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By John W. Tieman

The increasing magnitude of our nation's pollution problems seems to stem from two main factors: urbanization and technical advance. In 1920, less than half the country's 106 million people lived in cities. Forty years later, the urban population accounted for 70 percent of the nation's 179 million. It is predicted that by the end of the century, 95 percent of the U. S. population, estimated at 280 million, will live in urban areas. As these people live increasingly in city concentrations, their residues also concentrate. With technological advances to support the increasing population, the variety and quantity of goods that we use also increases. New materials and processes result in increases in pollutants, some of them new. The harmfulness of these pollutants is sometimes known, but sometimes only suspected. One pollutant of concern at the present time is sulfur dioxide, the product of combustion of sulfur-containing fuels. Research on processes to remove sulfur oxides from flue gas has been in progress for many years. Pioneers in this field were the British who, in the early 1930's, installed a full-scale flue gas scrubbing unit on a 120 MW boiler using alkaline water from a Thames estuary plus chalk. Since that time, various methods have been studied by many investigators. Federal laws covering air pollution started with the 1955 Air Pollution Control Act. With the advent of the Air Quality Act of 1967, and subsequent publishing of criteria and available technology for control of sulfur oxides in January 1969, the clamor for information on commercially available control techniques to remove sulfur from fossil fuels has rapidly increased. Although many state-of-the-art papers have deluged the literature during the past several years, the research going on in the area of sulfur oxides control is of such importance that periodic reviews are justified. It is the purpose of this paper, therefore, to again review the state-of-the-art, but this time from the stand-point of what is immediately commercially available

Jan 1, 1972

By Garry W. Warren

The electrochemical oxidation of chalcopyrite in the absence of-a chemical oxidant was studied in ammonia/ammonium sulfate solutions by anodically polarizing electrodes prepared from massive chalcopyrite. The effects of pH, cupric and ammonia ion concentration were systematically evaluated. Kinetic parameters were obtained from the anodic charge-transfer regions of the anodic polarization curves. Increasing ammonia and hydroxyl ion concentrations increased the rate of oxidation. A mechanism is proposed which explains the first order dependence of (NH3) and (OR) associated with a single electron transfer process. An empirical relationship which accurately describes the dependence of the rest potential (i.e. zero current potential) on solution composition is also given.

Jan 1, 1978

The viability of physico-chemical purification methods such as selective flocculation for separation of two components having similar chemical composition and same crystal structure but different surface properties is demonstrated. Loss of selectivity was observed in a dolomite-dolomite mixture with Polyethylene Oxide (5 million molecular weight) as the flocculant. Hetero-flocculation was minimized using a low molecular weight PEO (MW -105) as the site blocking agent (SBA). Near complete separation was achieved at pH 10.5 at 100% recovery level.

Jan 1, 1993

By J. S. Chung

As part of ongoing deep-ocean mining research, hydraulic transport systems as well as status of deep-ocean mining systems are reviewed in the aspects of manganese nodules and crusts from 800-6,000-m depth. The emphasis of the investigation of hydraulic transport is placed on the shape effect of particles on the pressure gradients and flowrates. Series of tests are being conducted to study the lift characteristics of a 2-phase vertically upward hydraulic transport of 2 types of small solid particles in a PVC pipe of 1-in (2.54 cm) diameter: irregular-shaped silica sands and equivalent spherical glass beads. Pressure drops and mass as well as volumetric flow rates were measured by electromagnetic (EM) flowmeter and mass flowmeter. The particle sizes used are 8-10 mesh. The results in turbulent flow range of 104 < Re < 105 show that pressure gradients or friction factors are smaller for the spherical beads than the sands. The larger the concentration of the particles are, the larger the pressure gradients become. The larger the particle concentration is, the less the effect of particle shape on pressure gradients becomes. The shape effect is greater for the minimum particle transport velocities than for the settling velocities.

Jan 1, 1999

By R. M. LaDouceur, C. A. Young, W. Nicholas

"Salicyl hydroxamic acid (SHA) adsorption on two rare earth oxides, lanthanum and yttrium, was studied. Adsorption at both surfaces occurred in two stages. Initially, the monovalent anionic collector appears to adsorb significantly and instantaneously in stage one and then becomes sluggish in stage two presumably because the initial stage passivated the surface. By comparison, adsorption during the sluggish second stage with lanthanum oxide did not stop but with yttrium oxide essentially stopped. Surface monolayer formation could not be observed in either of the two cases. Both stages appear to be due to multilayer formation of a surface precipitate as proven by Raman Spectroscopy for lanthanum oxide but inferred for yttrium oxide. Unlike the use of octyl hydroxamate as stated in the literature, increasing temperatures do not increase adsorption such that flotation of rare earths with SHA may be performed at room temperature leading to improved recoveries as well as significant energy savings. INTRODUCTION Rare Earth Elements (REEs) are comprised of the 15 lanthanides along with scandium and yttrium. The REEs with lower atomic numbers are relatively more abundant and are categorized as light REEs. On the contrary, the REEs with high atomic numbers are less abundant and referred to as heavy REEs. They are not really “rare” and, in fact, some of them are quite abundant in the Earth’s crust; it’s just that they “rarely” exist in concentrated deposits but rather are found dilute and practically everywhere. REEs share very similar physico-chemical properties but, because many of these properties are unique, they have gained enormous importance in recent times making several critical and strategic pending their use. For example, REEs have found extensive application in phosphor coatings, magnetics, and automobile cracking catalysts. Early technology was not advanced enough to produce commodity level production of the REEs and can be attributed to REE-bearing ores containing many rare earth minerals (REMs), not just one. In this regard, there are numerous REMs but bastnaesite, xenotime and monazite are considered to be the most common. Bastnaesite is a fluorocarbonate whereas the other two are phosphates. The separation of the individual REE-bearing minerals from the ores is not an easy task since they also exhibit very similar properties. Consequently, when flotation is used, it is done to produce bulk REM concentrates. For REM flotation, it is well established that octyl hydroxamate is more selective than fatty acid collectors (Pradip and Fuerstenau, 1983 and 1991). Liu et al. (2006) indicated that hydroxamates are the most common collectors for REMs. Pavez et al. (1996) studied the adsorption of oleic fatty acid and octyl hydroxamate on REM surfaces. Cui et al. (2012) studied the interaction of octyl hydroxamate with various REMs surfaces using various spectroscopic techniques such as XPS, FT-IR and Raman along with electron microscopy and concluded that such techniques offer ample information to establish adsorption mechanisms. Ren et al. (1997) studied napthalenic hydroxamic acid as a unique collector for flotation of REMs from bastnaesite ore and indicated that more selective collectors were needed. From these studies, it is clear that the quest of more selective collectors is essential but understanding how they adsorb at mineral surfaces is prerequisite to improving flotation performance."

Jan 1, 2016

By A. Martikainen, H. Dougherty

"At the Kemi Mine, a recent expansion into the Surmaoja orebody required an increase in ventilation capacity. A new ventilation shaft was built with two main fans. The installation is near the entrance gate and only 1.7 kilometres from the nearest permanent dwelling. The main fans were first taken into use as exhaust fans in October 2014. Shortly after the fan installation, comments concerning fan noise were received from the neighbours. The first noise measurements were taken at the main fan installation site by Outokumpu personnel in March 2015. Due to higher than expected recorded values, during late June, 2015, a two-week environmental noise study was planned by the engineers and executed by a consultant specialized in noise measurement. The measurement results were analysed and compared to the requirements of the environmental permit and Outokumpu’s factory standards. While the measured values at the nearest dwelling were within the environmental permit limits, high noise values were recorded at the fan station. A second two-week study will be performed after construction of the main-fan heating station has been completed. Actions taken will depend on the outcome. INTRODUCTION The Kemi Mine is a part of the Outokumpu chain of integrated ferrochrome and stainless steel manufacturing in the Kemi-Tornio region in Finland. The mine itself is a large underground operation with a production capacity of 2.7 million tons of ore per annum. It is also the European Union’s only chrome mine, and at present (2015) the mine extracts 2.4 million tons of chrome ore per year. Safety, cost-effectiveness, and environmental friendliness are hallmarks of the Kemi Mine. Environmental impact produced by the operation of the mine is limited due to the insolubility of the oxide chromium ore, the gravity-based and chemical-free enriching process as well as the closed circulation system of the process water which serves both the whole mine and the enrichment process (Outokumpu, 2015). Importance of the environmental impact of the Kemi Mine is amplified by its closeness to the cities of Kemi and Keminmaa with the nearest habitants living less than 2 km away from the mine site. To show the cooperation with residents the Kemi mine organizes special “neighbour days” for the habitants of the areas closest to the mine. Also, information letters are sent to the neighbours, when changes that may affect the neighbours are being planned and executed."

Jan 1, 2016

By Raymond A. Bradbury

Martin County Coal Corporation&apos;s operations are located on Wolf Creek in Martin County in the eastern part of Kentucky. The mining complex was started in 1971 and has grown to a 2.273 Mt/a steam coal operation. All of the production goes to Duke Power Company&apos;s Belews Creek electric generating station in North Carolina. Production comes from four seams that are mined by deep and surface mining methods. Surface mining accounts for 55% of the production and the remainder comes from 2 underground mines. Continuous miners are used exclusively underground. The preparation plant was originally designed to take coal at the rate of 907 Mt/h but that has gradually been increased to 1134 Mt/h. Other cleaning equipment includes Daniels DMS vessels, Model 77 Deister tables, 355.4-mm R. & S. Hydro- cyclones, Krebs 254-m classifying cyclones, Daniels froth cells and in 1980, 3 Krebs 508-mm heavy media cyclones were added to recover some lost and misplaced material. CMI centrifugaldryers and a Hey1 & Patterson size 100 thermal dryer are also part of the coal preparation equipment.

Jan 1, 1981

By G. Vallebuona

Currently, empirical models are used for predicting the hydrocyclone performance in terms of capacity, cut size (d50,c), water split and partition curve. These models, for example those of Lynch and Plitt, have been developed and checked for hydro cyclones with diameters larger than four inches. For smaller diameter hydrocyclones little empirical modelling has been done. This paper reports extended experimental research on small hydrocyclones. For these cyclones, the suitability of existing empirical models has been checked and their accuracy compared. Modifications of the existing models equations are proposed, improving their predictive capability for the small cyclones performance.

Jan 1, 1994

By P. M. Hawley

Kennecott Corporation, in joint venture with Galactic Resources Ltd., recently began operation of an open pit gold mining and milling facility near Columbia, South Carolina. The deposit consists of two ore bodies (North and South deposits) hosted in deformed and altered meta-volcanics and meta-sediments of the Carolina Slate Belt. This paper describes the rock mechanics and engineering geology investigations conducted for design of interim, ultimate and final reclamation slopes for the South Pit. Emphasis includes the successful use of drill core orientation techniques to confirm complex geologic structure at depth; the development of a three-dimensional rock mass competency model, incorporating surface mapping data, results of bench mapping documentation, field index testing and laboratory testing; and kinematic assessments for design of optimum slopes.

Jan 1, 1991

By M. K. Boateng, K. Awuah-Offei

"Mining companies have started using quantitative tools, including computer models of community interaction, to gain intelligence on social risks surrounding their projects. Models of changes in community preferences regarding mining projects over time are useful for evaluating changes in project risk due to changes in the social license to operate. For example, agent-based models that use information diffusion models and social networks are useful for studying those changes due to information diffusion. However, such agent-based models are sensitive to many input parameters including the parameters of the diffusion model and the average degree of the social network. This work evaluates the sensitivity of such a model to diffusion and network model parameters (probability of imitation, probability of innovation, and average degree) using the first order and total sensitivity indices. The results show that the model is much more sensitive to the probability of imitation than the other two parameters. Thus, to reduce uncertainty surrounding the model’s predictions of community acceptance of mining, mines need to obtain accurate estimates of the probability of imitation. INTRODUCTION Mining companies have started using quantitative tools, including computer models of community interaction, to gain intelligence on social risks surrounding their projects. Models of changes in community preferences regarding mining projects over time are useful for evaluating changes in project risk due to changes in the social license to operate. For example, agent-based models that use information diffusion models and social networks are useful for studying those changes due to information diffusion. However, such agent-based models are sensitive to many input parameters including the parameters of the diffusion model and the average degree of the social network. This work evaluates the sensitivity of such a model to diffusion and network model parameters (probability of imitation, probability of innovation, and average degree) using the first order and total sensitivity indices. AGENT-BASED MODEL OF COMMUNITY ACCEPTANCE A few researchers have started using agent-based models to study mining systems (Fujiono 2011; Nakagawa et al. 2013; Bahr 2015; Boateng and Awuah-Offei 2017a, b). Nakagawa and co-workers used ABM to evaluate dynamics of a mining project’s stakeholder networks whereas Fujiono used ABM to study innovation diffusion in the mining industry. Our previous work has presented models and a framework for modeling information diffusion in a mining community and its impact on level of acceptance (a measure of SLO) of the mining project (Boateng and Awuah-Offei 2017a, b)."

Jan 1, 2018

By I. J. Lin

The effect of various types of structural modification on the critical micelle concentrations (CMC) and hydrophile lipophile balances (HLB) of certain surfactants has been considered. Using the concept of effective chain length for the substituted species, an index of hydrophobicity (I) has been defined. It is hoped that such an index will allow one to choose surfactants for particular purposes in a less arbitrary fashion than heretofore.

Jan 1, 1973

By M. S. Prasad

In earlier work it has been shown that paper filler clay products can be obtained from primary kaolin deposits of Minnesota. The objective of the current work was to reduce silica and iron contaminants and to maximize kaolin recovery to higher value products suitable for paper coating. This results in achieving a finer and cleaner product conforming to paper coating specifications. Cationic flotation and high gradient magnetic separation were used to remove free silica and iron, respectively, while attrition grinding and ultrasonics have been examined for particle size reduction. The results of this work are presented and discussed particularly with respect to application-oriented product properties. Budgetary estimates are presented for a 200,000 ton/year processing plant based on the process flowsheet developed and optimized by the study.

Jan 1, 1991

By Randhir Sehgal

Heavy media processes have been used for cleaning +28 mesh coals for a number of years, Two applications, i.e., the vessels and the cyclones are widely used in the U. S. for this purpose. The basic reason for the popularity of these systems is their extremely high efficiencies for particle sizes above 28 mesh, However, application of heavy media technology to fine coals below 28 mesh, has been limited due to the following reasons: o Inability to make size separations effectively at sizes below 28 mesh o Necessity of feeding large quantitites of magnetite to the separators o Difficulty of recovering magnetite in the presence of large quantities of coal o High levels of coal contamination in the recovered media, leading to high circulating loads and ineffective control of media gravity

Jan 1, 1981

By M. S. Klima

A 25-mm diameter dense-medium cyclone was tested to investigate the effects of geometry and operating conditions on cyclone performance when processing -150 I&apos;m coal. The emphasis was on examining those variables (e.g., flow rate and inlet velocity) which impact the separation kinetics (specifically the number of g&apos;s and the mean retention time) and the occurrence of apparent bypass. Apparent bypass, indicated by partition curve "tails", results from the short circuiting of the feed coal to one or both of the product streams and represents a loss and/or contamination of the clean coal. This paper presents the results for this series of tests.

Jan 1, 1993

By R. J. Miller

Mechanized Roof Supports (MRS) have dramatically improved safety and productivity of retreat pillar mining in coal. Due to low capital cost and greater flexibility, retreat panels have in some cases approached the productivity of a longwall. Because of improved safety and rapid set-up time when compared to conventional timbering, MRS are driving a return to retreat pillar mining in many situations. This paper describes how panel layout can be optimized for safety and operational efficiency when using MRS for retreat pillar mining of coal. The potential for significant unit cost reductions will also be addressed.

Jan 1, 1996

By T. V. Ramey

Heap leaching in certain parts of the world, such as Chile&apos;s Atacama Desert, brings unique design problems in the form of possible large differential settlements of the foundation soils due to the dissolution of salts in northern Chile the soils often contain very high concentrations of soluble salts (nitrates, potassium, magnesium, and common sodium). When a leak in the liner occurs, the escaping solution dissolves these salts and triggers differential settlement. If the settlement is great enough, the geo-membrane tears, the leakage increases, triggering more differential settlement. The nitrate plants have experienced many occurrences of this phenomenon where a brine pond will undergo a sudden and complete loss of the impounded liquors. The authors present a simplified technique to quantify the differential settlement resulting from dissolution and provide a method which can be used to select a geo-membrane with suitable flexibility under axi-symmetric (multi-axial) load conditions to tolerate the predicted settlement. (This paper was previously published for Randol Gold Forum 1996 [Ref. 6]).

Jan 1, 1997

By D. A. Peterson

A research program is currently in progress at the University of British Columbia to determine the potential of composite cable bolt reinforcement in Canadian mines. Several prototypes of glass fibre cable bolts have been tested. Their evaluation consisted of lab testing at the University of British Columbia, United States Bureau of Mines (Spokane) and trial installations at Detour Lake, Winston Lake, and Myra Falls Mines. A market analysis of cable bolts within the Canadian mining industry has been completed. Fibre reinforced polymer composites have a high potential as cable bolt reinforcement in mining applications. They prove to be a viable alternative to steel cable bolting.

Jan 1, 1993

In the screening process, used to prepare particles for many applications, shape is known to have a significant effect. The degree of flakiness of construction aggregates has been considered particularly important. The objective of this research was to find values of operating parameters that optimize the separation of flaky from non-flaky particles by slotted screens. Thus an investigation was conducted to experimentally determine the influence of the particle size and thickness on the screening process. The Response surface method was employed for modelling and analysis of the data. Experiments employing a central composite design were performed on a pilot-scale, rectangular-aperture, vibrating screen to examine the effects of the screening variables the mass recovery of flaky and non-flaky particles to the oversize product. The SAS statistics package was used to fit a second-order model to each response and to analyze the fitted surface to determine the optimum levels. The optimization associated with a dual response system was then considered. The results of this study should provide a basis for optimizing screening conditions to obtain maximum recovery of non-flaky particles to the screen oversize while minimizing the recovery of flaky particles, which should be of interest to the aggregate industries.

Jan 1, 1999

By S. Tuylu, D. Adiguzel, U. G. Akkaya, A. Bascetin

"One of the main problems for storing of the tailings is acidity occurrence due to several factors such as existence of sulfuric minerals and also the pollution in seepage waters by mobilization of metal ions, which holds great risks in terms of environmental regulations. Because of these specified reasons, tailing materials to be used in a SPD formula should have comply with some specifications. Among these properties; oxygen content, temperature, matrix suction and pH are the most important parameters. In the study, the relationships between the parameters mentioned are investigated to reveal optimum paste design layout. The lowest amount of seepage water obtained from the paste layers in the pilot cabinet was found as 2150 ml from 3rd layer. As for the maximum seepage water and the average of the all 11 layers were found as 4909 ml from 6th layer and 3273 ml respectively. The reactions occurring according to the oxidation, as seen at seepage water of second and third layers, decreased the pH of system to the under of 7 value. Additionally, when the seepage water of first layer’s EC value is 2.93 mS/cm, the EC value of second layer is increased at 3.54 mS/cm. The other parameters are evaluated with the obtained results of the tests to determine the optimum storing conditions for SPD.INTRODUCTION Conventional waste disposal methods, although widely used, pose great environmental risks. One of the most important issues is acid mine drainage (AMD). Tailings of metallic mines contain heavy metals, aggressive chemicals and hazardous materials. In the presence of oxygen and water, an oxidation reaction can occur, causing a decrease in pH of the environment, and heavy metals that are present in the environment can dissolve easily. Subsequently, heavy metals can pollute underground water basins, creating a great amount of danger for the ecology and potable water resources. Another important risk associated with conventional waste disposal methods is accidents related to the waste dam. Higher volumes of water and tailings (usually 15% solids and 85% water by weight) are sent to waste dams, making it very difficult to control the stability of the dam under conditions such as static and dynamic loads (seismic activities, vibrations caused by blasting, etc.), flooding, and seepage. In case of an accident or failure, the spread of great amounts of mud containing hazardous chemicals and heavy metals can harm the environment of the dam site significantly (Bascetin et al., 2014). In the paste technology, depending on the type of ore, tailings used in the paste mixture can contain sulphide minerals (such as pyrite and pyrrhotite). These minerals are known to be reactive with water and oxygen to produce acidity (sulphuric acid)."

Jan 1, 2015

The dissolution kinetics of cobalt in iodine/iodide solutions was investigated using a rotating disc technique. Variables studied here included temperature, rotating speed, concentration of lixiviants, and pH of the solution. The overall dissolution reaction was found to be limited by mass transfer of tri-iodide through the diffusion boundary layer with Arrhenius activation energy of less than 16.2 kJ/mol (4 kcal/mol) over the temperature range, 2-42°C. The pH of the solution had little effect as long as the pH of the solution was less than 8. However, when the pH of the solution became greater than 8, the dissolution rate decreased dramatically due to passivation. The rate of dissolution was in good agreement with the dissolution model developed by the authors earlier.

Jan 1, 1994