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By G. R. Corbett

The introduction of roof bolts to Phalen Colliery in the Sydney Coalfield, Nova Scotia (annual output of 2Mt) has been successfully implemented in maingate and tailgate entries over the last four years. Monitoring of the roof bolted areas continues to be an integral part of the quality control program as the results are utilized to maintain safety and to aid in long-term design strategies. Although all gateroads in the Phalen Colliery have converted to roof bolts as their primary means of support, the majority of intersections which intersect the main slopes remain supported by large steel structures. Several intersections within the Phalen Colliery were monitored as they were created by the mining process. A comparison is made between intersections supported with only traditional 6.4 to 6.7 m steel structure and intersections supported by 2.44 m fully resin encapsulated roof bolts in conjunction with 7.6 m fully cement grouted cable bolts. Detailed monitoring was conducted using CA NM ET's intrinsically safe sonic probe extensometer datalogger which has the ability to read up to sixteen probes simultaneously at programmed intervals. The density of the data from the datalogger has allowed a better understanding of the deformation of cable bolted intersections than was possible with manual monitoring. Test results have helped mine operators to design safer cable bolted intersections.

Jan 1, 1995

By B. Tiryaki

Longwall shearers usually suffer from excessive pick and pickholder consumptions and severe wear of the back plate of the clearance ring section of shearer drums. In practice, most of the drums were seen to be withdrawn from the face due to the abovementioned problems, while vane picks and their holders were intact due to the improper lacing design of the clearance ring picks. However, few underground investigations and their results on the effect of lacing arrangement of clearance picks on the service life of shearer drums have been published. Nevertheless, the pick consumption characteristics of shearer drums were not investigated in detail, since these are fewer pick consumptions with shearers when compared to roadheaders. This paper is concerned with the comprehensive in situ trials on the effect of lacing of clearance ring picks on the lifespan of shearer drums, and the pick consumption characteristics of longwall shearers at Cayirhan Coal Mine in Turkey. The lifespan of shearer drums employed with shearers in this mine increased 70 per cent, while the consumption rate of clearance ring picks decreased threefold through using an alternative lacing for clearance picks, indicating the significance of utilizing proper design techniques for clearance ring picks for the service life of shearer drums. Statistical analyses carried out, using the raw pick consumption data, implied that the clearance ring picks experienced much higher loads than vane picks, revealing that special attention must be paid to designing clearance ring picks. An average maximum consumption value of 41 was determined for clearance ring picks, with corner-cutting picks having the most replacements, while it was 35 for vane picks, on three-day based pick replacements.

Jan 1, 2004

By A. K. Singh, R. Singh, P. K. Mandal

On the basis of in situ study of pillar loading at different sites, an attempt is made in this paper to visualize the development of mining induced stress under varying geo-mining conditions. Field study demonstrated interesting interaction between size of pillar and nature of roof rock mass under the influence of increasing dimension of the excavation. Stiffness of pillars/overburden, extraction ratio and depth cover are observed to be the important parameters for the estimation of mining induced stress over the pillar. These parameters influence, both, the value of ultimate induced stress (vertical) and its range of influence ahead of the face line. Further, it is observed that the change in width/height (w/h) ratio of a pillar has got considerable influence over the nature of mining induced stress over it. Impact of highly dynamic nature of mining induced stress over the natural supports is observed to be the most serious factor for the safety of working under a hard and massive roof rock mass. On the basis of these observations, a conceptual model of interaction between the natural support and overlying strata is discussed in the paper. ZUSAMMENFASSUNG: Aufgrund ist in situ Studium von Säule Beladung an verschiedenen Stellen, ein Versuch in diesem Papier gemacht, die Entwicklung des Bergbaus vostellen sich, Spannung unter Änderung von Geo Bergbau von Bedingungen hat veranlaßt. Feld Studium hat interessante Wechselwirkung zwischen Größe von Säule und Natur von Dach Felsen Masse unter dem Einfluß von Vermehrung Dimension des excavation vorgeführt. Steifheit des Säulen Overburden, Herausziehung Verhältnisses und Tiefe sind beobachtet bedeckt, die wichtigen Parameter für die Schätzung des Bergbaus zu sein, Spannung über der Säule hat veranlaßt. Diese Parameter beeinflussen, beide, der Wert allerletzter veranlaßter Spannung (senkrecht) und sein Bereich des Einflusses voraus von der Gesicht Linie. Weiter ist, es beobachtet, daß die Änderung in Breite Höhe (W H) Verhältnis einer Säule beträchtlichen Einfluß über der Natur des Bergbaus erhalten hat, Spannung hat darüber veranlaßt. Schlag sehr dynamischer Natur des Bergbaus ist Spannung über den natürlichen Stützen beobachtet hat veranlaßt, der ernsteste Faktor für die Sicherheit des Arbeitens unter einer harten und massiven Dach Felsen Masse zu sein. Aufgrund dieser Beobachtungen, ein begriffliches Modell der Wechselwirkung zwischen der natürlichen Stütze und der überlagernde strata ist im Papier diskutiert. RESUME: En se basant sur dans l'étude de situ de chargement de pilier aux sites différents, une tentative est faite dans ce papier pour envisager le développement de creuse la tension persuadée sous varier de conditions de geo creuse. L'étude de champs a démontré l'interaction intéressante entre la taille de pilier et la nature de masse de rocher de toit sous l'influence d'augmenter de dimension de l'excavation. La raideur de piliers overburden, la proportion d'extraction et la couverture de profondeur est observée pour être les paramètres importants pour le jugement de creuse la tension persuadée par-dessus le pilier. Ces paramètres influencent, les deux, la valeur de tension persuadée ultime (vertical) et sa gamme d'influence en avant de la ligne de face. Plus, il est observé que le changement dans la largeur hauteur (le w h) la proportion d'un pilier a reçu l'influence considérable par-dessus la nature de creuse la tension persuadée par-dessus il. L'impact de nature extrêmement dynamique de creuse la tension persuadée par-dessus les soutiens naturels est observé pour être le facteur le plus sérieux pour la sûreté de fonctionnement sous une masse de rocher de toit dure et massive. En se basant sur ces observations, un modèle conceptuel d'interaction entre le soutien naturel et les couches recouvrant est discuté dans le papier.

Jan 1, 2003

By G. S. Scott

Mine fires have occurred since the mining of coal was begun, and they are still occurring. The resulting economic waste may become considerable (219),3 especially if a fire is allowed to assume major proportions or to get beyond control temporarily. It is important, therefore, to act promptly whenever a fire is suspected and to have every action count. To do this effectively, it is necessary to know at the earliest possible moment and thereafter what is happening in a remote or inaccessible area. It is equally important to know before¬hand what may be expected as a result of any proposed combative measure. The logical method of combatting a fire demands the cooperation of both mining engineer and chemist. They should decide the course of action to be taken, drawing upon the mining engineer's intimate knowledge of the physical structure of the fire area, the cost and time required for proposed operations, and the probable efficiency with which they could be carried out, and upon the chemist's knowledge of the results to be expected therefrom.

Jan 1, 1944

By R. L. Castro

The extraction of ore in panel caving operations also involves the coextraction of non-economic material, known as dilution. Forecasting, avoiding, and understanding the mechanics of dilution is critical to longterm planning. The models of dilution that are currently in use in panel caving operations are those by Laubscher (1994), who postulated that dilution is due to gravitational flow and depends on the height of interaction, the column height, and the draw uniformity. This paper presents a back-analysis of extraction and dilution behaviour at Codelco?s El Salvador and Andina Divisions, which use panel caving as a mining method. This analysis was conducted in order to review the existent dilution entry mechanisms and calculation methods. Three sources of dilution were identified. The first source is ?gravitational dilution?, which is due to gravitational flow and mixing as dilution migrates by gravity from a sector located above the panel under analysis. The second source of dilution is ?caving dilution?, which occurs when an air gap is formed in a large area and a sudden propagation of a hang-up occurs, inducing early ingress of waste into the production level from a level above. The third mode observed is ?lateral dilution?, which occurs when the panel is located next to an exhausted sector and the broken material enters the draw column early during draw. In the last two cases, dilution could migrate large distances horizontally. The mine data indicated that draw and caving strategy are key for long-term planning of large panel caves.

Jan 1, 2014

By Miklos D. G. Salamon

If all stratifications are horizontal, the computation of surface deformation induced by coal mining involves the prediction of roof and floor convergence and then the transfer of the effects of this relative displacement to the surface through the use of the appropriate influence functions. A laminated model, in the form of a quasi- continuum, provides a simple means of computing the approximate convergence distribution and leads to the Gaussian distribution as the influence function. The ideas presented in this paper represent a subtle but fundamental generalization of the influence function Method. It is postulated that the influence of a small area of extraction is proportional to the roof and floor convergence and not to the thickness extracted. This difference in definition removes many conceptual difficulties associated with the influence function method. To demonstrate the utility of the model, the surface disturbances induced by the extraction of a parallel sided long panel are derived. Formulae giving subsidence, tilt, horizontal displacement and strain are given.

Jan 1, 1989

By E Kasai, T Nakamura, E Shibata

In the present study, formation of PCDD/Fs from carbon particles like æsootÆ, so called de novo synthesis, was experimentally simulated using the powder mixture of graphite and metallic chloride. Composite states of graphite and chloride particles were varied by the preliminary treatment, ie high-energy ball milling for different time or heating at different temperatures. These samples were subjected to the measurement of the rates of weight loss mainly due to the oxidation of carbon, the formation of absorbent organic chlorides (AOX) and the formation of PCDD/Fs at 300¦C. The amount of PCDD/Fs formation increased by applying certain pretreatments. Further, linear relationships were obtained among the formation rates of PCDD/Fs and AOX and the weight loss of sample. These results will give useful information to investigate the mechanism of PCDD/Fs formation from unburned combustible carbon and hydrocarbon in thermal processes.

Jan 1, 2002

By M. K. Mohanty, H. Akbari, L. A. Ackah

Dry separation was the predominant method of coal cleaning in the United States from the 1930s to 1980s. The application peak of dry separators for cleaning raw coal was in 1965, when about 23.1 Mt of cleaned bituminous coal was produced. The main advantage of dry coal cleaning is the elimination RIWKH GHZDWHULQJ VWDJHV DQG VLJQL¿FDQWO\ UHGXFHG moisture in comparison to wet processing. In addition, developed dust control systems have made dry cleaning method an environmentally friendly process. The largest air-based coal cleaning plant was built in Pennsylvania in 1968 and could clean 1,272 t/h of raw coal sized smaller than 19 mm. This was followed by a decline in dry coal cleaning to less than 3.6 Mt in 1988. Some of the main reasons that shifted coal operations IURPGU\WRZHWSURFHVVLQJZHUHWKHQHHGIRUPRUHHI¿FLHQW separations with lower density cuts, increase in raw coal surIDFHPRLVWXUHVSHFL¿FDOO\LQXQGHUJURXQGPLQLQJWRFRQWURO GXVW ¿QHUSDUWLFOHVL]HUHTXLUHPHQWV LQFUHDVHLQ¿QHVLQUDZ coal from underground mines, and health and safety concerns related to dust and noise (Arnold, Hervol and Leonard III, 1991; Miller, 2011).

By Charles B. Carpenter

For many years, studies of ground movement and subsidence accompanying subsurface mining operations have been part of the research program of the Bureau of Mines. Periodic observations by engineers of the Mining Division of the Bureau of man-built structures beneath which mining operations are conducted offer indisputable evidence of subsidence in the form of creeks in masonry structures and fractures and depressions in the surface of the earth. As the removal of subsurface rock and earth material by mining, especially by the room-and-pillar method, is equivalent to withdrawing some of the foundation of a building, subsidence of the formations above, the mining levels in certain areas is easily understood as a gravitational adjustment of the overlying earth formations.

Jan 1, 1940

By Charles B. Carpenter

For many years, studies of ground movement and subsidence accompanying subsurface mining operations have been part of the research program of the Bureau of Mines. Periodic observations by engineers of the Mining Division of the Bureau of man-built structures beneath which mining operations are conducted offer indisputable evidence of subsidence in the form of creeks in masonry structures and fractures and depressions in tie surface of the earth. As the removal of subsurface rock and earth material by mining, especially by the room-and-pillar method, is equivalent to withdrawing some of the foundation of a building, subsidence of the formations above, the mining levels in certain air-as is easily understood as a gravitational adjustment of the overlying earth formations.

Jan 1, 1940

By G Baiden

The removal of rock blockages in mining operations has long been a risky undertaking, especially in high overhead conditions. Moreover, the assessment of where to put charges and the placement of them has been difficult due to the lack of visibility and safe access to the area. Traditionally, wedging long poles with explosives on them to keep the operator at a relatively safe distance has been the tried and true method of attempting to remove the blockages. Unfortunately, this is not a perfect system as it usually takes several attempts to remove the blockage. Each successive attempt results in even more dangerous conditions for workers and/or damage to the mine due to the successively larger amounts of explosives used until the hang-up finally comes down.Over the years, different ideas have been proposed to improve this process and reduce the inherent safety risks. Some of the technologies that have been trialled include projectiles fired at the hang-up; large, cumbersome arms; and massive amounts of explosives, each of which come with their own inherent safety risks that result in dangerous situations for miners and the mine.After gaining a thorough understanding of the process, Penguin Automated Systems Inc has developed a robotic system that is capable of working in a rock blockage safely. The idea combines the latest in telerobotics technology with 3D scanning and underground geospatial positioning. The hang-up removal is performed by scanning the inside of the hang-up to rapidly develop a geospatially placed 3D model for the operator to use. The 3D model is detailed enough that the operator can attempt to pick the ‘keystone’. A blasting engineer or the operator can then determine the exact position where the explosive charge should be placed in the 3D model and thus at the actual hang-up. The operator, controlling the robotic arm, uses the 3D virtual reality model of the robot system and the actual drawpoint information model to display the location information, the arm can then reach into the hang-up to position the charge using the kinematic model of the robot system. The 3D model is used to provide views inside the hang-up so that the operator can move the arm safely and precisely. This process allows the operator to place the charge (using the 3D representation of the drawpoint) from a long distance away. As the process continues, the end of the arm drills the rock and precisely loads the explosives. The robot then returns the blasting cable to the command station, which is located in a truck at a safe distance from the blockage.This paper will review the development of the system and present the results to date.CITATION:Baiden, G, 2016. Robotic hang-up assessment and removal of rock blockages in mining operations using virtual reality for safety, in Proceedings Seventh International Conference and Exhibition on Mass Mining (MassMin 2016), pp 745–754 (The Australasian Institute of Mining and Metallurgy: Melbourne).

May 9, 2016

By H. C. Horwood

INTRODUCTION THE Argosy Gold Mines, Limited, which joined the ranks of active Ontario gold producers during the summer of 1936, holds a group of 21 claims on Casummit lake, in the Patricia portion, district of Kenora, northwestern Ontario. The Company is developing and mining goldbearing quartz veins that occur in a series of greywackes and slates of probable Keewatin age. The writer made a geological examination of the property and the surrounding area for the Ontario Department of Mines during the early part of the field season of 1936. This paper is a report on the general geology, structure, and ore deposits at the mine and is based almost entirely on data compiled during the examination. HISTORY Mineralization was first discovered on the property in May, 1929, by A. F. Hewitt, who, with J. A. Borthwick, decided that the country had prospecting possibilities and commenced work in April. Mr. Hewitt staked, and with his partner, J. Ziyone, still holds the group of claims lying immediately east of the present Argosy holdings. Mr. Borthwick staked six claims, K.R.L. 9,681 to 9,686, inclusive, adjoining Hewitt's on the west and later added claims K.R.L. 9,733 to 9,740, inclusive, to his holdings. F. Fiskness, who was also prospecting in the region, discoveted No. 1 vein on Borthwick's claims, and with his two partners, L. Parth and H. Jones, staked claims K.R.L. 9,758 to 9,763, inclusive, to the northwest of Borthwick's and Hewitt's ground. In July, 1929, the Casey Mountain Operating Syndicate, which held ground to the northwest, secured an option on Borthwick's claims. The Fiskness-Parth-Jones property was added in January, 1930, to protect the west dip of the veins. During the winter of 1930-31, the veins were explored by diamond drilling, No. 2 for a length ?of 900 feet and a vertical depth of from 51 to. 375 feet? and No. 3 .t~ a slope depth of 175 feet. I~ August, 1.931, after the msrallat10n of a miming plant, the Casey Summit Gold Mmes, limited, was incorporated to take over the property from the Syndicate. The Maple leaf Mines optioned a controlling interest in the stock in August, 1933, and on September 17th, 1934, brought a 50-ton amalgamation mill into production. From early in October to December 27th, 1934, when the mill was closed down, 4,094 tons of ore were treated to yield 887.89 ounces of gold and 87 .26 ounces of silver( ! ).

Jan 1, 1937

By Stephen A. Gasiorowski, Frank J. Hrach, James D. Bittner

Separation Technologies, LLC (ST) has developed a processing system based on triboelectric charging and electrostatic separation that provides the mineral processing industry a means to beneficiate fine materials with an entirely dry technology. The environmentally friendly process can eliminate wet processing and required drying of the final material. The process requires little if any pre-treatment of the material other than grinding and operates at high capacity - up to 40 tonnes per hour by a compact machine. Energy consumption is low, approximately 1 kWh/tonne of material processed. Since the only potential emission of the process is dust, permitting is typically relatively easy. In contrast to the other available electrostatic separation processes that are typically limited to particles greater than 75 µm in size, the ST belt separator is ideally suited for separation of very fine (<1 µm) to moderately coarse (500 µm) materials with very high throughputs. The triboelectric particle charging is effective for a wide range of materials and only requires particle-particle contact. The small gap, high electric field, counter-current flow, vigorous particle-particle agitation and self-cleaning action of the belt on the electrodes are the critical features of the ST separator. The high efficiency multi-stage separation through charging / recharging and internal recycle results in far superior separations and is effective on fine materials that cannot be separated at all by the conventional electrostatic techniques. Since 1995, this triboelectric process has been extensively used for the beneficiation of coal fly ash with eighteen separators in place and over 100 machine-years of operation at locations in North America and Europe. The technology has been also successfully applied to the beneficiation of a variety of minerals including calcium carbonates, talc, and potash.

Jan 1, 2012

By K. J. R. Ford, Botz. M. M.

Porphyry copper ores are frequently a source of low-grade gold ore, but gold in these ores is often associated with significant levels of cyanide-soluble copper. Cyanide leaching of such ores increases flowsheet complexity and operating costs, and requires thorough planning to satisfy environmental requirements for tailings disposal and mine closure. This paper presents a review of the chemistry of cyanide leaching of gold-copper porphyry ores, carbon adsorption phenomena and means of removing base metals from leach solution. The primary economic drivers behind the processing of such complex ores are also analyzed.

Jan 1, 2011

By A. J. Vietti

A pilot plant paste thickening campaign was conducted at the Anglo Platinum Limited Mogalakwena South Concentrator plant in South Africa in order to determine the water saving capability of P&TT technology. In the process a simple water consumption model was developed for estimating the overall water consumption of the mine. The model indicates that for the Mogalakwena tailings, significant water savings are achieved by discharging thickened tailing directly to the TSF but only at densities where free water release at the TSF is close to zero. Keywords Paste, thickened tailings, thickener, water savings, water consumption.

Jan 1, 2011

By S Robotham, P C. Stewart, K Maher

A data science based dilution study was conducted to identify the causes of dilution at South32’s Cannington Mine (Cannington), a large open stoping operation. In terms of industry benchmarks for unplanned dilution, Cannington is already performing very well, and so opportunities for improvement are more difficult to identify. The study is based upon back analysis of nearly 150 case studies from the mines reconciliation database, and has quantified the relative effect and significance levels for the following dilution parameters; time until paste filling, faulting and cable bolt reinforcement. Specifically, significant contributions were associated with faults and stope open duration. Quantifying the effect of faults on stability graph accuracy enabled a site specific adjustment to improve the predictive ability of the Cannington stability graph (unstable stope specificity improved from 63 per cent to 74 per cent). Despite Cannington’s already high levels of stope performance compared to industry benchmarks, data science methods have identified a complex interaction between identified dilution factors (ie stope open duration, presence of faults and cablebolting). Specifically, a third order Factorial ANOVA (Analysis of Variance) provided evidence that stope open duration reduces the effectiveness of cable bolts in faulted ground (average dilution = 2.1 m, p-value = 0.13). These results are consistent with site observations of a relationship between the stope open duration and the extent of failure when unravelling on a fault, even when cables are present.CITATION:Maher, K, Stewart, P C and Robotham, S, 2016. A data science approach to identifying and quantifying causes of dilution at Cannington Mine, in Proceedings Seventh International Conference and Exhibition on Mass Mining (MassMin 2016), pp 491–500 (The Australasian Institute of Mining and Metallurgy: Melbourne).

May 9, 2016

By V. Brabie, S. Jansson, L. Bohlin

The rate of dissolution of solid MgO-C and doloma into liquid in CaO-Al2O3-SiO2-MgO slag at different temperatures was studied under conditions of forced convection by rotating cylindrical refractory specimens in a stationary crucible containing the molten slag. The corrosion rate was calculated from the change in diameter of the cylindrical specimens. Refractory specimens were 13 mm in diameter and 70 mm long. The specimens were rotated for15 to 120 minutes at speeds of 100 to 400 rpm in the molten slag. The rate of corrosion increased with temperature and with the rotating speed of the rod, and decreased when the slag was nearly saturated with MgO. The experimental results confirm the assumption that the diffusion of magnesium oxide through the slag phase boundary layer controls the corrosion process. The corrosion mechanism seems to be the dissolution of the refractory materials into the slag, followed by penetration of pores and grain boundaries and dispersion of the grains in the slag. Keywords: MgO-C refractory, doloma refractory, molten slag, corrosion rate, corrosion mechanism

Jan 1, 2004

By X. T. Feng, Y. H. Hatzor, Y. Tal, G. Yagoda-Biran

"When studying jointed rock mass deformation around underground openings it is of great importance to model correctly the excavation sequence during the numerical simulation. This is because for effective arching mechanism to develop in the roof minute block displacements must take place and some of the available discontinuities shear strength must be mobilized. If from the beginning of the simulation the underground opening already exists in the numerical model, block displacements into the excavation space will initiate and develop from time zero, before the initial stresses in the model have attained their actual initial level in the field. These initial block displacements are therefore artificial and exist only in the numerical model, not in the physical reality, and may lead to erroneous assessment of the stability of the designed structure, typically on the conservative side. We have introduced sequence excavation capabilities both in the numerical manifold (NMM) and the discontinuous deformation analysis (DDA) methods and show here the advantages of this modification using three different case studies, each illuminating a different aspect of this enhancement.We begin with the 25 meter deep 2000 year old underground Zedekiah limestone quarry below the old city of Jerusalem, Israel, which is still standing today unsupported with a free span of 40 m. We show that when the opening exists from the beginning of the numerical simulation the required friction angle for roof stability is 25 degrees, whereas when the opening is removed after all stresses and displacements in the model have been stabilized the required friction angle for stability is only 15 degrees.We then model the excavation sequence of a tunnel model representing a 2500 meter deep research tunnel in the Jinping hydroelectric project, China, in order to determine the in situ stress field at this depth by a grid search inversion of displacement data obtained using the sliding micrometer technology in the course of tunnel excavation. Thus we are able to constrain the in situ stress field at these depths where standard in situ stress measurement procedures are extremely difficult to execute properly.Finally, we use sequence excavation modeling capability to find the total height of the expected loosening zone around tunnels excavated through columnar jointed basalts which pose a great engineering challenge because of the characteristic dense network of slender prismatic blocks that transect the opening at a steep inclination. We use MPBX data obtained during excavation of a deep tunnel through such a rock mass to validate our numerical results and show that application of standard empirical guidelines for dimensioning rock bolt reinforcement in such rock masses may in fact result in very un-conservative design because existing empirical approaches typically ignore the anisotropic nature of the structure of such rock masses which, as we show, plays a very significant role in determination of the extent, shape, and geometry of the loosening zone around the opening."

Jan 1, 2015

By G. Bourque

One of the design criteria for the Mount Wright facilities was to incorporate the latest proven automation techniques and devices for the new crushing, grinding and concentrating plant. The heart of the centralized control system is a Fox 1 process computer, located in the central control room in the administration building. The entire operation, i.e. crushing, conveying, storing, grinding and concentrating, is monitored and controlled, through the process computer , by one operator via a CRT console. In case of computer failure, the control is automatically, and without process interruption, transferred to manual back-up panels. One of the newest management tools, the process computer is programmed to collect and automatically print out shift. daily and monthly reports on tonnage, metallurgy and equipment operating time, for better planning of operations and preventative maintenance.

Jan 1, 1977

By C. Dorfling, M. Tadie, S. Grobbelaar

The physicochemical properties of the complex electrolytes used in direct copper electrowinning are an important consideration for the development of a high-fidelity model of the process. Direct electrowinning electrolytes typically contain a high background of metallic impurities. The effect of metallic ions on the properties and accompanying change in the limiting-current density for copper reduction have been the subject of several studies. Although various empirical correlations have been published for describing the physicochemical properties of electrowinning electrolytes, the correlations are only applicable to a limited range of conditions and cannot be extrapolated without further validation. Consequently, in this paper we validated existing physicochemical property correlations for the full range of operating conditions applicable to direct copper electrowinning and developed a new correlation for predicting the associated limitingcurrent density for copper deposition. Following, we evaluated the benefit of using the validated correlations as a component of a dynamic electrowinning model.

Jan 1, 2023