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By S. P. Molefe

Mr Chairman, members of the executive committee, the sub-committee, distinguished speakers at this opening plenary session, delegates, affiliates, ladies and gentlemen. It is with pleasure that I have been called upon today to make these opening remarks and officially welcome you al at this auspicious assembly, the Fifteenth Congress of the Council of Mining and Metallurgical Institutions. Not only am I pleased to open the proceedings at this plenary session but for me to do so at Sun City in the North-West Province makes me doubly pleased. It is my wish that al delegates and their companions will enjoy the activities that are planned throughout the Congress and leave here with minds refreshed and stimulated by the technical sessions and memories enriched by being in such a unique and truly delightful setting as exists here at Sun City. The mix of delegates present reflects CMMI activities in many countries throughout the world-Australia, Japan, China, United Kingdom and South Africa among others. When it comes to mining and related activities, South Africa has a place at the top, a dominant role in platinum, gold, chromium, vanadium, dimension stone, coal and so forth, and here in the North-West Province we can proudly declare that some 25 per cent of the revenue from minerals in South Africa, namely R47 billion come from this area. Furthermore, we lead in the production of platinum group metals with 94 per cent of South Africa's total sales and thus hold first place in the world, 46 per cent of dimension stone sales, 32 per cent of chromate and 25 per cent of gold sales.

Jan 1, 1994

By A. K. Das, S. Pathak, C. Bhanu, P. K. Tripathy

Ferroalloys are integral part of steel melting process. The purpose of using ferroalloys is three fold e.g. killing of steel, modifying the slag composition and steel alloying. Amount of ferroalloys used for alloying is subject to requirements of steel properties e.g. yield strength, ductility, formability etc. Variety of ferroalloys (some-times pure metal) is used by steel industries depending upon their techno-economic feasibility. Size, chemistry and modes of addition of ferroalloys are suitably engineered to bring in operational consistency and cost benefits. Of late, Tata Steel has tried out a few ferroalloys for the first time with interesting results to meet the specific requirements of high strength interstitial free (IF) and micro-alloyed steels. Some of these ferroalloys have been put into regular use with complete or partial replacement of ferroalloys used earlier. Size of one of the ferroalloys has also been modified without any other adverse effects. This paper summarizes requirements of ferroalloys for the steel industry with special emphasis on recent trials.

Jan 1, 2007

By B. I. Matshediso, J. Kaavera, E. Shemang, T. K. Dintwe, L. S. Teseletso, K. Fichani

The minerals sector continues to draw attention from policy makers who would want to see both old and new mineral projects add value to the minerals in the host country. The current technological development in the leaching of manganese oxide ores to produce a high-purity manganese sulphate monohydrate, a compound that is used in the manufacture of batteries for electric vehicles or long-life storage cells for the renewable energy market, has led to junior mining companies spearheading this technology in new projects across the globe. In this paper, we researched the high-purity manganese sulphate monohydrate project pipeline and used projected production volumes and C1 cash costs to construct the industry supply curve for six projects, including the K.Hill project owned by Giyani Metals Corporation near Kanye, in the southern part of Botswana. The aim was to determine the ideal conditions that would provide a comparative advantage for further local value addition to high-purity manganese sulphate monohydrate and to the end user product. The results showed that while the estimated C1 cash costs would place the K.Hill project as the second highest cost producer from among five projects, it would nonetheless have healthy profit margins due to the high projected price of high-purity manganese sulphate monohydrate. The study recommended policy options, which, if implemented, could further encourage the exploitation and value addition of battery metals in Botswana.

May 27, 2025

1. Book reviews Geophysical and geochemical techniques for exploration of hydrocarbons and minerals, edited by M. Sittig. (Reviewer: J. Keenan) Separation procedures in inorganic analysis. A practical handbook, by Roland S. Young. Charles Griffin, 1980. £23.00. (Reviewer: R. Murray-Smith) 2. Historical reprints Theinin~rs dictionary, by William Hooson. £14. Discovery of subterraneal treasure, by Gabriel Plattes. £12. Fodinae Regales (The Mines Royal), by Sir John Pettus. 3. De Beers' booklets Amborite - a remarkable new cutting material, by De Beers Industrial Diamond Division (P.O. Box 916, Johannesburg 2000). Booklet, 14 pp., free of charge. Natural and synthetic micron powders, by De Becrs Industrial Diamond Division (P.O. Box 916, Johannesburg 2000). Leaflet, 5 pp., free of charge. 4. New books Nickel in the environment, edited by J. O. Nriagu. New York, Wiley, 1980.928 pp. $65. Underwater minerals, by D. S. Cronan. London, Academic Press, 1980. 364 pp. $57.50. Data conversion integrated circuits, edited by D. Dooley. New York, Wiley, 1980.298 pp. $26.95 (cloth), $17.50 (paper). 5. NIM reports Report 2057 A mineralogical study of the Rooibokkop- Boschhoek copper deposit in the Marble Hall area. Report 2069 A utomatic setting of the distance between sample and detector in gamma-ray spectroscopy. Report 2070 The prereduction of chromites from the UG-2 Reef. Report 2075 The optimization of some of the conditions for analysis by spark-source mass spectrometry. Report 2082 A survey of the literature on gravity separation.

Jan 1, 1981

By N. P. Mabasa, N. Naudé, A. M. Garbers-Craig

An improved methodology is presented for assessing the economic feasibility and effectiveness of recycling MgO-C and Al2O3-MgO-C refractory bricks, which are widely used in the steelmaking industry. Since approximately 28 Mt of refractory bricks are discarded each year, it is logical to recycle them. When furnaces and ladles are relined, the spent refractory bricks become mixed up, and need to be sorted before recycling. This study examined the use of a hand-held X-ray fluorescence analyser (HH-XRF) to distinguish between spent oxide-based and oxide-carbon-based refractory materials, with special emphasis on spent MgO-C (MC) and Al2O3-MgO-C (AMC) bricks. HH-XRF analysis was conducted on 18 oxide-carbon refractory bricks as well as on MgO-chromite and bauxite-based refractories. X-ray diffraction, reflected light optical microscopy, and scanning electron microscopy with energy dispersive spectroscopy were used to characterize the MgO-C and Al2O3-MgO-C bricks to confirm the accuracy of the HH-XRF analyses. This study also underlined the importance of calibrating the HH-XRF analyser for the refractory bricks to be sorted. The HH-XRF was successful in distinguishing between the different oxide-carbon-based refractory bricks both before and after cleaning. This result is important as it proves that HH-XRF provides a method whereby spent MC and AMC bricks can be sorted quickly and reliably.

Jan 26, 2023

By G. van Aswegen

The geometry and morphology of a set of low-angle fractures around a stope in a deep Witwatersrand gold mine are explained in terms of extension fractures forming under variable conditions of stress. Primary extension fractures (E1) form some distance ahead of an advancing stope along the s1, s2 plane. With stope advance, a couple of these fractures end up in a stress regime conducive to transpressional shear and a secondary set of extension fractures(E2) is formed at a high angle to the primary fractures. i.e. at a low angle to the stope. As the E2 fractures are undermined, they migrate into a stress regime of transtensional shear and a third set of extension fractures (E3) may develop between E2 fractures. These have sigmoidal shapes, being parallel to the E2 fractures at the E2 discontinuity where s3 is negative, and curved through the unfractured rock between E2 fractures where s3 is positive at the instant of fracturing. The fractures all display fractographic features characteristic of dynamic extension failure with striae indicative of the direction of rupture propagation and the local, instantaneous orientation of s1.

Jan 1, 2012

By G. Popplewel

Commencing with the Pre-Feasibility Study (PFS) conclusions, the Orapa 3 process design evolved through a phase of value-engineering studies. An overall re-evaluation of the originally proposed process design was necessary both in order to address the interim increase in target throughput from 9.8 Mtpa to 12 Mtpa as well as to increase capital efficiency. In the interests of clarity, the PFS process design for Orapa 3 has been omitted from this paper, as it is no longer relevant. Recognition is however due to those engaged in earlier phases of the Orapa 3 project with respect to fundamental mass-balancing modelling; and ore and diamond characterization, which fanned the basis for the process design that has evolved from feasibility study activities.

Jan 1, 2010

By A. Dienenthal

"The casthouse floor has always been one of the most dangerous working places on a blast furnace or a ferro-alloy/nonferrous furnace. Apart from working in an atmosphere including toxic gases, fumes, and dust, the workers have to perform hard and heavy manual work close to runners and ladles filled with hot liquid metal and slag.Before the invention and installation of tapping equipment the tap-holes were opened and closed manually. Opening was done by means of steel bars and sledgehammers, whereas the tap-hole was closed by repeatedly ramming small amounts of clay or refractory material into the tap-hole, again with the help of long, heavy bars. In addition, on blast furnaces the blast had to be stopped, since it was impossible to close the tap-hole properly against the blast furnace pressure. This stoppage of the blast resulted in regular losses of production. Around 1900 a major change in technology occurred. Samuel W. Vaughen, superintendent of the blast furnace department of the Cambria Iron company at Johnstown, Pennsylvania (USA), invented the first clay gun in 1895 (Wiley, 1896) (Figure 1)."

Jan 1, 2014

By H. E. James

During the past ten years there has been an upsurge of interest in the development of selective ion exchange resins and solvents, and of ion-exchange and solvent extraction equipment tailored to the special requirements of mineral-processing circuits. It is therefore not surprising that the recent Symposium on Ion Exchange and Solvent Extraction in Mineral Processing, held at the National Institute for Metallurgy (NIM) on 7th and 8th February, 1980, was a resounding success. This Symposium, organized jointly by NIM. Ion exchange and solvent extraction The Symposium on Ion Exchange and Solvent Extraction in Mineral Processing, which was organized jointly by the National Institute for Metallurgy, the South African Institution of Chemical Engineers, and the South African Institute of Mining and Metallurgy, was held in Randburg on 7th and 8th February, 1980. Analytical chemistry The Fifth International Conference on Analytical Chemistry, organized by the Chemical Society, is to be held at Lancaster University, England, from 20th to 26th July, 1980. Coal mining The First International Symposium on Thick and Steep Seam Coal Mining will be held in London from 18th to 21st May, 1980. Mineral processing The XIV International Mineral Processing Congress will be held in Toronto from 10th to 16th October, 1982. The theme of the congress will be 'Worldwide industrial application of mineral processing technology'. Sessions will be held on the following:

Jan 1, 1980

By M. D. G. Salamon

If a transition from one equilibrium state to another occurs during the course of mining, energy transfer takes place in the rock mass, which is assumed to be an elastic continuum. The energy components are defined as follows: the work done by external and body forces, W; the increase in stored energy in the mass, Uc; the strain energy in the rock mined during the transition, Urn; the work done on mine support or backfill, Ws; and the released energy, Wr. The energy balance is defined as (W + Urn) - (Uc + Ws) = Wr> 0, where the first set of components in parentheses represents the sources of energy, while that of the second corresponds to the known modes of energy expenditure and the component on the right is the unaccounted-for energy surplus, which must be released and dissipated in some form. The inequality Wr ~ Urn> 0 applies. Expressions for the energy components are derived first for the general case and then for the 'slit' modal used to simulate tabular excavations. Through specific examples, the importance of the progressive nature of mining is emphasized. The size of the steps used to enlarge the excavations appears to play a significant role in the mode of energy transfer. This observation forms the basis of the second paper in this series of two papers.

Jan 1, 1984

By K. G. Lomberg, M. D. Lionnet

The Bafokeng Rasimone Platinum Mine (BRPM) is a joint venture between Rustenburg Platinum Mines Limited and Royal Bafokeng Resources (Pty) Ltd (Bafokeng). The mining lease has been granted over Boschkoppie 104JQ and is located approximately 10km south of the Pilanesberg Alkaline Complex. The Merensky Reef, which constitutes the principal ore body, is geologically complex. A relationship between its geological variability and the associated mineralisation has been established by defining a number of facies types. The Merensky Reef has been sub-divided into seven distinct facies types: the pegmatoidal facies, contact facies, FW1 pothole facies, FW3pothole facies, FW6 pothole facies, and FW7 pothole facies. The Merensky Reef, which does not form part of the potholed reef, has a large component of footwall mineralisation. The pothole facies, in contrast, has mineralisation located in the hangingwall. Statistical analysis of the facies types indicates that they are unique populations and hence need to be evaluated independently. The mining lease has distinct structural domains that have added additional complications to evaluation of the Merensky Reef. The Merensky facies on BRPM exhibit unique geological and statistical characteristics within well-defined structural blocks. Due to the extreme variability of the Merensky Reef on BRPM a unique approach has been developed, within Anglo Platinum, to evaluate the deposit. Mining cuts are defined and composited for the individual facies types, and then modelled individually by applying known geological controls. The resultant grade models are weighted based on statistical and local geological knowledge. The object of weighting the facies is to replicate the variability observed in the ore body. The introduction of stringent geological controls to the evaluation process has resulted in increased confidence in the in situgrades estimated as an input to the mine planning process

Jan 1, 2006

By Mike de Wit

Of the approximately 6,500 kimberlites known to date, less than 3% are diamondiferous and less than half of those are economically viable. Admittedly, this is a global figure and varies from area to area much depending on geological, logistical, and political circumstances. The number of diamond-bearing kimberlites is an important geobarometer, and an age-frequency profile has been compiled in order to identify diamond metallogenic epochs and provinces. Four primary diamond clusters have been recognized: Siberia (332-370Ma), Kaapvaal South(114-144Ma), Kaapvaal Southwest(84-95Ma), and Slave (52-55Ma). In addition, three secondary clusters are the Kaapvaal Central (S06-S38Ma), the Man Craton (139-lS3Ma) and the Kasai Craton (120-130Ma). The Kaapvaal is the only area where kimberlites with diamonds were discovered between 1870 and 1925, except for the Prairie Creek discovery in North America in 1906 and Colossus in Zimbabwe in 1907. Between 1906 and 1940 no major diamondiferous kimberlites were discovered, but many of Africa's alluvial deposits were found and exploited in that period. Advances in scientific prospecting in the 1940's rapidly accelerated the discovery rate that peaked in the 1990's; 39 diamondiferous occurrences were found in the 1980's, of which 8 became mines and 5 are in feasibility, and nearly 450ha of kimberlite was added to the global resource base. Despite the accelerated exploration expenditure, the last decade (e.g. 2000-2009) has been the leanest since the 1940's. The most important reason for this decline in exploration success is that any undiscovered deposits are largely buried by younger cover. Understanding complex and geophysical noisy basement geology, as well as decomposition of path-finder minerals are major challenges to further exploration success. Major investments in basic geological expertise and field research will have to be made in order to secure future diamond resources. Integrated geophysical studies, geochemistry diamond forensics, and improved imaging of Earth's upper mantle are perhaps foremost in this requirement, but the costs of these activities are such that government support will be required if countries are to sustain their diamond mining industry.

Jan 1, 2010

By S. Lohmeier, D. Gallhofer, B. G. Lottermoser, T. Schirmer

At a time of resource consumption, it is important to study the chemical composition of mining and metallurgical wastes to prevent the dissipative loss of metals and metalloids from the mining value chain. In particular, the recovery of critical elements from wastes is an option to increase the resources of such materials that are economically significant and have an overall supply risk. In this paper we report on the chemical composition, in particular the critical element content, of granulated slag originating from historical smelting activities in the Tsumeb area, Namibia. Laboratory-based inductively coupled plasma–mass spectrometry (ICP-MS) and X-ray fluorescence (XRF) analyses as well as portable X-ray fluorescence (pXRF) demonstrate that the slags are on average enriched in base metals (Cu 0.7 wt%, Pb 2.7 wt%, Zn 4.7 wt%), trace metals and metalloids (Cd approx. 50 mg/kg, Mo approx. 910 mg/kg) as well as critical elements (As approx. 6300 mg/kg, Bi approx. 3 mg/kg, Co approx. 200 mg/kg, Ga approx. 100 mg/kg, In approx. 9 mg/kg, Sb approx. 470 mg/kg). While metals and metalloids such as As, Mo and Pb can be determined reliably using pXRF instruments, the technique has inherent limitations in evaluating the contents of certain critical elements (Ga, Sb). However, there are positive correlations between the As, Mo, and Pb contents determined by pXRF and the Ga and Sb contents obtained through ICP-MS and XRF. Thus, quantitative pXRF analysis for As, Mo, and Pb allows calculation of Ga and Sb abundances in the slags. This work demonstrates that pXRF analysers are a valuable tool to screen smelting slags for their chemical composition and to predict the likely contents of critical elements.

Mar 1, 2021

By C Katongo

Ground condition at No1. Shaft varies across the mine. The different ground conditions arise as a result of the differences in the rock strength and structure, seismicity and induced stresses in abutments areas. Apart from being a major cause of Fall of Ground incidents/accidents, adverse ground conditions where encountered has affected the rate of development advance as well as production. This implies that for support to be cost effective Geotechnical section has to ensure that support is designed to prevailing ground demand to ensure the safety of personnel and minimize loss of production. We have also seen changes in mining methods as a result of change in ground conditions. To avoid incurring unnecessary costs through remedial works resulting from ground deterioration and collapses of development openings due to inadequate support, the principle in engineering design is ?Do it right the First Time?, and this can only be achieved through good understanding of Geotechnical environment. The paper discusses the different ground conditions encountered in various development ends at No.1 Shaft. It also discusses the principles of ground support, failure mechanisms, types of ground support systems employed, and the different techniques used to select support systems, and quality control techniques in underground support installation.

Jan 1, 2005

By Md. Amanullah

A novel triple action load cell assembly (LCA) was developed to determine three index parameters reflecting compressive, tensile and shear characteristics of mudcakes. The results indicate that the tensile, compressive and torsional behaviour of mudcakes are strongly influenced by the physics and chemistry of the mud additives. Eine neuartige dreifach wirkende Druckkammer zur Bestimmung der drei Indexparameter Druck, Zug, und Scherung von Spülungskuchen wurde entwickelt. Die Ergebnisse weisen auf einen starken Einfluss der physikalischen und chemischen Spülungszusätze auf Druck, Zug, Scherung hin. Un assemblage d'une nouvelle cellule a triple action (LCA) a été développée pour déterminer trois paramètres caractérisant la compression, la contrainte en traction et la résistance á la fracture des cakes. Les résultats indiquent que les comportements tensile, compressif et de torsion des argiles sont fortement influencés par la chimie et la physique des additifs des boues.

Jan 1, 2003

By X. M. Prévost

The reassessment of coal reserves has become a matter of urgency and has come as a result of the present situation of the industry, in the context of globalized coal economies, as well as new mining legislation and the advantages and difficulties of domestic coal suppliers. The de Jager report concerning coal reserves, released twenty years ago, can no longer be used as an estimate for accurately forecasting South Africa’s future coal production. The new reserve and resource study will promote the diversification of energy sources and provide a clearer view of the future of coal mining in the country. With plans to increase South Africa’s coal export capacity to approximately 84 million tons by 2005, it is uncertain whether the country really has sufficient reserves to meet this expansion, as well as satisfy the projected increase in inland demand. The face of South Africa’s coal industry and by association, the economy of our coal-dependent country, are both set to change. This is mainly due to factors such as the demise of most of the large collieries over the last approximately twenty years, growing numbers of economic empowerment producers, the emergence of strong competition in the export market, the dawn of Clean Coal Technologies (CCTs) and the Kyoto Protocol The paper will attempt to dispel some of the current myths about coalfields and reserves and highlight potential areas of high quality coal reserves, available mainly to new entrants in the industry. Keywords: Central Basin, Clean coal technologies, Coal combustion, Coal exports, Coalfields, coalLink, Coal reserves, Coal resources, Coal processing, Colliery, Economic empowerment, Discards, Fluidized bed combustion, Low-ash coal, Metallurgical coal, Power generation, Pulverized fuel, Reserve blocks, Richards Bay Coal Terminal, Run-of-mine production, Saleable production, SAMREC Code, South Dunes Coal Terminal, Steam coal, Synthetic fuels.

Jan 1, 2003

By M. R. L. Blackwell

Over the period 1964 to 1969 Conzinc Riotinto of Australia undertook and completed an evaluation of a large low-grade copper orebody on Bougainville Island in the Territory of Papua and New Guinea. From the outset it was clear that the geographic, climatic and topographic characteristics of the area would necessitate a heavy capital outlay on production and support facilities. Both the physical problems and the magnitude of the investment amplified the need for a thorough and rigorous evaluation of the various strategies for exploiting the orebody. In view of the number of independent and inter-related variables and the flow of new data, a computer-based evaluation process extended the scope and depth of the analysis considerably. The system used permitted an iterative assessment and re-assessment of the various strategies with the results becoming increasingly refined with time. This process encompassed the modelling of the orebody, the simulation of alternative operating strategies and the determination of the financial profitability of the project,

Jan 1, 2014

By A. Tosun

Muckpile fragmentation formed by blasting depends on the specific charge factor, the discontinuities in the rock mass, and the rock strength. Determination of the discontinuity characteristics and rock strength is a long and difficult process. These two parameters are directly associated with the rock drilling speed. Therefore, it is the drilling speed of the machine used for the blast-hole, rather than the blasthole discontinuity characteristics and rock strength parameters, that is used in the prediction of muckpile fragmentation before blasting. Primarily, it has been suggested that the muckpile fragmentation values can be correctly determined by establishing correlations between the efficiency of the loader and muck pile fragmentation, since fragmentation is directly correlated with the former parameter. Subsequently, a correlation predicting the drilling speed of the drill machine was developed according to the discontinuity characteristics of the blasting surface and the rock strength. Finally, a correlation was developed predicting muckpile fragmentation according to the specific charge factor and the drilling speed of the drill machine The data was obtained by conducting blasting tests in two different limestone quarries.

Nov 30, 2022

By R. Armstrong

The stability of rock slopes is significantly influenced by their curvature in plan view. The importance of this in open pit mining is indicated by the fact that, in a deep pit, steepening of the slopes by 1° may save as much as $100 million. It is considered that there are two significant factors that play a part in the influence of plan curvature. These two factors are the effect of stress, and the effect of geological structure. The scant literature that pertains to this aspect of rock slope design was reviewed. The geometrical influence of the plan curvature was then investigated. It was seen that it has a parabolic effect on the maximum possible wedge that can fail into a circular pit, where the tighter the concave curvature the smaller the wedge. The plan curvature also affects the volume of a particular wedge, where concave slopes result in an exponential decrease in the volumes and convex slopes have exponentially increased wedge volumes. A change in the strike of the wedge did not affect the curvature’s influence on the volume, but the volumes of shallower dipping wedges were affected more by the influence of the plan curvature. La stabilité des talus des roches est très influence par la courbure de celles ci dans la vue en plan.Son importance de l peut arriver à sauver même $100 millions. Il est considère qu il y a deux facteurs importants qui jouent une influence sur cette courbure. Il s’agit de l’effet des contraintes et l’effet de la structure géologique. La brève littérature qui se réfère à cet aspect du conception sur le talus des roches a été revue. L’influence géométrique de la courbure des plans a été investiguée. Il a été vu que cela un effet parabolique sur la bosse ou le su relèvement maximum possible qui peut faillir dans un puits circulaire, ou le plus resserre est la courbure concave, le plus petit est su relèvement (bosse). La courbure plane aussi affecte le volume d’un particulier su relèvement ou les talus concaves résultent dans une décroissance exponentielle en volume alors que les talus convexes accroissent la volume de ces su relèvements (bosse). Le changement de l’orientation de la bosse (su relèvement) perpendiculairement ou obliquement n’ a par affecte l’influence de al courbure sur le volume mais les volumes des bosse (su relèvement) peu profonds étaient affectes par la courbure des plans. Die Stabilität der Felsensteigungen wird erheblich durch ihre Biegung im Plan beeinflußt. Der Wert von diesem in der Tagebaugrube wird durch die diese Tatsache, in einer tiefen Grube, steepening der Steigungen durch 1° angezeigt; kann soviel wie $100 Million speichern. Es wird betrachtet, daß es zwei bedeutende Faktoren gibt, die eine Rolle im Einfluß der Planbiegung spielen. Diese zwei Faktoren sind der Effekt des Druckes und der Effekt der geologischen Struktur. Die dürftige Literatur, die diesen Aspekt des Felsensteigungdesigns betrifft, wurde wiederholt. Der geometrische Einfluß der Planbiegung wurde dann nachgeforscht. Es wurde gesehen, daß es einen Parabolischen Effekt auf dem maximalen möglichen Keil hat, der in eine kreisförmige Grube ausfallen kann, wo, das fester die konkave Biegung, das kleiner der Keil. Die Planbiegung beeinflußt auch das Volumen eines bestimmten Keils, in dem konkave Steigungen eine exponentiale Abnahme an den Volumen ergeben und konvexe Steigungen exponential Keilvolumen erhöht haben. Eine Änderung im Schlag des Keils beeinflußte nicht den Einfluß der Biegung auf das Volumen, aber den Volu

Jan 1, 2003

By P. P. Kim, M. Tangstad, T. A. Larssen

"The kinetics of MnO and SiO2 reduction in SiMn slags based on Assmang/Comilog ore and HCFeMn (highcarbon ferromanganese) slag were investigated between 1500 and 1650°C under a CO atmosphere. The results showed that charges containing HCFeMn slag had relatively faster reduction rates than those without. The difference in the driving force for MnO reduction was insignificant among the SiMn slags at 1500°C, which implies a low contribution of the driving force for reduction rate. The slag viscosities were also rather similar, around 1 poise at 1500°C, which could not explain the different reduction rates. Instead, the different charges containing various sulphur contents are believed to give rise to the varying reduction rates. The estimated activation energies for MnO reduction were around 500–920 kJ/mol for charges containing HCFeMn slag, and between 250–300 kJ/mol for those without. Based on the estimated kinetic parameters, the considered rate models were able to describe the reduction of MnO and SiO2 in SiMn slags between 1500 and 1650°C. IntroductionManganese ferroalloys such as ferromanganese (FeMn) and silicomanganese (SiMn) are important ingredients in steel production due to the beneficial effects of manganese on the physical properties of steel. Mn enhances the strength, toughness, and hardness of steel products, and both Mn and Si are used as deoxidizers to prevent the development of porous structures (International Manganese Institute, 2014; Olsen, Tangstad, and Lindstad, 2007; Subramanyam, Swansiger, and Avery, 1990; Tomota et al., 1987).The thermodynamic background of manganese ferroalloys is well established (Olsen, Tangstad and Lindstad, 2007), but kinetic information is rather scarce, especially for the SiMn process (Tranell et al., 2007; Tore-Andre Skjervheim, 1994). The absence of kinetic information makes it more difficult to understand the reduction mechanisms of MnO and SiO2. It is not clear how different raw materials affect the SiMn process. The main metal-producing reactions in the SiMn process are described by Equations [1] and [2]:"

May 1, 2019