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By Ian Hattie, Mark R. Wilson, T. Kurtis Kyser, Brian W. Janser

Petrographic, chemical and isotopic compo itions of auriferous and non-auriferous quartz vei ns from the Sta r Lake and Flin Flin-Amisk Lake areas of northern Saskatchewan indicate diver e origins fo r the fluids associated with gold mineralization. In the Sta r Lake area, the metavolcanic , Star Lake pl uton, and heared mafic dikes have retained their original igneous 81 80 values. The 81 80 value of quartz from mi neralized veins vary by I per mi! and range from+I0 to+IJ. The only quartz ample having a 81 80 value outside th is range came from a vein not associated wi th a dike or gold mineralization . Quartz from the Star Lake pluton has identical 8180 value to the qua rtz from mi neralized vei ns which suggests that the vei ns and the pluton are related to imilar proces es. The diffe rence in 81 80 values between mi neralized and barren vein may erve a a potential exploration tool in this area. Because o34S val ues of a limi ted number of amples of pyrite from gold-bearing quartz vei ns at Star Lake correlate directly with gold content. the gold may have been syngenetic with the su lphur and the 834 value may be useful for exploration . 8180 values of co-existing quartz, calcite, and amphibole in the veins from Star Lake indicate that isotopic disequilibrium among the minerals is common, but the val ues also record a high temperature of formation (ea . 500°C) involvi ng a component of magmatic fl uid. TheoD value of hydrou mineral from Star Lake retain their original igneous values but whole rock values are generally much lower, an effect attributed to interaction of the minerals with a late meteoric water. In the Fl in Flin-Amisk Lake area, auriferou and barren quartz veins formed from a mixture of hydrothermal and metamorph ic flu id at lower temperatures (ea . 350°C) than those at Sta r Lake. Becau e there i no apparent correlation between 8180 values of the quartz with gold content or relative age of the vein , nor between the 834S val ues of pyrite and gold content, table isotopes appear limited as an exploration tool in the Fl in FlonAmisk Lake areas.

Jan 1, 1986

By M. H. Fathi

The aim of this work was to prepare the metallic coatings on 316L stainless steel dental implant and evaluate the corrosion characteristics and thus the biocompatibility of the uncoated and metallic coated dental implants and comparison of the effect of the type of coatings on biocompatibility. Three types of metallic coatings including Tantalum, Niobium, and Titanium coatings were made using physical vapor deposition process on 316L stainless steel dental implant. Structural characterization techniques including; X-ray Diffraction, Scanning Electron Microscopy and Energy Dispersive X-ray Analysis were utilized to investigate the microstructure and morphology of the coatings. Electrochemical potentiodynamic tests were performed in two types of physiological solutions at 37±1 °C in order to determine and compare the corrosion characteristics. All three types of metallic coatings had a positive effect on improvement of the corrosion behavior so that the coatings could increase the corrosion resistance of 316L stainless steel and this trend was independent to the type of physiological environment. Biocompatible metallic coatings could decrease the corrosion current density that is a distinct advantage for prevention of ion release. This can improve the biocompatibility of the implant and, consequently prevention of tissue damages, inflammation and irritation and obtained desirable histopathological response.

Jan 1, 2007

By J. M. Newell, G. R. Peatfield

"The Red-Chris porphyry Cu-Au deposit is located between Ealue and Kluea lakes, southeast of the village of Iskut on the Stewart Cassiar highway in northwestern British Columbia. It was explored by Texasgulf Inc., in a joint venture with Great Plains Development Company of Canada, Ltd. and Silver Standard Mines Ltd., during the period 1973 to 1980. Exploration resumed in 1994, following acquisition of the interests originally held by Texasgulf and Great Plains Development by American Bullion Minerals Ltd.Prospectors were first drawn to the area by prominent limonitic stain zones exposed in creek gullies in the western part of the property. These zones are developed on the alteration halo at the western periphery of the deposit. The potential ore zones do not crop out and were first exposed in a bulldozer trench excavated in 1971. Subsequent exploration was by percussion and diamond drilling, guided to some extent by induced polarization surveys. In 1976, estimated resources contained within two crudely designed open pits were 41 million tonnes with an average grade of 0.56% Cu and 0.34 g/t Au, with a cutoff grade of0.25% Cu. New resource estimates based on a major drilling program completed by American Bullion in 1994 were released as this paper goes to press. These estimates were calculated using various copper cutoff grades; at the 0.4% Cu cutoff, the ""in-situ geological reserve"" is given as 100 million tonnes grading 0.58% Cu and 0.46 g! t Au (American Bullion Minerals Ltd., 1995).The deposit consists mainly of pyrite, chalcopyrite and increasing bornite at depth, in zones of quartz-vein stockwork hosted by an elongate body of altered monzonite porphyry of latest Triassic or earliest Jurassic age. The stock intruded volcanic and sedimentary rocks of probable Stuhini Group affinity and is in faulted contact with sedimentary rocks of the Jurassic Bowser Lake Group. Gypsum stockworks are developed in the higher levels of the subvolcanic porphyry system. Late-stage quartz-carbonate veins carry small amounts of galena and sphalerite. Complex faulting within the deposit makes drill-hole correlations difficult. Alteration assemblages include an early potassic phase, almost completely destroyed by later phyllic alteration, and surrounded by a propylitic assemblage dominated by ankeritic carbonates in altered sedimentary rocks.The deposit has characteristics of bath the alkalic and calc-alkalic classes of porphyry copper deposits. The development of quartzvein stockwork suggests a calc-alkalic affinity, but the hostrocks contain little or no free quartz, molybdenum is present in trace amounts only and gold values are significant. Copper grades vary between wide extremes with unusually high grades in some sections of the deposit. The weight of evidence available in the 1970s led us to place the Red-Chris deposit firmly in the alkalic family. The quartz-sericite alteration assemblage was attributed to breakdown of potassium feldspar in a near-surface alteration environment in which seawater may have had a significant role. These interpretalions are retained here, but preliminary conclusions from the most recent work suggest that they may require some modification."

Jan 1, 1995

By C. B. Webber, W. A. Grell

"Sherritt Gordon's Ruttan Mine is a copper-zinc operation located approximately 600 miles north-west of Winnipeg. Open pit mining began in 1973 at 10,000 Tpd., with a change over to underground mining in 1981 producing 7,500 Tpd. Ore is crushed to -3/4"" followed by rod and ball mill grinding (two ball mills in series), differential copper-zinc flotation, and dewatering. The copper and zinc concentrates are trucked 75 miles to Lynn Lake, where they are shipped by rail to the HBM&S smelter at Flin Flon.This paper describes a method used to predict the effect of grind particle size on metallurgical performance, as well as details on the copper and zinc metallurgical performance due to fine grinding in actual plant operation.Initial statistical studies on historical data (including ore source, head gr3de, grind, etc.) indicated that copper and zinc recoveries increased with fineness of grind, in the range of 50 to 65% -200 mesh.In order to extrapolate beyond 65% -200 mesh, and to develop expected nonlinear relations between grind, Cu concentrate grade, and recovery, the assays of screen fractions of copper concentrate and tailing were used to determin8 the relation between net smelter return (a function of grade and recovery) and grinding cost. The optimum economic grind would be that grind at which the net smelter return less grinding cost reached a maximum."

Jan 1, 1982

By G. Eaton

Safety management is an important mortal and business function in construction. Contractors have traditionally tracked and reported lagging indicators, e.g. fatalities and lost-time accident rates, to measure their safety performance and stay in compliance with relevant regulations. Over the last several decades, contractors became more proactive in their approach to safety and developed programs that track leading indicators, e.g. safety audits and safety climate. In particular, safety climate measures workers? perception of safety management and its effectiveness in the workplace. Past literatures indicated that, while some industrial construction contractors ignore safety climate measures, others are limited by a lack of a formal means to measure safety climate. In this study, a survey approach is used to measure an industrial construction contractor?s safety climate through three key areas: management commitment, job control, and general safety climate. As a pilot study, a total of 214 individuals at a fabrication facility participated in the survey to verify the validity and effectiveness of the proposed survey approach. This survey study also confirms that job control and management commitment have a positive correlation and that worker demographics have an effect on respondents? perceptions of management commitment.

Aug 1, 2013

By M. Dupuis

Recently, a new approach to controlling alumina feeding in a H.H. cell has been proposed [1, 2 and 3]. This approach, labeled In Situ aluminium cell control, is based on a correlation between the slope of the cell voltage during a no feed observation period and the dissolved alumina concentration in the bath. Once the dissolved alumina concentration has been estimated, a primary calibration surface uniquely relating the dissolved alumina concentration and the anode-cathode-distance (ACD) to the cell voltage is used to estimate the cell ACD. Once both the alumina concentration and the ACD have been estimated at the end of the observation period, a PID controller can be used to regulate the rate of alumina feeding using only the normalized cell voltage to calculate the error between the estimated dissolved alumina concentration and a target value. The In Situ aluminium cell control algorithm has now been tested with the Dyna/Marc [4, 5 and 6] cell simulator demonstrating that it should be possible to control a H.H. cell in this manner with less variation in the dissolved alumina concentration and other process variables producing a prediction of improved cell current efficiency and power efficiency.

Jan 1, 2011

By T. W. Wong, M. A. Whitney, A. Hadadzadeh

Uniaxial compression tests were performed on cylindrical specimens, 10mm in diameter and 15mm in height, machined from an extruded AZ31B magnesium billet. The tests were conducted under isothermal conditions to a true strain of 0.5. The study compares macroscopic flow anisotropy between the extruded (ED) and transverse (TD) directions in the temperature range of 300°C to 500°C, and strain rate range of 0.001s-1 to 1s-1. Compression of ED specimens at low strain rate (0.001s-1) exhibited axisymmetric flow, and no significant differences were observed between geometries of specimens deformed above 350°C under the same strain rate. Deformation of TD specimens at low temperature and/or low strain rate resulted in elliptical cross-sections, with the anisotropy of flow being less significant at higher temperatures. Other studies performed using rolled plates have proposed that pyramidal slip and cross-slip at higher temperature eliminate the effects of initial texture, while the dominance of prismatic slip at lower temperatures will result in anisotropic flow. It is believed that the initial fiber texture common among extruded HCP-structured materials plays a role in the anisotropic deformation behaviour observed in the extruded specimens

Jan 1, 2015

By K. Mayhew, R. Bruce, A. Heidel, G. P. Demopoulos

"Teck and Aurubis are working together to commercialize a technology for the processing of copper arsenic sulphide concentrates that is economic and sustainable with regards to the environment and community. The pressure hydrometallurgical approach is a desirable option as mineral extraction and arsenic fixation can take place in a single autoclave vessel. A test work program was carried out where a range of copper concentrates with varying arsenic grades was processed under CESL leach conditions. This paper discusses the stability character (in terms of arsenic) of the resulting residues and their mineralogy. The basic ferric arsenate sulphate phase (BFAS; otherwise known as type 2) was identified as the main arsenic carrier. All CESL residues demonstrated high stability (<1 mg/L As) through a range of aggressive (pH and ORP) environmental leach conditions.INTRODUCTIONArsenic deportment and control in the copper industry needs an integrated approach involving each stage of the value chain, i.e. exploration, mine operation, refining process and mine closure. Teck Resources Limited (Teck), Canada’s largest diversified mining company and Aurubis, Europe’s largest copper producer, have formed a partnership to advance the application of CESL copper-gold technology for the development of high arsenic bearing copper resources (Bruce et al., 2011).Among the options for arsenic control in the metallurgical treatment of copper concentrates is the precipitation of ferric arsenate, which is widely accepted as the most suitable method for stabilizing arsenic (Ferron and Wang, 2003). The pressure hydrometallurgical approach to processing arsenic bearing copper concentrates is a favorable option as mineral extraction and arsenic fixation can take place in a single autoclave vessel. Under CESL pressure leaching conditions (150 °C, 1380 kPa) high copper extraction and arsenic (V) fixation is possible.Within the pressure leach autoclave, arsenate and ferric iron react to form scorodite type phases. The precipitate formed under CESL conditions is dependent on the Fe (III) /As (V) ratio and the tenor of cations and anions, particularly excess sulphate (Gomez et al., 2011a). Previous studies on CESL residues have found arsenic to be present as crystalline scorodite (FeAsO4.2H2O) (Bruce et al., 2011), basic ferric arsenate sulphate (BFAS: Fe(AsO4)1-x(SO4)x(OH)x·(1-x)H2O, where 0.3<x<0.7), and/or arsenate adsorbed on to hematite (Gomez et al. 2011b). Although not a focus of previous work, scorodite was the predominant precipitate formed when the concentrate Fe/As was <1.5 (Mayhew et al., 2010), and BFAS was the predominant precipitate when the concentrate Fe/As was >10 (Gomez et al. 2011b)."

Jan 1, 2012

By Tyler Roberts

New Afton mine is an 11,000 tonne per day block caving operation, located 8 km west of the city of Kamloops, British Columbia. Due to the nature of block caving and the weak rock mass at New Afton, the mine has faced and overcome many blasting challenges during its ramp-up to commercial production. As New Afton Mine continues to grow the demand for drill and blast precision has continued to grow as well; any misstep incurs delays in achieving full production capacity. The block cave mining method used at New Afton employs single-shot draw-bells, fired with very little void and blind undercutting, allowing little margin for error. New Afton has made continuous improvements to its blasting strategy by reacting quickly to real-time problems and employing sustainable, repeatable solutions to overcome its unique blasting requirements. Examples of these solutions include: increasing blast hole diameter, casing production drill holes, developing pre-loading procedures and developing strategies for remotely blasting under-broken remnants in both draw-bells and undercutting. Increasing the blast hole diameter has alleviated initial problems with hole plugging in the highly jointed rock mass at New Afton. This has reduced drill-cleaning time significantly and enabled New Afton to meet blasting targets. PVC hole casing was trialed when blasting in extremely fractured ground, where drill holes continually plugged. The casing allowed the drill holes to remain open long enough to load and blast. Calculations were carried out in order to achieve the same explosive energy in the cased holes as a typical blast. Results were generally positive, but more testing is required. Production flexibility and scheduling reliability have been maintained at New Afton by developing a pre-loading procedure for the production undercutting. In doing so, New Afton has been able to keep productivity high by having a flexible production schedule that is not reliant on a specific piece of equipment or production drive to remain productive; this flexibility is because the mucking of undercut material can occur at any stage of the drill/blast/muck cycle. New Afton has developed a strategy for blasting remnant under-break in its draw-bells and undercutting by remotely drilling holes near to the under-broken section and then loading the toes of these holes with emulsion, the remainder of the hole is then filled with grout. The holes are grouted in order to prevent damage to permanent pillars between draw-bells (where the majority of the recovery holes need to be located). Several critical areas were recovered using this technique with little to no damage to the remaining permanent pillars. Innovative blasting solutions have allowed New Afton to overcome obstacles in order to become a producing operation. Moving forward, New Afton looks to continue its trend of innovative drilling and blasting techniques when faced with out of the ordinary situations.

Aug 1, 2013

By S. Castro, L. Gutiérrez, L. Uribe

"Use of lime in seawater as a pyrite depressant decreases Mo recovery in flotation of Cu- Mo sulfide ores. When technology that uses sodium metabisulfite (MBS) to depress pyrite is applied, the process is carried out at pH 6.5–7.5, the range where Mo recovery is higher than the usual pH 11.0–12.0 when lime is applied. Redox conditions and chemical reactions involved in depression mechanisms of pyrite by MBS, or sodium sulfite, in seawater are investigated and discussed based on the acidifying effect of MBS, oxidation of sulfite ions by dissolved oxygen, and the role of catalyst of some metal cations (e.g., copper ions) adsorbed on pyrite’s surface.RÉSUMÉ L’utilisation de chaux dans de l’eau de mer comme agent déprimant de la pyrite réduit la récupération de molybdène (Mo) dans la flottation de minerais sulfurés de Cu-Mo. Lorsque l’on applique la technologie utilisant du métabisulfite (MBS) de sodium comme agent déprimant de la pyrite, le procédé se fait à un pH de 6,5 à 7,5, gamme dans laquelle la récupération de Mo est supérieure au procédé habituel utilisant un pH de 11,0 à 12,0 lorsque l’on applique de la chaux. Les conditions de réduction-oxydation (redox) et les réactions chimiques impliquées dans les mécanismes de dépression de la pyrite par le MBS (ou sulfite de sodium) dans de l’eau de mer sont étudiées et débattues sur la base de l’effet acidifiant du MBS, de l’oxydation des ions sulfites par de l’oxygène dissous et du rôle de catalyseur de certains cations métalliques (par exemple les ions de cuivre) adsorbés à la surface de la pyrite. INTRODUCTIONThe copper industry is aware of the difficulties of floating Cu-Mo sulfide ores in seawater. Molybdenum recovery is partially depressed when lime is used to reject pyrite. In plant practice, sodium metabisulfite (MBS) has been demonstrated to be the most promising option for replacing lime in seawater."

Jan 1, 2017

By Desmond Y. M. Lee

This paper presents a procedure to prepare input for the computerized pit design system at Iron Ore Company of Canada. The procedure is simple and requires very little training. Also, it is general enough to accept both bench (horizontal cross section) maps and section (vertical cross section) maps. The output of this procedure is data which represent blocks of ore and waste with dollar values based on mineral content. The ultimate pit design is presented in printer-generated graphs, with numbers indicating the depths of pit bottom walls. Roads are added manually by the engineer with the aid of other computer programs. Section maps and bench maps are also printed as part of the output of the ultimate pit design.

Jan 1, 1978

By Louis Cabot

A pilot plant of the Modular Gold Processing Unit (MGPU) was designed, installed and operated, over a 8 months period, by RSW-Béroma, at the Granada Mine located near Rouyn-Noranda, Quebec. A description of the project geology, plant set up as well as exploitation results, including productivity and profitability curves, are given for a small scale mining operation in comparison with larger ones. Copyright ã 2001 CIM

May 1, 2001

By Francis Gray

Mr. F. W. Gray: It is not my intention to read my paper as it is too long, so I will touch only on the high lights. The Sydney field is the most favourable example of undersea coal mining that exists, and I have not been able to find anything like it elsewhere. The nearest approach to it is a field in England where the Whitehaven collieries are operating, but it has a lot of faults. The net result of these faults so far met with in the seaward advance of the workings has been to increase, by something over 100 feet, the gain in depth of cover, in a distance of approximately three and three-quarter miles. In the Sydney field there are no faults of any consequence. On the east side, the English measures rise. In Australia the sea bottom fell and the cover became too light. On Vancouver Island the coal ran out, and in Japan the seams are steep and contorted. The Chilian fields resemble our own to some extent. An inundation of two collieries took place there some time ago, due, it is said, to the rise workings being allowed to approach the sea bottom too closely in the vicinity of a fault. The Cape Breton undersea field has been proved over a frontage of about thirty miles and has been attacked and penetrated for a considerable distance along that front. We have passed the prospecting stage and now generally use developed land areas as points of attack to win the undersea coal. Of our mining under the sea, it can be said that, with the exception of No. 1-B and Princess colliery, Sydney Mines, no real attempt has been made to win the undersea coal.

Jan 1, 1927

By Tong Guan, Guangqin Fu, Lihong Deng, Yuanlin Chen, Xiaotong Zhou

"In natural world, some kinds of scheelite minerals are rich in molybdenum. Molybdenum exists in the crystal lattice of scheelite in the form of isomorphism, and the content of MoO3 varies from 2% to 10%. As a result, the flotability of seyrigite (scheelite with molybdenum) turns to be weaker. One seyrigite mine, which has been built for 3 years,still could not produce qualified seyrigite concentrate due to the weak flotability of seyrigite (Mo-bearing scheelite) in raw ore. In our experimental research, through adopting new seyrigite collector TA-3 and advanced mineral processing technology, the seyrigite concentrate with a grade of 65.62% WO3 at a recovery of 87.47% was obtained for the raw ore containing 0.19% WO3 and 0.074% Mo. By applying the new technical achievement, for the raw ore containing 0.272% WO3, the seyrigite concentrate assaying 68.03% WO3 with a recovery of 77.56% was obtained in industrial production.INTRODUCTIONIn natural world, some kinds of scheelite minerals are rich in molybdenum. Molybdenum exists in the crystal lattice of scheelite in the form of isomorphism, and the scheelite is changed to be seyrigite (Ca[(W,Mo)O4]) (Ma, Bian, & Wang, 2013). The content of MoO3 in seyrigite varies from 2% to 10% usually, the content of MoO3 in some of the seyrigite even reaches 34%. The flotability of seyrigite is weak (Zhang, 2007), and the seyrigite is difficult to be recovered by flotation with common collectors and regulators. One scheelite mine in Anhui China, which is a skarn type seyrigite mine, has not produced qualified concentrate yet since 3 years it has been built due to the limit of beneficiation technology. Therefore, it is necessary to conduct research on the collectors with high efficiency and developing advanced processing flow for this kind of ore."

Jan 1, 2016

By R. Esteban, D. Runnels, J. Torrealba-Vargas, G. Couture

"Data handling is an important step in the development of a simulator of a mineral processing circuit. The model requires representative data of the scenario to be modeled. The model development involves protocols that must be followed very closely to complete a successful project.Data handling of large and diverse datasets (metallurgical test results, geological data, mining models, historical data, etc.) is a key element of the model. The information needs to be processed, reconciled, interpreted, modeled and presented to support the design or the optimization of a mineral processing plant.Best practice recommends that teams from different disciplines (such as mining, metallurgy, geology and environmental) interact to define the most important variables that could influence the simulator. For example by adopting a geometallurgical approach in the earlier stages of the project, it is possible to consolidate the number of main ore rock types in a testwork program (saving money and time) by involving geologists and metallurgists in the sample selection and data interpretation.Planning the development of a model involves an understanding of the software capabilities but also the limitations and the magnitude of the data required to calibrate the model in case of changes in the project.A successful model requires a deep understanding of the circuit to be modeled and thus plant personnel should be considered as members of the team.This paper describes the use of the "state of the art" tools for data analysis, simulation and optimization; and shows three practical examples of the use those tools in the design of mineral processing plants."

Jan 1, 2015

By Lawrence Devon Smith

The selection of the production rate is one of the most crucial decisions to be made in the development of a mineral property. However, it is not uncommon for the production rate to be decided arbitrarily, before any technical evaluations begin, and it is often not reconsidered when better data becomes available. A number of methods are used in the mineral industry to select the production rate for a project. There is general agreement that the size of the ore reserve has a strong influence on this decision, but what other factors are involved? Is there a way to identify an optimum rate? This paper examines the factors that influence the selection of a production rate from the perspective of project economics. The NPV maximum value should be viewed as a “failure” point. The “two times capital” maximum is proposed as a lower limit. A practical check is suggested to confirm that a selected rate is in an optimum range. Production rate assumptions are much more likely to be reviewed for marginal projects, but they should also be reviewed for viable projects.

Jan 1, 1997

By Haruka Takeura, Tomoaki Murata, Kazunari Yoshida, Masato Adachi

"Pure magnesium is a material with high functionality, however, the cold drawing of this material is very difficult, that is why, until this day there are no optimal cold drawing conditions. Furthermore, cold drawing of pure magnesium wire shows a problem with internal defects that occurs under certain conditions. In this research, the aim is the suppression of internal defects, and final target is to create the optimal cold drawing conditions for pure magnesium wires. The first step is the investigation of the drawing limit by using 250°Cannealed wire. As a result, reduction of 10% per pass was chosen for stable wire drawing. However, in this case, it was found that internal defects occurred at total reduction of over 45% during drawing. Investigation of intermediate annealing conditions that can suppress internal defects, and influence on internal defect that the die half angle and reduction per pass. As a result, it was found that the drawing condition capable of suppressing internal defects most efficiently was 13% reduction drawing by using under 6°half angle die. Consequently, it’s possible to manufacture a cold fine drawn pure magnesium wire of 100µm, without defects in the center of the wire and hindering its mechanical properties.INTRODUCTIONMagnesium is a light and high functionality material that has high vibration absorbency, heat dissipation, electromagnetic wave-shielding and recycling efficiency (Conruy, 1989). However, proper cold wire drawing conditions haven’t been established, that is why warm or hot processing is commonly used (Oishi, Mori, &Kawabe, 2005). As a result, strength improvement of the wires is not possible, that is why the production of medical tools is disregarded. If it was possible to cold draw magnesium wires, the applications for material products would expand. Further, in wire drawing such difficult processing material, if appropriate processing conditions are not selected, defects will be generated inside the drawn wire."

Jan 1, 2017

By Frédéric Bélanger, George P. Demopoulos, Pascal Coursol, Thomas Feldmann

"The use of scandium in industrial applications is expected to rise in the coming years, in large part due to the expected adoption of new, clean energy technologies such as solid oxide fuel cells or Sccontaining high strength aluminium alloys. Given that the supply of Sc is currently dominated by only a few countries (Russia and China) other sources for scandium extraction need to be investigated. This paper looks at different options for the recovery of scandium from waste solutions generated during the production of TiO2 pigments via the chloride process route. In particular, a direct solvent extraction (SX) approach and possible options for concentrating scandium before the SX step were investigated. It was found that the presence of Ti during solvent extraction causes severe formation of stable emulsions, which can complicate the successful application. This was particularly a problem after multiple contacts of the organic phase with fresh aqueous phase. On the other hand it was noticed that the presence of certain elements in the solution, e.g., iron, could possibly be utilized to concentrate scandium in a solid precipitate.INTRODUCTIONMany newly developed high-tech products depend on the use of chemical elements that are only produced in very small quantities. This can result in high and fluctuating prices, as can be seen from Figure 1, which may cause substitution with inferior alternatives, if possible at all (Reck & Rotter, 2012; US Dept. of Defense, 2013; Whittaker, 2011). One example is scandium (Sc) a member of the extended rare earth element family. There are only a few scandium ore deposits, but most Sc is produced from the processing of by-products of other metallurgical processes (Melcher & Wilken, 2013). Increasing demand for scandium metal and oxide (Sc2O3, scandia) is coming from its increased use in applications such as ceramic lasers (Li, Ikegami, & Mori, 2005; Rainer et al., 1982), high strength aluminium alloys (Lathabai & Lloyd, 2002) as well as solid oxide fuel cells (SOFC) (Thijssen, 2011). Especially, the spread of climate friendly SOFC’s, which are a commercial product today (Bloom Energy, 2014), is expected to be a main driver for future Sc2O3 demand. However, the rate of market penetration of this green technology depends on the availability of high purity Sc2O3 (>99.999%), since it specifically contributes to longer life-time and better safety of the SOFC’s (Bloom Energy, 2014; Irvine, Politova, & Kruth, 2005)."

Jan 1, 2016

By D. Emadi

The ASTM B108 Mould and a Modified Mould were used to cast test bars under a variety of conditions: mould and pouring temperatures, mould coating and tilt. Mechanical properties were determined in the as-cast and heat-treated conditions. The ASTM Mould is less sensitive to casting variables. Enlarging the gating system and adding additional gates to the ASTM mould can improve properties in the tilt position. The reproducibility of properties in as-cast and T6 heat treated bars was investigated.

Jan 1, 2004

By J. Oré

An alternative method for dewatering slurry (tailings) is the use of geocontainers (MacTubes). The practical application of this work was carried out in the concentrator plant of the Raura Mining Company, located in the occidental mountain between Huánuco and Lima in Peru?s central highland. For the development of the research, the MATLAB R2012a software MGeST (v. 1.0) was used (Slurry Geocontainer Maccaferri Treatment). MGeST is used for sizing MacTubes, which allows determination of the most important design parameters, such as height (H), filling residual pressure (P1O ), strength of geosynthetic (T), and dehydration height. Compared with GeoCoPS v. 3.0, there is a maximum difference of 3% between the results obtained. The tailing to be treated in the MacTube have a specific weight of 11.62 kN/m3. After several tests it was determined that a MacTube of an apparent opening size of 0.22 mm was required for this specific weight.

Aug 1, 2013