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Hydrometallurgy has a history of over 300 years with copper leaching and cementation having been exploited in Spain as far back as 1670. Since then, hydrometallurgy has become an integral, expanding branch of extractive metallurgy. This paper reviews major developments in hydrometallurgy over the past century with emphasis on recent commercial developments and their impact on the mining and metals industries. The environment in which these developments has taken place has changed significantly in the past two decades and many factors, often non-technical, have emerged as constraints on the operation of existing plants and the expansion and development of new hydrometallurgical operations. Finally, a number of possible new developments that will shape the future of hydrometallurgy in the new millennium are discussed, particularly as they relate to the assimilation of technical advances in other areas of science and engineering. The impact of current trends in the education of hydrometallurgists and the provision of research in support of these future developments is also addressed.

Jan 1, 2000

By B Brattli

The dispersion pattern of heavy metals in soil and water is a consequence of complex geophysical and geochemical processes. Metal release from mining sites and subsequent migration occur primarily through acid mine drainage and erosion of waste and tailings dumps. Water plays a significant role in heavy metal mobilisation. Whilst it acts as a storage buffer for the pollutants, it is also the medium in which most of the reactions take place, and is undoubtedly the most significant transport vector in the pollution process. The intrinsic properties of the acidic drainage such as chemical composition, speciation of key mineral components, redox potential and pH are master variables controlling metal release, transport, deposition, reactivity and availability to biota. The mobility of heavy metals is strongly increased by acidification from acid mine drainage, and the discharge of these metals into the receiving waters results in numerous physical, chemical and biological responses in which the environment can affect the metal and vice versa. The result is an overwhelming number of association/dissociation, substitution, adsorption/desorption reactions, giving rise to a complex migration pattern. The attempt to understand and describe the dispersion pattern of heavy metals is complicated by the nature and level of interaction between the geochemical and hydrodynamic processes that generate and control the movement of the pollutants in the geosphere. Transport models which can be used to predict the behaviour of metal pollutants in a natural environment are still in the initial phases of development and their application to real life situations is limited. The Biochemical Cycle adds another dimension to the mobility of heavy metals. Metals form an important component of the food chain for man and plants. Biological uptake of metals from the bedrock and soil by organisms can result in migration paths very difficult to follow. Biodegradation or assimilation is just a tip of the iceberg.

Jan 1, 2003

The Central Andes in Peru, Chile, Bolivia, and Argentina, contain two contiguous terranes which were accreted i, Gondwanaland between the end of the Devonian and the end of the Triassic. These terranes, Arequipa in the north, anni Chilenia in the south, differ from each other in the timing and style of their metallogenic development. However, they contain over 90% of the Central Andean porphyry copper resource. The copper porphyries in the Arequipa terrane are Paleocene to lower Oligocene in age, whereas the Chilenia deposits are mid-upper Cretaceous and mid-upper Miocene. Porphyry copper deposits occur outside these terranes, but are all Miocene in age. Miocene porphyry-style mineralisation also exists in the Arequipa terrane, but is copper-deficient and gold-rich. The accreted terranes may have favoured porphyry and other styles of copper mineralisation because they possessed relatively thin continental crust compared to adjacent parts of the Andes. Crustal thickening which commenced at about 30 Ma in the Arequipa terrane coincided with a major change to polymetallic, precious metal mineralisation which commonly displays high sulfidation charcteristics.

Jan 1, 1995

By K Heiskanen

Flotation is affected by several factors, part of which depends on the mineralogical characteristics of the ore and part on process variables. Sulfide Ni-Cu ores occur typically in mafic and ultramafic igneous rocks. Serpentine minerals are also common. As a consequence of metamorphosis, sulfides and secondary minerals may be finely disseminated in an altered ore matrix. The floatability of minerals depends also on process variables. Oxidation of sulfide particles, process iron and dissolved ions in process water affect the behaviour of sulfides. The effects of some essential factors on flotation of Ni-Cu ores are considered.

Jan 1, 2005

By Shinnosuke U, Zhang HE

In this paper, it is shown that the higher the pre-activation concentration of copper ions in pulp, the larger the adsorption amounts of copper ions and xanthate on arsenopyrite surface, and the better the arsenopyrite flotability in strong alkaline medium. On arsenopyrite pre-activated with cupric ions, the xanthate adsorption density in strong alkaline medium is approximately equivalent to that of cupric ions. It is therefore concluded that an amount of copper ions adsorb on arsenopyrite surface first, and then an amount of xanthate can (and only can) adsorb dependently on the surface active sites produced by these adsorbed copper ions on the mineral, so that arsenopyrite is kept rather flotable and is hardly separated from pyrite even in very strong alkaline medium. Selectively wiping out the surface copper active sites on arsenopyrite is the key point of successful separation of pyrite from arsenopyrite. According to this theory, a new 'SZLI' (know-how) method was recommended to satisfactorily deal with the difficult separation.

Jan 1, 1993

By M M. Tarshan

Separator performance is evaluated by the so-called separation efficiency. The concept of efficiency in mineral dressing operations must be interpreted with considerable care. Although qualitative use of term efficiency is valid and useful, difficulties arise in expressing it quantitatively because two conflicting criteria, grade and recovery are normally involved in its evaluation. It is undesirable to express efficiency as a single value, even though this is frequently done in practice, since there are strictly speaking an infinite number of combinations of grade and recovery that can give that one value. Inefficiencies in processes can be attributed to three broad sources: mineral limitations as represented by the separability curves, equipment limitations (which prevent the maximum separation indicated by the separability curves), and human failure to minimise these inefficiencies. In the present paper, the efficiency of a two-constituent separation process has been examined. The separation process has been evaluated by comparing the sharpness factor of the actual, the absolutely efficient and the absolutely inefficient operations.

Jan 1, 2000

Higher commodity prices and environmental considerations will make selective narrow-vein mining more attractive in future. Unfortunately, hand-held airleg (jackleg) mining is a mature technology that has safety and productivity limitations. Despite decades of attempted innovation, no obvious successor to airleg mining has emerged. A review of some of the possible technologies is followed by a speculative description of the mine of the future, intended to stimulate thinking and discussion during the conference.

Jan 1, 2008

By Gillies A. D S

Technology transfer is a vital requirement for increasing national capability of coal mine production in Indonesia. The term can cover the introduction of new equipment, facilities and processes and approaches to training and education. Constraints on technology transfer within the Indonesian coal mining industry are reviewed. The contributions that foreign companies working within the industry can make are discussed. It is concluded that the development of major Indonesian coal mines needs input of advanced foreign technology. The foreign mining companies are investing significant capital in operations and are permitted to import outside expertise due to some lack of national skills. Expatriate employees are expensive and have a direct effect on profitability. The success of any replacement program of foreign employees is dependent on technology transfer. There are statutory Indonesian Government directions to reduce dependency on foreign expertise over time.

Jan 1, 1995

By A B. Bell

The health and in some cases survival of mineral exploration and mining companies is, in today's markets, more dependant than ever on the effective use of information technology. The need for speedy collection, organisation, maintenance and distribution of corporate and project information is a phenomenon that will continue to strengthen with market thirst.Geographic Information Systems (GIS) provide a medium for storage, maintenance and retrieval of data, and Internet Mapping adds a technology for effective distribution of that data. Combining these technologies can return benefits both fiscally and technically by reducing costs of ownership in IT infrastructure and increasing the efficiency and effectiveness of both internal and external information delivery.GIS and Internet Mapping technologies have reached a practical stanza in their evolution and will continue to develop as a key business tool in the natural resources sector.

Jan 1, 2002

By Mckenzie CK

Delay scatter, although widely recognised, has rarely been studied with the aim of critically reviewing blast designs. With current trends towards increased deck charging, and the effect on the number of separate delays in blast designs, delay scatter is shown to have a rather profound influence on the control of initiation sequence and the ability to successfully con- duct pre-splitting and smooth blasting. Determination of realistic delay scatter distributions is the first step towards application to blast design. Delay scatter must be evaluated in terms of deviation from the nominal time, not in terms of deviation from the batch mean, since the latter is not usually known without specific testing, requiring accurate timing instrumentation. Computer programs using Monte Carlo simulation can then be developed to investigate the probabilities of out-of-sequence initi- ation or near-simultaneous initiation within any specified interval. The procedures have been applied to both production and development blast designs in Australia and Chile to improve initiation sequence control and to rationalise and simplify blast designs.

Jan 1, 1988

External pressures are being exerted on busi- ness, and especially the mining and energy in- dustries, as never before. These pressures are burdensome, they emerge in unique forms, and they constitute an entirely new operating environ- ment for business. They pose one of the signi- ficant challenges to senior management today. To cope with these pressures-which we have termed the new public realities-we must deal more effectively with the media, the public, and government. However, before examining methods for improvement, it is essential to understand the nature of these new public realities and par- ticularly their determinants-the underlying eco- nomic, sociological, political, and international events and trends which have shaped them. Previously the productive element of society had only to concern itself with what might be termed `conventional realities' : the costs of labour, equipment, and land, as well as marketing and distribution factors.

Jan 1, 1978

The hazard posed by underground mine fires is illustrated in the first part of this paper by means of a review of experiences in four mining countries over the last three decades. This brief review indicates that while much progress has been made generally in preventing fires and providing means of protection to miners, the possibility of disasters occurring must continue to be regarded as very real. Based upon recent investigations by the South African mining industry, an integrated strategy for providing protection to personnel in the event of a fire is outlined in the second part of the paper. The main, complementary, elements in this strategy are the prevention of ignitions, the limitation of fires, provision of protection systems and equipment, training for emergencies, and effective implementation of safety measures. Some comments are made on important aspects of these elements and on possible further developments.

Jan 1, 1988

By J Garritsen, P F. Wells, M Xu

IncoÆs Clarabelle mill currently processes ores from eight mines in the Sudbury basin area in Ontario, Canada. The ore from the Garson mine contains a much higher concentration of arsenic than the other ores. Adding this ore into the feed to the mill has resulted in an increase in arsenic content of the Cu-Ni bulk concentrate to a level that significantly affects the smelter operation, and more importantly the efficiency of Cu-Ni separation in the Matte separation plant. The arsenic occurs mainly as gersdorffite (NiAsS), with a small amount being in the form of cobaltite (CoAsS). Extensive laboratory tests on depressing arsenic in Garson ore flotation have been conducted and two reagent suites have been identified as effective arsenic depressants. One is the so called MAA depressant which is a mixture of magnesium chloride, ammonium chloride, and ammonium hydroxide. This reagent combination was reported to depress other arsenide minerals such as arsenopyrite (FeAsS) and enargite (Cu3AsS4). However, in this study for the first time it has been shown to have a depressing effect on gersdorffite. The other reagent suite, a mixture of triethylenetetramine (TETA) and sodium sulfite, that has been reported as an effective pyrrhotite (Fe1-xS) depressant in pentlandite ((NiFe)9S8) flotation, has not been reported as gersdorffite depressant before. The effectiveness of both reagent suites is more pronounced when the arsenic minerals are oxidised through pulp aeration or the addition of hydrogen peroxide. With a flow sheet consisting of a magnetic separation, rougher- scavenger flotation, followed by regrinding and cleaning of combined magnetic and scavenger concentrate, the arsenic recovery to the final Cu-Ni bulk concentrate was reduced from 73 per cent in baseline test to less than 30 per cent with either reagent suite at no decrease in nickel recovery. The TETA/sulfite reagent combination has the advantage over the MAA suite in that pyrrhotite is also depressed, rather than being activated, and the copper and nickel concentrate grades are therefore increased.

Jan 1, 2005

ALTHOUGH the mineral Stannite (Cu2S, FeS, SnS2 , also known as "bell 'metal" ore, tin pyrites, etc.) is found in various parts of the world, in only three iocalities has development proved it to exist in sufficient quantity to warrant the erection of treatment plants. Two of those mines are in New South Wales and one is an Tasmania. The writer will deal with the latter-the Conah mine, Zeehan, Tasmania, it being the most important and extensive occurrence so far worked. The Conah mine was first worked by a Tasmanian company for silver-Iead, and was fairly remunerative until the zone of secondary enrichment was passed through, when the lodes became too poor for further exploitation. During the time that the line was thus operated the stannite lode was discovered. It occurs in a graphitic slate, which, in common with the slates and spilites of the Zeehan field, is probably underlain by the stanniferous granite which outcrops two miles to the west. The Conah stannite lode is older than the galena lodes of the district, being faulted by one of the latter. Near the surface the lode was very rich.Shipments were sent out assaying 150 oz. of silver per ton, 20% copper, and 18% tin. An .apparently homogeneous sample of stannite, analyzed by the writer for the Tasmanian Geological survey, gave the following results:

Jan 1, 1915

THE following description of the surface plant of the Great Fitzroy Mines is to be understood as having been compiled by a mechanical engineer, who concerns himself more with the various appliances used, their correct construction to enable them to accomplish their prescribed work, and the production and transmission of the power required to operate them, than with the reasons for the physical and chemical processes which those appliances are called upon to assist in carrying out. Hence the metallurgist will not find herein more than the skeleton of the organism, which perhaps he would wish to be clothed with the detailed description of the substances undergoing treatment, in their various combinations, at all stages, and the results attained in separating the valuable constituents from the worthless. So, also, no details will be found of the methods employed by the management for. the purpose of determining by sampling and assaying the nature of the various products obtained.GENERALThe ore being worked at the Great Fitzroy Mine is divided into two classes :-1. Ore that requires concentration before smelting.2. Ore that can be smelted direct.Flow-sheet (Fig. 1) shows in outline the process of treatment to which ore of the first class is subjected, and the writer will endeavour to fill in that outline with some details of the appliances used.

Jan 1, 1911

By Reynolds JO

This contribution by. The Australasian Institute of Mining and Metallurgy has three main thrusts. First, an Institute (and industry) view on academia and the need for more entrepreneurship at top academic levels, second the need to lift our technological game, and third, professionalism and the perceived role of mineral industry education. While I will deal with each of these separately they are of course inter- related and can be brought together under the frequently used, but insufficiently practised title, "communications". First then, The Institute and industry view of academia. There are some academics in the audience and I imagine they may wish to reply to my remarks with an academic view of industry. That is not unreasonable. Like all human institutions, academic institutions vary in quality and characteristics. Some are successful and some less so. Some historically are well renowned. Others that were once successful schools have declined. Lesser known schools have grown into prominence. What is it that sets apart 'good' highly regarded schools from those that are not so well regarded? It comes down to one main ingredient - "leadership". The strong mining schools in the past 100 years have been strong because they have had outstanding and clearly identified leaders. Strong clearly identified leadership has always had rapport with, and the support of the industry. The two go hand- in-hand, each nourishing and supporting the Other.

Jan 1, 1986

The great philosopher, Marshall McLuhan, is said to have stated that the use of forecasting as a means of guiding future actions is akin to driving an automobile through observations made in the rear-view mirror! In effect, in forecasting it is assumed that there will be an orderly progression from the past into the future, and that the model will be sufficiently unvarying for use to gauge both the directions and the rates of change. The concepts of forecasting have served man well in disciplines in which the relationship between causes and effects can be clearly demonstrated; such as between rainfall and crop yield, for example. These are of no value, however, when conditions change rapidly and unpredictably, or when there is no model at all. Even worse, under such circumstances our preconceived notions may cause us to make some horrendous errors in judgement. Such are the risks at present in attempting to make an assessment of the educational needs of the minerals industry for the coming century! The model, and the conceptions that we have had of the linkages between cause and effect are in disarray. Minerals markets are chaotic, and there is almost no ability to forecast trends in metal values. Linkages between supply and demand seem tenuous. Internationally, producers are struggling for survival. Mine closures, temporary shutdowns, and reopenings are frequent occurrences. Decision-making under uncertainty is probably one of the most certain things about the world mining industry Today!

Jan 1, 1986

In the Ora Banda area of the Eastern Gold- fields, the ultramafic rocks tend to be more deeply lateritized than most of the surrounding rock types, and lateritic nickel concentrations have been formed. Extensive drilling_has shown that, of the two intermixed suites be- neath the laterite - an extrusive peridotite- pyroxenite suite and an intrusive, highly magnetic dunite - the latter weathers to a more nickel enriched laterite. The top horizon I of the laterite consists of ferricrete. Horizon II consists mainly of bands of secondary silica in a clay matrix, formed in the reworking zone around the water table and stranded as the weathering profile migrated downwards. Horizon III ('ºaprolite") is composed of serpentinite, magnesite, iron oxides and silica, and grades dowil to the fresh bock composed variously of olivine, ser- pentine, talc, amphibole-chlorite and iron oxides. The main locus of nickel deposition is the zone containing the bottom of horizon II and the top of horizon III. The water table is also at this general level. .

Jan 1, 1973

By N Bennett

This paper examines the practical and economic benefits of using bulk emulsion explosives in underground development mining; compared to ANFO, ANFO derivatives and packaged explosives. The key economic benefit of bulk emulsion is the replacement of relatively high cost packaged explosives with a bulk product. Key practical benefits include water resistance, improved coupling of explosive, reduced toxic gas production, increased shock energy and improved manual handling through the use of bulk products. Each of the benefits is proven using a variety of measurements and field results in order to quantify them. Where possible, dollar values are determined so that the benefits can be shown to translate into savings for the mine operator. The results show that, despite the difference in price between ANFO and bulk emulsions, bulk emulsions are most capable of delivering the lowest total cost of blasting. The savings potential of the introduction of bulk emulsion systems can result in an improvement in drill and blast costs for a mine operator, or a significant increase in profit margin for a contract mining company.

Jan 1, 2007

By Roderick W. F

The equipment and procedures used for green pellet production on a laboratory scale are given, together with a description of the straight grate pellet strand analogue which has been developed to examine the response of various ore types to heat hardening. The capabilities of the analogue are illustrated with data obtained from the balling and drying studies using a manganese ore. Differences in inter-batch pellet quality are discussed, and method of minimising the experimental error that can arise from these differences is Presented.

Jan 1, 1974