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By Dominic Howarth, Diana Drinkwater, Don McKee

At a time when the mining and minerals industry across the world is undergoing unprecedented change, the very fabric of the tertiary education system which is the principal source of trained professionals to the industry is in decline in many countries. The change sweeping the industry is globalisation as evidenced by the emergence of a relatively small number of increasingly dominant corporations with operations in most of the major mining countries. The education sector is struggling to provide sufficient graduates as the viability of small mining schools declines. That is only part of the problem as the global operating industry is increasingly seeking graduates who are comfortable working in different countries and cultures. One obvious response to the industry needs and developments is for the education sector to consider how it can best respond to the global opportunities. This paper presents the case for a global education network which is based on a network of international thinking Universities and which makes use of the latest in educational thinking and technologies to provide a quality education and in the process produce graduates fitted for international careers.

Jan 1, 2003

By Johan C. van Dyk, Johan W. van Zyl, Martin J. Keyser

"Coal is a crucial feedstock for South Africa’s unique synfuels and petrochemicals from coal industry and it is used as the main feedstock to produce synthesis gas (CO and H2) via the Sasol-Lurgi Fixed Bed Dry Bottom gasification process. Detailed coal characteristics are essential to predict gasification behaviour when a specific coal source is to be gasified.The principle aim of this paper is to highlight and discuss those specific coal characteristics, which affect gasification behaviour and stability.In order to determine the suitability of a coal source for gasification purposes, the coal is characterized and the results compared with historical data. Benchmark data, where it was possible to operate the gasifier with ease and relatively high stability, is used as a reference.Coal sources with extreme properties (i.e. low reactivity, ash content <10% as is used by Dakota Gasification Company, or “brown coal” with moisture >30%) can probably be gasified in a Sasol-Lurgi Fixed Bed Dry Bottom gasifier provided that certain operational changes are implemented. Other properties, like high caking and extreme ash content for example, require blending to acceptable levels."

Jan 1, 2003

By Daniela Venter, Stephen Chryssoulis, Ken Stowe

"A sampling campaign was conducted at Kemess in order to identify and assess the chemical and physical factors, which control free gold flotation kinetics in the rougher and cleaner circuits. The rationale behind this approach was that accurate knowledge of the parameters affecting free gold flotation kinetics, can be used to determine how to accelerate free gold flotation. Collected samples were composites of 5-6 cuts over a four-hour period, at steady plant conditions.In the rougher circuit, coarser equidimensional gold particles floated ahead of the finer grained and the flaky gold. Sulphur followed by molybdenum and to a lesser extent silver enhanced gold flotation kinetics, while hydroxyl followed by carbonate ions induced depression."

Jan 1, 2003

By Leon Lorenzen, Rodrick M. Lamya

"Leaching behaviour of nickel – copper matte in a CuSO4–H2SO4 solution during the repulping stage of a matte pressure leaching process has been studied. The base metal recovery process investigated in this study consists of a matte repulping stage prior to a series of pressure leach stages. The repulping stage is essentially an atmospheric leach stage in which the Ni-Cu matte, containing small amounts of cobalt and iron, is leached in copper spent electrolyte from the tankhouse, resulting in dissolution of the nickel with simultaneous precipitation of almost all the copper.Effects of various process parameters on the kinetics and extent of the leaching reactions, as well as on the cementation of copper from the solution have been quantified. The parameters investigated were temperature, particle size, pulp density, stirring speed, residence time, initial copper concentration and initial acid concentration.Leaching characteristics of the preleached matte during the subsequent pressure leach operation has also been studied. The effects of variations in the conditions in the repulping stage on the kinetics and degree of base metal dissolution during the pressure leach stage have been investigated. Any transformations that occur in the mineral phases of the matte during the leaching process have been studied, and a leaching mechanism proposed."

Jan 1, 2003

By Ronald Smeink, Ton de Gouw

"Reagents are an important cost-factor in the flotation of minerals. The mechanism of collectors and frothers has been studied extensively, but on depressants – probably the biggest cost-factor in the reagent suite – very little is actually known. Theories are frequently faced with the bare facts, pointing in another direction. Fundamental research is complicated by the fact that the amount of possible interactions in the flotation cell is almost unlimited and makes “change-one-parameter-at-a-time” experiments questionable and at least difficult to interpret. Also, the adsorption of depressants on the ore is very strong and desorption merely impossible. Detection methods therefore tend to be indirect and – therefore - non-specific about the location of the depressant on the ore.Depressants are supposed to adsorb selectively on gangue minerals; not on the valuable minerals in the froth. In order to be able to develop better and ‘’smarter’’ depressants, an analytical method is therefore required that will enable to detect which (=qualitatively) depressant, in which concentration (=quantitatively) sits where exactly (= selectively) on the mineral surface. (Answering the question: ‘’ Which minerals is located direct under the depressant?’’)And also: does the depressant compete with other reagents for that location? (like collectors) This analytical method is under development. The actual status of the method is promising and the results will be shown."

Jan 1, 2003

The introduction and subsequent ascendancy of autogenous and semi-autogenous milling for comminution circuits has undoubtedly lead to many economic advantages. From a process viewpoint, however, at least one downside has been the sensitivity of these machines to process input variations. Foremost among these is ore competence, though feed size comes a close second. This sensitivity is due to the reliance of ag/sag mills on the feed ore for their grinding media competence and size. Autogenous (ag) mills are the most sensitive in this respect with semi-autogenous (sag) mills being increasingly less so as the ball charge is increased. Increasingly designers and operators are recognising the importance of feed size and the benefits of manipulating it to improve performance. This has been achieved by installing additional crushing/screening capacity ahead of the ag/sag, better operation of the primary crusher, better control of segregation cased by stockpiles and bins and by changing blast design/practices to modify the ROM size distribution. This paper describes the influence of feed size distribution on ag/sag mill performance with reference to a range of plant data. It particularly concentrates on how changing blasting practice to modify ag/sag feed size can have a considerable overall benefit.

Jan 1, 2003

By Jeremy Bosman, Niel Lourens

"Cyclones are used in four main applications in primary wet heavy mineral processing plants i.e. upfront desliming, densifying, and concentrate stacking and tails deposition.UPFRONT DESLIMINGMany heavy mineral ore bodies are associated with high slimes varying from 15 to 60%. The increased viscosities arising from the slimes impact negatively on heavy mineral recovery in the spiral plant. Recoveries can be reduced by up to 10%. Cyclones have proven to be able to remove slime efficiently with acceptable loss of valuable heavy mineral in the overflow. For low slime applications, typically below 25%, it is possible to achieve the desired results using a single stage of cyclones, whilst for higher slimes, two stages of cyclones are required. The overflow of the primary stage is retreated through a second stage to minimize heavy mineral loss."

Jan 1, 2003

By G. Demi, G. Belardi, N. Shehu, S. Cico

The physico-chemical interaction between minerals such as olivine, chromite and serpentine and the ions most commonly present in solution, like Ca and Mg and flotation reagents such as EDTA and oleic acid was investigated. The study was conducted via release tests, electrophoretic measurements and microflotation of selected minerals coming from the Kukes deposit (Albania).

Jan 1, 2003

By P. Huang, D. W. Fuerstenau

Various factors that control the natural flotability of talc, including differences due to crystal face and edge effects, were delineated. For study of talc depression phenomena, dextrin was used as a model depressant. For the enhancement of talc flotation, dodecylammonium acetate (DDAA) was used as the collector. The interaction of DDAA with talc was assessed by flotation experiments and electrokinetic (zeta potential) measurements, from which the role of hydrophobic bonding can be demonstrated. The results presented in this paper provide useful information on how the crystal chemistry and surface chemistry control the electrical double layer, adsorption phenomena, wettability, and flotation behavior of talc in aqueous media.

Jan 1, 2003

By Konstantin Fedotov, Victor Beloborodov, Anatoly Potyomkin

"There are areas in Russia, which cover huge territories and they are north, and Siberia. These difficult to access regions with cold climate are rich in a great number of distant deposits of valuable and rare metals, gold and platinum. The development of such deposits requires highly effective technologies of mineral processing which could be realized in modular and quick-built processing plants.The work presented includes the results of long term research in the development of new technologies of processing of zirconium (in the form of rare mineral Baddeleyite – natural zirconium dioxide) bearing ore of the Kovdor deposit which is located in the Polar region of the Kola peninsular and also in Siberia deposits of of ledge ores of gold."

Jan 1, 2003

By Chris A. Bennett, Glenn S. Dobby, David A. Bulled

Establishing reagent dosing strategies for new ore bodies has traditionally involved a combination of experience and empirical experimentation using standard laboratory tests. The grade and recovery data resulting from these lab tests have historically been used as direct indicators of plant performance despite the obvious differences between the flotation environments. A reagent scheme selected in this way would subsequently be employed to generate the grade and recovery information for the geometallurgical model which in turn was used for metal production and cash flow forecasts. If the reagent scheme was sub-optimal then so too would be the forecasts and the resulting cash flow.

Jan 1, 2003

By B. C. Qi

"In water treatment, flocculation or coagulation with aluminium or ferric salts has been widely used for many years to remove natural organic matter (NOM), including humic acids. However, the adsorption of NOM to aluminium hydroxide flocs during conventional coagulation/flocculation processes is very complex, with the flocculation of aluminium hydroxide particles and the adsorption of NOM molecules on flocs occurring simultaneously. Any effect on the surface characteristics and micro-structures of the humic acids and aluminium hydroxides could affect the adsorption efficiency.It has been widely observed that if a reaction system (liquid-liquid or liquid-solid) is exposed to an ultrasound field, under appropriate conditions, a variety of physical (emulsification, aggregation/flocculation) or chemical (the production of radical and exited species; single electrotransfer) actions may be activated. Though the ultrasound effects have been used in biological and chemical decontamination in many conventional environmental protection practices, the idea to explore the ultrasound effects in the removal of humic acids by preformed aluminium hydroxide flocs is relatively new. In this paper, the effect of an in-situ ultrasonication on removal of the humic acids extracted from the acidification fermentation of lignocellulosic residues, by a preformed aluminium hydroxide, was evaluated; the effect of ultrasonication on the surface complexation of the humic acids with the preformed aluminium hydroxides was investigated."

Jan 1, 2003

By Victor Avdokhin, lvan Kovlekov

"Studies of the process of concentration of gold-containing sands and technogenic resources show that the main reason of gold losses is misbalance between size of gold particles and degree of roughness of mineral bed. This results in free circulation of small gold particles in pores with following washing off the particles from the bed by turbulent flows.We elaborated design of magnetic sluice, intended for improving efficiency of recovering fine gold by optimizing magnetic field of a magnetic system on the base of forming catching coat from magnetic mineralsThe magnetic sluice includes trough-shaped body from magnetic-conducting material. On the bottom of the trough, magnets are placed, and opposite poles of the magnets are oriented outwards. Thickness of the bottom is determined to be sufficient for locking magnetic lines of force of the magnets on each other. The magnets of rectangular plate shape are placed on the rough bottom, covering the whole surface or with spare areas; the magnets are placed across the trough with alteration of rows with the same pole orientation."

Jan 1, 2003

By A. V. Nozhkina

"Transformation of diamond into graphite was investigated in the region of diamond metastability under the action of media chemically active relative to carbon in the temperature range from 770 K up to 2200 K and pressure range from 10-3 Pa up to 3 GPa/IV VIII group metals of periodic system and oxygen were used as media chemically active relative to diamond.Methods of electron diffraction, chemical analyses, emission spectroscopy and X-ray phase analyses were used for determination of the reaction products.It was found that in the region of diamond metastability the stage of catalytic phase transformation of diamond into graphite took place during the interaction between diamond and metal. Metal reduce activation energy for transition of diamond into graphite from 109,4 kcal/mole to 77,4 kcal/mole.Kinetic of phase transformation of diamond into graphite was investigated.Pressure does not considerably influence on the rate of phase transformation of diamond into graphite in the presence of transition metals."

Jan 1, 2003

By James Y. Oldshue

"Very seldom is it possible when contacting a gas with a slurry to measure the dissolved gas concentration in the slurry, and even were it possible, seldom are equilibrium data available with a suitable Henry’s law constant.In general, by assuming a reasonable value for the dissolved gas concentration in the slurry and a corresponding equilibrium gas partial pressure P*, Kga values can be calculated for the pilot plant and scaled up. Then, with the same P* value at various reaction conditions, a mixer can be designed which is quite satisfactory, having a reasonable design factor for full-scale performance.We will take as an example a slurry of a known solids composition and use a continuous 4 tank system. By assuming a percentage saturation of the dissolved gas in the first tank, the dissolved gas concentration can be obtained in the other three tanks. It usually is possible to measure the off-gas composition in each of the 4 tanks. If the top of the tanks is connected in the form of a multi-compartmented horizontal autoclave, then a modified top off-gas composition in each compartment must be used."

Jan 1, 2003

By Y. F. Hou

This paper reports the results of the study of the influences of concentration and modulus of sodium potassium silicate solution (Na-K activator) and curing mode on the phase composition, mi-crostructure and strength development in the geopolymers prepared using Class F fly ash. X-ray dif-fraction (XRD), Fourier transform infrared spectroscopy (FTIR) and MAS NMR are utilized in this study. It shows that the compressive strength increases while sodium potassium silicate solution modulus increases, but when modulus exceeds 1.7, the compressive strength decreases, and it decreases markedly while modulus is greater than 2.0. The compressive strength improves with increase of sodium potassium silicate solution concentration. When the concentration is 36%, the compressive strength reaches the maximum. Elevated temperature can increase the strength of samples synthesized using sodium potassium silicate solution with 32% concentration and modulus 1.2. Compared to the strength of the sample cured at 50?, the strength of the samples cured at 65? and 80? are higher at 1 day and 3 days, but when cured at 80?, strength is smaller than that cured at 50? for 7 days. When temperature is too high, too long curing time will decrease the strength. Long precuring at room temperature before application of heat is beneficial for strength development, and there is about 10%~50% increase in strength of the samples cured at 1 day precuring and 2 days elevated temperature as compared to the strengths of the samples cured for 3 days at elevated temperature or cured for 28 days at room temperature. The main product of reaction in the geopolymeric material is amorphous alkali aluminosilicate gel.

Jan 1, 2014

By Sepideh Javanshir

The process of liquid?liquid extraction of gold from chloride solution is complicated by the presence of many variables acting simultaneously in an unknown non-linear fashion for the determination of the final extraction efficiency. In practice, it is quite difficult to develop a model for predicting various properties of such process. Therefore, an alternative approach based on Artificial Neural Network (ANN) is considered to assist in the simulation process. Artificial neural networks (ANN) are powerful tools that can be used to model and investigate various highly complex and non-linear phenomena. This paper presents application of Multi-Layer Perceptions (MLP) to construct relationship that will be employed to develop a quantitative method for the estimation of the extraction efficiency as a function of hydrodynamical parameters such as stirrer speed, [AuCl4]- and DBC concentration, organic and aqueous flow rate. The model is shown to be in excellent agreement with the experimental data (R2 value for training and testing data was 0.9992 and 0.9915 respectively). Therefore, it can be used to optimize the parameters of liquid?liquid gold extraction with dibutyl carbitol (DBC).

Sep 1, 2012

By A. C. Maffei, M. V. Lins Gonçalves

Ore concentration processes are a function of the respective particle size distribution; however, most of them do not use an efficient operational method to determine it. From a practical point of view, the surface area can be calculated for any size analysis. The physical principles for determining the size distribution in each method are different, for the results will not be compared directly. During the development of the research project of the sulfide ore flotation method using inert gas, different methods for calculating the specific surface area have been used, such as sieving, sedimentation/X-ray, laser diffraction and BET, i.e. specific techniques to determine the specific surface area of copper and gold ore concentrates. The statistical method of minimum squares was used to achieve practical correlation equations among them. Regarding these two ores, if one knows a specific surface area value using one of the methods above, one can predict the result of the others. Diminution of the reagent consumption was so controlled and it could be even decreased by using inert gas.

Jan 1, 2003

By Ying Gu

Automated mineralogy methods and tools, such as the Mineral Liberation Analyzer (MLA) and the QEMSCAN, are now widely used for ore characterization, process design and optimization. Several case studies published recently demonstrate that large gains can be obtained through grinding and flotation optimization guided by automated mineralogy data. However, since automated mineralogy can only provide the information pointing to where the process gains can be made, it does not directly impact the production gain. Thus, a question is often asked: how to value the contribution of automated mineralogy to process improvement of a particular plant. This appears to be a difficult question. On close examination however, it is found that this is essentially a question of the value of information and it is reasonably well documented in various other industries. Hubbard (2010), in chapter 7 ?Measuring the Value of Information?, dealt with exactly this type of problem. The value of information is the reduced risk of an investment and opportunity loss. The methods Hubbard developed can be applied to estimate the value of automated mineralogy, as well as metallurgical test work, which also produces information that reduces the risk of investment. This paper first introduces Hubbard?s theory on the value of information and how to measure it. It then applies his methods to estimate the value of automated mineralogy, using Anglo Platinum?s fine grinding project as an example. In this case, the value of automated mineralogy includes the reduction in investment risk worth US$ 62.5million, in project rejection worth US$197 million and in opportunity loss worth US$320 million. In the end, a general model is developed to allow the simulation of the value of automated mineralogy in different mining operations constrained by different parameters.

Sep 1, 2012

By V. Beskrovnaya

Oxidised lead-bearing ores of one of the deposits of Russian Federation represent complex raw materials. Its main components are lead (3.2%~4.7%), silver (100~300 g/t) and zinc (0.7%~0.8%). The sample is characterized as oxidized ore. Silicium (37.4%) and iron (33.2%) are its main com-ponents and present in oxide form. Lead presents as cerussite, anglesite and plumbojarosite have a subject role. Zinc occurs as smithsonite. Certain part of zinc is associated with manganese minerals (psylomelane-pyrolusite). Close association of valuables with manganese-iron mineralization is ob-served. Silver is present in native finely dispersed form. Three options of flowsheets have been developed to recover valuables from the ore. 1. Hydrometallurgical flowsheet of lead and silver recovery on the basis of chloride leaching. 2. Flotation. 3. Flotation -flotation tailings cyanidation. Hydrometallurgical flowsheet of ore processing on the basis of chloride leaching (option I) al-lows to achieve recovery into saleable products of 68.8% Pb and 70.2% Ag. High quality lead concentrate with 71.7% lead and 700 g/t silver was obtained during flotation (option 2). Flotation tailings cyanidation (option 3) provides 24% silver additional recovery (from the ore). Technical and economical evaluation demonstrated that ore flotation (option 2) and flotation with subsequent flotation tailings cyanidation (option 3) are the most cost-efficient. Option II is the most cost-efficient variant of 1 tonne of ore processing (9.05 US dollars).

Jan 1, 2014