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By J. M. Eriksen, T. Rosenqvist, H. Elstad, S. Seim, A. Hildal

The titanium industry demands high titanium feedstock for their processes. As rutile resources are limited, ilmenite has become the most important titanium source. Ilmenite smelting is an important part of upgrading ilmenite to high titanium feedstock. In the year 2005, upgrading of ilmenite by smelting, producing a slag with 80-90% Ti02, accounted for approximately 40% of the feedstock to the Ti02 pigment industry. In ilmenite smelting molten iron is produced together with a slag, which in addition to titanium oxide contains iron oxide as well as various impurity oxides of manganese, magnesium, silicon, aluminium, etc. Titanium is present mainly as Ti02 but partly also as Ti203. It is known that the concentration of Ti203 increases with decreasing concentration of FeO, but this dependency is affected by the nature of the impurity oxides. Sigurdson and Moore1 showed that slags high in CaO and MgO had a lower concentration of Ti203 than slags high in Si02 for the same amount of FeO. Pistorius2 showed in 2002 that if the impurity oxides MnO and MgO are counted, on a molar basis, as FeO, and Cr203, V203 and part of the A1203*), as Ti203, industrial slags will have a composition close to that of the M305 phase, where M denotes the elements Ti, Fe, Mn, etc, and which has the pseudobrookite structure. However, for equilibrium with liquid metallic iron he computed, by means of a computer program FACT, that the slag equilibrium composition is represented by a curved line in the ternary phase diagram FeTi03-TiO2-Ti2O3, but with a significantly higher concentration of trivalent titanium than actually observed in the industrial slags, and he discussed various mechanisms by which the slag during solidification could change its composition to a lower Ti203 content, but the possibility that the computed compositions might be wrong was not mentioned. Trane113 found in her research on titaniferous silicate slags a lower Ti3+/ Ti4+ ratio than that which is computed by the FACT program. The purpose of the present investigation was to study the equilibrium composition of Fe-Ti-O slag in equilibrium with liquid metallic iron, as well as the effects of impurities such as Si02, CaO and MgO on the slag composition. Industrial slags from TINFOS Titan and Iron KS (TTI) will also be discussed and their compositions will be plotted in the ternary phase diagram. These are slags produced from Tellnes ilmenite, quite high in magnesium and iron. Experimental In the past, equilibrium studies of the Fe-Ti-O slag system were difficult when it came to producing the slag. It was difficult to find a suitable crucible for the meltings. The highly corrosive slag would attack all known refractories, and the metal would attack metallic crucibles such as those made of platinum and molybdenum. In the present investigations the slag-metal combination was prepared in a high-frequency induction furnace with a vertically segmented water-cooled copper crucible. The crucible is shown in Figures 1 a and 1b. It was designed by the Australian Nuclear Science and Technology Organisation (ANSTO) with power from a 75 kVA high-frequency generator (750 kHz) supplied by Farfield Electronics Pty, Ltd, Australia. This enabled the slag-metal combination to be melted with turbulent stirring and is expected to be isothermal. The entire temperature gradient

Jan 1, 2007

By R. S. J. Toit

Discussion: T. L. Gibbs,* (Honorary Vice-President and Fellow): In terms of the Pneumoconiosis Compensation Act of 1962, a Pneumoconiosis Risk Committee was established whose function it is to estimate (by whatever means the committee deems fit) in respect of every controlled mine the pneumoconiosis risk to which persons employed in a dusty atmosphere at that mine are exposed. In estimating such risk the committee may estimate different risks in respect of individual mines or parts of mines or classes or groups of mines or occupations or localities at mines. The pneumoconiosis risk may be reviewed and re-estimated at any time. The Act provides further that the General Council for Pneumoconiosis Compensation shall apportion the levy imposed on owners of controlled mines on the basis of the pneumoconiosis risk determined by the risk committee and the numbers of persons employed in a dusty atmosphere. The task of the risk committee is a most responsible one and also a very difficult and complex one in view of the many different types of mines, rock formations, dust conditions, etc. Quite obviously, comparisons between mines cannot be made on dust concentrations alone as different mineral dusts have different toxicity or pneumoconiosis response factors. However, with its present knowledge, the risk committee is satisfied that the risk at mines, other than coal mines, is related to the mean quartz-equivalent dust concentration to which persons are exposed and the estimation of risks is based on this relationship. From the above, it will be clear that the work done by Dr du Toit on the problem of basing the current rate of levies to provide for pneumoconiosis compensation on the current dust hazard at mines has been of immense value to the risk committee. Up to now the risk committee has not been able to obtain complete and accurate information on the dust exposure of persons at all mines - and, in fact, it is doubtful whether it will be economic or practicable to obtain this in the foreseeable future - but reasonable assessments have been possible from routine dust sampling in some cases and from periodic comprehensive dust surveys in others. As a temporary measure the risks of some mines were estimated initially on a group basis relating to average dust conditions and the type of rock and mineral mined, but as more information became available, differentiation between individual mines became possible. It is the aim of the risk committee to eventually apply such a differentiation in all cases and to ensure that within the bounds of practicability each mine pays for its risk and for its risk only. In this connection, the relationship between the levies and the amounts actually paid out in compensation are examined regularly. In conclusion, I wish to add my congratulations to the author on his excellent paper. His findings will assist materially in the just administration of that very important piece of beneficial legislation, the Pneumoconiosis Compensation Act. G. K. Sluis Cremer MD (Visitor): Dr du Toit has made a valiant attempt to relate dust hazard and the rate of collecting funds for the purpose of paying compensation for Pneumoconiosis. In doing so he has had to make a number of assumptious, some of which touch on the medical aspects of pneumoconiosis. It is worth discussing whether these assumptions are justifiable. Pneumoconiosis is defined in our Pneumoconiosis Act as permanent disease of the cardio-respiratory organs which is caused by the inhalation of mineral dust. To a non-medical person this definition has probably a clear cut meaning. The doctors however have to deal with such conditions as silicosis and asbestosis where there is a well defined dose response relationship to the inhalation of quartz and asbestos respectively and on the other hand chronic bronchitis where the relationship to dust inhalation is poorly defined and where certainly no clear dose response relationship has emerged after many investigations in this country and overseas. Nevertheless since 1953 about half of our certifications for Pneumoconiosis are on the grounds of chronic bronchitis i.e. the X-rays show no evidence of silicosis, asbestosis or other relevant disease. This fact must affect Dr du Toit's computations. The next assumption we should examine is the manner in which toxicity factors have been allocated to the various mineral species. These allocations have in part been based on a restricted number of animal experiments carried out overseas but mostly in South Africa by Webster at the Pneumoconiosis Research Unit. To extrapolate the findings in a relatively small number of animal experiments to the expected reactious in man is a notoriously dangerous exercise. Furthermore the bracketing together of all silicates (except asbestos) and the insoluble metal oxides is entirely unacceptable. Talc (a hydrated silicate of magnesium) and muscovite mica (a silicate of aluminium and potassium) cause pneumoconiosis in their own right. On the other hand

Jan 3, 1970

The theory of geostatistics covers a branch of .applied statistics aimed at a mathematical description and analysis of geological observations. Geostatistics can be used in pure geology (for example, for the analysis of trace elements in a metamorphic rock), in mineral exploration (for example, for the analysis of geochemical exploration data), as well as in mine valuation. This book is intended to provide a practical introduction to the theory of geostatistical methods of mineral evaluation. Over the years, various mathematical models have been developed to represent the distribution of values in mineral deposits. The simpler models are based on the assumption that the values are randomly distributed. Classical statistical methods, based on this assumption of the random distribution of values, are used to analyse mineral deposits to which these models apply or are assumed to apply. In all mineral deposits, however, one recognizes the presence of areas where the values are higher or lower than elsewhere. Also, the values of two samples in a mineral deposit are more likely to be similar if the samples are taken close together than if they are taken far apart. This indicates that there exists a degree of correlation between sample values, and that this correlation is a function of the distance between the samples. Models have been developed which take this correlation into consideration, with the degree of correlation between sample values being usually measured by the semivariogram function. In these models the fact that two samples taken next to each other will most probably not have the same value, must also be considered; even for very short distances the correlations are usually not perfect and a purely random component is present in the value distribution. The mathematical models will therefore assume the presence of two sources of variability in the values: a correlated component and a random component. Finally, one must consider the particular and very common case of mineral deposits in which the values present a systematic variation in space. This variation is usually referred to as a drift, or a trend. For example, the grade of an ore body may increase with depth of the ore, or it may decrease when one moves away from a central volcanic pipe. The earlier models did not give a satisfactory representation of drifts, and more complex models have been developed, in which three sources of variation are represented. These models are made up of: a deterministic component, a correlated component, and a random component. The deterministic component is used as a model of the drift. The correlated component explains regular changes in values which are not represented by the drift. The random component represents variations which cannot be explained by any of the above factors. The simpler models, based on the assumption of a single random component, will be described first (Chapter 2). The models based on the hypothesis of the superimposition of a correlated component on a random component, will then be analysed in detail. These models are most commonly used in the analysis of mineral deposits (Chapters 3-1 I). Finally, how to deal with the presence of a drift will be briefly described (Chapter 12). This book has been written essentially for students in mining engineering and for mining engineers who are interested in the background to the theory of geostatistics as well as its practical applications. The assumption is made that the reader has an elementary knowledge of statistics. Some knowledge of linear algebra is useful in part of Chapter 9, and is necessary to read Chapter 12. A proof is given of all the equations related to geostatistics, and which are not usually found in elementary textbooks on statistics. Understanding of these proofs is not necessary for practical application of the theory, and the reader may wish to skip them on a first reading, concentrating attention on the numerous simple practical examples given. Although the theoretical geostatistician will not find much new material in this publication, it is anticipated that he will develop some interest in the practical approach chosen to prove the various geostatistical equations. Many people and institutions contributed to the preparation and completion of this work. I am much indebted to Dr D. G. Krige and the Anglo Transvaal Consolidated In- vestment Company Limited, who gave me the opportunity to spend a considerable amount of time working on geostatistical problems, both theoretical and practical, during the time that I was in their employment. Dr Krige contributed greatly in developing my interest in studying both the theory and practice of geostatistics, always insisting that a correct balance be kept between theory and practice. I am grateful to Professor H. M. Wells and the Mining Department of the University of the Witwatersrand for inviting me to give lectures in a post- graduate course on geostatistics. The notes 1 prepared for that course became the foundation of the present work. I am also indebted to the Centre de Geostatistique of the École des Mines de Paris, where I received my first formal education in geostatistics during a summer course given by Charles Huijbregts, after many years of my lonely plodding through the published literature. Many graphs in the present volume are reproduced with the permission of the Centre de Geostatistique. The Department of Metallurgical and Mineral Engineering of the University of Wisconsin-Madison has also contributed in making this work possible, by allowing me to spend a considerable amount of time and resources in the writing, typing, and correcting of successive drafts. I am thankful to Lynn D. Kendall, who typed the entire manuscript under constant pressure.

Jan 1, 1978

Petrus (Peter) Lambooy was born in Johannesburg of Dutch-speaking parents on 13th November, 1911, and died in August 1988. These are the bare statistics, which obviously tell nothing of the years between and the man who lived them to the full.

Jan 1, 1988

Letter to the Editor With reference to the recent questionnaire in the December 1980 issue on 'The Contents of Journals', I have made the following observations.

Jan 1, 1981

By J. H. Fourie

This paper highlights modern practices in ore-treatment plants, with particular reference to the flotation of P2O5 at the plants of the Phosphate Development Corporation (Foskor) at Phalaborwa in the northern Transvaal. The following aspects are covered: design criteria, equipment and personnel, production standards and control. cost control, maintenance, and process development.

Jan 1, 1981

By R. R. Maclachlan

The Estimation of Fragmentation in Blast Muckpiles by Means of Standard Photographs, by H. van Aswegen and C.V.B. Cunningham. Journal of the South African Institute of Mining and Metallurgy, vol.86,no. 12. pp. 469-474. Dec.1986.We have recently read the above paper and wish to make a number of observations.

Jan 1, 1988

By A. G. R. Coreejes, G. Ferreira

The paper sets out briefly the methods used for the planning and control of the construction work at Grootegeluk Coal Mine near EIIisras, Transvaal. It includes a discussion of the programming, the updating of programmes, and the progress reporting.

Jan 1, 1982

A. Sutherland Brown (ed.). Porphyry deposits of the Canadian Cordillera. The Canadian Institute of Mining and Metallurgy, Special Volume 17, 1976. C. G. Down and J. Stocks. Environmental impact of mining. G. B. Rothenberg. Refractory minerals. Park Ridge (V.S.A.), Noyes Data Corporation, 1976. Geology, mining and extractive processing of uranium. London, Institution of Mining and Metallurgy, 1977.

Jan 1, 1978

Council for 1998/99 President R.P. Mohring President Elect J.R. Dixon Vice Presidents Senior junior M.H. Rogers Dr L.A. Cramer Immediate Past President Honorary Treasurer Dr N.A. Barcza J.A. Cruise

Jan 1, 1985

By D. Menne

An empirical dimensionless correlation is presented that relates system variables to the superficial slip velocity between solid mineral products and an interstitial fluid. The correlation is valid within engineering accuracy for all solids and fluids at all concentrations. The particular usefulness of the correlation is that it provides explicit equations for both slip velocity and voidage.

Jan 1, 1983

By G. E. Blight

The mining industry is making increasing use of pumped tailings fills. The properties that affect the performance of tailings fills are described by means of typical examples. They are the particle-size grading for maximum density, the water content for pumpability, settlement after placing, compression and drainage under stress, shear strength, and resistance to shock loading.

Jan 1, 1979

By J. C. David, G. Coetzer

The effect of varying aliphatic, olefinic, and aromatic groups in the N- and S-positions of dithiocarbamates was investigated in the selective and bulk flotation of a mixed copper-lead-zinc-iron ore. Selective and bulk flotation were found to be dependent on the type of functional group, as well as on the position of substitution.

Jan 1, 1989

By A. A. Hazell

Mine management by objectives by A. A. Hazel Published in the Journal, September 1972 DISCUSSION H. H. McGREGOR Mr Hazell is to be complimented on a thoroughly down to earth analysis of the uses ot which work study can be put and the benefits of properly applying it in the management of underground production.

Jan 9, 2007

By G. J. C. Young

The new metallurgical plant has a simple, compact layout, being designed for a small team of operators. The reasons for building the new plant are given, and its various sections are briefly described. These include the conveyor plant, milling plant (for run-of-mine milling), thickener plant, agitator plant, filtration, clarification, smelthouse, and central core joining the mill and filtration sections.

Jan 1, 1978

By W. K. C. Boemer, G. A. Davies

Vanadium slag production in the shaking ladles started in April 1968, steelmaking was begun in July 1968 and the first continuously cast blocks were produced soon after on the 29th July, 1968. Nominal monthly production of over 20 000 tons was reached in seven months and by December 1970 about 12 000 heats were cast and a monthly production of 35000 tons has been achieved.

NEW BOOKLET FOR POTENTIAL ENGINEERS A new booklet "Professional Careers in Engineering" for issue to high school students who are considering engineering as a profession has been prepared for general distribution. The booklet is intended to help high school students to decide whether a career as a professional engineer would appeal to them, and to tell them how to set about becoming a professional engineer. Copies of the booklet may be obtained free of charge by writing to: The Federation of Societies of Professional Engineers, P.O. Box 5907, Johannesburg.

Guide Io Ihe Preparailon Of Papers For Publication In The Journal Of The South African Institute Of Mining And Metallurgy The following notes have been compiled to assist authors in the preparation of papers for presentation to the Institute and for publication in the Journal. All papers must meet the standards set by the Council of the Institute, and for this purpose all papers are referred to at least two referees appointed by the Council.

Jan 1, 1975

In many practical situations, calculation of the point semivariogram is not necessary. Such a case is analysed in this chapter. The purpose of this analysis is to give a better understanding of the meaning of the mathematical formulae developed in the previous chapters. A similar problem will be studied in Chapter 11, using the point semivariogram.

Jan 1, 1978

By P. S. Turner

After a brief account of the differences between the control of underground fires and those on the surface, the paper describes the analogue detection system used on the mines of the Anglo American Corporation of South Africa Limited. The system comprises Spanair gas analysers, Becon combustion-particle detectors, a telemetering system, a surface signal-recording and-processing system, and an alarm system. The use of the system is described and illustrated.

Jan 1, 1982