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By S Sineva, E Jak, M Shevchenko, D Shishin

This study represents a part of comprehensive research aimed at integrating nickel into a thermodynamic database constantly developed at Pyrosearch. The behaviour of Ni in calcium-ferrite slags is considered. An integrated approach combining experimental and thermodynamic modelling methods has been employed to predict phase equilibria in the NiO-CaO-FeO-Fe2O3 system under oxidising conditions and in equilibrium with the metal FeNi phase. The compositions of liquid slags and coexisting solid solutions have been determined through the analysis of equilibrated and quenched samples by electron probe microanalysis technique (EPMA). The research results are presented in the form of liquidus projections on the corresponding phase diagrams, considering both oxidising and reducing conditions. The solubility of Ni in spinel, dicalcium ferrite and calcium oxide as well as solubility of Fe and Ca in Ni monoxide, have been examined under several atmospheric conditions. Additionally, the compositions of the NiO-FeO monoxide in equilibrium with metal phase have been studied. The experimental data not only support the outcomes of thermodynamic modelling but also validate the parameters of the applied thermodynamic models, thus confirming the reliability and accuracy of the integrated approach.

Aug 21, 2024

By S Grano, M Fordham, H Manouchehri, J Curral

This paper focuses on the impact of high pulp temperature on sphalerite flotation after the zinc regrind circuit in the Zinc Plant of Somincor, owned and operated by Lundin Mining Corporation. In the zinc circuit, the zinc rougher concentrate is reground with forged steel media before flotation with one stage of roughing and scavenging, and three stages of cleaning to obtain a zinc final concentrate (zinc grade >50 per cent). After regrinding, sphalerite flotation has been found to be seriously affected by high pulp temperature which may occur during the summer months. Mineral recoveries were found to be seriously reduced at pulp temperatures above 60¦C. At this high pulp temperature, neither elevated copper sulfate concentration nor a decreased pH alone appreciably increased Zn recovery. However, a combination of these two (eg a decrease in pH from 11.5 to 10.8, and an increase in copper sulfate dosage from 400 g/t to 800 g/t) was found to reduce Zn depression at high pulp temperature. At pulp temperatures below 45¦C, the negative influence of pulp temperature on mineral recoveries was minimal. A systematic series of flotation tests and solution/surface analyses were performed to reveal causes for poor sphalerite flotation at high pulp temperature after regrinding. The decrease in mineral recovery was shown to be associated with variations in the surface species on mineral particles in response to the increased pulp temperature. These variations in the surface species include collector desorption and superficial oxidation to form lead/zinc oxide/hydroxides on mineral particles. The influence of the type of regrinding media on sphalerite flotation at high pulp temperature was also addressed in this work.

Jan 1, 2008

By Cooper W. C, Stokes M. A

Proterozoic gold deposits in the Pine Creek Geosyncline are at present receiving renewed attention with the opening of old mines and several new discoveries. This important polymetallic province contains occurrences of gold, base metals, tin, tungsten, tantalum, platinum, palladium and aluminium. These resources have been exploited over the past century with periods of major interest during the turn of the century and during the past 20 years. Economically viable resources of predominantly gold, eg Pine Creek, Woolwonga, Brocks Creek and Union Reefs, and Ag-Pb-Zn, eg Woodcutters are currently in development or being mined. A variety of genetic models, ranging from magmatic through hydrothermal to syngenetic, have been postulated in the past for the formation of gold deposits in the Pine Creek Geosyncline. The first discussion on the regional geological factors that control ore deposition in the Brocks Creek-Howley District was by Sullivan and Iten (1952). They recognised that the most important ore deposits are associated with anticlinal and domal structures and that granites may be a controlling factor in the localisation of the mineralisation. More recently a group of authors, Needham and Roarty (1980), Goulevitch (1980), Nicholson and Eupene (1984), Sanger-Von Oepen, Friedrich and Kater, (1988), Nicholson and Eupene (1990) and Kruse, Whitehead and Mulder (1990) have suggested an exhalitive syngenetic origin, or remobilised syngenetic during dolerite intrusion and/or regional deformation, for gold mineralisation, especially those associated with South Alligator Group lithologies (eg Bridge Creek, Mt Bonnie group of mines and Cosmopolitan Howley). Studies carried out at the Bridge Creek and Western Arm Prospects over the last three years suggest that syngenetic models for gold mineralisation are less relevant to gold mineralisation in the Howley District than first thought (Wall, 1989; Partington, 1990). The Bridge Creek prospect has been cited as an example of a syngenetic-syngenetic remobilised deposit (Oepen, Friedrich and Kater, 1988) while the Western Arm prospect is more clearly a vein hosted epigenetic deposit and a comparison of the styles of mineralisation at both prospects will be made. The nature of the gold mineralisation at both prospects will be described and compared, and possible genetic models for gold mineralisation and their relevance to regional exploration discussed.

Jan 1, 1994

The mathematical modelling of rock fragmentation by blasting is one of the most difficult and challenging problems of applied mathematics. Not only is complex mathematics required but there is incomplete understanding of the basic physics and chemistry involved. The possibility of getting the physical basis of a model correct by simple mathematical and experimental procedures is demonstrated for the novel process of fragmenting rock by high-pressure arc discharges. While the importance of obtaining the correct physical basis for a model is emphasised, high-pressure arc induced fragmentation of rock is shown to be a powerful laboratory tool for the study of blasting.

Jan 1, 1990

By Quan P. M

The great advances made in the application of solvent extraction to the recovery of copper from low grade ore sources over the past 15 to 20 years are well known. Solvent extraction is an essential step in the recovery and purification of copper from dilute sulphate leach solutions by which some one million tonnes of copper are now electrowon annually. A reagent is also available for the selective recovery of copper from chloride leach solutions and this may hold the key to the processing of complex sulphide ore concentrates. By comparison, the use of solvent extraction in the recovery and processing of zinc has as yet found little favour and is confined to only a few specific and comparatively small applications. This is despite the ready availability of a large number of low grade zinc sources and zinc-bearing wastes and residues. It is suggested that this difference is due in large part to the absence of suitable reagents having the particular features required to enable them to fit into a solvent extraction - electrowinning based process for zinc. Ideally, for the recovery of zinc from dilute sulphate solution, an extractant should operate on a proton exchange principle and be strong for zinc in the same way that o-hydroxyaryloxime reagents are strong towards copper. It should load efficiently with zinc at the pH of typical sulphate feed streams without the need for neutralisation and yet be stripped efficiently by spent zinc electrolyte. Another factor of major importance for many applications, however, is that it should be highly selective for zinc over ferric iron. These features have now been realised in a development extractant DS5846, which is a formulation of a novel class of reagent currently under investigation by Zeneca Specialties. The properties of this reagent are described with respect to selectivity, isotherms and how they compare with phosphoric and thiophosphoric acids that have been previously proposed for the extraction of zinc. For the recovery of zinc from concentrated chloride solutions a solvating or neutral donor type of extractant is required which again should ideally have high selectivity for zinc over a number of other metals, particularly iron. The new reagent Acorga ZNX50 is based on a formulation of a novel class of compound developed specifically for this purpose. It gives efficient extraction of zinc from feed solutions that are four to six molar in chloride ion but is readily stripped at 60 - 65¦C using either water, dilute brine, or spent zinc chloride electrolyte. The reagent is highly selective for zinc over iron and a range of other metals including cadmium, arsenic, lead and magnesium.

Jan 1, 1993

Low-grade, porphyry copper type mineralization at the Moonmera prospect is related to the intrusion of a granodiorite porphyry mass into the Upper Permian "Gracemere granodiorite". Significant copper mineraliza- tion appears to be associated with the alteration assemblage quartz-sericite- kaolinite. The ore shell is surrounded by a zone where montmorillonite and kaolinite are in greater abundance and this assemblage is over- lapped, mainly at depth, by potassium feldspar alteration. Secondary biotite is abundant throughout the mineralized zone. Preliminary sulphur isotope results on the sulphide mineralization are compatible with a magmatic origin for the sulphur.

Jan 1, 1974

By Koppe JC, Strieder AJ

The Rivera Crystalline Island (RCI) is an erosional window of the intracontinental Parana Basin that outcrops in the Rivera Department, north of Uruguay. RCI is made up mainly by Precambrian granites, metasediments and granite-gneisses. This island is crosscut by a dextral transcurrent shear zone system, the Rivera Shear System (RSS). The bulk strain ellipsoid was defined by previous work and has allowed the evaluation of shear dynamics. The geometry of the shear system is made up of two shear directions: E-W (P-shear), which turn right to NW-SE direction (R-shear), leading to the development of extensional bends. The shear zone system was developed in brittle-ductile to brittle regimes, under temperature conditions compatible with greenschist facies metamorphism. The shear zones are marked by an intensive fracture cleavage development. Mylonites develop only in narrow, discontinuous higher strain zones. Internally, the shear zones are dominated by intrusive rocks, mainly granites, dacites and diorites. Hydrothermal alteration has been developed in several areas.The economic significance of RCI is given by several small gold deposits, which have been exploited since 1869. One major new gold mine is under development, the San Gregorio Gold Mine. This gold deposit is locally controlled by a dilatant site where R-shear turns right to P-shear. Mine lithologies were deeply altered by hydrothermal fluids in the dilatant structure. This work presents the lineament-structural analysis carried out to identify similar structural patterns in all RCI sites favourable to host other gold deposits. The exploration program also considered remote sensing, geology, geophysical and geochemical survey.

Jan 1, 1997

Agglomeration pre-treatment is a new process now being used here and overseas whereby problems arising with the heap leaching of gold and silver from materials containing critical amounts of fines or clay can be simply and cheaply overcome. The technique involves mixing the material with a suitable binder, commonly Portland Cement, and tumbling the moistened material to agglomerate the fines. These agglomerates are placed on the leach pad and cured prior to leaching. Test results, plant and operating cost data are presented. INTRODUCTION Heap leaching is a low capital and operating cost alternative to conven tional processing techniques for gold and silver extraction. A number of commercial-scale operations have recently started in the United States and the method is being considered for further deposits there and elsewhere.

Jan 1, 1982

The detailed work done by Stillwell and Edwards on the occurrence of cobaltite and safilorite-Iollingite at the South Mine, followed by its presentation as a paper to the Institute, calls for, a few notes on its occurrence elsewhere in the Broken Hill field. No massive cobaltite similar to that in the South Mine veinlet is known except from the Consols Mine (as mentioned in the paper). Fine grained cobaltite has, however, been found in low-grade ore from the North Mine. Microscopic grains occur in a mineralized green feldspar pegmatite. The feldspar has been replaced in part by graphite, and the cobaltite occurs in association with the graphite. In its hardness, pinkish-white colour, and resistance to the standard etchingqeagents it is similar to the South Mine cobaltite; it is etched by acid permanganate solution. An interesting feature of this occurrence is the way in- which some of the minerals (notably galena) have forced apart the graphite lamellae in crystallizing, forming lenses enclosed by the curved cleavage surlaces 0;[ the graphite.StillwelI and Edwards cite a note by G. Smitht for the statement that "cobaltite has been recorded from the Australian Broken Hill Consols Lode in the vicinity of the rich silver deposits, though not in contact with them."Smith, however, is here referring to the oxidized zone. Elsewhere in the same article he states "... a deposit of cobaltite in a very much altered condition was found. This was impregnated with silver, and assayed as high as 3,000 ounces," Of the cobaltite in the unoxidized zone, Smith simply states that it became rarer with depth.Cobaltite has also been recognized by Mr. H. F. Whitworth, M.SC., Curator of the Mining Museum, Sydney, in specimens from Burt's Copper Mine eight miles south of Broken Hill.

Jan 1, 1944

The first stage in the refining of lead blast furnace bullion is the removal of copper and this is normally done as a batch process in open kettles,A number of attempts have been made in the past to establish fontinuous processes operating in reverberatory type furnaces, but the growth of accretions in the furnace has always presented a serious problem.This has been overcome in the plant of the Broken Hill Associated Smelters Pty Ltd at Port Pirie by the construction of a reverberatory furnace and ancillary cooling system of novel design.Although a number of mechanical and metallurgical problems still remain to be solved, it is claimed that a workable continuous copper drossing process has been established.

Jan 1, 1963

By Wu Y, Qu Q

The Central Coal Mining Research Institute has developed the MAE acoustic emission monitoring system, the BD4-1 portable acoustic emission monitor and the MRB rock burst monitoring system. In the MAE system there is an IBM-PLAT, a receiver and 16 channels and the investigating range is 100 m. The main functions are detecting acoustic events from the working faces, periodically making statistics, prints, displays and storing of the results, and performing the off-line process such as drawing the curves of acoustic activity. The BD4-1 instrument has four channels, it works for more than 24 hours continuously, and keeps the data for more than 30 days after power tum-off. The BD4-1 is suited to the monitoring for a long or a short time as a fixed point where the system is invalid, especially to the monitoring of the acoustic activity promoted by the blasting. There is an IBM-PC/AT, a receiver and 16 channels spread 10 km in the system MRB. The system could on-line collect microseismic events throughout the whole mine, calculate the source location and the energy, and off-line draw the seismic activity draft of time-based or distribution in space. In practice, the forecasting is successful by using the acoustic emission and microseismic monitoring system and the portable instrument.

Jan 1, 1991

By Scott A

The object of most blasting operations is to destroy the insitu structure of the rock mass so that mechanical equipment can efficiently excavate the rock fragments. In achieving this objective the blasting engineer is also concerned with minimising damage to the adjacent rock which forms the mine structure relied upon to provide support. Damage to this "structural" rock is undesirable but usually occurs as a result of two distinct processes: ò readjustment of stresses around the excavation as a result of the mining process itself ò impact of vibration and high pressure gases from blasting operations. Gross damage to mine structures from either cause is observed as visible alteration to the appearance of the rock structure in the form of cracking, slabbing, back or over break and visible displacement. Recent work at the Julius Kruttschnitt Mineral Research Centre (JKMRC) has shown that significant reduction in the strength of a rock mass can take place well before the onset of these obvious signs of damage. It has been demonstrated that the effect of blast damage on the behaviour of the rock mass can be many times more prominent than the effect of stress redistribution. This offers the blast design engineer the opportunity to significantly reduce blast induced damage to rock structure by modifying blasting practices. This paper introduces the current JKMRC postgraduate research projects investigating the evaluation and control of blast damage.

Jan 1, 1990

The Burragorang Valley lies approx. 95 km by road south west of Sydney and some 35 km west of Camden. It is over 80 km in length and varies in width from 3 km to over 16 km. Geologically, the history of the Burragorang Valley is of interest. It was referred to by early geographers and N.R.M.A. booklets as the largest sunken valley in Australia. This description is incorrect as it is a water worn valley formed by the dissection of an uplift in the south western portion of the large Sydney Sedimentary Basin. Ages2 ago there extended right across the Blue Mountains, a continuous tableland into which the Nattai, Wollondilly and Cox's Rivers have carved out the formation of the Burragorang. This dissection together with other valleys such as the Megalong, Jamieson and Grose, formed part of the eastward drainage pattern of the uplifting tableland into the Pacific ocean. The lapse of time since the streams in the Burragorang began their work of erosion can

Jan 1, 1976

To provide suitable backfill material for the cut and fill mining method being used to extract ore from the C.S.A. mine, flotation tailings are deslimed in single stage cyclones. The sand fraction is stored on the surface in unagitated storage bins before being pumped underground, while the slime portion is thickened and pumped to a residue dam. Design and operating details of the sand preparation and storage sections are given.The initial preparation of a stope for filling, consists of laying percolation and decantation drainage pipes on the sill floor. Preparation for fllling of subsequent lifts consists of rearing up the ventilation pipes at the ends of the stope, preparing the decantation system, and building a barricade or wall. The fill is carried to, and discharged into, the stope through 4 in. diameter pipes and filling of any section is carried out 24 hr/day normally without supervision. The fill is retieulated underground to the 1200 ft level through rubber lined pipe installed in the upcast shaft. Boreholes of 3 in. diameter drilled from the1200 ft level convey fill to the 1800 ft level. The mine drainage system is basically designed to handle the water associated with hydraulic filling. A system of primary and secondary sumps has been installed to handle the percolation and decantation drainage from stapes and to allow settling of fines before the water is fed to the main pump station.A programme of investigation into the properties of the emplaced fill is in progress. Results to date indicate that the fill as presently placed and drained, will not cause any problems in the mining of vertical orebodies by cut and fill methods for lifts in excess of 300 ft.

Jan 1, 1969

By B C. Povey

HPGR technology has been used at a number of magnetite mines in the world and have significant energy advantages over SAG and AG technologies. The early design at Los Colorados in Chile has been in operation for more than 12 years - and operates very successfully though only reduces the feed size to -5mmThe Whyalla project magnet design pushed the concept to produce a preconcentrate of 80%-350micron - a significant reduction on previous plants though with some wear problems in the early years. The Karara design backpedalled slightly and will only crush to 80%-1.8mm.However, the design issues of using a HPGR to further reduce the feed size continue to be explored. The aim is to reduce the process risks associated with wear and also to reduce the complexity of the downstream process - with consequent benefits in terms of capital and operating costs.The designs are being developed for a couple of projects - one planned to produce 20Mtpa of concentrate with the potential to not only remove SAG and AG milling but also ball milling. The concept is to use multiple passing through the HPGR since, on the data available, the efficiency of the HPGR to reduce size does not significantly diminish as the feed size is reduce. This can be have benefits in both capital and operating cost.CITATION:Povey, B C, 2013. Pushing the use of high pressure grinding rolls in magnetite circuits, in Proceedings MetPlant 2013 , pp 176-189 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 15, 2013

By Dickson T. J

Slag cleaning is an important part of the pyrometallurgical operations at the Kalgoorlie Nickel Smelter. It is a complex system with many streams of different phases and composition. Some of these streams are very difficult to control and/or monitor. Through the use of a statistical computer package, called Minitab, key relationships affecting the economical operation of the slag cleaning process have been found. Data for the statistical analysis was collected from all possible variables around the appendage.

Jan 1, 1991

By T C. McCuaig, D B. Mapleson

The Wannaway Deposit is a structurally modified komatiite-hosted nickel-sulfide deposit. Until recently, nickel sulfide accumulations surrounding the Widgiemooltha Dome had been studied with a focus on understanding volcanological aspects of komatiite flow regimes and nickel-sulfide accumulation. Although volcanological features can be observed at Wannaway they are overprinted by several generations of structures associated with multi-phase deformation of the Dome. On the mine scale, two significant deformational events can be distinguished that control ore distribution. The first deformational event is represented by the formation of a layer parallel foliation within the footwall metabasalt and boudinaging of the ore into two distinct orebodies (mega boudins) during a north-south compressional event. Evidence of a second compressional event (east-northeast-south-southwest) is defined by reverse > dextral thrust-folding of the ore zone. The latter deformational event focussed the sulfide ore into thrust front positions where folded ore sequences are mined with stope widths up to nine metres wide. Later stage compressional and extensional deformation phases are observed but have minor, localised effects on the geometry of the ore zone. Four orders of control on the geometry and distribution of ore are interpreted through a combination of primary and secondary features observed at Wannaway. Extending the structural aspects of the secondary overprint features into areas of potential mineralisation has not only defined targets for extensions to the Wannaway Deposit, but has also aided to delineate high grade mineralisation and aid mining decisions. Obtaining an understanding of the volcanological conditions of formation, and more importantly, the structural evolution of the Wannaway region has been an integral part in optimising production.

Jan 1, 2003

Upper Cretaceous and Eocene coal measures of the Ohai Coalfield are stratigraphically complex, and coal seam geometry and quality are influenced by washouts and partings resulting from accumulation in a fluvially active environment. Mining efficiency is influenced by these seam discontinuities, which are difficult to predict in the absence of refined paleoenvironmental models of peat accumulation. Petrographic variations between the Upper Cretaceous and Eocene coals indicate differences in the environments of peat accumulation. Seams in the Upper Cretaceous Morley Coal Measures accumulated autochthonously (in situ) in predominantly forest swamps with a high water table. These swamps were occasionally subject to brief floods. No significant changes in swamp vegetation, as indicated by petrography, have been detected between seams. In contrast, the greater content of mineral matter and maceral detritus within the Eocene Beaumont Coal Measure seams indicates hypautochthonous (locally transported) peat accumulation under more frequently flooded conditions. A precursor forest-moor is again indicated but the greater resin content of these coals compared with the Upper Cretaceous examples may suggest a greater contribution from conifers. Integration of coal petrography with investigation of other seam characteristics and coal measure sedimentology is expected to result in a detailed understanding of original depositional controls on peat accumulation. Paleoenvironmental models derived in this way should facilitate prediction of seam geometry, roof and floor conditions, and variations in coal quality, with obvious benefits to exploration and mine development.

Jan 1, 1983

By Wilson AC

Permian coal from Western Australia's only producing coalfield at Collie is the dominant fuel used in generating electricity for the State's interconnected grid. Collie coal is sub-bituminous, non-coking and has a low ash, medium volatiles and high moisture content. The seams were laid down in a fluvial basin which extended beyond the Collie Basin and included the Wilga and Boyup Brook Basins at least. Adjacent parts of the southwest Yilgarn Block are prospective for Collie-type basins. In the past few years significant deposits have been delineated within the Perth Basin, specifically on the Vasse Shelf and in the Hill River area. In the former area high quality steaming coals are correlated with the lowest coal bearing member at Collie. The seams are amenable to underground mining and because of their high quality, the coal may have export potential. Sub-bituminous coal deposits of Jurassic age are present in the Hill River area. Exploration has down-graded the prospectivity of the Carnarvon and Canning Basins for sub-bituminous near-surface coal deposits. Tertiary lignite deposits are present in palaeo-drainage systems in the southern part of the State and their potential for development is being evaluated.

Jan 1, 1986

By Chia A. H

This paper presents an overview of the development and operation of the PT Adaro Indonesia coal mining project. This operation is an initial two million tonne per annum mine, located in South Kalimantan, Indonesia.The paper places emphasis on some of the more unique infrastructure development and operational challenges that exist in such a remote location environment.A brief summary is also given of the Indonesian coal industry, its direction and position as a significant coal producing competitor for Australia.

Jan 1, 1992