are a sophisticated certification procedure, electronic monitoring of DPF operation and meticulous periodic exhaust gas inspection of the engines.

Jan 1, 2005

By Enga B. E

Following considerable laboratory studies concerning diesel particulate control systems for underground use, a Canadian program was initiated to implement practical, real-life systems. This program covers the application in seven mines throughout Canada, of a particulate control system, to 14 engine models from four engine manufacturers in 18 different vehicle types, for a total of 23 vehicles. Partially funded by the Canadian National Research Council (NRC), this program required detailed analysis of operating cycles, maintenance variabilities and installation problems. This paper summarizes the work carried out to date to define real-world targets and the success achieved so far in attaining practical underground particulate control.

Jan 1, 1988

TUNGSTEN occupies an outstanding position amongst metals to-day, for by its use modern manufacturing methods have received a wonderful impetus. The important part played by tungsten in the recent war is not generally recognized. It was tungsten steel, in the shape of highspeed tools, that kept our soldiers supplied with munitions of war at more than one critical period. Tungsten added the necessary hardness and durability to various metals which were indispensable for carrying the war to a successful conclusion. In the words of...

Jan 1, 1921

By Moort van J C

A new low-intensity magnetic separator which operates by spinning particles in a continuously rotating magnetic field is able to reduce particle entrapment of non-magnetics to an almost insignificant level. In such separators the removal of ma

Jan 1, 1997

By M Olsson, I Bergqvist

A Swedish table of blast damage depths has, in one form or other, been in use since the late-1970s. Its history and the underlying theory are described. New experimental and theoretical findings that point out a number of shortcomings in the table and the underlying theory are presented and discussed. A revised version of the blast damage table was recently introduced in conjunction with new but incomplete recommendations for cautious perimeter blasting. The new table leaves the difficult task of taking into account factors like decoupling, water in the borehole, the rock properties, type of initiation, charge length and the actual bit diameter to the user. This paper discusses different ways of doing this, based on the experimental findings and a recent formula for the prediction of the lengths of radial cracks behind the half-casts. The material presented in this paper is meant to supplement and extend the new Swedish recommendations for cautious perimeter blasting of tunnels, shafts, pits and road cuts.

Jan 1, 2001

New Zealand is an exposed part of a sub- continent that was detached from Australia when the Tasman Sea opened in the Late Cretaceous. The pre-separation rocks occur in three main belts. A western belt or terrane was part of Antarctica, was continuous with southern Australian rocks, and was moved eastwards in the Mid Devonian. A central belt of Hokonui and Caples rocks can be correlated broadly with the Gympie Terrane of eastern Queensland. It was an island arc, fore-arc basin and accretionary wedge system, and it was accreted to eastern Australasia in the Mid Triassic. The third belt consists of Torlesse rocks and was possibly emplaced over the Caples rocks by at least three pulses of strike-slip, in the Triassic, the Jurassic and the Cretaceous. The three episodes of strike-slip can be correlated with regional events in eastern Australia. Pre-Cainozoic New Zealand was an amalgam of terranes that had moved eastwards from south of Australia and southwards from east of Australia.

Jan 1, 1987

By J P. Wyethe, D P. Padayache, B R. Green

The development of an ion exchange process for the recovery of vanadium from solutions containing low concentrations of vanadium and/or slurries is discussed. The process can be used to improve overall vanadium recovery throughout the plant, and/or to reduce the vanadium concentration of waste materials prior to their disposal. The development of the process on a laboratory and miniplant scale is discussed, and includes:selection of a suitable resin with the desired loading and elution characteristics; laboratory-scale testwork to evaluate the use of the resin in both resin-in-pulp and fixed bed configurations; recovery of a high-value vanadium product from the resin eluate; and a preliminary techno-economic assessment of the financial viability of the process.

Jan 1, 2000

By E Mofya, R Kaunda, P Lever

One of the fundamental requirements for being able to optimise blasting is the ability to predict fragmentation. An accurate blast fragmentation model allows a mine to adjust the fragmentation size for different downstream processes (mill processing versus leach, for instance), and to make real time adjustments in blasting parameters to account for changes in rock mass characteristics (hardness, fracture density, fracture orientation, etc). A number of blast fragmentation models have been developed in the past 40 years such as the Kuz-Ram model (Cunningham, 1983). Fragmentation models have a limited usefulness at the present time because:The input parameters are not the most useful for the engineer to determine and data for these parameters are not available throughout the rock mass. Even if the input parameters are known, the models still do not consistently predict the correct fragmentation. This is because the models capture some but not all of the important rock and blast phenomena. The models do not allow for ætuningÆ at a specific mine site. This paper describes studies that are being conducted to improve blast fragmentation models. The Split image processing software is used for these studies (Kemeny, 1994; Kemeny et al, 1999).

Jan 1, 2001

By Das A. K

Investigations were carried out to understand the effect of liquid viscosity (u = 1 x 10-3 - 5 x 10-' Ns/m2) on the size of primary bubbles formed at high gas injection rates (Q = 100 - 1000 cc/s, U = 0.04 - 0.42 mach) under room temperature conditions using flush tuyere (3 mm diameter) operating vertically upward. Tuyere pressure fluctuations were correlated to the mode of bubble formation by simultaneously filming the bubble and the corresponding tuyere pressure fluctuations displayed on an oscilloscope screen. A simple mathematical treatment is presented to estimate bubble size in viscous liquids. The theoretical results are compared with the experimental measurements.

Jan 1, 1987

By M Denton, M Rheinlander, S Mundell, M Broadgate

The manufacturing industry reinvented its approach to the manufacturing process by managing and measuring it end-to-end. This improved returns on production assets, improved information quality and reduced delivery time, resulting in larger net profits through cost reduction and improved cash flow. Today this approach is standard in the manufacturing industry. Resource development has many requirements in common with the manufacturing production line. These include: control of the various steps, transparency of the state of the process to various levels of the organisation and the overall efficiency with which the process is executed. The authors argue that the introduction of manufacturing execution systems (MES) concepts and technologies to resource development processes will lead to similar improvements in control, transparency and efficiency and could improve profitability and enable staff to work more effectively and make better decisions.

Jan 1, 2009

By Holla L

There exist several legislative provisions in N.S.W. which work together to control surface subsidence due to extraction of coal by underground methods. The important ones are the Coal Mining Act, Coal Mines Regulation Act, Mine Subsidence Compensation Act and Dams Safety Act. In addition, there are guidelines laid down by the Chief Inspector of Coal Mines for mining under and in the vicinity of tidal waters and the ocean. There are also conditions of coal mining leases and conditions of approvals given to undertake various methods of mining which stipulate further controls. The legislative provisions and relative controls are designed to minimise surface damage, ensure safety , of major public utilities, control- surface land use and compensate damage caused by subsidence as a result of coal mining operations. They aim at balanced and responsible development of our valuable coal resources consistent with adequate safeguards to surface improvements and natural features. The paper discusses in detail these legislative provisions and the mechanics of their operation with a view to emphasising the fact that underground coal mining operations are undertaken responsibly and in a planned and rational manner for the overall benefit of the community. Further, the paper aims to demonstrate the need for legislative measures and conditioning of mining operations to keep abreast of developments in the knowledge and skills of mining and subsidence engineers and continuing improvements in mining technologies. Likewise there is a need on the part of engineers and those associated with introduction of new technologies to appreciate the requirements and existence of legislative and other measures having a direct or indirect association with surface subsidence as a result of coal mining operation.

Jan 1, 1986

As a number of underground fires have unfortunately happened in the Broken Hill mining district, the writer trusts that a paper dealing with such a subject may prove of interest. To simplify matters, the subject is classed under three mainheadings- I Origin of fires; II Methods of subduing them; III Precautions to minimize the risk of their occurrence.Underground fires may be started in three ways - arson, spontaneous combustion, or carelessness.With regard to the first-mentioned cause, direct evidence is usually lacking to prove that any fire has been caused maliciously; Though definite proof of spontaneous combustion having been the cause of a mine fire has not been brought forward, nevertheless it should be considered, especially in the case of sulphide ore bodies of a more or less friable nature. The writer has been informed on reliable authority that in an open stope on the...

Jan 1, 1911

While specific definitions of the main categories of mineral reserves and mineral resources are becoming well established through the efforts of the Australasian Joint Ore Reserves Committee (JORC) and the Combined Reserves International Reporting Standards Committee (CRIRSCO), there has been perhaps less attention paid to the standardisation of language used in the definition and reporting of Mineral Exploration Results and a clear understanding of the transition to Inferred Mineral Resources. This is an area of significant importance to small and medium sized enterprises in the mineral exploration sector as it represents in many cases the only tangible information by which the reader or potential investor can evaluate the future potential of such enterprises. By its very nature information in the Mineral Exploration Results category is incomplete, and frequently complex, and it is open to a broad range of interpretation by readers of various competency levels and disciplines. Many will have a short-term speculative view rather than a long-term perspective, with others out deliberately to misrepresent the information, and as such it can have an enormous impact on investment decisions if the risks associated with this information being reported are not fully understood. Authors of reports on Mineral Exploration Results, who may be Competent Persons or company directors, have to put themselves in the shoes of the reader of the report, second-guessing if you like what the reader will understand by a report, which in many cases will be of a highly technical nature. This raises reporting dilemmas and questions that require to be understood and addressed. Looking at reports on Mineral Exploration Results from the other side, readers have a degree of responsibility as well, particularly if they engage in an advisory or communications role. The tendency of commentators, journalists, analysts, and bulletin board posters to over-exaggerate the significance of a particular exploration result is all too familiar. Questions arise here as well about whether there should be more regulatory supervision and control exercised over those who use this information, all of whom greatly influence investment decisions, and many of whom have no idea there is a Reporting Code, far less an understanding of it. Examples are given and questions raised to illustrate the dilemmas surrounding the reporting of Mineral Exploration Results. In order to retain credibility with markets it is incumbent on companies to be transparent, not to be selective and to report all material information. On the other hand, information has to be taken and read in its proper context in order to avoid fuelling dramatic and unjustified company share price escalation. Timing of course is another factor that can affect the market price of shares, which may be beyond the control of those making the reports. Emotive and imprecise language, however, when reporting Mineral Exploration Results, coupled by speculation, can trigger damaging short runs on shares and destroy credibility where formerly there was long-term promise. The paper will review how Mineral Exploration Results are dealt with in various jurisdictions, and conclude that there has to be a balance between prescription and the tempering of undue optimism on the one hand, and the entrepreneurial spirit, which the industry needs, on the other.

Jan 1, 2002