Search Documents

By Vladimir I. Ryaboy, Konstantin M. Asonchik

"At flotation of sulfide-barite ores of one of deposits sulfide and barite concentrates are obtained. In sulfide cycle potassium xantogenate as a collector in consumption of 200 g/ton, methylisobutylcarbinol (MIBC) as a foaming agent in consumption of 30 g/ton and also liquid glass are used. In barite cycle tall oil as fatty acid collector in consumption up to 400 g/ton is used.Sulfide concentrate represents mainly gold- and silver-containing pyrite. The contents of gold makes not less than 10 g per ton, silver - not less than 278 g/t. Barite concentrate contains up to 86% of barite.Factory is working in water recirculation conditions. Owing to that in barite cycle fatty acid collector is used, technological water from tailing repository contains fatty acids soap up to 25 mg/l. Before submission into sulfide cycle this water is conditioned with active carbon to delete the main part of fatty acid collector. The active carbon consumption makes 0,4-0,5 kg per 1m3 of water or 1,5-2 kg per ton of ore. The above mentioned consumption of active carbon improves reducing of contents of fatty acid collector from the initial concentration of 25-30 mg/l to 4 mg/l. At concentration 4 mg/l fatty acid collector does not render negative influence on flotation index in sulfide cycle. At the absence of active carbon pollution of sulfide concentrate and its irrevocable lost are observed."

Jan 1, 2003

By Takashi Furuyama, Sukeyuki Mori, Abel Bissombolo

"In flotation practice, a good recovery of minerals largely depends on the degree to which the valuable minerals have been liberated from the associated gangue during the grinding process. Therefore, a regular measurement of the degree of liberation can provide data for the assessment of the quality of separation and predicts the effect of changes in the grinding-classifying circuit on flotation process. Generally, the standard procedure for measuring the degree of liberation requires the preparation of polished sections - a time consuming operation that also has the disadvantage of providing an overestimated number of free particles because of the stereological nature of produced samples.The present work is an alternative approach to avoid these miscalculations and establish a system of control for fluorite flotation plants. The system deals no only with the state of liberation but also the dynamic behavior of individuals particles and mineral components within the grinding-classifying and flotation circuits. It involves methods such as sieving, x-ray diffraction analysis, study of polished sections and microscopic counting of preliminarily sieved minerals particles from a fluorite processing plant, randomly dispersed on a glass slide, but not embedded in a resin mounting medium. If a complete information on the textural properties of minerals in the ore (including its mineral components distribution) can be obtained through x-ray diffraction analysis and study of polished sections, the microscopic counting is used to determinate with enough accuracy the mineral liberation, estimate the grade of fluorite ore and products, determinate the deportment and approximate recovery of individuals particles and mineral components within the investigated circuit. For a count of 100-1000 particles in each n-size range, the counting method was found to be a particularly reliable and less time consuming operation that could substitute the chemical analysis of fluorite ore for an estimate of the grade:"

Jan 1, 2003

By T. Kumaresan

The Bayer process used for refining bauxite to smelting grade Alumina serves as the linchpin of the Aluminum production industry worldwide. Even though the process is well established, the presence of impurities in the liquor affects the quality of product and imposes a major economic cost on the industry. This review article focuses on the issues pertaining to Gibbsitic (Al2O3.3H2O) precipitation circuit. The comprehensive review provides a basic understanding of the aluminum trihydrate precipitation and agglomeration phenomena. Crystal growth rate and agglomeration play a significant role in determining the output PSD of agglomerates. Hence, the effect of certain thermodynamic and hydrodynamic parameters along with the impact of impurities (oxalates, aldols, acids etc.) and additives on hydrate growth has been reviewed.

Sep 1, 2012

By D. P. Chakraborty

Joda East Iron Mine, one of the captive iron ore sources of Tata steel, located in the state of Odisha in eastern India caters to approximately 45% of the iron ore requirement of the Jamshedpur Steel Plant. The iron ore occurring in the mine having high in iron content along with high in alumina. Clay and gibbsite are the predominant mineral phases present as surface coating, fracture filling and/or free occurring and are responsible for alumina content higher. Alumina in iron ore impacts the techno-economic performance of a steel plant by impacting sintering and blast furnace productivity. The impact is even higher when it comes to fine ore used in the blast furnaces in the form of sinter as it constitutes a major portion of the blast furnace burden. Therefore, it is beneficial to upgrade iron ore in the mine head and to reduce alumina before it is subjected to agglomeration. Mineralogical test works reveal, that alumina in iron fines is mainly associated with the clay attached to the hematite particles, either free or interlocked to a very fine size. The paper describes the efforts made to reduce alumina in the iron fines in Joda East processing plant, without much of capital investment for a very sophisticated fines beneficiation circuit. In this process, a suitable dispersant was added in the plant that dispersed the masked slime coating over the iron ore fines, thereby making a better quality iron ore fines with reduced alumina content. The alumina in fines improved by 0.2 units? means from a label of 2.4-2.6 % reduced to 2.2-2.4 %. With this initiative, not only the primary objective of alumina reduction is met but also it has given substantial benefit in reduction of silica and as well as moisture in product. This moisture reduction also has given bottom line impact by reducing idle freight and royalty.

Sep 1, 2012

By H. U. R. Kattentidt, W. L. Dalmijn, T. P. R. de Jong

"Research at Delft University aims to develop systems for automatic inspection and sorting of bulk solids which can be applied in the mineral processing and recycling industry. A recent development includes an automatic sorter based on airport X-ray inspection technology. It is designed for continuous inspection and sorting of 5 – 150 mm solids and has as objective a cost effective and high capacity on-line inspection and sorting.Dual energy X-ray transmission imaging provides instantaneous data about particle dimensions and the atomic number distribution. The system provides particle thickness and average atomic number on a pixel level at scanning speeds between 250 and 500 lines / second. With existing X-ray components inspection speeds between 0.5 and 2 m/s at approximately 1-meter inspection width and between 1.5*1.5 and 5*5 mm2 sensor resolution can be achieved.Imaging algorithms that were developed by Delft University for applications in recycling, waste cleaning and other applications acquire shape, size distribution and composition data. Currently on-line processing of a product at a rate of around 200 particles per second is possible using a standard PC. Experiments with a demonstration X-ray unit indicated good potential for various applications in solids processing. They include continuous inspection of organic content, sulphur, chlorine, ash, and metal distribution. It is applicable for coal cleaning, ore sorting, industrial minerals, and various applications within waste cleaning and recycling. Dual energy X-ray transmission fundamentals and recent progress in system development and applications are presented."

Jan 1, 2003

By E. Barsky

"The aim of separation is to obtain two products that are as distinct as possible from each other. It is currently believed that the most objective criteria for the quality of a separation are the Hancock criterion and the entropy criterion.1. Hancock criterion:- for yield of fine product"

Jan 1, 2003

In order to determine the optimal process parameters of agitation leaching and provide industrial process design parameters, experiments were carried out on leaching behaviors of copper oxide ore with high mud content. Condition tests show that the main factors affect the leaching efficiency as follows: Temperature, Initial acid concentration, leaching time and particle size. As the temperature increases, the copper leaching rate was increased. At 60 ?, the initial acid concentration 80g / L, leaching time 2h, liquid-solid ratio 2:1 and grinding fineness65%-0.074mm, the optimal copper extraction was 83.15%, the acid consumption was 187.91kg / t. ore. Keywords: agitation leaching, copper oxide ore, mud

Sep 1, 2012

"The first 90 years of the last century generated a considerable volume of technical literature on the subject of grinding mill power and its prediction. It is therefore surprising that during this time there were no published models for predicting grinding mill power draw which were validated using a wide range of comprehensive industrial scale data.Notwithstanding this lack of data, the majority of models placed limited emphasis on the internal dynamics of mills and relied on simple assumptions which considered the charge to take up a fixed position and shape.Laboratory based studies (Liddell, 1986), and industrial data (Morrell, 1993), showed that these assumptions did not hold over a wide range of operating conditions, and brought into doubt the ability of the (then) existing models to accurately predict grinding mill power draw. Furthermore no model treated AG,SAG and ball mills as a single class of devices whose power draw could be predicted with the same equations.Through a detailed investigation of the charge dynamics, coupled with a large data base of industrial mill power draws, this situation was rectified by the end of the century, by which time a model had been developed and validated, which accurately predicted the power draw of all wet tumbling mills. This paper describes this model and reviews some of the earlier attempts at mill power modelling."

Jan 1, 2003

"The first 90 years of the last century generated a considerable volume of technical literature on the subject of grinding mill power and its prediction. It is therefore surprising that during this time there were no published models for predicting grinding mill power draw which were validated using a wide range of comprehensive industrial scale data.Notwithstanding this lack of data, the majority of models placed limited emphasis on the internal dynamics of mills and relied on simple assumptions which considered the charge to take up a fixed position and shape.Laboratory based studies (Liddell, 1986), and industrial data (Morrell, 1993), showed that these assumptions did not hold over a wide range of operating conditions, and brought into doubt the ability of the (then) existing models to accurately predict grinding mill power draw. Furthermore no model treated AG,SAG and ball mills as a single class of devices whose power draw could be predicted with the same equations.Through a detailed investigation of the charge dynamics, coupled with a large data base of industrial mill power draws, this situation was rectified by the end of the century, by which time a model had been developed and validated, which accurately predicted the power draw of all wet tumbling mills. This paper describes this model and reviews some of the earlier attempts at mill power modelling.INTRODUCTIONThe early 1900?s saw the beginnings of published papers which tackled the problem of what influenced the power draw of tumbling mills and what equations (models) were suitable for predicting power draw. This interest continued for the rest of the 20th century and the literature contains many papers that attempted to satisfactorily answer these questions. A common and disappointing theme in the majority of them, however, is the distinct lack of suitable experimentally derived power draw data. This deficiency consequently limited the practical application of many of the attempts at modelling mill power draw. Prior to the early 1990?s some limited data on the power draw of grinding mills in the literature can be found, but as Harris et al (1985) remarked they are ?... too frequently unusable simply because one or more essential variables have been omitted?. The absence of published results, from vigorous experimental testing of the various models, has resulted in a general lack of evaluation of the validity of assumptions and hypotheses that such models contain. Harris et al (1985) however, did make some efforts in attempting to evaluate the performance of various power prediction equations and in so doing further developed a semi-empirical one of their own. However, in using manufacturers? published data, which themselves were undoubtedly generated by proprietary equations of unproven validity, they probably succeeded in generating little more than a consensus of the various errors in these models."

Jan 1, 2003

By Xiaolu Ye

"Comprehensive utilization of Bi and Sn from the tin-associated polymetallic tailings by “gravity separation – flotation combination process” has been studied, which was verified that the novel process is an effective method to deal with the high content pyrrhotite tin-associated polymetallic tailings. In this investigation, ore property analysis and magnetism analysis of pyrrhotite were conducted to research and develop reasonable beneficiation flowsheet. The results of ore property analysis present that pyrrhotite was not closely related to bismuth and tin minerals. Particle size analysis results indicated that pyrrhotite was mainly in the form of fine particles. The magnetic analysis results show that pyrrhotite was distribution in all the three types of pyrrhotite in a single mining area, which indicated that variable magnetism of with different crystal structure pyrrhotite. The process of “low intensity magnetic separation - high intensity magnetic separation” shown an excellent adaption for the high content pyrrhotite tin-associated polymetallic ore compared with the single flotation process based on the magnetism variable of pyrrhotite. The results of whole process test indicated that a bismuth coarse concentrate assaying 5.63% of Bi at 81.77% recovery was obtained, which treat the conditions for the Bi-S separation flotation. In addition, the content of sulfur in the tin concentrate decreased from 2.5% to 1.5%, which provided a new reference for other tin-associated polymetallic tailings. INTRODUCTION Tin has been applied extensively in catalytic chemistry, gas sensors, tin plating, and plumbing. Tin-bearing polymetallic ores have been the important deposit types to recycle tin with the rapid depletion of mineral resources. The comprehensive utilization of the associated elements has been a preoccupation for the mineral processing researchers."

Jan 1, 2018

By H. D. Yu

In this paper, an evaluation about the process mineralogy of the rich iron mine in Mongolia with comprehensive methods is given; this provides foundation of the comprehensive recovery of iron and cobalt in the ore. The research shows that the iron?s grade is 61.23%, Co?s grade is 0.02%, the ore is rich iron ore and its Co content also reaches border mining grade. For the ore, if want get high grade iron concentrate powder, must identify the mineral composition and the occurrence of iron and take into ac-count the recovery of Co content as associated resources. Chemical phase analysis results show that 86.35% of iron exists in magnetite, which means that the theoretical recovery ratio of iron is close to 86%. Minerals spectrum analysis confirmed that the magnetite containing a small amount of Mg, Al, and other impurities, the actual iron minerals to 70.28%, which means that theoretically iron grade iron concentrate only close to 70.28%. Based on the result of iron chemical phase analysis, by investigating the liberation of sulfide minerals and gangue, the recovery index of iron can be forecasted, when grinding fineness is 35%, 45%, 55% and 65% bellow 0.074mm,theoretical content of Fe in iron concentrate separately is 67.71%,67.88%,68.78%,and 69.43%,accordingly the theoretical recovery of Fe is 87.38%,87.05%,86.92% and 86.63%. From the perspective of process mineralogy, the forecast mineral beneficiation indicators show that the ore is easy sorting ore, iron processing operations have higher recovery rate, but wants sorting of high-grade iron ore concentrate still need appropriate grinding fineness. Furthermore, associated element Co, existing mostly in pyrite and pyrrhotite, is valuable in the ore. Pyrite and pyrrhotite have ideal liberation under grinding, so cobalt can be easily enriched in sulfide concentrate.

Jan 1, 2014

By Dongyun Liang

Process mineralogy focuses on the chemical components and mineral composition of ore, dissemination size of valuable minerals, the occurrence of valuable and detrimental elements as well as the behavior of each mineral in the process. Through determining process mineralogy parameters and analyzing the characteristics of minerals, the results of process mineralogy study can provide mineralogy data for making a reasonable mineral processing technology program and optimizing the process. A detailed process mineralogy study is carried out for a complex rare metal ore in this paper and the results show that niobium mainly exists in the form of ferrocolumbite as well as nioboaeschynite and zirconium primarily occurs as zircon. The valuable minerals including Th-nioboaeschynite, ferrocolumbite, zircon, etc. have the characteristics of fine dissemination size, wide size range, complex chemical composition and variable physical properties, which mean it is a refractory ore. According to the results of mineral composition of ore, chemical composition of minerals, dissemination size of minerals, magnetism ranges of minerals and the distribution of niobium and zirconium, the process of ?desliming-Nb-Zr bulk flotation? is designed for this ore and the niobium-zirconium bulk rough concentrate with the grade of Nb2O5 9.43%, ZrO2 24.95%, Ta2O5 0.36% and the recovery of Nb2O5 77.66%, ZrO2 76.70%, Ta2O5 75.13% to crude ore can be obtained in the whole process closed-circuit test.

Sep 1, 2012

By R. L. Pascual, W. J. Whiten

"The froth flotation process is not well understood. Both flotation models, and the parameters used to describe the stream flows are not well defined. They in fact vary considerably in different applications. This creates difficulties is designing a simulation program suitable for use by plant personnel, consultants, and researchers. In addition to simulation, an effective simulation program can be expected to provide a range of other services.This paper shows how a process circuit simulator can be designed with sufficient flexibility to satisfy these needs, and discusses some of the additional services.OVERVIEWThe development of a simulation program for froth flotation circuits faces several challenges as flotation models and the associated stream descriptions are not well defined. There is little agreement on the best form for a flotation model, or on how the plant streams should be defined.In addition to simulation, a flotation simulator is generally expected to provide other services such as data input, data reconciliation, model fitting, and accuracy estimation. Additional services may also be needed beyond what might initially be envisaged. A summary of some of these possibilities is included.To apply simulation to a flotation circuit it is necessary to develop a flotation cell model, for instance based on the general outline given in the appendices. Experimental data, usually from the plant, is needed to determine cell model parameters. This is generally done by first undertaking data reconciliation to determine if mass flow constraints are sufficiently closely satisfied. At the same time the data is inspected for outliers that might bias subsequent calculations. Next the data is fitted to a model to back calculate ore characteristics. If there is sufficient agreement between the fitted model and the data, the model can then used to make predictions of the effect of changes to the plant. The changes, that the simulation shows are beneficial, can be applied to improve plant performance"

Jan 1, 2003

By S. Fiore, M. C. Zanetti, C. Clerici

The processes and fluxes of a cast iron foundry plant located in the North of Italy were analyzed in order to determine the amount and kind of wastes produced from the different activities. The main fractions are the molding sands, furnace muds and powders coming from the dust abatement plant, the exhaust lime, the furnace refractory, the metallic shotting and the sludges and powders coming from the dust abatement plant of molding lines for a total production equal to 800 t/d. All wastes were sampled and particle-size and chemically characterized to evaluate the best recycling or reuse solutions. Wastes were sieved and divided in three categories according to the particle-size dimensions: below 0.1 mm, between 0.1 and 0.6 mm and above 0.6 mm. The fraction above 0.6 mm dimension underwent magnetic separation to recover and quantify the potentially available iron fraction. The fraction between 0.1 mm and 0.6 mm was chemically characterized in order to understand if it could be fed to the sand regeneration plant. The below 0.1 mm fraction was characterized to evaluate the following recycling and reuse solutions: additive for molding sands and/or raw material for the concrete industry.

Jan 1, 2003

By L. Q. Luo

SHP-F3200 wet high-intensity magnetic separator (HIMS) was successfully used to separate the complex and weakly magnetic iron ores being composed of specularite, limonite and siderite in Ji-uquan Iron and Steel (Group) Co Ltd (JISCO). It is more and more difficult to separate iron ores from gangues, such as quartz, jasperite and phyllite, as the properties of iron ores gradually become more complicated and refractory. Some technologies have been used to improve SHP-F3200 HIMS, including modifying angle of magnetic polar from 90°to 83°, cooling exciting coils by oil instead of air, adding reverse-washing device to wash off magnetic particles, adjusting the tooth-space of matrix from 5.0 mm to 3.5 mm or 2.5 mm, so as to enhance the recovery of fine iron ore particles. It is still difficult to meet the requirement for recovering more difficultly-separated iron and the demands for high-grade concentrate of iron. In this paper, after analyzing magnetic force exerting on iron ore particles within different separating sections of SHP HIMS, it is proposed to apply the flowing-film technique into the HIMS. Thus a new-type LY matrix is designed to form magnetic gradient vertically, combined with a special flowing-film feeder to improve the existing SHP HIMS. The moving pattern of magnetic particles in pulp in HIMS separation district also has been analyzed in this paper. And the test on the SHP-F700 HIMS shows, under the condition of iron ore containing 30.52% Fe, with particle size of ?0.074 mm accounting for around 75%, if applied with flow-film technique, the iron recovery will be up from 69.45% to 76.07%, by 6.62 percent, with the same grade of concentrates of iron. The calculation of iron yield of every size fraction and the tests showed that film magnetic separation (Film-MS) could promote the iron yield of each size fraction, denoting an excellent result of application of the film technique to SHP HIMS. The mechanism of the film magnetic separation technique is to convert the turbulent flow and disordered movement of dynamic mass particles in the pulp into a directional and ordered laminar flow along the surface of tooth plate so as to strengthen the separation effects.

Jan 1, 2014

By F. Y. Kang

Graphite with layers structure is easily to form graphite intercalation compounds (GICs) by means of intercalation reactions due to the weak cohesion force among carbon layers, van der Waal?s interactions. By controlling the oxidation-intercalation, high quality exfoliated graphite with low residual sulfur content and MClx-GICs (M=Fe, Co, Ni, Cu, Zn) powder for electromagnetic wave absorbing and shielding materials have been invented. The expansion volume of expandable graphite can be larger than 160 mL/g while the residual sulfur content is less than 800 ppm. The MClx-GICs powder can shield infrared ray and laser completely up to 15 min. We have also in-vented exfoliated graphite for heavy oil adsorption and mild-expansion exfoliated graphite for anode materials in lithium ion battery by controlling the intercalation/de-intercalation. The exfoliated graphite can adsorb heavy oil up to 80 g/g, it also exhibits better performance than commercial active carbon in sewage treatment. The mild-expansion exfoliated graphite as anode material shows high capacity of 370 mAh/g and good cycle performance.

Jan 1, 2014

By Zoran M. Stevic, Mirjana M. Rajcic-Vujasinovic, Zvonimir D. Stankovic

"Huge electrochemical investigations have been performed on Technical faculty in Bor (Serbia) which main goal was the clarification of the copper sulfide minerals behaviour in hydrometallurgic and flotation processes. Modeling of these processes was a part of the effort for better understanding of the reaction mechanisms.The consideration of electrical analog circuit and mathematical model of processes at interfaces copper sulfide/electrolyte (CuS/(CuSO4+H2SO4), Cu2S/H2SO4 and CuFeS2/H2SO4), based on studies of the overvoltage – time transients, will be presented. The transients were obtained using single pulse galvanostatic method and electrochemical cell with standard three electrode assembly. In that goal it was developed an original system for computer measurements that enables the application of several methods for electrochemical investigations (galvanostatic, potentiostatic, cyclic voltammetry, electrochemical impedance spectrometry etc). The system was tested and adjusted using commercial electrochemical equipment made by AMEL, Milano.In the first stage of consideration the different equivalent electrical circuits have been tested by computer programme OrCAD 9.2 in order to identify the circuit with responses equivalent in shape to experimentally obtained ones. In that way it was established a configuration of an analog electrical circuit for investigated electrochemical system. That phase enabled only very rough determination of values of circuit components and their relative ratio.In the second stage the method for determination of all elements of electrical analog circuit is described. It is based on mathematical consideration of a given circuit on one hand, and valves of the overvoltages at selected times, obtained from charging and discharging parts of galvanostatic transients, on the other."

Jan 1, 2003

By Ji Hoe Kwon

Hindered-settling column process has been used for the separation of mineral particles for many years. In this study, a model based on DEM (Discrete Element Method) was used to simulate the movements of particles in a settling column separation process. DEM model is capable of describing the motion of particles and calculating the impact forces between particle and particle, and particle and wall contact under various operating conditions. Drag force, rotation induced Magnus lift force, contact force and the gravitational force acting on individual particles were considered for establishing the mathematic models. The overall motion of the particles in water is satisfactorily simulated by the DEM, and the result shows good agreements with the result of lap-scale experiment.

Jan 1, 2014

By J. Qiu

By means of natural sedimentation, two different bentonite samples from Shandong province were purified, this paper studies the Hydro-properties of the two purified montmorillonite samples. Firstly, the layer charge of two purified montmorillonite samples were calculated by crystal structure formula reckon method and general hydro-properties were also measured. The research results showed that the layer charge of montmorillonite correlated well with its hydro-properties: mont-morillonite with lower layer charge had better hydro-properties, such as Mont-1, which had higher swelling volume and gelling value with lower CEC; while, montmorillonite with higher layer charge had worse hydro-properties, such as Mont-2, which had lower swell volume and gelling value with higher CEC; it proves that the hydro-properties of montmorillonite depends on its layer charge characteristics, layer charge characteristic is the inherent factors deciding the hydro-properties of montmorillonite, montmorillonite with lower layer charge has better hydro-properties than the one with higher layer charge. In this paper, the relation between the medium condition and colloid performance of Mont-1 are also studied. The results show that the hydro-properties of Mont-1 could be changed by changing slurry concentration (w/w) and shear rate or adding certain amounts of inorganic cation electrolytes, dispersants and surfactants. The viscosity of montmorillonite slurry could be enhanced by increasing slurry concentration,adding univalentcation electrolytes (less than 4% w/w) or proper amounts of dispersants and surfactants (less than critical micelle concentration); The slurry viscosity could be reduced by decreasing slurry concentration, increasing shear rate, adding proper bivalent (more than 4% w/w) cation electrolytes or proper quantities of dispersants and surfactants (more than critical micelle concentration).

Jan 1, 2014

By Sun Chuanyao, Jia Muxin

Generally, if the bond valence (BV) between metal ion and oxygen of the mineral is greater than 0.8, only surface species –Me-O-H or –Me-O exposures on the mineral interface, if the BV is between 0.2-0.8, the metal ion exposures on the interface, and if the BV is less than 0.2 the metal ion dissolves into water. The PZCs of oxide minerals and island silicate minerals are determined by the bond valence of the bond in the mineral crystals, the higher the bond valence the lower the PZC of the mineral. So the PZC sequence of Al2SiO5 minerals is kyanite> andalusite> sillimanite. The general rule for framework silicate minerals is as: The higher the Al content, the lower the PZC of the mineral, when the ratio of Al to Si in the tetrahedron skeleton is below 1:3. The higher the Al content, the higher the PZC of the mineral, when the ratio of Al to Si in the skeleton is between 1:3 and 1:1. The general rule for layer silicate minerals is summarized as: the three-layer silicate minerals have much lower PZCs than that of the two-layer silicate minerals. The threelayer silicate mineral with the octahedron layer occupied by lower charged cations has lower PZC than that of the three-layer silicate mineral with the octahedron layer occupied by higher charged cations. The twolayer silicate mineral with the octahedron layer occupied by lower charged cations has higher PZC than that of the two-layer silicate mineral with the octahedron layer occupied by higher charged cations. The layer silicate mineral with Al substitution in the tetrahedron layer has lower PZC than that of the layer silicate mineral without Al substitution in the tetrahedron layer. Such pyroxene minerals whose M1 is occupied by a trivalence cation and the M2 is occupied by a monovalence cation has lower PZCs than those both M1 and M2 are all occupied by bivalence cations. Such hornblende minerals whose M2 is occupied by a trivalence cation and the M4 is occupied by a monovalence cation has lower PZCs than those both M2 and M4 are all occupied by bivalence cations. There is no Si4+ or 4 coordinated Al3+ exposures on the surface of framework silicate minerals, the metal ions of three layer or chain silicate minerals are compact between tetrahedron layersor chains, they hinder the metal ions to interact with oleate acid radical, the metal ion octahedron layer exposures on the surface of a two layer silicate mineral, but the the oleate acid radical can not attach to a metal ion by replacing a –OH- that connects three metal cations in the same time, So the floatability of such silicate mineral is bad. The metal octahedron chain style of an island silicate mineral affects it floatability, the mineral exposures octahedron chain metals with two dangling bonds in two directions floats better than the mineral exposures octahedron chain metals with two dangling bonds in one direction.

Jan 1, 2003