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Modelling of Synergistic Effect of Cyanex 302 and D2EHPA in Zinc Solvent Extraction A comprehensive model is presented to predict the synergistic effect of D2EHPA and Cyanex 302 on co-extraction of zinc and manganese. The experimental results indicated that pH, temperature and the extractants ratio have strong effects on the extraction process. Correlations were proposed to predict the distribution coefficient of zinc and manganese between two phases at different conditions by multiple linear regression. The correlations were simplified by eliminating less important terms by analysis of variance. Optimum conditions (ie pH, temperature, extractants ratio and aqueous to oil phase volumetric ratio) for obtaining maximum separation of zinc from manganese at different zinc concentrations and number of extraction stages were determined. For finding the optimum condition genetic algorithm was used. Comparison the model estimations and the experimental data show that the presented model has good ability to predict the behaviours of zinc extraction system over Cyanex 302 and D2EHPA.

Sep 13, 2010

By A R. Butcher

Gold deportment and ore characterisation studies are key tools in gaining an appropriate understanding of complex gold ores for process development and optimisation. These studies have historically involved imprecise chemical methods with slow and costly optical microscopy for gold identification. The traditional approach requires highly skilled petrographers, is prone to human error, and is not scalable, reducing the usefulness in practical analysis. The proposed methodology utilises a decision tree and knowledge base in a staged approach to gold ore characterisation, building up progressively more detailed information about the sample mineralogy, gold deportment and key mineral properties, as the process is followed. Whilst the automated QEMSCAN« system is used for mineral and gold identification, interactive and focused data analyses are used to give more efficient and accurate results. This is complemented by smart sample preparation and chemical methods to enhance and validate the data, making the staged approach methodology reliable, scalable and therefore practical and economical.

Jan 1, 2007

By Van Nostrand J

The resettlement and relocation program that is being carried out at Gold Fields Ghana's (GFG's) Tarkwa Mine is currently the largest of its kind in Ghana, and West Africa as a whole. While such projects have been initiated previously in Ghana, in connection with the development of the Volta River Dam, Tema, and a number of other smaller resource development projects, they were not subject to the statutory requirements of Ghana's relatively new Environmental Protection Agency (EPA). Nor were they subjected to the kind of global scrutiny that is now being applied to such projects by international agencies like the World Bank. This is a result of the international community's criticism of major energy projects like the Three Gonges Dam in China and a number of similar hydro-electric projects in Southern Asia. It has meant that for this project the expectations are considerably more challenging then they have been in the past.

Jan 1, 1997

The energy crisis and the general increase in fuel prices have changed the position of coal in the world. Countries need to review their policies on coal, depending on available reserves and their accessibility. On the demand side, a distinction should be made between the steel industry's specific demand for coking coal and the needs of power stations where coal is used in competition with other sources of energy. Coal consumption in these two sectors is expected to increase considerably over the foreseable future. Some countries have sufficient coal of their own to meet this increased demand but others will have to rely on imports. As a result, the tonnage of coal transported by sea may double by 1985. The coal industry lacks flexibility. The opening of new mines and the construction of a transport system to ship the coal takes time. This time-lag, coupled with the enormous expenditure involved, makes long-term contracts between producers and consumers essential.

Jan 1, 1975

In presenting the paper, Mr. Davey quoted subsequent work which yielded k, at miscibility gap composition, of about 50.We can confirm the authors' findings for k j 300 for nearly pure tin to k 2 about 50 (average 47) from our own experience and from repeat experiments on materials described by the authors, at 1150°C.During laboratory-scale trials we also found confirmation of the authors' view that it is more difficult to reach equilibrium from the high-iron (in slag) side than from the low-iron (high-tin) side. Working from the high-iron side tends to yield results that point to a high k, leading to optimistic values of iron/tin ratio in final slags. In practice the smelting of a tin concentrate, unless it is exceptionally low in tin and high in iron, must yield initially a tin-rich slag and therefore equilibrium can only be reached from the "tinny" side.

Jan 1, 1967

In 1975, following a programme of solution characterization and small scale laboratory test work, a pilot plant was constructed to treat waste liquors from the Risdon works. The plant was designed basically to neutralize liquor to a desired pH, and to flocculate, thicken and then filter the resultant pulps. The primary objective was to purify waste liquors to stand- ards set by Tasmanian environmental regulations and at the same time to provide design data for construction of a full scale treatment facility. Waste liquors were divided into two groups, those from the Zinc Plant, and those from the Acid and Superphosphate Plants, and were treated independently. To satisfactorily purify Zinc Plant waste liquors the following reaction sequence was required: 1. Neutralization to pH 10.5 (with aeration for Mn removal). 2. Further reaction of neutralized pulp with Na2S at an addition rate of typically 5 mg of S2-/litre of liquor treated to remove Cd.

Jan 1, 1977

All sections of our community are becoming increasingly aware of the dangers of uncontroll- ed erosion associated with modern earthworksy whether they be concerned with the protection of capital structures, reforestation of mine tailings or generally the aesthetic and ecol- ogical impact. Because of the many ecological variances and climatic conditions no single technique may be offered as the complete answer. Rather that a combination of a series of techniques is nec- essary to achieve an individual end result. These techniques may appear to be expensive initially, but when considered in relation to the overall cost, and we realise that this work represents our only insurance of the stability of our project, the cost of stabilisation is insignificant. Once erosion has commenced the cost of stabilisation escalates dramatically which highlights the definite need to include the requirement of stabilisation in early design of your projects. Stabilisation should commence during construction to ensure that control of mobile soils is gained at the earliest possible time.

Jan 1, 1976

The Mining Act (1992) and the Petroleum Act (1980) provide for the Government of Papua New Guinea (PNG) to take up equity holdings in mining and petroleum projects. The price the Government pays for its share is based on the historical cost of exploration and development on the project to the date of government equity acquisition. The equity level to be acquired is not fixed and ranges up to 30o for mining and up to 22.5s for petroleum at the discretion of the Government of the time.The objective of this paper is to examine the pros and cons of State equity holdings in PNG from the point of view of both the State and the developer. Using an economic model of the PNG mining taxation system an assessment is made of the effective return on investment received by the State from such equity holdings. The results are compared with government revenues from other taxation measures.

Jan 1, 1994

By S Furman, M Caccetta, A Hacket, B McDonald, M A. Wells, D Lau

In 2004, the Western Australian Department of Industry and ResourcesÆ Burrup Rock Art Management Committee commissioned a number of independent scientific studies to evaluate the condition of rock art in the Burrup Peninsula near Karratha (Western Australia). These studies are evaluating the physico-chemical aspects of the effect of environmental modification on the visible appearance of the rock art. Because of the cultural significance of the sites, the research approach has been to employ non-destructive testing strategies and work in the field has progressed with respect for the importance of the area. This paper only reports the spectral mineralogy monitoring at each of the sites to evaluate whether changes in mineralogy are observed on rock surfaces. Reflectance spectroscopy is a non-destructive, in situ materials characterisation technique that provides information about the mineralogy. The minerals detected include haematite, kaolinite, chlorite, goethite, gibbsite and manganese oxides. Current results indicate that the surface mineralogy of the rock art has not changed in the last four years.

Jan 1, 2008

Australian mining practice operates at the forefront of technology. In recent times Australian designers, contractors and operators have shown many examples of technical "entrepreneurship" in solving geological mining and metallurgical problems. Developments have occurred in the fields of equipment, processing, operating techniques and training which have relevance to the mining industry in other countries. Our mineral exports play a key role in main- taining the viability of the Australian economy. Although the export potential of our specialised equipment and technology is at a much lower level it is a growth area. The export of our mining technology can continue to be basically the result of individual efforts but the question of whether it would be war- ranted and desirable, to establish a coordinating structure should be examined. Existing and new initiatives by the Federal Government indi- cate the Government's interest in the export of technology. The mining industry should take a proactive role formulating policy and programs within its technical jurisdiction.

Jan 1, 1988

By P Wollants, B Blanpain, R Ding

Vacuum oxygen decarburisation (VOD) is the refining process used by ALZ (Genk, Belgium) for their production of stainless steels. The process consists of three stages: oxygen blowing at a pressure of 100 mbar, degassing, and reduction of the slag with ferrosilicon at 5 mbar. The magnesia-chromite bricks used in the slag zone of the ladles suffer from acute wear. In this paper results obtained from a program to improve the refractory life span are presented. The dominant wear phenomena were identified with an electron microscopy study of bricks taken from different locations in the ladle. Concurrently a dynamic model for the vacuum oxygen decarburisation (VOD) refining process was developed. The model calculates the elementsÆ oxidation rate during the blowing oxygen stage and allows the continuous calculation of the change of the metal, slag and gas composition throughout the VOD process. From these activities a general scheme of the refractory wear was worked out and measures to improve the refractory life were proposed and implemented.

Jan 1, 2000

The metallurgical testwork program is generally the most important critical path item for the completion of a bankable feasibility study and hence can become the critical parameter for financing of potential mining projects. This paper presents generic detailed testwork programs suitable for bankable feasibility studies for a gold leaching and polymetallic flotation study. The design of the metallurgical testwork program for each of the two differing processes is discussed and the critical factors that effect the selection of the testwork programs are highlighted. The importance of the metallurgical testwork results in predicting the metal recoveries and cash flow prediction for the project is presented. The detail of the testwork programs costing is broken into activity based methods based on the laboratory and management hours/costs, such that generic rule of thumb costing guidelines can be generated. The scheduling, costing and importance of the metallurgical testwork program to process feasibility studies are discussed in this paper.

Jan 1, 2000

By E S. Bernard

Steel fibre reinforced shotcrete (SFRS) is increasingly being used as ground support in both civil and mining applications. In recent years, methods of assessing the performance of SFRS have been developed. These include the beam test such as that prescribed by ASTM C-1018 and the panel test prescribed in the EFNARC European Shotcreting Standard. The panel test has gained popularity in recent times due to the two-way action modelled in the test. However, some difficulties have been noticed. Shear failures sometimes occur and there appears to be a rather high degree of variability in the panel test results. A new method of testing panels has been proposed. A circular panel supported on three symmetrically arranged points has been assessed at the University of Western Sydney. This paper describes the new test which may be the basis of a new specification for the testing of toughness of SFRS and summarises research work which has been carried out to-date.

Jan 1, 1999

Disastrous earthquakes are a reality on the Australiancontinent. Unfortunately it has taken the fatal 1989 New-castle earthquake to demonstrate to all Australians that we do not reside on a "stable continent". While the world accepts the potential of plate tectonics and its associated plate margin earthquakes, particularly around the active Pacific Rim, the realisation of devastating intra-plate, or continental, earthquakes is only now beginning to take effect. The 1989 Newcastle earthquake provides many lessons on which to further fundamental earthquake research and the applications to the future welfare of human civilisation. To mitigate the earthquake hazard in relation to the devastation to life, property and industry, research must be undertaken with the resulting informa-tion to be included in the nation's disaster management programs. The earthquake hazard is everpresent in east-ern Australia and the major step in its quantification is a more realistic determination of earthquake risk estimates through an integrated study of seismology, engineering, insurance and sociology.

Jan 1, 1990

By W J. Rankin

A study of refined metallic copper and nickel production was carried out using Life Cycle Assessment methodology to estimate the life cycle emissions of greenhouse and acid rain gases for these metals using data derived from the literature. Various processing routes were investigated which included a pyrometallurgical and a hydrometallurgical route for each metal. The effect of a number of process variables, namely ore grade, fuel type for electricity generation and efficiency of generation were also examined in the study. The results of the study, expressed in terms of total (or full cycle) energy consumption, Global Warming Potential (GWP) and Acidification Potential (AP), showed that the hydrometallurgical processes involving solvent extraction and electrowinning had higher energy consumptions and GWPs than the pyrometallurgical processes for both metals. Nickel metal production was shown to be several-fold more energy intensive than copper metal production. The significant effect that falling ore grades have on attempts to meet greenhouse emission targets was also highlighted in the study.

Jan 1, 2000

Financial theory often takes some time to penetrate industry and when it does it can result in a paradigm shift in valuations and mental models. The Black Scholes option valuation was first published in 1973, although the authors were only awarded a Nobel Prize in 1997. The valuation of real options has been applied to the oil and gas industry for some time, however it has only recently been more widely applied to the non-oil, mineral resource sector. The use of real option valuation (ROV) for the valuation of marginal and short mine life resource projects is a more useful valuation tool than the conventional DCF, NPV valuation tool. The application of ROV has major implications for corporate strategy. It generally favours equity over debt funding and non-hedging over hedging. A retrospective assessment of the successful development of the Lennard Shelf Operations demonstrates the concepts of implementing real options and the value destruction of limiting operational flexibility through debt and hedging activities.

Jan 1, 2003

This paper will present a series of examples drawn for a number of Australian and international mining companies showing their recent attempts at optimisation of capital. The results will be compared, contrasted and discussed in the light of six factors that are considered crucial to any analysis of this subject. The factors are: ò the market availability of capital ò the corporate strategy and performance ò the capital structure appropriate to the corporate positioning within the industry ò the parties to the optimisation equation ò the measurement of success of optimisation The factors above are not mutually exclusive and are generally interdependent so their order above is of little consequence. Other papers presented at this conference will dwell in more depth on all these factors, therefore this paper shall focus only on the key elements of each factor. By way of summary this paper will also address the issue of the longevity of optimisation - is it temporary or long term.

Jan 1, 1991

By J F. Penrose

To obtain cost-efficient financing by way of securing an optimal credit rating, the operating and market risks of a single-asset mining project should be accommodated in the financial structure. Weak financing structures can cause projects to fail, as evidenced by the Murrin Murrin and Bulong examples; these can be compared to the investment-grade structure of Straits (Nifty), which managed operational, market, and financing risks well. Most mining projects are capital-intensive, and have heavy dependency on debt financing. A weak financial structure may result in the early failure of an otherwise sound and economically viable project. Appropriate management of technology, construction, and management risks generally will get a project built; of the project failures that occur, most are caused by a liquidity crisis as the project goes through ramp-up (the transition period between completion of construction and full operation). A projectÆs viability can be enhanced through sound hedging practices, while poor hedging can increase the likelihood of financial default.

Jan 1, 2003

By Trevits MA

The United States Steel Corp. in cooperation with the United States Government is conducting a large-scale methane drainage field demonstration using stimulated vertical boreholes drilled in advance of mining. A grid pattern of 23 boreholes, isolating approximately 1.5 km2 of coalbed area, has been drilled to the lower bench of the Mary Lee coalbed, Jefferson County, Alabama. Upon completion of drilling operations, various hydraulic stimulation treatments utilizing nitrogen-generated foam, water, and gelled fluid were performed to enhance the rate of methane gas removal. Production from the grid pattern began in September 1977 and continued as the last borehole was placed on production during October 1980. To date, in excess of 33,800,000 m3 of methane gas has been drained as a result of this effort. Underground mining operations were approximately 3.2 km from the grid pattern when production began and have currently progressed to within 1.6 km. Underground interception of the grid is expected in 1986.

Jan 1, 1982

By S Vianna

Mineralogical information obtained from plant surveys is subject to errors, both due to sampling and experiment. To reduce these errors, and to ensure that information is consistent, a data reconciliation model has been developed for mineralogical data. Its capability includes mass balancing size data, total assays, assays within size-classes and liberation data. Unlike any other mass balance package, this package also allows reconciliation of the complex mineralogical information. For example, particles cannot simply be treated as binary, but consist of combinations of many minerals. Hence the distribution of mineralogical information is multidimensional and the mineralogical distributions are referred to as multiphase. In this paper, the different levels of mass balancing are explained, including how to mass balance liberation data. Furthermore a new technique based on probability theory can be used to infer distributions even when there is insufficient information to perform a mass balance, and this technique is also explained. Results for various stages are given.

Jan 1, 2002