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By C. V. Corless

1. Introductory Some members may recall that at the Annual Meeting two years ago I read a paper, 'The Future of the Mining Industry in Canada." Discussing this large subject it was possible only to outline the facts and inferences leading to ?the conclusion that Canada is a country endowed with enormous mineral wealth, of which the fringes are yet scarcely touched. In the present paper, I wish to examine in somewhat fuller detail the evidence, both direct and inferential, concerning the mineral wealth of the greatest physical and geological feature of Canada-the Precambrian Shield. Many, if not most, of these facts are already familiar to you. But, since they will form the basis of the reasoning employed, they will be recalled for explicit reference. First, let us review very briefly the position and extent of the Shield. The area of the entire Shield is given in textbooks as 2,000,000 square miles, of which perhaps 10 or 12 per cent. is exposed in the south-easterly part of Canada's Arctic islands. The remainder occupies roughly two-thirds of the North-west Territory; the north-east corner of Alberta; one-third of Saskatchewan ;two-thirds of Manitoba; three-fourths of Ontario; and nearly ninety-five per cent. of Quebec.

Jan 1, 1924

By M. S. Badollet

INTRODUCTION THE DEMAND for general knowledge on asbestos fibres has increased considerably in recent years. A few publications have printed data showing some of the physical and chemical prupertie3 of asbestos, but in many cases this information is difficult to find and is seldom available when needed. During the past ten years, Johns-Manville have received many inquiries on the physical and chemical properties of asbestos fibres. Fortunately, we had some of the information in our files, and we willingly supplied the data. To help relieve this need, we have tried to present briefly in this paper some of the interesting and out-standing properties of asbestos. This information was obtained over a period of years by search of the literature and by experimental investigations. PROPERTIES OF ASBESTOS FIBRES Table I (1, 2) presents, in convenient form for easy comparison, data on the principal properties of the several varieties of commercial 'asbestos' -actinolite, amosite, anthophyllite, chrysotile, crocidolite, and tremolite. Under each variety of fibre is a brief statement describing the properties in terms of structure, mineral association, origin, etc. Some of the more important data in Table I are expanded and presented in Table II (3). SOLUBILITY OF ASBESTOS A report ( 4, 5) discussing the effects of acids and caustic on asbestos fibres was published in Germany in 1927.

Jan 1, 1951

By O. M. Arafat, J. A. Finch

"The Functional Performance Equation calculated from a plant grinding survey defines two distinct ball mill circuit efficiencies and how they relate to total production rate through the target grind size. The survey data are also used to calculate a complete ball mill size distribution model, represented by the energy specific grinding rates, not just through the target grind size, but through all the size classes. Cyclone separation performance is represented by individual size recoveries to underflow. When these two unit operation performances are entered into the circuit modelling program (Streamline™), along with the circuit feed rate and size distribution, all the circuit survey size distributions and mass flows are perfectly regenerated by the program. The many issues associated with the historical Epstein (breakage-selection) models are eliminated. Once the circuit program is populated, pump and cyclone performance changes can be evaluated using a step-by-step procedure in order to maximize Classification System Efficiency. Mill water use and media sizing opportunities are also diagnosed in order to maximize Mill Grinding Efficiency at the size of interest. An example is provided. This circuit analysis and modelling system, and related training, is provided through a web-based application.IntroductionSince its development (McIvor, 1988), the Functional Performance Equation for ball milling has facilitated new understanding of industrial circuit cause and effect relationships, leading to significant strides in operational performance. Success stories of this refreshing approach to plant circuit performance improvement are now too numerous to list. Finch and McIvor (circa 1986) also discovered that the Functional Performance “Mill Grinding Rate” at the size of interest was the same cumulative grinding rate that is calculated from mill feed and discharge size distributions using a first-order rate equation. By calculating these cumulative grinding rates for all screen sizes, a complete ball mill model is generated (as used by Finch and Ramirez, 1981). Others in industry, Hinde and Kalala (2009), for example, have noted the same. Lacking the complexity needed to maintain their interest, most researchers have ignored this model, broadly opting instead for Epstein’s (1948) characterization of grinding as a chemical reaction, combining “selection rate” and “breakage size distribution” functions. The much simpler ball mill model presented here has previously been incorporated into a proprietary circuit modeling program (McIvor, 2005) and used for plant improvement work (for example, see McIvor and Finch, 2007, and McIvor, 2014). Now, by combining this extremely business-friendly ball mill model with optimization criteria from Functional Performance Analysis, a circuit modeling system (including the needed supplementary steps to assure successful plant implementation of circuit design changes) is at the disposal of every plant metallurgist, grinding equipment/material provider, and circuit designer."

Jan 1, 2017

By James Ransford Dankwah

This work investigates the effect of waste plastics addition on the reduction of iron oxide by sawdust. Composite pellets of iron oxide containing sawdust (SD), high density polyethylene (HDPE) and blends of SD/HDPE were fired under argon in a horizontal tube furnace at temperatures between 1300 and 1500 °C. Reduced samples were weighed after 10 minutes of reduction and the extent of reduction was calculated from the measured oxygen contents of the compact. The results showed improved extent of reduction when SD was blended with HDPE. The highest extent of reduction was achieved at SD:HDPE ratio of 2:3.

Jan 1, 2014

By N. Yamazaki

The supply of clean copper ores, which have high copper concentration and low impurities like arsenic, has declined year by year. Therefore, both mine and smelter sides have to consider how to remove impurities like arsenic. We focus herein on arsenic as an impurity because it is an extremely important issue from the environmental point of view. Approximately 150,000 t of arsenic is input into the copper industry every year. A small part of it is mainly treated in the smelting side. For instance, Ministro Hales Limited, which is a mining corporation in Chile, has performed the calcination process to remove arsenic from ore with high-arsenic content. In the process, flue gas is washed by water, and the final residue is treated by a hydrometallurgical process. Many processes for arsenic removal in various stages have been proposed, and several bottlenecks exist to achieve it. One of the difficulties encountered is getting an assessment of the process, which depends on the countries and/or areas of operation. The standardization of the assessment procedure will be desired in the near future to keep the same environment standards all over the world, and now is the time to start making discussions on this matter. This will be the first step in making an international assessment procedure for arsenic treatment in the copper industry. INTRODUCTION Using the term “sustainable development” without any scientific basis can give people a false sense of security. Engineers and scientists must analyze the total mass flow of energy and materials and estimate local drain on the environment as well as the global impact of a particular industrial activity to ensure sustainability on this planet. The operations of the mining and smelting industries have a strong effect on the environment even if they provide useful materials for human beings. The copper mining and smelting industries have brought about serious environmental problems in the past. For example, the Ashio mine pollution caused big damage to the agricultural sector near the Ashio area in Japan in the late 19th century. One of the most serious problems at that time was SO2 emission because copper ore is sulfide, and the smelting process basically results to sulfur oxidation. The resource balance from a copper smelter in a year, assuming a total production of 16 million tons, can be summarized as follows: discarded minerals, 30 billion tons; sulfur, 16 million tons; iron oxide, 8 million tons; additional smaller amounts of other metals, electricity, and fuel.

Jan 1, 2019

By P. C. Holloway, A. Tshilombo, T. Xue, M. J. Collins, R. Lopetinsky, I. Mihaylov, I. M. Masters

The Voisey’s Bay deposit contains a trace amount of cadmium, which reports to solution during pressure leaching of the nickel concentrate at Vale’s Long Harbour Hydrometallurgy Plant, and must be removed to produce high quality nickel cathode. In 2006, Vale approached Sherritt Technologies to collaborate on the development of a process for removing cadmium to low levels (<1 mg/L) in the nickel raffinate. Following successful bench scale and pilot plant testing at Sherritt’s laboratories, the cadmium removal process was then moved through engineering and construction, culminating in the successful commissioning and startup of a cadmium removal circuit at the Long Harbour Hydrometallurgy Plant in 2017. This paper presents the results of this collaboration and the challenges that were encountered through each stage of development, as well as current results from operation of the commercial cadmium removal circuit. INTRODUCTION Vale’s Long Harbour Processing Plant, with a nameplate capacity of 50,000 t/y nickel, began operation in 2014. In addition to electrolytic nickel rounds, the plant also produces electrolytic cobalt rounds and copper cathode. The Long Harbour Processing Plant uses a unique hydrometallurgical process developed by Vale Base Metals Technology Centre, as shown in Figure 1, to treat a nickel sulphide concentrate produced at the Voisey’s Bay mine and mill located in northern Labrador (VBN concentrate) (Stevens et al., 2009).

Jan 1, 2019

By A. Philipp, A. S. Middleton, G. A. Harron, A. B. Durham

"Basal till sampling techniques were used to search for gold mineralization in the Timmins, Ontario area. During 1978 and 1979, approximately 90 overburden sampling drill holes were completed in Murphy and Hoyle Townships to test specific geophysically defined target areas. A conventional tricone dual tube drill system, and a unique retractable tricone/rock coring system were used to various advantages.First pass till sampling at 800 to 1200 ft intervals perpendicular to ice transport direction yielded anomalous gold values in till and carbonatized quartz pyrite-rich bedrock chips, and lateritic soil. Subsequent induced polarization-resistivity surveys defined the areal extent of a pyritic carbonate alteration zone. A second pass till sampling/limited rock coring program evaluated the gold mineralization potential of the alteration zone. Diamond drilling has substantiated the till and bedrock gold anomalies. Further evaluation of this mineralization is currently in progress. IntroductionThis paper describes an integrated geochemical/geophysical gold mineralization discovery case history in Hoyle Township. This discovery is on a property jointly owned (I983) by Canamax Resources Inc. and Du Pont of Canada Exploration Limited. Exploration of the property began in 1978 by Rosario Resources Canada Ltd. and in 1979 a joint venture agreement was signed with Du Pont of Canada Exploration Limited. Rosario Resources Canada Ltd. was taken over by Amax Minerals Exploration in 1981, which became Canamax Resources Inc. in 1982.The work described in this paper deals with a gold mineralization discovery located three-quarters of a mile northwest of the gold deposit currently being readied for underground exploration and development. Further drilling is required to investigate the economic potential of the gold mineralization herein described."

Jan 1, 1987

By E. S. Moore

"The Centre of the silver-producing section of the Gowganda area lies about 55 miles northwest of Cobalt, and the village of Gowganda is 71 miles by road from New Liskeard. The geological similarities of the Gowganda and Cobalt areas led prospectors westward from the rich Cobalt field, first to Elk Lake and then on to Gowganda, where mineralization was found in 1907. A year later many showings were found, and rich hand-picked ore was shipped. Most of the ore has come, however, from two mines, both of which are still operating; the Miller Lake-O'Brien, which was purchased by Siscoe Metals of Ontario Ltd. in 1945, and the Castle-Trethewey. The annual production of these two mines runs over one and one-half million ounces of silver and considerable cobalt. The total production of the camp has reached about 32,000,000 ounces of silver and a large amount of cobalt, the total not recorded.General GeologyThe general geology of Gowganda is in many respects much like that of Cobalt. There are areas of Keewatin basic and acid Javas mixed with tuffs and basic intrusions. These rocks are deformed and partly altered to schists, and have been intruded by some Haileyburian basic and ultra-basic rocks and by Algoman granite. These were followed by a large number of porphyritic Matachewan quartz diabase dykes. After a period of extensive erosion the Huronian sediments were deposited on a pene-planed surface over all the older rocks; these sediments include large quantities of conglomerate (partly tillite), quartzite, and greywacke. The Keweenawan rocks include the Nipissing quartz diabase sill, later quartz diabase dykes, and one long olivine diabase dyke, the latest Precambrian rock. The area has been extensively glaciated.Structural FeaturesThere has been little folding in the area since the Algoman batholiths were intruded, and the Huronian sediments lie nearly flat, with dips of 10, 15, or rarely 25 degrees. The Matachewan dykes show a remarkably uniform, nearly north strike, indicative of east-west tension when they were intruded. On the other hand, the dykes later than the sill strike nearly east, tangentially to the northeasterly and northwesterly strikes of the Miller Lake basin."

Jan 1, 1949

By William Shaw

Conditional simulation is now an accepted tool for managing ore block design at a number of operating mines. It provides a way to consider the quality of data, local continuity and economic risk in defining ore and waste across the cut-off boundary. In addition a computer based system can ensure consistency in making decisions to meet multiple criteria such as cut-off grades, minimum ore-block size and contaminant grade limits. The development of a procedure for using multiple criteria allows ore blocks to be defined using alternative strategies depending on the specific production requirements. This has introduced the opportunity to define ore blocks for different destinations based on their material types and opens the way for geometallurgical modelling to be incorporated into grade control.

Oct 1, 2009

By I. L. Sills

Introduction So many minerals and mineral products are used in the glass industry that it would require an unduly long paper to deal adequately with all of them. Only those that go to make up the batch for the more common types of glass will be discussed here, and even with these only, the list is a lengthy one. It is true that for the body of the glass comparatively few materials are required-as silica sand, soda-ash, lime, and feldspar. The others are used mainly to colour or decolorize the glass, or to give it some other desired characteristic, such as high lustre, greater physical strength, or opalescence; but, although they may be present in very small quantities, they are just as in-dispensable to the glass industry as are the main constituents of the batch. Sand Sand is essentially quartz, the dioxide of silicon, Si02. Most glass contains from 71J to 75 per cent silica. Sand for use in the glass industry, or &apos;glass sand&apos;, is obtained both from deposits of unconsolidated material, commonly referred to as &apos;sand&apos;, and from solid rock-sandstone, quartz, or quartzite. For the manufacture of glass, the material must possess a high degree of purity, as noted below, so that, although sand is widespread in most parts of the world, and sandstone, quartz, and quartzite are not at all uncommon, it is only in certain places that suitable deposits are found. At the present time, most of the glass sand used in Canada is imported from France, Belgium, and the United States. The French material, from Fontainebleau, near Paris, is known the world over as a very high quality glass sand. That from Belgium is nearly as good and is lower is price.

Jan 1, 1934

By R. H. Colquhoun

"INTRODUCTION The Holt-McDermott Mine is wholly-owned gold mining operation of American Barrick Resources Corp. that begun operations in June 1988.The property is located 0.5 km. south of Highway 101 East in the Harker-Holloway Townships of Northeastern Ontario, 7 miles south of Lake Abitibi and 15 miles west of the Quebec-Ontario border.Employees of the operation travel daily from various communities in the area, predominantly from Kirkland Lake, Ont., which is located 65 km. to the southwest.The significance of the operation is that it is the first full scale operation associated to the Oestor-Porcupine Fault to go into full production in recent history as well as the first Carbon-in-Leach (CIL) operation in the province owing to the natural occurring carbonaceous ores that are associated to the ore body and the geological fault systems.GEOLOGYThe Holt-McDermott deposit is located in the Abitibi Greenstone Belt, a short distance west of the Ontario-Quebec border. Ore grade material follows the footwall contact of a fault zone known locally as the McKenna Fault, which is thought to be a splay off of the Oestor-Porcupine Fault, itself a major feature in the Abitibi belt.The McKenna Fault strikes approximately east-west (as does the Oestor-Porcupine) and dips to the south at sixty-five to seventy degrees. The fault lies within a package of mafic volcanic rocks (basalts). These rocks have been strongly altered and mineralized adjacent to the McKenna Fault, and the resulting lens-like ore bodies constitute the mining targets."

Jan 1, 1989

About MAC ? The national organization of the Canadian mining industry ? Mining, smelting and refining of base and precious metals ? Mining of iron ore, diamonds, uranium, oil sands, coal and industrial minerals ? Many associate members ? www.mining.ca

Aug 1, 2013

By H. McLeod

Introduction In the period from 1939 to the present, Canada has experienced a remarkable industrial expansion, rising to probably seventh in rank amongst world countries. In the early part of this period, the desperate need for military supplies unloosed tremendous amounts of capital for building new factories and for expanding and converting existing facilities. Mines, factories, and other divisions of the industrial economy bent every energy toward greater and greater output. The result was an 80 per cent increase in the volume of the nation&apos;s production within a period of four years, a truly remarkable accomplishment and one in which the mining industry had a very vital part. After the critical year, 1944, the tempo of industry eased off a bit, dropping approximately 20 per cent by 1946. At this time the prospects or post-war industry were clouded by monetary and political chaos in overseas countries, by trade restrictions, and by market uncertainties. There was, of course, a pent-up demand, both at home and abroad, for civilian goods that had been curtailed during the war and for capital equipment that had been destroyed. In the midst of this world-wide uncertainty, if anyone had ventured to predict that by the end of 1950 Canada&apos;s industrial output would be back to the 1944 level and humming along at nearly twice the best pre-war pace, he would have been considered rash indeed. Yet this has been the case.

Jan 1, 1951

By R. D. Parker

Location The Frood ore-body is expressed on surface as a prominent gossan ridge, with a total length of approximately two miles. The original Frood (the old No. 3 mine of the Canadian Copper Company) is at the southwest end of this gossan; adjoining it on the northeast is the Frood Extension (until 1929 the property of i:he Mond Nickel Company), while at the extreme northeast end is the Stobie mine. The first two of these divisions of the ridge form the Frood mine as it is known today.? This lies in lots 6 and 7 of the sixth concession, township of McKim, and is two and a half miles north of the city of Sudbury. The general elevation is 1,000 feet above sea level. The Ore-Body The Frood-Stobie parallel offset(l), as its name implies, has no connection in the field with the main mass of the Sudbury nickel eruptive-a norite. It lies one mile to the southeast of that body, and, in general, parallels it in strike. The ore occurs as a more or less tabular structure in what is known locally as the Sudbury series. They are the oldest rocks of the district, and have been placed by Collins(2) as earlier than the lower Huronian, of pre-Cambrian time. The series is comprised of sediments, volcanics (both acid and basic flows), tuffs, agglomerates, breccias, and basic intrusives, all highly metamorphosed, yet all forming a more or less regular picture. The controlling feature of the area has been the attitude of the sedimentary strata, from which has arisen the present sill-like character of the flow rocks, the basic intrusives, and the ore-body itself.

Jan 1, 1932

By Anil K. Beersing

Effective drainage systems are required for reclamation of mine-disturbed areas to control surface water runoff and avoid excessive erosion. For the conventional structural design approach, armouring material necessary to satisfy the design criteria should not move during the design flood event since displacement would uncover the erodible underlying materials. This paper discusses an alternative geomorphic approach for designing drainage channels and watershed landscape. The approach is based on quantitative studies of geomorphic processes operating in a watershed. A design based on the geomorphic approach replicates the configuration, channel regime, sediment volume and hydrology of natural and mature drainage systems. Movement of some armouring material is acceptable in such an approach because the channels are allowed to mature by natural degradation and aggradation, with erosion rates comparable to the natural environment. The key advantages of a geomorphic approach over a purely structural approach include reduced sizes of armouring material, geomorphologically sustainable landscapes, ?walk-away? or maintenance-free design and reduced liability in the future. The geomorphic approach is illustrated using the example of a coal mining operation in northwest U.S.A. The paper discusses field data collection, design criteria, typical design details, and construction methods.

Apr 1, 2005

By Theo. A. Link

ACCORDING to our office dictionary, geology is "the science that investigates the structure of the earth and its successive physical changes", and a geologist is "one who knows the science of the structure of the earth". No doubt this definition does not suit all of us. Another dictionary would have the definition slightly different. As an example, one dictionary stated that "a geologist is one who practices geology". (Some of our clients told us to quit practising and get to work). There are many different types of geologists engaged in various branches of the profession and some of these are further broken down into subdivisions so that specialization is becoming more and more prevalent. As a result it is, in some cases, doubtful whether or not we are actually dealing with a geologist in the generally accepted sense of the term.

Jan 1, 1956

By Michel Robert

"In 1974, Copperfields Mining Corporation and Soquem formed a new company, Niobec Inc, to bring the niobium deposit of the St-Honore carbonatite into production.St-Honore is located in the Saguenay area, near the cities of Chicoutimi and Arvida, and about one hundred and forty (140) miles north of Quebec. The discovery of the carbonatite complex was made in the fall of 1967 as a result of an airborne radiometric survey in search of uranium. The detailed exploration of the carbonatite indicated two niobium-bearing formations besides the original discovery of a rare earths zone. During the following years, the niobium formations were defined by diamond drilling and a decline was driven down to obtain adequate samples for metallurgical evaluation. In 1974, after seven hundred (700) bench scale tests, eleven (11) months of pilot plant 2nd a worldwide market research, a joint decision was made to initiate the development of a fifteen hundred (1500) T.P.D. mine and mill, under the management of Teck Corporation. The construction of the facilities were completed in early 1976 both on time and within budget. Niobec is now the only north american and the world second largest producer of Niobium concentrate.The process used at Niobec was developed from the pilot plant programs and later modified by the mill personnel. A simplified flowsheet for this process is shown on the slide. Briefly, run of mine ore is crushed to minus 5/8"" and fed to a rod mill, ball mill, and screens circuit where the ore is ground to 92% passing 65 mesh. The ore is deslimed in two stages of cycloning, and the final cyclone overflow at 85% minus 11 microns goes to waste. The cyclone underflow is conditioned prior to flotation of a carbonate-apatite concentrate. This concentrate is cleaned twice and then pumped to tails. The carbonate rougher and cleaner tails are cycloned in two stages to change the process; water and then sent to the pyrochlore rougher flotation. The rougher concentrate is cleaned five times. This is followed by pyrite flotation to remove sulfur, leaching with hydrochloric acid to remove phosphorus and dyed to less than 0.1% moisture before being sent to packaging."

Jan 1, 1978

By Mohsen Mohammadi, Edward Cyr

"To date, several studies have been performed on the static mechanical properties of SLM-AlSi10Mg alloy. There have also been more recent studies on the relation between scan strategy, texture, and mechanical properties of SLM metals and composites. However, there is a huge knowledge gap in the available literature regarding texture and mechanical behavior of SLM-AlSi10Mg alloy under high strain rates. Therefore, in this study, dynamic mechanical behavior of AlSi10Mg_200C alloy manufactured by DMLS technique was investigated at high strain rates ranging from 900/s to 1700/s using Split Hopkinson Pressure Bar. Texture using X-ray diffraction technique of the initial samples were measured. The yield strength, peak flow stress, and ductility increased in all samples with increase of strain rate. TEM studies have also revealed evidence of continuous dynamic recrystallization in grains after 900/s–1700/s strain-rate tests. A Taylor polycrystal crystal plasticity constitutive model was then developed to capture and predict the texture evolution and mechanical response under dynamic loading, using plastic work as a critical parameter for the onset of recrystallization.INTRODUCTION Additive manufacturing (AM) powder techniques are among the fastest advancing breakthroughs in manufacturing in recent years, defined by a bottom-up layer by layer process of joining with energy input from lasers or electron beam (Herzog et al., 2016; Gibson et al., 2015). Among alloys fabricated by SLM, AlSi10Mg is of high interest to industry and academia due to its low density, high specific strength and excellent corrosion resistance, making this alloy a viable contender for aerospace, automotive, and marine applications. Circumstances such as car crash or bird aircraft strike hazards subject potential additively manufactured AlSi10Mg parts to impact loadings. This drives an interest in understanding and predicting dynamic behaviour of these alloys. AlSi10Mg is the AM counterpart of A360 die-cast aluminum, which possess hypoeutectic microstructure (Li et al., 2015). Up to the present time, many studies have presented the mechanical properties of SLM-AlSi10Mg alloy. The mechanical properties and microstructure of AlSi10Mg produced by selective laser melting (SLM) or DMLS techniques can be controlled using different parameters, such as feedstock powder (Asgari et al., 2017), and process parameters (Olakanmi et al., 2015). The microstructure and mechanical properties of AlSi10Mg can also be controlled using post heat treatment after SLM process Li et al., 2016). The mechanical properties of SLM-AlSi10Mg are sensitive to strain rate and can both change under quasi-static (Rosenthal et al., 2017) and high strain rates (Asgari et al., 2018). However, a significant knowledge gap in available literature regarding modeling these behaviours, and especially micromechanical modeling of dynamic behaviour."

Jan 1, 2018

By Virginia T. McLemore

The Gallinas Mountains are in northern Lincoln County and southern Torrance County, New Mexico, USA where a series of alkaline igneous bodies, including porphyritic latite, trachyte/syenite, andesite, and rhyolite laccoliths, flows, dikes, and plugs, have intruded Permian sedimentary rocks belonging to the Permian Abo, Yeso, and Glorieta Formations. A small amount of bastnaesite, a REE mineral, was recovered during processing for fluorite from the Gallinas Mountains. Four types of deposits are found in the Gallinas Mountains: epithermal REE-F veins, Cu-REE-F veins, REE-F breccia pipes and iron skarn deposits; all are associated with Tertiary alkaline to alkalic-calcic igneous rocks. Alteration includes brecciation, silicification, chloritization, and fenitization. District zonation is defined by Cu-REE-F (±Pb, Zn, Ag) veins that form center of the district, surrounded by REE-F veins. Carbonatites are inferred at depth by the presence of fenitization, carbonatization of the breccias, presence of REE and similarity of the intrusive rocks and mineralization to areas with known carbonatites.

May 1, 2011

By J. Abrahams, A. Nesbitt

Over the past half-century, researchers have commented on the complexities of ion-exchange processes, but have been forced to use gross assumptions to simplify the associated mathematics sufficiently for mathematical models to be of practical use, given the available computational power. This paper reviews the development of increasingly complex models as computational power has increased over the past half-century, from the direct application of Fick&apos;s Law in 1947, through to today&apos;s models requiring finiteelement methods. The assumptions required for and the associated limitations of the various models are presented and the associated computational complexities are discussed. A case study is presented in which a continuous loss of capacity in an acid resin was observed over about sixty cycles of loading and elution. Resin poisoning does not explain this observation. This paper presents the capacity loss data, speculates on possible causes of the phenomenon, discusses why conventional kinetic and equilibrium mechanisms cannot explain it and concludes that the need to develop a more rigorous model is apparent. The significance of this observation is that standard tests done for a new resin application could significantly overestimate the commercial performance of the resin concerned, highlighting the importance of computer simulation in this field of process engineering.

Jan 1, 2005