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By M. de Beer

The conversion of carbon-containing feedstock into liquid fuels can proceed via the Fischer-Tropsch synthesis, which is catalysed using supported cobalt catalysts. These catalysts contain noble metals to facilitate the reduction of oxidic cobalt species in the catalyst precursor to metallic cobalt, which is the catalytically active species for the Fischer-Tropsch synthesis. This is thought to occur via hydrogen spillover, i.e. the diffusion of atomic hydrogen over the support from the noble metal to the oxidic cobalt moieties. Noble metals may also affectthe dispersion of cobalt in the active Fischer-Tropsch catalyst. The economic aspect of the addition of noble metals to the Fischer-Tropsch catalyst is discussed.

Jan 1, 2014

By E. Moosavi, K. Tolouei

In mine production scheduling problems are well-known, where most are categorised into deterministic and non-deterministic NP-hard problems because of their complexity. Many researchers have attempted to solve the problem by applying various optimisation techniques. While using traditional methods they observed extreme difficulty in solving highly complex problems. In the 1990s, many researchers addressed long-term production scheduling (LTPS) by using simulated annealing, the genetic algorithm, the tabu search algorithm, and the ant colony algorithm. These algorithms are known as the meta-heuristic algorithms, and have proved to be the most efficient algorithms for solving LTPS thus far. The firefly algorithm is one of the best methods for visualising problems related to LTPS, and provides the best possible optimisation. It is one of the simplest methods, and easy to apply to any NP-hard problem. The experimental, and comparison with other recently published algorithms shows that the proposed algorithm is feasible, and is an effective approach for long-term production scheduling problems. The results indicated that a better solution is obtained by the proposed method, compared to other methods in terms of cumulative net present value, and average ore grade. Additionally, the CPU time via the proposed model is roughly 2.52% higher than the other method.

Sep 1, 2021

By M. Pierce, E. Karampinos

"One of the main challenges in the numerical modelling of ground support in underground excavations is to reproduce the performance of the sequential installation of the reinforcement while capturing the rock mass behaviour of an advancing face in 3D. The 3D modelling approaches used to simulate the progressive advance of excavations are mostly continuum and often cannot reproduce the rock mass failure mechanisms. The 3D discrete element method (DEM) can better reproduce structurally controlled rock mass failure mechanisms and can explicitly represent the reinforcement elements. This paper builds on previous work that reproduced the structurally controlled squeezing conditions in an underground hard-rock mine using 3D DEM and the in situ behaviour of reinforcement under pull conditions. It addresses important issues on the way reinforcement is explicitly introduced in discrete element models. A pseudo-3D model is employed to overcome the computational restrictions and time limitations of a 3D modelling approach. The work focuses on the scaling of the material properties of the ground support elements when the thickness of the model is not equal to the out-of-plane spacing of reinforcement. It demonstrates the scaling methodology based on the type of the modelled reinforcement elements used and investigates the significance of this approach. The advantages and disadvantages of this approach with respect to 2D and 3D methods are discussed. The results are compared with field data and previous modelling work done at the mine. IntroductionNumerical models can provide significant insight into the anticipated behaviour of underground excavations. The modelling of ground support, however, is not a trivial exercise. An effective representation of ground support in underground excavations should capture the behaviour of both the rock mass and the support elements. When numerical models are used for design purposes, the complexity of the problem requires significant time and expertise (Sweby, Dight, and Potvin, 2016).At a laboratory scale, numerical models have successfully reproduced the results of laboratory tests on rockbolts by explicit modelling of the bolt, the borehole, and the grout. Chen and Li (2015) used a continuum FLAC3D (Itasca Consulting Group Inc., 2012) model to simulate the mechanical behaviour of D-bolts as observed experimentally. Grasselli (2005) used a 3D finite element code to model the behaviour of fully grouted rods and expandable bolts under shear."

Dec 1, 2018

By J-N. Oyourou, R. McCrindle, C. J. S. Fourie

"Many mines in South Africa were inappropriately closed and left unattended during the last century. These old mines are potential sources of environmental pollution and may pose a health risk to local populations, since the surrounds contain elevated levels of toxic elements. Soil from the old Edendale lead mine property in Mamelodi Extension 11, east of Pretoria, which was suspected to be contaminated with lead, was analysed. The mine, which primarily extracted galena, was decommissioned in 1938. During this study, the old mine property and surrounds were screened for zinc and lead using a field-portable X-ray fluorescence (pXRF) spectrometer. The metal concentrations, which ranged from 18 to 7 300 mg/kg for zinc and from 50 to 21 000 mg/kg, for lead, were plotted together with the GPS coordinates to produce a concentration distribution map for lead and zinc. This map revealed three anomalies of unacceptably high concentrations, possibly corresponding to areas where ore had been piled or dumped to waste from the old mine. Thirty-six of the soil samples that were analysed by pXRF on site were selected and analysed in the laboratory using inductively coupled plasmaoptical emission spectrometry (ICP-OES) for verification purposes. The zinc and lead concentrations obtained from the two analytical methods were compared using linear regression analysis. Excellent correlation was obtained between the results from the two methods (r2 = 0.99 for zinc and r2 = 0.95 for lead). IntroductionEarly economic development in South Africa was based mainly on mining. However, these activities left a legacy of approximately 6 000 improperly closed mines scattered throughout the country (SAI, 2009; van Schie, 2012). Due to their proximity to settlements, these abandoned mines may pose a potential health risk to humans and an environmental hazard. Mining activities generate large amounts of waste, mostly in the form of overburden and process tailings, which often contain high concentrations of toxic elements. Bioavailable toxic elements can contaminate crops growing in the polluted area (Kala, 2010; Marwa, Meharg, and Rice, 2012) or eventually migrate and detrimentally affect the groundwater (Rösner and van Schalkwyk, 2000). Moreover, sulfides accumulated in mine waste generate acid minewater (Rösner and van Schalkwyk 2000). Unfortunately, owners of mines, closed before the promulgation of the Minerals Act more than twenty years ago (Act 50 of 1991), avoided the compulsory rehabilitation of the environment enforced by this legislation. Toxic elements, such as lead, which were confined within ores, may become exposed through mining and are therefore more easily mobilized within the environment. Elements essential to human and plant metabolism, such as zinc, when exposed by mining activities, may become hazardous due to elevated concentrations (Aslibekan and Moles, 2003; Wuana and Okiemen, 2011). Humans exposed to potentially toxic metals may experience harmful effects as discussed elsewhere (Nriagu and Pacynar, 1988; Wayne and Ming-Ho, 2005)."

Jan 1, 2019

By P. Kitobo, T. Nduba, D. Mbay, J. B. Vangu, R. Ciband

The flotation plant tailings at Kamoa Copper Mine concentrator were found to contain a high proportion of extremely fine particles. The potential issues with settling these fine solids were resolved by the use of a poly-di-allyl-di-methyl ammonium chloride (DADMAC) coagulant, Flobead DB 45 VHM, in conjunction with a standard anionic polyacrylamide flocculant. This paper outlines some of the issues encountered and how they were resolved at the Kamoa concentrator. The potential to use this process and technology at other sites is also considered

Jan 1, 2023

By K, J. MAUNDERS

This paper briefly describes a computerised model of the South African electricity system which has been developed jointly by the Atomic Energy Board and the Electricity Supply Commission. The results of an analysis of this system have been subjected to a fairly extensive sensitivity analysis which reveals that up to the year 1990 between 680 and 700 million tons of coal will be required for electric power generation, together with between 7 000 and 10 000 tons of uranium. This result is fairly insensitive to data variations, but the prediction of a cumulative requirement up to the year 2000, of between 1 300 and 1 800 million tons of coal and 25 000 to 70 000 tons of uranium, proves to be very data-sensitive.

Jan 1, 2014

By L. Lorig

"Two types of extreme event, earthquakes and rainfall, potentially affect open pit slope stability. In the case of earthquakes, there are rather well-developed analysis procedures and acceptability criteria. The analysis procedures relate mainly to selection of the dynamic loading either through design earthquakes and/or pseudo-static seismic coefficients. The acceptance criteria are typically expressed in terms of a minimum safety factor in pseudo-static analyses. The acceptance criteria are often promulgated by governments despite the fact that no open pit slope has ever been adversely affected by an earthquake. This paper explains why open pit slopes are seemingly more resistant to dynamic loads than natural landforms, which can experience catastrophic landslides.Extreme rainfall events are much more likely to cause open pit slope problems than earthquakes. Two types of problem are common – slope erosion and slope instability. Slope erosion is often mitigated by appropriate surface water controls. Slope instability due to elevated transient water pressures is more difficult to mitigate. Analysis procedures and acceptability criteria are rare. This paper will discuss the mechanisms for rainfall-induced slope instability, as well as analysis methods. Examples will be discussed and analysis methods are proposed. IntroductionTwo types of extreme event, earthquakes and rainfall, potentially affect open pit slope stability. In the case of earthquakes, there are rather well-developed analysis procedures and acceptability criteria. The analysis procedures relate mainly to selection of the dynamic loading either through design earthquakes and/or pseudo-static seismic coefficients. The acceptance criteria are typically expressed in terms of a minimum safety factor in pseudostatic analyses. The acceptance criteria are often promulgated by governments (e.g., Peru, Chile) despite the fact that no open pit slope has ever been adversely affected by an earthquake. This paper explains why open pit slopes are seemingly more resistant to dynamic loads than natural landforms, which can experience catastrophic landslides.Extreme rainfall events are much more likely to cause open pit slope problems when compared to earthquakes. Two types of problems are common – slope erosion and slope instability. Slope erosion is often mitigated by appropriate surface water controls. Slope instability due to elevated transient water pressures is more difficult to mitigate. Analysis procedures and acceptability criteria are rare, but do exist. In Peru, for example, slopes are required by law to be designed for a 100-year storm."

Jan 1, 2016

By C. J. Badenhorst

The primary focus of management today is safety, or preventing negative, generally irreversible, events of acute duration. The outcomes of safety-related events are usually visible and can evoke strong emotions if the results are severe. Experts now see that occupational illness and disease also result in significant emotional and financial toll to workers, their families and communities, and to their employers. Effective health and safety management must include acknowledging the importance of occupational health hazards and the proportionate application of resources to address those issues. Improvement in workplace conditions and decrease or elimination of illness and disability are due to actions within the workplace and result from the implementation of risk prevention and control measures. However, success may only be visible months or years later and may require interventions that have to be maintained over prolonged periods. This demands continuous, co-ordinated effort to ensure sustainability of diverse occupational health programmes and the relevant management systems. Too often occupational health is not seen as being part of the general management of business, but rather the function of a medical practitioner somewhere off site in a clinic. Integration of occupational health management systems with other management systems within an organization is essential for its success.

Jan 1, 2004

By J. A. L. Napier

It has been established that significant time-dependent stope convergence may occur over time periods of hours and days in certain hard-rock gold and platinum mines. The source of this time-dependent behaviour appears to be associated with both pre-existing discontinuities and with mining-induced fractures that form near the stope face. These induced fractures may be associated with blasting processes and may also be formed in response to high stress concentrations in the unmined regions immediately ahead of the stope face. In shallower platinum mining operations, time-dependent behaviour is, however, observed to be much less marked unless some form of specific mining-induced fracturing occurs. One particular case of considerable interest is the time-dependent behaviour that is found to be associated with the formation and deployment of crush pillars. The purpose of the paper is to present a simple limit-equilibrium computational model of this behaviour that is sensitive to both the formation sequence and the size of planned crush pillars in a mine layout. This model provides a useful means to optimize the sizing of crush pillars, and at the same time may be used to identify potentially hazardous circumstances in which pillars may not crush in a stable manner.

Jan 1, 2012

By Z. Halifa, P. G. Geyer

Tapping a blast furnace is necessary not only to deliver the product, but is also essential for the safety of the furnace and workers in the cast-house. This paper will highlight the practices at ArcelorMittal’s blast furnaces in the Vanderbijlpark Works, with specific focus on tap-hole design and monitoring as well as casting practice. Extension of the tap-hole life and hearth campaign will be illustrated with reference to the methods of maintenance of the tap-holes, troughs, runners, and cast-house equipment. The importance of proper cooling, good thermocouple installation, and temperature monitoring will be explained.

Jan 1, 2014

By P. K. Hofmeyr

Traditional fire assay dates back over 3000 years and has changed very little over that time. The only improvement is to replace the gravimetric finish with dissolution of the Precious Metal bead followed by AA or ICP analysis of the solution. The newly developed FIP A (Fast In-line Fire Assay) method allows full automation of the fire assay process from sample preparation to spark analysis of the Pb button. This results in fully quantitative analyses for Pt, Pd, Rh, Ru, lr, Au and Ag in typically less than an hour after a sample is entered into the system. Detection limits are theoretically Pt 0.08 ppm, Pd 0.002 ppm, Rh 0.002 ppm, Au 0.08 ppm and Ag 0.002 ppm but in practice the lower measurable limits are about double these figures. Few opportunities have been available to present data obtained using the FIFA system as all FIFA laboratories have been in the domain of a Pt mining company which prefers to keep all Pt analytical matters confidential. However, IMP has recently participated in the round robin exercise to establish recommended values for a new series of Merensky Reef and UO-2 Layer reference materials produced by African Mineral Standards. The precision of the results was excellent being on average Pt 2.05%, Pd 1.25%, Rh 4.08% and Ru 4.94% being expressed as Relative Standard Deviation. The excellent precision is a reflection of the efficient collection of POEs in the Pb buttons and the homogeneity of the Pb buttons. However, the accuracy was not as good. The poorer accuracy is interpreted as the calibration of the spectrometer not being as good as desired due to the difficulty in acquiring a suitable range of standards with reliable recommended values for the PGEs. The most recent spectrometer was calibrated with the greatest care and produced slightly better results for Pt, Pd and Rh and slightly worse for Ru.

Jan 1, 2014

By S. W. Evans, G. Pienaar

Weldable steel plate with a good combination of strength and toughness is currently produced from 0,12 to 0,28 per cent carbon low-alloy steel heat-treated by roller quenching and tempering. Alternatively, steel plate of the same strength can be produced at a lower production cost by the use of very-low-carbon steel (0,03 to 0,08 per cent carbon) processed by in-line quenching without tempering. This paper reports the results of experimental work on these steels, and compares them with the properties of conventional steel. On thinner sections, it was found that the properties of the experimental steels compare favourably with those of conventional grades.

Jan 1, 1989

By Z. Zitron, G. J. de Korte, D. W. Horsfall

This paper summarizes work carried out on the treatment of fine coal, nominally classified as minus 0,5 mm (wedge-wire screen), which is removed from the raw coal prior to the treatment of the plus 0,5 mm sizes. The minus 0,5 mm coal divides, for treatment purposes, into fines, nominally between 500 and 150 !tm, and ultrafines, nominally minus 150 !tm. Studies on processes for the treatment of minus 0,5 mm coal are discussed, and the lower size limit beneficiated is indicated for each process. The installation and operational results from a pilot froth-flotation plant treating minus 150!tm coal are described.

Jan 1, 1986

By M. Kumral, S. Hmoud

Optimising the configuration of infill drill holes is an important step during mineral exploration campaigns. However, this optimisation process encompassing all possible drilling configurations within a mineral deposit is highly combinatorial and hard to solve in a reasonable time. This paper proposes using spatial clustering algorithms to divide the orebody into contiguous zones and target the best zones with infill drilling in order to reduce the size of this optimisation problem. Several clustering algorithms are assessed in a spatial context on hypothetical datasets. This evaluation shows that the hierarchical density-based spatial clustering application with noise (HDBSCAN) algorithm can be used in combination with the uniform manifold approximation and projection (UMAP) dimensionality reduction algorithm to identify contiguous zones in the orebody.

Sep 1, 2021

By B. Besa, S. Nalukui

Globally, the demand for mineral products is ever increasing. Extraction of these mineral resources results in the continuous production of a huge volume of waste material, including tailing dumps. The mass of tailings usually exceeds the actual resource and often contains hazardous contaminants. This study investigated the effects of tailings disposal on soil, water, and air quality in the Nampundwe area. Water, soil, and dust samples were collected from different locations in the surrounding communities. The constituents analysed in the samples included copper, cobalt, iron, sulfate, and silica. According to the results obtained, some seepages occurred from the tailings impoundment to the shallow aquifer in the area. However, the general water quality meets the Zambia Environmental Management Agency (ZEMA) statutory limits. Recorded concentrations of sulfate (1500 mg/l), copper (1.5 mg/l), cobalt (1.0 mg/l), iron (2.0 mg/l), and silica were between 0.003 mg/l and 705 mg/l, which is far below ZEMA’s statutory limit. Silica concentration was also evident in the air. The highest concentration recorded was 260 ppcc (particle per cubic centimeter) recorded in July 2019 from the northern direction of the tailings dam. The concentration was below the statutory limit of 350 ppcc. The topsoil from the northern part of the tailings recorded a silica dust concentration of 39.9 ppcc. Iron was evident in the underground soil with a concentration of 8.01 ppcc, cobalt 0.005 ppcc, copper 0.051 ppcc, while sulfate was recorded as 0.41 ppcc.

Oct 9, 2024

By J. K. Pothal, S. Basu, R. Barik, P. K. Senapati, A. Dubey

The aim of this paper is to study the characteristics of limestone particles (size varies from 4 mm to 20 mm) during its transportation from open cast mines through pipes. The influence of four different size fractions of limestone samples (4–6 mm, 6–10 mm, 10–15 mm, and 15–20 mm) on pipe flow characteristics during vertical transport in a 100 mm NB hose pipe was investigated. The flow velocities in the vertically lifting pipe was varied from 0.95 m/s to 2.78 m/s and a rotary feeder of 2 to 4 tonne/hr. capacity was employed to feed the limestone samples to the lifting pipe. The pressure drop data for the different size fractions of limestone samples at different mixture velocities were analysed. The effect of input volume fraction and superficial velocity of limestone samples on hold-up ratio were discussed. It was indicated that there was no substantial increase in pressure drop of slurry samples in the studied range of concentrations (CW = 4.22% - 12.54%), particle size, and low to medium range mixture velocities with respect to water run head loss data. The hold-up for the larger size fractions (15–20 mm) of limestone samples was found to be significant as compared to smaller size fractions, which may be due to terminal settling velocities of individual fractions of the studied samples.

Mar 4, 2025

By P. Cowx, L. Els, P. Smith, R. Nordhagen

"Tapping operations at ferroalloy smelters generate a significant amount of fume. Effective capture of fumes is required to meet the obligations of environmental, as well as occupational, legislation.A study was completed on an existing fume extraction system at a ferromanganese furnace tapping area. The area under consideration included the tap-hole, launder, and ladle area. The study consisted of site test work as well as computational fluid dynamics (CFD) modelling to identify and evaluate solutions.Site test work and observations during furnace operation provided a baseline of system performance as well as input parameters for CFD modelling. Gas flow rates and energy contents from each extraction area were measured. Photographs and video footage were taken to evaluate areas of fume leakage.The CFD study was firstly validated against site observations to ensure the accuracy of input parameters. Thereafter several modification concepts were modelled and suitable combinations were investigated to ensure robust solutions. The following concepts were considered:•,Air curtains•,Ladle hood aspect ratio and position•,Increase of ladle extraction volume•,Extension of the length of the tapping garage structureThe paper presents the results of a performance test on a working ferromanganese tapping area fume extraction system and the results of CFD modelling as compared to site test results. Upgrade options are evaluated and an integrated robust upgrade of the system described."

Jan 1, 2014

By J. Petersen, H. Naderi, M. H. Nikzad, M. Karimi

In this research, the thermodynamic study of sodium persulfate (Na2S2O8) solution in the presence and absence of H2SO4 and Fe3(SO4)3 was done. Eh-pH and equilibrium distribution diagrams were constructed using Outotec HSC Chemistry Software and the main stable ionic species were determined. Also, the mean activity coefficient and Pitzer model coefficients were evaluated. Effects of system composition, sodium persulfate concentration and temperature were investigated. According to the results, HS2O7 -, HS2O8 -, S5O3 2-, S4O3 2-, S3O3 2-, HS- and NaSO4 - are the main stable species in these three systems. Increasing of sodium persulfate concentration resulted in disappearing of SO4 2- and the appearance of NaSO4 -. The main effect of increasing the temperature from 25 to 75oC, is changing the stability regions of HS2O7 -, NaSO4 -, SO4 2- and S2-. From equilibrium studies, it was concluded that at 25 and 50oC, increasing the persulfate concentration results in a 55-60% decrease for HS2O7 - and an 20- 30% increase for HS2O8 -. At 75oC, HS2O8 - becomes the main species and its percentage decreases with increasing the persulfate concentration. Keywords: Thermodynamic, sodium persulfate, activity coefficient

Jan 1, 2020

By F. Nakhaei, M. Le Roux, Q. P. Campbell, S. Botlhoko

The results of coal sink and float tests are plotted as washability curves. Analysis of these curves indicates the most effective method by which the coal can be cleaned. Sink and float experiments are samplingdependent, destructive, and use toxic chemicals. The present research introduces an alternative method based on a 3D imaging system called RhoVol, in which the density of individual particles is determined from mass and volume measurements. A quantitative error analysis was conducted on coal sample density measurements obtained by RhoVol, and the main factors influencing the errors identified and investigated. The results show that the drawback of this technique is related to its not being able to detect hidden concavities in the particle, resulting in an overestimation of particle volume. Furthermore, it is difficult to capture the impact of porosity and cracks on the volume of coal particles obtained from 3D silhouette images. This mismatch between the RhoVol data and sink and float test results has led to attempts to apply neural network (NN) and linear regression techniques to produce a fully reliable model for correction and estimation of coal density. The NN approach offers superior predictive capability over linear regression, and the estimated density distribution is in line with the sink and float analysis. The root mean square error in estimation of density using the NN model was less than 0.05 g/cm³.

Aug 2, 2022

By B. McFadzean, S. Pikinini, C. T. O’ Connor

Sperrylite (PtAs₂) comprises about 21% of the platinum group minerals (PGMs) in the Platreef ore and regularly reports to the tailings due to its poor floatability. Hence, improving its recovery will be of great economic value to the South African PGM industry. The reasons for its poor floatability are not yet clear. This paper seeks to understand the interactions occurring between PtAs₂ and common thiol collectors, viz. potassium normal butyl xanthate (PNBX), sodium normal dibutyl dithiophosphate (SNBDTP) and sodium normal mono butyl dithiocarbamate (SNBDTC). By understanding its interactions with these collectors, it is hypothesised that it will be possible to suggest ligands that may help improve the floatability of sperrylite. Mineral-collector interactions were studied by determining the molar energy of interaction using isothermal titration calorimetry and electrochemical techniques. The hydrophobicity of the mineral before and after adsorption of the collectors was determined by heat of immersion and its flotation response determined by microflotation tests. Microflotation tests using synthetic sperrylite at pH 9 showed low collectorless recovery of 34.8% and after adding the equivalent of one pseudo-monolayer of the PNBX collector, the recovery of 32.5% was obtained. Moreover, the addition of up to three pseudo-monolayers coverage of PNBX did not result in any increase in flotation recovery. A small recovery improvement was noted when synthetic plant water with the ionic strength of 0.0484 mol/L was used, but this did not hold for all collectors, with SNBDTP exhibiting higher recoveries in distilled water. Keywords: Sperrylite; flotation; recovery; adsorption energy; collectors; 2SPW (synthetic plant water)

Jan 1, 2020