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By F. T. Da Silva

Concentrates of titaniferous minerals containing around 30 wt% Ta2O5 are processed hydrometallurgically by hydrofluoric acid leaching and solvent extraction, followed by the precipitation of hydrated potassium heptafluorotantalate. A fundamental study of the thermodynamics of this precipitation and recrystallisation was undertaken to increase understanding of the conditions most conducive to the production of pure, well-crystallised K2TaF7. Activity-pH diagrams for the Ta-K-F-H2O system explained the dissolution of Ta2O5 in fluoride solutions quite well and also the precipitation-recrystallisation of K2TaF7.H2O. X-ray diffraction and scanning electron microscopy confirmed the thermodynamic observations. It was concluded that the best precipitating agent for K2TaF7 from fluoride solutions is KF but a recrystallisation step in a HF environment produces purer, well-crystallised K2TaF7.H2O, eliminating oxy-salts and other impurities

Jun 21, 1905

By J Kokado, N Hatta, S Yabushita

A theoretical model is described for prediction of the capacity of fines from porous ores, such as cokes and sintered ores, to be removed by a pneumatic, horizontal-type classifier prior to charging into a blast furnace. First, the influence of variation in the apparent density and drag coefficient of porous ores on removal efficiency is analysed from a stochastic standpoint. The effect on efficiency of collisions between particles in the classifying region is then examined analytically in relation to the ratio of the mass flow rates of particles and air (the loading ratio). Finally, a theoretical model is constructed that takes these factors into account. Theoretical and experimental results are compared and classifying efficiency is discussed from both experimental and theoretical viewpoints.

Dec 1, 1993

By A Misra

In pursuit of solving the development rate problem the coal industry has investigated various development systems. While all the systems may improve the development rate they may not necessarily he cost effective. This paper carries out an economic analysis by developing cost models for present and future development systems for retreating longwall faces with particular reference to Australian longwalls. A critical cost analysis of various development systems is presented by taking into consideration all the costs associated with development systems. The costs have been divided into equipment, face and panel services, belt and structure, wages, roof and rib support, ventilation, consumables, power and maintenance. The annualised cost of various equipment has been obtained on the basis of depreciation rates prescribed by the Australian Taxation Office.

Jan 11, 1996

To maximise recovery by highwall mining, pillars must be designed which are long, slender and of relatively low width-to-height ratios. The strength of pillars with width/height less than 2 depends primarily on the mechanical response of the coal, due to the reduced influence of frictional restraint between roof and floor. A suitable pillar design approach therefore requires a method of estimating coal-seam properties. Experimental studies were carried out to determine ways of reliably predicting the large-scale mechanical properties of coal seams from small-scale test data. The studies led to a method of practical, systematic assessment of coal-seam properties based on measurement of coal rank and seam brightness profiles. The criterion employs the parameters sigma(c), m and s of the generalised Hoek-Brown empirical strength criterion for rock masses. A novel design approach combines the flexibility of modern numerical modelling programs with simple hand calculation for rapid assessment

Jun 21, 1905

The deposit was discovered during systematic reconstruction of the geological history of glacial overburden, which averages 6 m in thickness over 80% of Sweden, by geochemical sampling and searching for small grains of eroded bedrock. The gold is mainly concentrated in and around high-grade quartz veins within a broad shear zone, though the correlation coefficient between quartz and gold in samples is not significant. Production from two pits, now connected, in the Central and Eastern orebodies has increased steadily from 1 238 kg Au in 1989 to 2 120 kg in 1994, the highest in Europe. The mine has adapted and improved its mining methods to achieve significant productivity increases and cost reductions. Most of the improvements have been achieved through a better understanding of the controls on mineralisation and of the implications of those controls for selective mining. Geostatistics has played an important role in the quantification of grade variability and gold occurrence. Better blasting and loading techniques have improved selectivity, grade control has been enhanced by a grade-control drilling programme, and significant improvements in mineral processing have been made

Dec 1, 1995

By I. L. Bell

The ironmasters of America had asked the Iron and Steel Institute to visit the USA. The Council decided it was not possible to accept, but Mr. Bell visited; this is an account of his trip. Topics covered include transport, charcoal, coal measures, coal, anthracite, bituminous coal, flux, magnetic iron ore, specular iron ore, limonite, red hematite, clay ironstone, black band ironstone, smelting works, blast furnaces of Pennsylvania, Lake Champlain furnaces, Lake Superior furnaces, Cleveland furnaces, Pittsburg furnaces, Missouri furnaces, and those of the southern states. He goes on to describe Catalan hearths, malleable iron works, Bessemer works, the Blair steel process, and labour.

Jan 12, 1875

By D. C. Bailey, D. I. Hodson

Paper presented at the annual joint meeting of the IMM and IMinE held in Harrogate, 31 January 1991. The Neves-Corvo copper-tin mine is the highest-grade large-tonnage copper operation in the world and is now arguably the most significant producing base-metal mine in Europe, rating in the top ten world producers of both copper and tin. A description is given of the initial exploration work and the development of the project from the orebody discovery in the Iberian Pyrite Belt of southern Portugal in 1977 to full operating capacity in 1990. The chronological account includes discussion of the main organisational, financial, technical and environmental decisions and of the various difficulties encountered, and the challenges of the future are identified. The project was brought in on schedule and within budget

Jan 1, 1991

By S. A. Sayed, M. N. M. Ahmed, M. A. Doheim

The performance of a 12.7 cm hydrocyclone was investigated by considering the effect of design variables (diameters of the vortex finder and apex) and operating variables (pressure drop and solids content of the feed) at a medium feed solids concentration of mixed minerals. Cut-size was found to be the most important parameter in hydrocyclone design and operation. The effect of feed pressure in reducing hydrocyclone cut-size is less pronounced at medium feed solids concentration with a mixed mineral feed. The choice of vortex finder diameter and apex diameter becomes more sensitive at medium feed solids concentrations. The effect of feed solids concentration in increasing the cut-size becomes less marked at higher concentrations. Predictions of an empirical model were found to be in good agreement with experimental data. Comparison of results obtained from the model with those predicted by theoretically derived models showed the latter to be more promising, with the turbulent two-phase model giving closer agreement with the experimental data

Apr 1, 1995

By T. Serradj

A study has been carried out to: develop a method for routine characterisation of rock strength and drillability through the particle-size distribution of crushed or drilled rock products, defined by the Protodyakonov index; establish correlations between the Protodyakonov index, uniformity coefficient and the constant grading equations; and propose an alternative rock characterisation index to classify rock strength and drillability for the northeast region of Algeria

Dec 1, 1996

By R. A. Lord, H. M. Prichard

Paper presented at Mineralisation in the Caledonides, the Mike Gallagher memorial meeting held in Edinburgh, 27-28 June 1996. The complex exemplifies a class of olivine-rich, platiniferous ophiolite complexes generated by unusually high degrees of hydrous melting above a subduction zone. Crystallisation of abundant olivine from unusually picritic magmas produced an exceptionally thick sequence of crustal dunite cumulates. Significant (1-4 ppm) concentrations of Pt+Pd occur where sulphide-bearing dunites are spatially associated with podiform chromite concentrations. In the area north of the Balta Sound, the chromitites appear to lie in distinct stratigraphic zones. A detailed programme of lithogeochemical and soil-rock interface geochemical exploration led to the intersection by diamond drilling of three stratiform horizons of sulphide-bearing dunites and associated precious-metal mineralisation. Patterns of cryptic geochemical layering, at scales from 200 m to less than 1 cm, suggests open-system fractionation

Jun 19, 1905

By G. G. Roy, R Shekhar

Pachuca tanks are extensively used for the cyanide leaching of gold and the carbonate leaching of uranium, processes in which oxygen mass transfer plays a very important role. Experiments were carried out to clarify the effect of design and operating parameters on oxygen mass transfer. Parameters such as the ratio of tank height to tank diameter, the ratio of draught-tube diameter to tank diameter and the tank design were found not to influence oxygen mass transfer. Results also showed that equal superficial gas velocities may be used as a criterion for scaling up oxygen mass transfer in both full-centre-column and free-air-lift Pachuca tanks with clear water. A volume-averaged, volumetric gas-liquid mass-transfer coefficient (k'av) was used to characterise oxygen mass transfer in full-centre-column tanks. The axial dispersion model was used to determine k'av. The resulting model used only tank geometry and air flow rate as inputs for the prediction of k'av in industrial-scale tanks. Predictions from the model show clearly that "local" mass-transfer coefficients, measured at one or two locations, may not adequately represent gas-liquid mass transfer in industrial tanks. It is therefore necessary to obtain an estimate of k'av

Jun 18, 1905

By J. D. T. Capocchi, M. B. Mourao

The rate of reaction between iron oxides and carbonaceous materials, agglomerated as pellets, was studied experimentally by measuring the weight loss as a function of time. The effects of temperature, carbon type, inert gas flow rate, pellet size and additions (sodium. carbonate and Portland cement) were determined. It was shown that the value of the apparent activation energy can display large deviations under different experimental conditions; in the present work it was found to be 226.6 kJ/mol. The reaction with coke is slower than with charcoal, and the rate increases as the flow of inert gas in the reaction vessel decreases. Comparison of the rates for pellets of different sizes has shown that for small pellets the initial rate is faster but that it slows down at high conversions owing to the penetration of inert gas into the pellet. Additions of sodium carbonate and Portland cement increase the rate; sodium. carbonate promotes the catalysis of the Boudouard reaction, which is the slowest of the partial reactions. The increase in the rate with Portland cement is attributed to the release of water vapour

Jun 18, 1905

By R Lastra, J. A. Finch

An artificial standard material has been developed and used to examine the robustness of some of the procedures for correcting stereological bias. Different mineral liberation distributions were constructed from the standard material. The particles were mounted, sectioned and the sectioning data measured with an electron microscope interfaced to an image analyser. Four correction procedures were used and the corrected and true liberation distributions compared. It was found that the large-sections correction provided a simple, uncorrupted correction. Hill's fast approximation performed well except in cases of narrow liberation distributions; the sectioning data appeared to support the assumption that the locked section and locked particle distributions are identical. Barbery's correction performed well in most cases, having difficulty only with the very irregular liberation distribution. The PARGEN correction was able to provide a good estimate of the true amount of free material, but had difficulty in predicting the locked particle distribution

Jun 21, 1905

By P. H. Davenport, L. W. Nolan

Paper presented at the 28th International Geological Congress held in Washington DC, July 1989 (International geochemical mapping sessions). Geochemical mapping provides a direct approach to delineating areas of epigenetic mineralisation and for relating the regional distribution of this mineralisation to an overall tectonostratigraphic and structural framework, as well as to extensive areas of hydrothermal alteration. Organic lake sediment is a widely available and effective sampling medium for regional geochemical mapping in Newfoundland, that has proved to be valuable in Au, Sb and W exploration

Jul 1, 1991

By A. Sutton-Pratt

The African continent has been the most prolific producer of gold since mining began. Although most of this gold has come from South Africa, other countries have also been important contributors in the past. There is currently little production outside South Africa, Ghana and Zimbabwe, but the gradual globalisation of the industry over the past decade has resulted in growing interest in the region which bodes well for its future development. An outline is given of prospects and activity (or lack of it) in South Africa, Lesotho, Swaziland, Zimbabwe, Mozambique, Madagascar, Botswana, Namibia, Zaire, Tanzania, Kenya, Uganda, Rwanda, Burundi, Zambia, Malawi, Angola, Congo, Central African Republic, Gabon, Equatorial Guinea, Ethiopia, Eritrea, Djibouti, Somalia, Sudan, Chad, Libya, Tunisia, Egypt, Algeria, Morocco, Ghana, Ivory Coast, Liberia, Sierra Leone, Guinea, Senegal, Guinea-Bissau, Gambia, Mauritania, Mali, Burkina Faso, Togo, Benin, Niger, Nigeria and Cameroun

Apr 1, 1996

By H. Forster, F. H. Koenemann, U. Knittel

The greenstone belt developed along the Sandawana line, an anastomosing, transcrustal shear zone. The lode gold is concentrated in veins and along brittle-ductile shear zones and other faults. Gold contents of 200 rock samples were found to be well below economically significant levels, excluding purely syngenetic deposit formation. Average gold content of unmineralised banded iron formation decreases from 7.3 ppb in the east (Manica) to 1.6 ppb in the west (Odzi), where depletion reflects hydrothermal leaching. The mineralising fluids may have been generated during deep crustal deformation, metamorphism and magmatism. Gold was hydrothermally deposited during carbonatisation and sericitisation of ultramafic and mafic rocks and during hydrothermal overprinting of banded iron formation and felsic rocks. It is present in native form and as microscopic to submicroscopic inclusions in pyrite, arsenopyrite and pyrrhotite. Argentiferous galena and other sulphides are commonly observed. Rezende, which produced over 38 t Au, is hosted by a granodiorite stock. By-product gold was produced from Cu-Ni sulphides at Mundonguara. The deposits are related to the older, but not the younger, of the granitoids intruding the belt's supracrustal sequences; the estimated age of mineralisation is 2700-2600 Ma. Odzi district, with 61 mines, has produced only 3.5 t Au as its higher-level host rocks have apparently been eroded. Mutare (formerly Umtali) district, with 133 mines and 9 placers, has produced 68 t Au (65 t from Rezende and adjacent deposits), and Manica district, with 23 mines and 8 placers, 12 t Au. Estimated reserves for the Rezende area are 20 t Au and for Manica district 4 t lode Au and 19 t placer Au

Apr 1, 1996

By R. L. F. Kay, T. A. Fletcher, A. J. Boyce, C. M. Rice

Paper presented at Mineralisation in the Caledonides, the Mike Gallagher memorial meeting held in Edinburgh, 27-28 June 1996. The synorogenic, mafic Ordovician intrusion comprises orthopyroxene-rich xenoliths and mafic-ultramafic cumulates with low-grade pyrrhotite, chalcopyrite and pentlandite mineralisation. Despite abundant textural, mineralogical and O isotope evidence for significant assimilation of country rocks, S isotopes indicate only a modest uptake and suggest that mineralisation is dominated by magmatic sulphur. The preferred explanantion is that the magma was close to S saturation on emplacement. Uptake of elements such as Si and O led to early crystallisation of orthopyroxene, resorption of olivine and early segregation of a sulphide liquid. Post-magmatic interaction with a high-temperature, surface-derived fluid, whose movement may have been controlled by regional shear zones, reset biotite and whole-rock O isotope values but not those of orthopyroxene. This model identifies the presence of olivine-rich rocks and evidence of extensive assimilation as guides to prospectivity

Jun 19, 1905

By R. H. T. Garnett

N.B. This paper provoked much (positive!) discussion in later issues, with responses from the author (and thanks also for the many private contributions he had received) - see under Garnett R.H.T. Expanded version of a paper originally presented at the Alluvial mining conference, London, 11-13 November 1991 and published in Alluvial mining, Barking: Elsevier Applied Science for IMM, 1991, p.115-156. The usual measure of performance in gold and tin dredging is the R/E factor. It compares actual production or recovered grade for a given period with that estimated from the original sampling. The factor is a multiple of four component factors, each ideally approaching 1.00. The factors are concerned with estimation, selection, excavation and treatment. The estimation factor reflects the errors involved in determining the grade and depth of single drill-holes or pits. An optimum selection factor is achieved by a higher drilling density. The excavation factor is affected by failure of the dredge to excavate the total volume contained within its course. The required dredge throughput rate influences not only the success in digging recovery but also the treatment factor. No two alluvial deposits are the same, but, in general, the greatest divergence from 1.00 is invariably demonstrated by the estimation factor. A major divergence in one of the other factors may also be the cause of the R/E factor being significantly different from 1.00. The component factors are examined in detail and historical trends in R/E factors are discussed

Sep 1, 1991

By P. S. Heyns, M. Heyns

A computer model has been developed of mine hoisting systems in deep South African gold mines. Particular attention was paid to the contribution of different modelling assumptions for the guides and guide-roller assemblies. Objective functions indicative of guide-roller tyre endurance, slipper-plate forces and perceived vibration levels were introduced to quantify dynamic performance. These objective functions were used to compare models. It was found that the choice of guide and guide-roller models did not influence the forces on the guide rollers significantly for typical shaft and conveyance characteristics at typical levels of viscous damping coefficients. The rigid and finite-element guide models gave the same results as those of the effective-stiffness guide model, and while the latter is suitable for simulation for design purposes, the finite-element model should be used for unusual guide geometries

Jun 19, 1905

By C. A. Pickles, J. M. Toguri

The refining of two molten Ag-Cu alloys, containing 7.5 and 11.2 mass% Cu, with a borosilicate slag was investigated using both air and pure O2 to determine the effects of the following variables: flow rate of oxidising gas; injection time; mass of sodium borosilicate flux; and injection of the oxidising gas into either the slag or the metal. The results demonstrate that more than 90% of the Cu can be removed with Ag losses of less than 5% and that refined metal with a Cu content of less than 0.5 mass% can be produced. Ag losses to the slag increased with the amount of Cu removed, and a mechanism is proposed to account for this

Dec 1, 1995