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By E. A. Bekchurina, Yu. P. Morozov

"This paper presents the results of a study of the concentration of flotation froths in tapered chutes. The tests were conducted on lab and full-scale plants, and the results obtained were mathematically processed. The kinetics of monophase recovery from a stationary flotation froth, hydrodynamics of froth flows traveling in a tapered chute were investigated. The effect was studied of the mass fraction of the valuable component in the chute feed, yield of the chute’s overflow, and chute design on the concentration performance. Processing of the collected data revealed the general laws of the process and allowed to develop a technique for modeling concentration of the flotation froths of sulphide copper ore in a tapered chute to predict the performance without testing. It was found that concentration in tapered chutes allows to obtain products that are comparable in quality with froths after one or several cleaner flotation stages.INTRODUCTIONThe present production expansion rates require continuous improvement in the grade of flotation concentrates, while the grade of the mineral feed is constantly deteriorating. This leads to a significant complication of flotation flowcharts. Flowcharts become multi-staged with multiple cleaner flotations, negatively affecting the production costs.In recent years, researchers are paying close attention to the processes occurring in the froth layer in the flotation cells. Improving the concentrate grade is facilitated by secondary concentration of minerals in the froth layer, which consists in fixing the hydrophobic particles released as a result of the coalescence of the bubbles of the upper layer when moving downward at the liquid-gas interface of the froth layer. In this case, the released hydrophilic particles, trapped in the froth layer as a result of mechanical removal, migrate from the froth together with the liquid phase."

Jan 1, 2018

By Hong Nguen Vu, Pavla Ovcarí, Peter Fecko, Barbara Tora

The aim of this paper is to evaluate the suitability of a coal sample from the mine Jaworzno (Poland)- locality for bacterial leaching. Laboratory research used a pure bacterial culture of Thiobacillus ferrooxidans. The results showed that bacterial leaching was effective, with a one month leaching time, when 65% of total sulphur and 85% of pyritic sulphur was leached. The paper describes changes to the pyrite during and after bacterial leaching.

Jan 1, 2003

By Kaustubh Joshi, Pradip, Beena Rai, Venugopal Tammishetti

"Rapid depletion of high grade iron ores coupled with the increasing demand for the blast furnace grade iron ore in recent times has shifted the research focus on the development of appropriate technologies for the utilization of low - grade alumina rich iron ore slimes. These slimes are currently being dumped into tailing ponds owing to their high alumina content. Typical constituent minerals present in the Indian iron ore slimes are hematite, goethite, gibbsite and kaolinite. Considering the fine particle size distribution (<37 microns) in the slimes, selective dispersion-flocculation seems to be one of the most appropriate process which has been explored by us. We present our successful results on a natural iron ore slime sample obtained from one of the mines in India. We have been able to achieve a concentrate assaying >67% Fe, and <3% Al2O3 and 2.8% loss on ignition (LOI) from the slime sample assaying 60.4% Fe, 7.7% Al2O3 and 5.45% LOI with an Fe recovery of 62-69% simply by adjusting the pulp pH. We have scaled up the process to a semi batch scale as a prelude to commercialize it for the beneficiation of low grade iron ore slimes."

Jan 1, 2014

By Matthew Thurley

Optimisation and control of comminution, pelletization, and agglomeration processes is a complex task with large potential for gains in productivity, energy efficiency, and particle size distribution quality. One factor in realising these gains is the requirement for fully-automated online particle size distribution measurement. Moreover, online particle size distribution measurement that is based on the particles on the visible surface and can avoid or mitigate substantial errors that result from under-sizing overlapped particles and over-sizing areas of fines particles. Literature review indicates a body of substantially 2D photographic based particle size measurement systems that suffer from a large number of significant errors except in the simplest case of a monolayer of particles under good illumination with limited color variation in the material. In order to measure the visible particles on a pile there are a number of requirements including; avoiding particle delineation errors due to variation in material color and shadows, detect overlapping versus non-overlapping particles, and identify areas of fine particles as fines and not large rocks. Results are presented using a fully-automated online measurement system of crushed rock on conveyor belt using a 3D surface laser profile. The system provides continuous online measurement and results are shown on over four hours of production after the primary crusher. Size distribution results are calculated using volumetric estimation of the particles on the surface of the pile. The results show a strong capability to discriminate size variation especially in the 10% and 20% passing values. Furthermore results show that if areas of fines are misclassified as large rocks, and overlapped particles misclassified as small rocks, then a near complete loss of discrimination occurs for the P10 and P20 values which become largely constant values.

Jan 1, 2014

By Gaurav Soni, Roe-Hoan Yoon

A first principle flotation model has been derived from the basic mechanisms involved in flotation. The model consists of a series of analytical equations for bubble generation, bubble-particle collision, attachment, detachment, and froth phase recovery. The model can predict flotation from both hydrodynamic and surface chemistry parameters such as bubble size, particle size, energy dissipation rate, ?-potentials, contact angles (?), etc. The model predictions have been compared with the results of a series of laboratory flotation tests conducted using mono-sized glass beads of different particle sizes and contact angles under different operating conditions. Some of the experiments were conducted using a 1:9 mixtures if hydrophobic silica and hydrophilic magnetite, so that the product graded could be readily determined by simple magnetic separation. The model predictions are in good agreement with the experimental results both in recovery and grade. A computer simulator developed on the basis of the model is capable of designing a preliminary flotation circuit on the basis of feed characteristics, e.g., size-by-liberation data, and the hydrodynamic information on the flotation cells to be incorporated in the circuit.

Jan 1, 2014

By Lj. D. Andric

By the micronization-milling of the material, the size and the structure of its particles are changed and it comes to the increasing of the potential energy of the system as well as to the chem-ical activity of the material what is the result of an increased free surface and of the concentration of the grate defects, that is of the internal energy of the system. All these changes that are reached, show that new characteristics of treated materials are got by micronization process. Controlling the process of the micronization and by purpose directing of the new characteristics of the activated materials, we can have the positive effects and use them in more technologies. Talc is important nonmetallic mineral raw material that is widely used as either the basic raw material, or as filler. This has stimulated its technological investigation, as well as the investigation of its physical-chemical characteristics. In this paper are shown experimentally reached results of the physical-chemical characteristics of the talc during the process of the micronization in high energetic mill. In this paper, the optimum conditions of miconization of talc in high-energy-speed rotary mill and its influence micronization on a degree of Fe2O3recovery by hydrometallurgical methodes, are presented. The X-ray analysis of the obtained products showed that high quality talc with low content of can be obtained by these physical-chemical processes In this paper, the principles and application or fine and ultra-fine grinding high-energy attriton mill with small balls, enabling fast, efficient grinding, low energy consumption, short grinding time and easy handling will be described.

Jan 1, 2014

By Z. F. Hu

Tourmaline has the characteristics of piezoelectricity, thermoelectricity, spontaneous polarization and far-off infrared radiations. Ultra-fine powders of tourmaline have extensive applications in the fields of electron, chemical and environment protection, as well as health protection. The preparation technology of ultra-fine tourmaline powder is discussed. The key equipment of a pilot plant for producing ultra-fine tourmaline powder with jet mill and stirred ball mill is described. Using this pilot plant facility it is possible to produce tourmaline powder with particle size smaller than 100 nm, and a continuous production process can be realized. The final powder product has many superior performance such as high whiteness and large specific surface area, and it?s a negative ions emission can reach the value of 7190 ions per cubic centimeter.

Jan 1, 2014

By Ping Fang, Dezhou Wei, Zichuan Guan, Wengang Liu, Yanbai Shen

A new cationic collector, bis(2-hydroxy-3-chloropropyl) dodecylamine (N23), that can be dissolved in water easily was synthesized successfully. Its flotation performance to quartz was investigated compared with dodecyl amine in hematite reverse flotation system. It was found that N23 showed stronger collecting performance to quartz than dodecyl amine. The maximum recovery of 98% to quartz was obtained at a collector concentration of 43.3 mg/L in the pulp pH range of 6-9. This collector can be used to float quartz from hematite when starch was used as depressant. Optimal separating results with 90.06% iron recovery and 66.3% iron grade to artificially mixed sample were achieved at a collector concentration of 43.3 mg/L and a starch concentration of 23.3 mg/L at neutral pulp pH when hematite and quartz were mixed at a mass ratio of 3:2. The adsorption mechanism of the collector on quartz surface was investigated by infrared spectroscopic analysis and zetapotential measurements, which revealed that electrostatic attraction and hydrogen bonding adsorption occurred between the collector and quartz surface.

Jan 1, 2014

By A. N. Lazaridi, S. I. Afanasenko, S. A. Safonov

"This scientific work presents the results of comparative tests of centrifugal concentrators with a vertical and horizontal axis of rotor spinning. The article also describes a qualitative analysis of the behavior of mineral particles in a centrifugal field with fluidization for concentrators with a horizontal axis. The analysis was aimed at studying the effect of the quantity of fluidization holes in the basket on the degree of magnetite recovery and the effect of the basket rotation speed. The experiment demonstrated that concentrators with a horizontal axis are not inferior in terms of the qualitative recovery indicators to concentrators with a vertical axis. The researches also provided facts about the wide practical application of concentrators with a horizontal rotor arrangement. INTRODUCTION Methods of gravity concentration, attractive for their ecological purity, see their revival. First of all, this is due to the invention of centrifugal concentrators with the fluidization of the layer of mineral particles. The creation of a new generation of gravitational centrifugal concentrators made it possible to achieve a tangible breakthrough toward the direction of reducing the grain size of mineral particles effectively divided by density, up to 10 µm at a high production capacity of the vessels reaching 500-600 tons per hour. Such separators enable dressing a crushed ore of flotation grade and in some cases replace the flotation process, especially in primary operations, in joint cycles. In the long term, this method of concentration should significantly expand the scope of application, replace partial flotation processing, ensure the introduction of environmentally friendly energy-saving technologies at ore-processing plants. Summarizing the international experience for the last 30 years, it can be confidently asserted that centrifugal methods of concentration have become widely used in processing schemes for the separation of finely dispersed products in the mining industry. An interest in the creation of installations using centrifugal acceleration for the separation of mineral particles by density has particularly grown. Dozens of centrifugal concentrator designs have been created and continue to be improved. Centrifugal concentrators have a number of obvious advantages, which are especially relevant today. Losses of fine gold during the process of mining are well known. Gold washers screw, spiral separators, jigging machines and sluices traditionally used in the production processes do not solve the problem of fine gold recovery. Table 1 shows the results of comparative tests of a centrifugal concentrator (ITOMAK) and other concentration equipment. According to the research conducted by the company GMRS, Krugersdorp, South Africa (2000), the initial material was gold ore crushed to 150 micrometers (90%)."

Jan 1, 2018

By John Nell, Paul den Hoed

Carbochlorination tests were conducted with matched particle-size fractions of rutile, ilmenite and high-titania slag in a small bubbling fluidized-bed reactor. The effects of temperature, the type and proportion of solid reductant in the charge, and the fraction of Cl2 in the fluidizing gas were investigated. Tests confirm the need for solid carbon in the bed if chlorination is to run at high rates. With solid carbon in the bed, CO supplied with the fluidizing gas does not increase significantly the degree of chlorination after 75 minutes. Ilmenite is chlorinated more quickly than titania slag, which in turn is chlorinated more quickly than rutile. Rates of chlorination at 1100°C and 1000°C are much the same and significantly higher than at 900°C. Chlorination is associated with significant increases in particle porosity (even for rutile), which is brought about by the rapid initial chlorination of FeO and MnO (in ilmenite and slag) and (it is argued) by the chlorination of Ti2O3 which forms at high-energy surface sites. A reaction mechanism is presented; where possible, its validity is demonstrated by the support of empirical observations.

Jan 1, 2003

By Masanori Mori, Hajime Miki, Osamu Ichikawa, Tsuyoshi Hirajima, Mitsuru Sawada, Keiko Sasaki

For pretreatment of selective flotation, surface oxidation of chalcopyrite and molybdenite was applied by oxygen plasma then the minerals were washed by solution at pH 9 with oxygen bubbling. Surface characteristics of these minerals were investigated with AFM, XPS, zeta potential and contact angle measurements. Contact angle of chalcopyrite and molybdenite decreased a lot by plasma treatment. When they were washed with pH 9 solution with oxygen bubbling, contact angle of molybdenite increased whereas chalcopyrite one kept low. Adhesion force measurements indicated similar behavior. Result of flotation experiments indicated low recovery of both chalcopyrite and molybdenite after plasma treatment and only molybdenite recovery became higher after washing. Selective flotation of chalcopyrite and molybdenite could be achieved with this process. Possible mechanism of selective flotation was proposed from the results of XPS, AFM, etc.

Jan 1, 2014

By André Mans, Frans B. Waanders

Current losses of Ferrosilicon (Fe-Si), which is used in the dense medium separation (DMS) of iron ore at Kumba Resources, Sishen, South Africa occur due to adhesion to the separation products and also by being present in the effluent stream, due to abrasion. The losses contribute greatly to the running cost of the plant and the purpose of this project was to determine the characteristics of the unused Fe-Si and then to characterise the changes that occur during storage and the use thereof. A Scanning Electron Microscope (SEM) and Mössbauer Spectroscopy (MS) were used to investigate the characteristics of the fresh and used Fe-Si. It was found that the biggest loss of Fe-Si was due to the abrasion of the particles during the DMS process, which resulted in the liberation of Fe and subsequent formation of an oxihydroxide froth. A possible change in magnetic properties was also observed, leading to further losses that could occur during prolonged use of the medium. No clear changes to the Fe-Si occurred during correct storage methods, as was initially thought.

Jan 1, 2003

By A. P. Purgin, M. G. Viduetsky, I. F. Garifulin

"The combined treatment process for mine, tailings storage facility, quarry, circulating, and waste water in the mining and metals industry brings together the conventional chemical treatment processes and pneumatic flotation cells of the KFM series. The key principle of the process is preparing the water for treatment by saturating with finely dispersed air bubbles in the flotation cell blowers. Gas-air lift dispersers located in the lower part of the cell body additionally saturate the cell’s contents with finely dispersed air. Due to the residual content of flotation agents in the treated water, hydroxide ion-air aggregates form at the aerator outlet, supporting the efficient precipitation of hydroxide ions of heavy non-ferrous metals, calcium and magnesium ions. This process was tested in the pilot plant KFM-180 with a raw (untreated) water capacity of up to 18 m3/h per 1 m3 of the flotation cell volume using a mixture of the tailings storage facility and mine water from JSC Safyanovo Copper. The treatment process included raw water treatment with lime, aeration in KFM cells, and filtration in a sorbent bed. The content of metal ions in the treated water is lower than in the feed water by a factor of up to 170,000 and approaches the standards: aluminum 0.016-0.02 mg/l, copper 0.0043-0.0045 mg/l, zinc 0.049-0.052 mg/l. circulating water of Soryin Tailings Storage Facility at JSC Svyatogor. The treatment process included raw water treatment with lime and alkali, aeration in KFM cells, and filtration in a sorbent bed. The content of metals in the treated water is lower than in the feed water by a factor of up to 9000: copper 0.022 mg/l, zinc 0.012 mg/l, iron 0.012 mg/l, manganese 0.015 mg/l, nickel 0.132 mg/l, arsenic 0.016 mg/l. Water hardness is significantly lower: calcium - 12.6 mg/l, magnesium - 1.1 mg/l. This process can be used in the treatment of mine, quarry, tailings storage facility, and circulating water at mining and non-ferrous metals projects."

Jan 1, 2018

By Girolamo Belardi, Silvia Serranti, Giuseppe Bonifazi, Roberta Palmieri

Ore textural and structural characterizations play a fundamental role in any preliminary study (i.e. comminution, classification, separation) addressed to the design and set up of beneficiation flow sheets. The possibility to utilise automatic tools able to perform a classification, and a quantitative description, of the mineralogical and petrographical characteristics of raw ore samples thus represents an important step to define, to control and to verify the entire set of parameters, ore-texture-related, that can affect the final beneficiation results. The procedure usually adopted is based on the analysis of polished sections and more in details the recognition of the different mineralogical species and associations and the measurements of some quantitative parameters estimating both the geometrical characteristics of each species and the possible spatial relationships between them. This approach, originally carried out by experts, utilising optical and/or electronic microscopy, was ‚replaced? during the years by more and more sophisticated devices integrating analytical facilities and acquired data processing. Such integrated analytical devices formed the breakthrough platforms into what is now known as modern Process Mineralogy. In this paper the possibilities offered by chemical imaging based devices and techniques, to perform ore minerals recognition/classification, and to perform their topological assessment, are presented. Tests have been carried out and are discussed in order to analyze the problems related to the development of suitable and low cost strategies addressed: i) to realize a full mapping of ore minerals/gangue inside selected samples, ii) to define the optimal data-flow handling to optimize the speed of processing versus the quality of the results and iii) to start to define logics and procedures finalized to implement innovative smart detection engines, chemical imaging based, for mineral processing addressed to perform both a preliminary characterization of the ore, at laboratory scale, and a further possible control of the different processed minerals flow streams.

Jan 1, 2014

By Jorge Rubio, Gabriel Berkowitz, Fabiano Capponim, Carlos Perez Guerrero, Elves Matiolo, Denise G. Nunes

This paper describes some advances in flotation research in fines (“F” 38 to 13 µm) and ultrafines (“UF” < 13 µm) mineral recovery by two different techniques, at laboratory scale. Extender flotation and flotation with .multi-bubbles. (bubbles with a wide size distribution) of copper sulphide fines (ore feed of about 1 % Cu) were compared with a .standardised. mill laboratory procedure. Comparative evaluation was made through concentrate grade and recovery (size by size results included), .true. (bubbles-particles attachment only) flotation recoveries and process kinetics. Both techniques yielded higher metallurgical efficiencies than the mill standard but better results were obtained with the extender flotation, with emulsified diesel oil (90 gt-1). Concentrate recoveries were of the order of 85-90 % (84 % in standard conditions), 14-17 % Cu grade (15 % Cu in the standard) and 3.5-4.5 min-1 for the Klimpel rate constant (3 min-1 in the standard). Size by size and true flotation results proved that metallurgical and kinetic gains, obtained with the two techniques, might be attributed to fines and ultrafines enhancement. Data obtained are discussed in terms of physical and physico-chemical parameters related to aggregation and capture (of particles by bubbles) phenomena and the practical potential of these techniques are envisaged.

Jan 1, 2003

By P. Fawell, C. Castillo, C. Ihle

"The need to reduce fresh water consumption has pushed many Chilean mining companies to utilize seawater obtained from distant locations. At the same time, increasing amounts of fine particles in copper tailings raise new operational challenges, in particular, the thickening and transport of tailings featuring significant fine fractions, which are predominantly clays. In the present paper, we study the role of salinity – using seawater and NaCl – on the flocculation efficiency of copper sulphide tailings to which kaolinite was added. To mimic the water recovery stage in thickeners, flocculation has been induced in jar tests and the corresponding aggregate size distribution has been estimated from chord length distribution data obtained using a focused beam reflectance measurement (FBRM) probe, at various mean turbulence intensities. Results show that for constant flocculant dosing, a measurable influence of the salt on the resulting aggregation exists. For each case, resulting optimal turbulence levels are also reported, a particularly interesting feature when comparing flocculation efficiency of the coarse and fine fraction. INTRODUCTION The concentration of copper minerals through comminution and flotation is intensive in the use of fresh water. The need to reduce the consumption of fresh water and the environmental standards associated with increasingly demanding mining operations have driven improvements in the techniques of recovering water from tailings. The challenges are even greater when required to treat minerals with high clay contents. In Chile, kaolinite is one of the most important clays to consider due to its abundance in the tailings from many operations. The most common and highest throughput unit operation in the mining industry for the recovery of water from tailings is gravity thickening, with sedimentation of fine particles assisted by flocculation. Flocculation is the process of forming aggregates by contacting the suspended particles with a flocculant. The flocculant is typically a water-soluble synthetic long-chain polymer, where copolymers of acrylamide and sodium acrylate are the most common types used in the Chilean mining industry. The aggregation mechanism includes the following key steps: (1) flocculant distribution through the suspended particles, (2) flocculant adsorption onto particle surfaces, and (3) collisions between particles leading to polymer bridging to form aggregates, but concurrently (4) breakage of aggregates becomes a factor under prolonged shear (Gregory, 1988)."

Jan 1, 2018

By V. Tsyplakov

This article reviews factors of preg-robbing effect, occurring in the course of pressure oxidation of ore and concentrates, containing chloride compounds and so-called &apos;organic carbon&apos;. The article also summarizes the main results of the studies and testwork conducted to overcome this effect. The following efficient preg-robbing mitigation methods have been noted: higher temperature of pressure oxidation process, preliminary removal of natural carbonaceous material from concentrate, chloride removal prior to concentrate pressure oxidation, and addition of water-soluble organic blanking agents, which suppress the adsorption activity of the native ore adsorbents. Keywords: preg-robbing, double-refractory gold concentrates, pyrite, arsenopyrite, blanking agents, pressure oxidation, autoclave leaching

Sep 1, 2012

By Peter Scales, Ricardo Jeldres, Fernando Concha, Pedro Toledo, Shane Usher, Anthony Stickland

The impact of several electrolytes present in seawater on the rheological properties of flocculated mineral suspensions was assessed using the creep test. Flocculated suspensions were obtained by adding polymer flocculant to a cylinder of mineral suspension and aggregating the suspension using the plunger method. The suspension was allowed to sediment and the supernatant liquid decanted prior to tests for the viscoelastic properties of the resulting sediment. The solid used was alumina AKP-30 both, below and above the isoelectric point. The polymer used was AN934SH, an anionic flocculant with high molecular weight. Salts analyzed were MgCl2, CaCl2 and NaCl, known as water structure makers, and KI and KCl, known as water structure breakers. A high salt concentration of 0.5 M was used to approach the ionic strength of seawater. For both pH’s studied, the sediments demonstrated a viscoelastic non-linear behavior observed as a non-linear relationship between yield strain and applied stress. In the absence of flocculant, it was observed that the viscosity and yield stress of a suspension increase in the presence of structure maker salts for the case of both silica suspensions and alumina suspensions. These results were explained using hypernetted chain statistical mechanics models describing the interaction of ions with solvated surfaces. In contrast, with the presence of flocculant, the shear yield strain of alumina suspensions increases with the breaker character of the salts, however, this result has been explained by an extension of the results from the models. The work has significant implications for the flocculation of mineral suspensions in the presence of seawater.

Jan 1, 2014

Goethite ore are the third most abundant source of iron. The overwhelming part of these ore is represented by low-grade varieties which cannot be used in iron and steel industry without preliminary beneficiation. Biomass is a renewable solid fuel, which is feasible for the substitution of coke and coal in the manufacturing due to its lower contents of harmful elements and abundant raw material sources. Utilization of biomass in iron ore sintering process as heating agent and reducing agent contributes to energy conservation and emission reduction. The biomass was mixed together with goethite ore for roasting process to investigate the effects of reduction roasting. The results show that the goethite ore is dramatically reduced and magnetized into maghemite by biomass with the biomass dosage less than 20% and the roasting temperature below 650 oC. When the goethite ore roasted with biomass, the magnetization values could be enhanced more than two orders of magnitude, meets the standard of magnetic separation, which could significantly reduce the iron beneficiation cost. Keywords: biomass, goethite, reduction, magnetization, roasting

Sep 1, 2012

By Neill Bartie, Jacques Eksteen, Sharif Jahanshahi, Shouyi Sun

The gradual increase in Cr2O3 levels of UG-2 ores has become a matter of concern for platinum producers in South Africa due to the formation of chromite spinels in melters. The effect of bulk FeOx/MgO ratio, Cr2O3, temperature and oxygen partial pressure on phase stability and composition in the system FeOx-MgOSiO2- Cr2O3-Al2O3-CaO has been studied between 1400°C and 1600°C using the drop-quench technique. An increase in temperature was found to result in a decrease in [Fe/Cr]spinel. An increase in bulk FeOx/MgO caused Mg, Al and Cr in spinel to decrease, forming more magnetite relative to other spinels. [Fe]spinel decreased and [Cr]glass increased with a decrease in oxygen partial pressure.

Jan 1, 2003