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By V. P. Yakushkin, B. S. Ksenofontov

"Multistage model designed and used for more detailed description of floatation process. The study develops a new model of flotation kinetics description. It defines flotation as process that consists of several stages: air bubbles and particles are separate, air bubbles and particles form a raising aggregate, aggregate raises to froth layer. This description significantly differs from commonly used model, which is much simplified. The multistage model gives an in-depth description and considers different aspects of flotation. Experimental approval of the new model resulted in its accuracy.The model is to be used for description of all flotation processes’ kinetics of wastewater treatment. It helps in accurate designing of flotation treatment plants and may be used for further research of flotation process. Columnar flotation installation was designed by using multistage model. This installation consists of new tubular aerators with special ejectors, froth pressing system as well as unit of thin-layering lighting to catch microflotocomplex “particle – bubble”. Usage of tubular aerators allowed to aerate the overall volume of pulp. Due to use of special ejectors with longer mixing camera we state higher volume of small-sized floto-active bubbles. Use of multistage model allowed to optimize and get higher technological results of potash salts enrichment. Tests were conducted on centrifuges-floatation installation system. Meanwhile, froth concentrate contained mainly thin hydrophobic particles sized circa 0,1 mm. As a result we set that during floatation cleaning process of froth concentrate 95-98% of chloride potassium (KCI) is derived from foam.The final product satisfies production quality. Columnar floatation installation productivity was 17 – 21 m3/m2h, which is a high technological result. Columnar floatation installation is one of the best examples of concentrating equipment using nearly all technological indices."

Jan 1, 2018

By B. McFadzean, J. Taguta

The enthalpy of immersion is the heat change arising from the replacement of the solid-gas interface with the solid-liquid interface when a solid surface is immersed in a liquid. Although immersion calorimetry has been established as a valuable and reliable means of determining solid surface properties such as wettability, it has seldom been applied in mineral processing research. In this study, precision solution calorimetry was employed to measure the enthalpies of immersion of different minerals in water. The enthalpies of immersion were then related to the first-order flotation rate constant as determined by the microflotation technique. The same measurements were also made on sulphide minerals whose surfaces were modified to different degrees of hydrophobicity using different percentage coverages of amyl xanthate collector. The enthalpy of immersion technique was capable of distinguishing and ranking minerals according to their wettability. All mineral types and collector-treated minerals conformed to the same relationship that was found between the enthalpy of immersion and the flotation rate constant. This conformed, empirically, to a power law equation. As the enthalpy of immersion decreased, there were large increases in flotation response for very small changes in hydrophobicity. In addition, a critical enthalpy of immersion (CEI) was found, above which no flotation could occur. The scatter in the data points could be corrected for by adjusting the rate constant using the density of the minerals to produce a robust relationship between the rate constant and enthalpy of immersion. These results have shown that the enthalpy of immersion is able to indicate both the natural mineral hydrophobicity and the extent to which collectors can render a mineral hydrophobic. This technique has considerable potential to be used as a sensitive and accurate measure of mineral surface wettability in order to predict flotation performance.

Jan 1, 2018

By Kyle Bartholomew, Robert McIvor

"Functional performance analysis of closed circuit grinding provides valuable insight into the two components of ball mill circuit grinding efficiency: classification system efficiency and mill grinding efficiency. Classification system efficiency isolates the combined effect of classifier performance and circulating load ratio from other circuit variables, such as ore grindability and the mill grinding environment. Optimization of classification system efficiency ensures grinding energy is applied to particles needing further size reduction and not to overgrinding. Entirely based on size distribution data, classification system efficiency precisely distinguishes subtle changes in classification system performance. Use of the functional performance equation to isolate mill grinding efficiency allows for proper optimization of the mill grinding environment by isolating confounding effects of changes in classification and ore grindability. Variables such as mill percent solids and grinding media selection can be optimized using the mill grinding efficiency subcomponent of functional performance. First published by McIvor in 1988, the functional performance equation provides a set of standardized, quantitative optimization criteria, simple and powerful, which link circuit performance to plant design and operating variables that can be manipulated. Functional performance optimization has been applied in numerous mineral processing plants globally and continues to gain acceptance as a practical means for grinding circuit optimization. In this paper, examples of derivation and industrial application demonstrate the means by which functional performance analysis dissects grinding circuit efficiency into its subcomponents allowing the reader to apply this straightforward, powerful optimization methodology at their mineral processing operation."

Jan 1, 2014

By Shankar Narasimhan

Data Reconciliation is a technique that has been developed more than fifty years ago and has been refined over the past few decades and is now being deployed routinely in several process industries such as refining, petrochemicals, mineral processing and hydro-metallurgy. The main aim of data reconciliation is to obtain accurate estimates of all process variables and parameters using plant measurements that are invariably corrupted by random errors and may also contain biases and other gross errors. These reconciled estimates are subsequently used either in offline exercises such as simulation, retrofitting, and de-bottlenecking or in online optimization and control applications. In this presentation, a brief history of data reconciliation, its assumptions, and uses are reviewed. New developments in this area are highlighted such as robust data reconciliation to handle model uncertainties, and reconciliation using identified models derived purely from operating data. Several case studies in the mineral processing industries reported in the literature are also highlighted to indicate the potential benefits of this technique.

Sep 1, 2012

By K. C. Corin

It is well known that the grinding circuit plays a crucial role in flotation. The effect of pulp chemistry during grinding is often overlooked. It is believed that the surface properties of the minerals can be adjusted during flotation rather than during grinding. However, recent development in surface analysis techniques (TOF-SIMS, XPS, and AES etc.) have proven that the hydrophilic iron hydroxides formed at the mineral surface during grinding make it difficult for collector adsorption, which may result in poor grades and recoveries of the valuable minerals. This study investigated the effect of the pulp chemistry conditions during milling and the subsequent effects on flotation performance of an Nkomati ore. The results have shown that there was approximately 10 % increase in Ni recovery, when the ore was ground at a dissolved oxygen (DO) concentration of 0 ppm (DO-0) in comparison to no gas control during the grinding stage. However, when the pH was changed from 9 to 11, no gas control resulted in a 20 % decrease in the Ni recovery compared to only 5 % decrease in the Ni recovery at DO-0. A noteworthy observation is that controlling a combination of DO and pH during grinding is of critical importance for better floatability and selectivity for such a system. It also became clear from this study that the presence of oxygen is critical to the consumption of xanthate, which is consistent with the general literature. It has been established that grinding at lower DO levels/redox potentials (Eh) in the presence of xanthate significantly improves the flotation performance of the valuable minerals.

Sep 1, 2012

By H. U. R. Kattentidt, W. L. Dalmijn, T. P. R. de Jong

"Research at Delft University aims to develop systems for automatic inspection and sorting of bulk solids which can be applied in the mineral processing and recycling industry. A recent development includes an automatic sorter based on airport X-ray inspection technology. It is designed for continuous inspection and sorting of 5 - 150 mm solids and has as objective a cost effective and high capacity on-line inspection and sorting.Dual energy X-ray transmission imaging provides instantaneous data about particle dimensions and the atomic number distribution. The system provides particle thickness and average atomic number on a pixel level at scanning speeds between 250 and 500 lines / second. With existing X-ray components inspection speeds between 0.5 and 2 m/s at approximately 1-meter inspection width and between 1.5*1.5 and 5*5 mm2 sensor resolution can be achieved.Imaging algorithms that were developed by Delft University for applications in recycling, waste cleaning and other applications acquire shape, size distribution and composition data. Currently on-line processing of a product at a rate of around 200 particles per second is possible using a standard PC. Experiments with a demonstration X-ray unit indicated good potential for various applications in solids processing. They include continuous inspection of organic content, sulphur, chlorine, ash, and metal distribution. It is applicable for coal cleaning, ore sorting, industrial minerals, and various applications within waste cleaning and recycling. Dual energy X-ray transmission fundamentals and recent progress in system development and applications are presented."

Jan 1, 2003

By Isaak I. Maksimov, Tatyana E. Koltunova, Mikhail F. Yemelyanov, Liudmila A. Otrozhdyonnova

"INTRODUCTIONMetals losses amount up to 50% in coarse fractions in (>100 µm) and composite particles, and to 20- 25% in fine fractions (<10 µm) at non-ferrous floatation concentrating plants of the CIS. Therefore, reduction of metals losses in difficult fractions is of high significance.IMPROVEMENT OF FLOATABILITY OF COARSE AND COMPOSITE PARTICLESReagent regimes with application of strong collectors – xanthates ?5-?8, combination of butyl xanthates and aerofloats ?10-?12, butyl xanthates with hydrocarbons are proposed for this purpose. Application of such reagent regimes for copper and copper-molybdenum ores permitted to increase copper and molybdenum recovery by 0.5-3.9%.Studies, performed by means of specially designed non-frothing flotation machine with independently controlled agitation intensity and narrow size-ranges of air bubbles, established that the best results are achieved with employment of bubbles of 0.5-0.8 mm size regarding particles of any size, with small amounts of up to 2 mm size “transport” bubbles to be expediently used for floatation of coarse particles.Energy dissipation in the main volume of floatation cells must be lower than 0.2-0.25 m2/s3.Performed experiments permitted to formulate requirements to development of machine for floatation of coarse and composite particles. Such floatation machine with volume of 8.5 m3 provided for weak agitation in the main volume of floatation cell and uniform distribution of coarse particles throughout the depth owing to establishing of pulp circulation with upward flows. In addition, in the upper part of floatation cell where agitation is considerably weaker, favorable conditions are created for attachment of particles to bubbles. Testing of this floatation machine demonstrated a 7.5% increase in recovery of +0.2 mm particles in pyrite floatation and a 12-14% increase in recovery of +0.2 mm particles in apatite floatation as compared with a reference floatation machine."

Jan 1, 2003

By T. Shumba

The solvent extraction section of an old Uranium Plant in the Vaal River region produced a sub-stance called Crud (Chalk River Unidentified Deposit) that formed within the aqueous/organic interface of the settler of the solvent extraction circuit. The crud was deposited together with gold tailings to the tailings dam many years ago. Previous research done on the crud confirmed that ex-posed crud leaches Mn and Ni at concentrations that are well above their acceptable risk limits as well as Zn that leaches at concentrations that are slightly lower than its acceptable risk limit. Soil washing and bioremediation technologies were employed to treat the contaminated soil. Various laboratory test work and the pilot scale studies were conducted in parallel with each other and the results of the laboratory studies were used to determine critical parameters. Four lixiviants, i.e. sulphuric acid, acetic acid, oxalic acid and ethylene diamine acetic acid were tested at three concentration levels i.e. 0.001M, 0.0001M and 0.00001M, respectively. Column tests showed that the leaching of the heavy metals increases as the soil porosity increases. Silica sand was added to increase porosity of the contaminated soil. Highest Mn removal was achieved mainly by sulphuric and oxalic acid at 0.001M at all soil levels. EDTA was significantly efficient in the removal of Ni and Zn. The recovery of heavy metals, particularly Mn, decreased as the depth of sampling in-creased. Heterogeneous bacteria and filamentous organism plate counts were conducted to evaluate the growth of the bacteria and filamentous organisms in the soil. Results showed that more organism growth took place in the bioremediated soil with a fertilizer added to it. The leaching of metals from the soil that was bioremediated in the pilot study was generally higher than the extraction of the metals from the soil that was leached with no bioremediation carried out. The results from this study suggest that the leaching of heavy metals from the contaminated soil is to a large extent dependant on the pH of the leaching solution. By increasing the soil?s porosity and bioremediating the soil, higher extractions of metals were achieved.

Jan 1, 2014

By A. Güney

Currently, recycling technologies use relatively homogeneous plastics because hand-sorting waste feed is too expensive. Many promising technologies for separating mixed thermoplastics are being investigated, but they are still uneconomical and unreliable. Burning plastics for recycling is not used because of poisonous gases released when their burning. PET and PVC cannot be separated using conventional gravity separation techniques because their specific gravities overlap; PET density changes from 1.33 g/cc to 1.37 g/cc and PVC density is between 1.32 g/cc and 1.37 g/cc. For this reason, plastic recycling needs new techniques. Among these techniques froth flotation, also used in mineral processing, can be useful for its cost and simplicity. In this method, a plastic is selected from mixture, tried to regain its natural property, hydrophobicity. In this study the experiments were applied by using plasticizer reagents to make the selected plastics hydrophobic and us-ing NaOH to render the other hydrophilic. Post-consumed PET and PVC are evaluated by concerning the effects of selected parameters (particle size, concentration of plasticizer reagent, amount of NaOH, conditioning time and the effect of conditioning temperature). At the end of the experiments, optimum parameters for selective flotation of PET from PVC was found as particle size of -4.76 + 3.36 mm, NaOH amount of 30 kg/t, conditioning temperature of 75°C, conditioning time of 30 minutes, reagent amount of 300 mg/L. Consequently, PET was re-covered with 99.7% purity and 57% efficiency.

Jan 1, 2014

By M. Saghaeian, R. Hejazi, H. Abedini, M. Zare

Water recovery in mineral processing plants is one of the most important subjects because water supply is a critical matter economically and environmentally, especially in desert areas. In this paper, the filtration behaviour of two iron ore tailing sample has been investigated using laboratory scale vacuum and pressure filtration units. These samples including tailing from Sirjan and Zarand concentrate production plants with the d80 of 94 and 41 micron, respectively. The results show that by using vacuum filtration the cake moisture content of Sirjan sample would be about 24%. But the filtration time is too long and vacuum belt filter cannot be used in industrial scale. Adding about 40 g/ton of flocculant would decrease the filtration time by about 30% and make the vacuum belt filter appropriate for dewatering of this sample. For Zarand tailing sample, the vacuum filtration would produce a wet cake by about 31% moisture content. Filtration time is too long and adding flocculant would not improve the results very much. So pressure filtration must be used for dewatering of this sample. The results of laboratory tests show that using pressure filter would reduce the cake moisture content to 21%. The filtration time is logical, so this process can be used for Zarand tailing dewatering.

Jan 1, 2014

By Francesco Vegliò, Luigi Toro, Francesca Pagnanelli

Different hydro-metallurgical processes have been studied in order to recover manganese(II) from oxidised minerals such as MnO2. An innovative acid reductive leaching carried out in mild experimental conditions was here considered using agricultural and industrial wastes containing carbohydrates as reducing agents. The leaching process was investigated from a kinetic and equilibrium point of view in order to optimise the experimental conditions, develop a kinetic model and obtain high purity concentrated MnSO4 solutions. To study the leaching kinetic a Shrinking Core Model (SCM) was modified by a variable activation energy term to take into account both the variable reagent concentrations and the reaction rate change with respect to the manganese dioxide conversion. The influence of the particle size in the kinetic model is discussed with the support of SEM analysis before and after leaching. Manganese extraction yield was maximised (170-190 g/L) using appropriate carbohydrates and acid excesses, while impurity concentrations were kept low (Fe<10ppm and Ca<300ppm) pre-treating the ores, using hydro-alcoholic leaching medium and different combinations of down-stream processes. In particular precipitation, solvent extraction and adsorption onto active carbon were tested to eliminate Fe and Ca from MnSO4 solutions.

Jan 1, 2003

By Wang Xu, Tao Dongping, Zhang Jie, Tao Youjun

Based on the principle of fly ash triboelectrification, the mineral electrical index and testing method are introduced. The electric differences of various mineral components of fly ash are discussed in view of the results of chemical and mineral composition analysis of the fly ash sample acquired from the Xin-wen power plant. The dielectric constant and charge-mass ratio of carbon and ash in the fly ash are determined. The data were then used along with the rotary triboelectrostatic separator (RTS) testing results to investigate the charging characteristic of fly ash particles in different sizes. The results show that the dielectric constant of fly ash with different particle size decreased with the decrease in particle size, which led to a poor electrical conductivity. Thus particle size has an important effect on conductivity. The charges of carbon and ash particles increased with decreasing particle size. The charge-mass ratio of carbon and ash particles of the same size increased with decreasing particle size. This indicates that finer particle size is more favorable for triboelectrification separation from the charging efficiency point of view. The rotary triboelectrostatic fly ash separation tests show that the best decarbonization performance was achieved with particles in the size range of 0.038-0.074mm with which the decarbonization rate and efficiency index reached 38.93% and 120.83% spectively.

Jan 1, 2014

By Johannes Käppeler, Alexander Weh, Harald Giese, Klaas van der Wielen

"High voltage breakage is a novel comminution technology that shows considerable potential for various applications in mineral processing and recycling. It relies on highly energetic electrical pulses to induce electrical explosions in rocks, causing the formation of plasma channels and powerful shockwaves that result in fracturing and fragmentation of particles. There has been considerable interest in this technology for its ability to weaken rocks and preferentially liberate target minerals, as previously demonstrated by other authors. Weakening has the potential to significantly reduce energy consumption during comminution, or alternatively, increase throughput of a circuit. Better liberation may yield an improved concentrate grade and/or recovery, reduce fines losses to tailings or increase the grind size required for liberation, thereby also reducing energy requirements. This review aims to increase general awareness of this technology, and promote further research into it by providing a general summary of the theory underlying high voltage breakage, as well as the envisaged applications of this novel technology. A brief history of the technology is presented before progressing onto the physics underlying the electrical and geomechanical aspects of high voltage breakage. Key results regarding weakening and liberation are discussed, and some mention is made of current challenges and planned developments to increase the throughput of high voltage breakage units to the level where it can be integrated into new and existing processing circuits."

Jan 1, 2014

By M. Saghaeian, R. Hejazi, L. Hosseini, M. Zare

Difference between plant feed specifications in practice and design feed is a problem that most of processing plants face during operating and commissioning. This topic has led to inappropriate operating and necessitates repeating the basic tests on new feed. Gol-E-Gohar fourth concentrate line with a capacity of 2 MTPY, located in Kerman province, is the first iron concentrate plant in Iran in which High Pressure Grinding Roll (HPGR) technology has been applied. Plant&apos;s feed consists of 30% AG mills pebbles of lines 1-3 and 70% run of mine crushed ore whose Fe=51%, Fe/FeO=2.5, S=1.7% and work index=15 kWh/t. Desired concentrate has Fe>68% and S<0.7%. After the plant construction and operation commencement, providing design feed was not possible due to the crushing unit`s not being complete, therefore the plant was fed by AG mills pebbles. For predicting optimal conditions of the plant and investigating the possibility of improving the current concentrate specifications, sampling from the new feed and laboratory and pilot tests was performed again. Studies showed that new feed has Fe=41%, Fe/FeO=3.5, work index=17 kWh/t. Results of laboratory tests with Davis tube device and pilot tests run using magnetic separators with simulating the plant`s circuit showed that with current feed, achievable recovery in industrial scale would be 75.52% which compared to plant&apos;s recovery in studied period (75.94%) shows that plant operated in optimal conditions. To improve the current concentrate specifications (Fe=66%, S=1.03%, Ferec=75.94%) and for achieving desired concentrate, samples were reground to four fractions with k100= 300, 212, 100, 45 and Davis tube tests were performed on each of the samples separately. Results showed that the fraction whose k100=212 µm or k80=200 µm has respective Fe and S grades of 68.27% and 0.681% which are consistent with the desired concentrate.

Jan 1, 2014

By Chiharu Tokoro

Acid Mine Drainage (AMD), high acid water containing heavy metals discharged from mines, has been recognized as major cause of mine pollution. In Japan, the government spends billions of yen every year to prevent pollution caused by AMD in about 80 abandoned mines. It is widely recognized that the treatment could continue for long decades or an even century. However, costs and environmental loads are uncertain during the treatment because a predictive model for the quality of AMD, the dosage of neutralizer, and the amount of sludge that is applicable for abandoned mines with limited data has not yet been established. In this study, a two-steps predictive model for solution composition and neutralization chemical requirements of AMD in future was constructed based on the geochemical modeling. Requisite input data of the model was the past historical water quality data from AMD monitoring, such as metal concentration and pH in the solution, instead of the sample rocks as other conventional prediction methods. In the first step, solution composition of AMD in the future was extrapolated from the available historical data using geochemical simulation considering the first order kinetics for the mineral dissolution. In the second step, neutralizer dosage and sludge generation in the future was predicted based on the geochemical simulation supposing the chemical equilibrium and oxidation state for all of elements in the solution. Based on case studies of two abandoned mines in Japan, solution composition, neutralizer dosage and sludge generation were estimated. The results of this study demonstrate the effectiveness of our model for the prediction of AMD quality and chemical requirements of neutralization treatment after mine closing. The model is useful for the estimation of the neutralizer dosage and the sludge volume in abandoned mines with limited data. Keywords: acid mine drainage, predictive model, geochemical modeling, first order kinetics, water monitoring

Sep 1, 2012

By John Ralston, Stephen Grano, Yongjun Peng, Daniel Fornasiero

"A specially designed mill which allowed the control of pH throughout grinding was used to study the effect of grinding conditions on galena flotation and galena separation from pyrite. The changes occurring on the mineral surface during grinding were investigated by EDTA extraction and ToF-SIMS measurements.Galena flotation and galena separation from pyrite were strongly dependent on the type and amount of oxidation species produced on galena and pyrite surfaces under different grinding conditions. Iron oxidation species depressed both galena and pyrite flotation, whilst lead oxidation species activated pyrite flotation but had little effect on galena flotation. Optimum galena flotation and galena selectivity against pyrite were achieved by selecting grinding conditions that enabled lead and iron oxidation production to be controlled.Grinding conditions had a large effect on the flotation of the galena particles of different sizes. Flotation of fine galena particles (-10 µm) was depressed by iron oxidation species derived from the grinding media. Chromium grinding medium decreased the production of iron oxidation species and therefore increased the flotation of fine galena particles."

Jan 1, 2003

By F. Burat

The present research covers the results of experiments carried out with high frequency vibration screen on dewatering of coal fines. In the tests, the addition of surface active reagents was studied employing a high frequency vibrating screen. To increase the efficiency of mechanical dewatering processes, ultrasonic treatment was applied along with surfactants and optimum dewatering conditions were obtained. The moisture content of the feed material was from 82.5% to 41% by the optimization of operation parameters including the angle of the screen, vibration frequency, feed rate and screen opening size. Optimum parameters obtained in dewatering processes carried out with the vibrating screen were kept constant and the effects of surface active reagents and ultrasonic treatment on dewatering were investigated. Finally, the moisture level of the material was further reduced from 41.0% to 37.66%.

Sep 1, 2012

By O. Guven, I. Karaagaçlioglu, O. Ozdemir, M. Çelik

In this study, the effect of morphological properties such as shape factors and roughness of the glass beads on their flotation efficiency were determined using image analysis and profilometer methods. There is a considerable correlation between the shape factors, surface roughness and flotation behavior of the glass sample. These results indicate that as the particle shape is away from roundness and smoothness, it acquires more hydrophobicity.

Jan 1, 2014

By D. Krawczykowski, D. Saramak, T. Gawenda

"Annual world zinc consumption is as high as nearly 14 millions of tonnes. Approximately 50% share of zinc is used for corrosion protection in processes of continuous galvanization and the hot dip processes. In the latter, two zinc containing residues are produced: zinc ash and hard zinc, which constitute around 10% each. Paper concerns the method of possible separation of metallic zinc from the non-metallic zinc compounds from the zinc ashes – the waste product of hot dip galvanization process. The investigative programme covered the comminution tests of the feed (zinc ash) in selected crushers: jaw crusher, roller crusher and impactor. Results of investigations show that application of individual crushing device results in various breakage of the feed sample. Impact force caused the highest increase in finest particles size fractions of the product, while metallic and non-metallic fractions were comminuted differently. The compression force, in turn, caused the selective comminution, i.e. the breakage of metallic zinc was observed in a higher degree. The presented approach appears to be an economical supplementary method of initial recovery of metallic zinc from metallurgical zinc waste. For the high demands for the zinc in the world and the need of corrosion protection, the method presented in the paper helps in more effective zinc recovery and environmental protection.INTRODUCTION AND METHODOLOGY World production of metallic zinc during last decade shows a slight increase and in recent years its consumptions reach 14 millions of tonnes. Figure 1 shows world production of zinc in the time period 2009 – 2016. Main directions of zinc utilization include: - Galvanization - Production of zinc alloys - Brass and bronze production - Semi-manufactures of zinc - Chemicals The major share in global zinc consumption constitute galvanization process (Bright 2007). Two main types of zinc galvanization are: hot-dip galvanizing (HDG) and electro-galvanizing."

Jan 1, 2018

By Mingxia Liu, Qi Liu, Tao Jiang

"In addition to physical parameters such as small mass and high specific surface area of fine and ultrafine minerals, chemical parameters such as the adsorption affinity of collectors on the minerals also plays an important role in fine particle flotation. In this study, we have examined collectors with two different ionized groups, carboxylate and hydroxamate, on the flotation of fine niobium oxide (pyrochlore). To facilitate comparison, two hydrocarbon radicals were tested: octyl and oleoyl, which led to four collectors that were studied: octyl hydroxamic acid (OHA), sodium octanoate (C8OONa), oleoyl hydroxamic acid (C18HA), and sodium oleate (NaOl). Small-scale flotation and isothermal microcalorimetric titration measurements were performed to determine the flotation recoveries of different sized pyrochlore and the enthalpic behavior after adsorption of the collectors on pyrochlore. It was found that the flotation performance of the carboxylate-based collectors was generally inferior to hydroxamate-based collectors. Sodium octanoate could not float pyrochlore irrespective of the particle size of the pyrochlore tested. With a longer hydrocarbon chain, sodium oleate was effective to float the relatively coarse pyrochlore (>20 µm) but its collection efficiency dropped sharply for particles smaller than 20 µm. On the other hand, the two hydroxamate-based collectors, octyl hydroxamic acid and oleoyl hydroxamic acid, showed good collecting ability to both the coarse and fine pyrochlore. The isothermal microcalorimetric titration studies indicated a consistent correlation of chain length with floatability of collectors for relatively coarse pyrochlore, as well as a positive relationship between the adsorption affinity and fine pyrochlore flotation recoveries. The key finding of this study was that efficient fine particle flotation could be achieved when strongly chemisorbing collectors were used.INTRODUCTION The first detailed study of the effect of particle size on flotation was made by Gaudin (1931) with sulphide ores. In 1942, Gaudin again demonstrated that (Gaudin et al., 1942) fine particles possess different flotation properties from larger particles. Since then the effect of particle size on froth flotation has been an important research topic by many researchers, e.g., Gaudin (1957), Miettinen et al. (2010), Warren (1976) Jameson (2010), summarizing the behavior of fine particles in terms of their low particle momentum, leading to low rate of collision with bubbles which reduces the chance of adhesion. The suggested remediation methods are mainly based on two approaches: increasing particle size or decreasing bubble size (Warren, 1976). Sand-fine splitting followed by separate flotation treatment of the sand and fines, using deep flotation cells, using starvation quantities of collectors, and using long flotation times, are also strategies to address the problems of fine particle flotation."

Jan 1, 2018