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The following report summarizes the results of engineering feasibility studies whose purpose was to assess the probable efficiency, reliability, safety and cost of a number of possible methods for removal of radon gas from the ambient air in underground mines. Fourteen candidate techniques were evaluated. Seven of these were based on specific individual principles, and seven were based on combinations of these principles. The individual principles were as follows: 1. Activated charcoal 2. Organic fluids 3. Semipermeable membranes 4. Molecular sieves 4. Cryogenics 6. Chemical reaction 7. Centrifuge The combinations were: 8. Cryogenics and activated charcoal 9. Cryogenics and molecular sieves 10. Cryogenics and chemical reactions 11. Membrane filters and organic fluids 12. Membrane filters, cryogenics and activated charcoal 13. Membrane filters and chemical reactions 14. Silica and an Organic Fluid

Jan 1, 1975

By Lloyd A. Morley

The problems associated with the presence of organic materials and of water in explosion-proof enclosures used in high voltage, high capacity applications were examined through a literature search and theoretical reasoning. Information on volatilities is presented. The conclusion is reached that explosive pressures are significantly enhanced by inclusion of these materials.

Jan 1, 1976

By Fumito Tanaka

The Mitsubishi Process is the sole pyrometallurgical process for the continuous production of blister copper from copper concentrates. Continuous converting originates from the application of the proven technology of a lime-ferrite slag (CaO-FeOX-Cu2O) on the Converting Furnace (C-furnace). Recent improvements on the C-furnace operation have included increasing the processing of recycled materials and the investigation of alternative fluxing agents. However, some minor oxides adversely affect C-furnace operation, with respect to magnetite behavior of the slag, with the most significant impact having been observed with the silica content of the slag. This paper will quantify the impact of silica on the lime-based slag, and discusses the controls that have been identified to sustain continuous converting operation.

Jan 1, 2005

By T. C. Eisele

The use of column flotation was considered for the ?reverse flotation? of iron ore, where the gangue (quartz) was recovered in the froth product. This use of the froth for carrying the gangue mineral rather than carrying the valuable concentrate significantly changes the operational requirements of the column. The objective of this work was to determine which of several column flotation technologies would be most suitable for this type of flotation operation. Studies were carried out using both the Jameson column and the Deister column. Comparative results are presented that show the capabilities of both column types in this application relative to conventional Wemco flotation cells. Columns were demonstrated to have grade-recovery performance superior to what could be achieved with conventional cells. Two-stage flotation with the columns could produce a concentrate that was up to 70.2% Fe at 87.5% iron recovery, compared to 70.4% Fe at only 77.7% iron recovery for four stages of flotation in conventional cells. It was shown to be particularly important to operate the columns to recover a maximum of the quartz gangue into the froth. It was noted that there are often problems in scale-up of laboratory columns to plant scale, because the increase in height and the decrease in the ratio of height to diameter at the larger scale allows more axial mixing and bubble coalescence, both of which degrade the column performance. Horizontal baffling was shown to improve column performance by reducing axial mixing and breaking up large bubbles, and so the use of such baffles in the reverse flotation application was investigated.

Jan 1, 2007

By S. M. Spottiswoode, J. A. L. Napier, M. Kataka

The move away from the use of strike stabilising pillars at depth and the adoption of the more flexible system of mining towards final dip remnant pillars brings new opportunities for optimising mine design. In the initial planning stage, the size and spacing of the final pillars is designed using classical design criteria, through limiting modelled values of Energy Release Rate (ERR), Average Pillar Stress (APS) and Excess Shear Stress (ESS). In reality, mines often leave pillars that are larger than those originally designed. One of the reasons for leaving more ground is an unexpectedly high rate of seismicity. In this paper, we present developments in integration of modelling and seismicity that are aimed at developing design criteria that are more responsive to local conditions.

Jan 1, 2003

By Juan M. Antorena

A pile driving and testing program was undertaken to evaluate installation procedures, assess capacity, particularly in uplift, of 360- and 460-mm (14- and 18-inch) square prestressed concrete piles and provide foundation design parameters for the New Mid-Point Bridge project in Fort Myers, Florida. Nine piles were dynamically monitored during installation, and six piles were monitored during restrike driving to evaluate pile drivability and uplift and bearing capacity including time related capacity increases due to soil "set-up". In addition, two static load tests (tension and compression) were performed to calibrated the results obtain during the dynamic testing. This paper presents descriptions of the pile driving testing program along with findings regarding pile uplift and compression capacities from the static load testing, pile capacities from dynamic testing (CAPWAP® analyses), soil-pile adhesion values, wave equation factors, soil strength vs. time dependency, foundation design (anticipated pile tip elevation) and pile driving recommendations.

Jan 1, 1995

By Eugene T. Sheridan

The Bureau of Mines annually canvasses the fuel-briquet and packaged-fuel producers in the United States and publishes economic data on these industries, based upon reports submitted voluntarily by producers. This publication lists all producers that reported commercial production to the Bureau for 1960 and presents data on individual plants. The companies named herein represent virtually all producers of processed minerals fuels. A few small plants may not have been canvassed or failed to respond to the survey because some of the smaller plants operate intermittently and the survey is voluntary. All plants that reported commercial production were included; regardless of size. Specifically excluded were plants that manufactured briquets from wood charcoal. Fuel briquets and packaged fuel are manufactured solid fuels, produced by mixing fine-sized mineral fuels with binding materials and compressing into small individual shapes, Briquets are produced in pillow-shaped and cylindrical form, are 2 to 4 inches long, and weigh 2 to 4 ounces. Packaged fuel consists of 3- or 4-inch cubes; 6 or 8 of which are wrapped together in heavy kraft paper to form a package weighing 10 to 15 pounds, Briquets are durable and may be stored and handled as bulk fuel; packaged fuel breaks easily and must be stored indoors to prevent it from deteriorating. Whereas briquets are consumed in many areas as a general residential fuel, packaged fuel is more of a specialty item, used at times to supplement other fuels. Packaged fuel is burned without re-moving the paper and is referred to as the "white glove" fuel.

Jan 1, 1961

By A. Sinha, N. K. Babar, H. R. Kalihari, A. K. Chakraborty, M. R. Saharan, C. P. N. Pathak

A case study is presented on the optimization of cable bolting patterns in cut-and-fill stopes at the Chikla Mine, MOIL, India. Rock mass characterization, using Bieniawski’s RMR and Barton’s Q, indicated that the stopes lie in the “no supports required” to “spot bolting required” support categories. In contrast, the current practice of cable bolting in a 2.0 m by 2.0 m grid pattern for stope widths less than 12 m displays different results. Numerical modelling results are in line with the rock mass characterization study. It can be affirmed, as well, that no cable is carrying rock loads greater than 5 t. This fact is derived from observational behaviour of the crown pillar of an experimental stope with open stoping operations and hanging cables in the cut-and-fill stopes of the mine. An increase in the cable bolting grid spacing is, hence, recommended for implementation by mine management, based on the study described in subsequent sections. It is also suggested that the mine adopt the open stoping method, provided results of a rock mechanics instrumentation program in an experimental stope with a cable bolting grid of 2.5 m square are favourable.

Jan 1, 2007

By C. T. Shaw

Fur a secure mineral supply position to be maintained in the Fiuropean Community there must be a supply of qualified people in the minerals industries. The education of the people required to run and develop these industries should be a priority in the community. This means that there should be a strong capability in mining engineering education. The mining engineering professors decided in 1990 to get together in a new Society to discuss the problems. The Society of Mining Professors/Societat der Berg-baukunde was formed at a meeting in Austria in October 1990. It is basically a F.uropean Society with a few member professors from outside Europe to keep the Society conversant with trends elsewhere. The objectives of the Society are to see that the mining universities in Fiurope maintain standards and produce enough mining engineers. The present membership of the Society and the work of developing a database of current courses is described. Working from the knowledge base developed, it will be possible to design a 'European' mining degree course. The problems which will have to be addressed have been identified and are described in detail.The paper finally goes on to discuss the other problems that universities are facing, the economic problems and above all the lack of students applying for mining courses across Europe. The help and active participation of the mining industry, if that industry still wishes to employ mining engineers, is identified as the only possible solution to those problems.

Jan 1, 1993

By Nobel Insurance Service

[Executive Director’s note: ISEE is committed to continuing its efforts to ensure that blasters be made aware of the issue of migration of carbon monoxide resulting from blasting operations. In the July/August 2001 issue of the J o u rnal we printed excerpts from “Carbon Monoxide - The Silent Hazard,” an article from the Safety Update, published by Nobel Insurance Services. We also re minded readers of the text from the 17th edition of the ISEE Blasters Handbook in its section on trench blasting as follows: “...consideration must be given to the proper venting of gases generated from the blasting. Should those gases spread laterally rather than vent directly to the surface, the gases may travel underg round and finally vent well outside of the planned area. Such events may be caused by the strata, soil conditions or root systems, or existing and/or abandoned utilities or other man-made structures. In the worst situation, gases resulting from the detonation such as CO2, CO, and/or N Ox may travel through the strata and find their way into basements of nearby homes or businesses.” While incidents are rare, a number of cases in re c e n t years have resulted from outdoor blasting operations p roducing carbon monoxide gas that has migrated t h rough the earth and accumulated in nearby enclosed spaces. T h e re are steps that a blaster can take to be proactive in preventing incidents. These steps and studies of the occurrence have been expertly presented in several papers presented at ISEE conferences and included in the ISEE Conference Proceedings, available th rough the Blasters Library. In addition, Material Safety Data Sheets provided with explosives used in surf a c e blasting should provide additional information on gases p roduced by detonation. Below, we have reprinted the IME white paper, entitled “Fumes from Blasting Operations.” The paper underscores the unique set of circumstances that combine to contribute to high concentrations of CO measurements in underground, enclosed spaces following the detonation of explosive materials and provides recommendations to blasters

Jan 1, 2004

(Published by courtesy of the Great Boulder Pty. Gold Mines, Limited)1. INTRODUCTIONThe faults described in the following paper are of a somewhat unusual character, and have presented a serious problem both in the development and mining of many ore-bodies on the Eastern side of the Boulder Belt. They are mentioned only briefly in the literature of the field, but were observed by, both Stillwell (1)t and Gustafson (2), and have been studied by other geologists and operators in various parts of the "Belt." Their effect on the lodes of Hamilton Section, Great Boulder Mine, was described by King (3) in 1937, and, during recent years, they have been encountered in most of the Great Boulder workings extending east of the Boulder Dyke.Although this paper is based mainly on a study of faulting and development problems on the Great Boulder mine, the general conclusions reached may be applicable to the solution of similar faulting problems in other mines throughout the field.In order to arrive at a clear understanding of the somewhat complicated relationships which the east-dipping faults bear to the lode systems it will be necessary to give a brief outline of the salient geological and structural features of the "Belt" before proceeding to describe the faults themselves.2. GENERAL GEOLOGYThe most recent descriptions of the geology of Kalgoorlie are those by Stillwell (1) and Gustafson (2) and the reader is referred to these as representing the basis of current knowledge of the geology of the field.The Boulder Belt is comprised of a central core of altered quartz dolerite which is flanked on either side by fine grained greenstones and lavas, usually referred to as the calc schists. Down the centre of the quartz dolerite mass there is an infolded bed of slate (2, p. 105) which has been intruded in lit par lit fashion by albite porphyry; the composite body of slate and porphyry so formed is known as the "Boulder Dyke." Numerous smaller porphyry dykes intrude both the quartz dolerite and the calc schist; these vary in composition and range from chloritised hornblende porphyrites to albite porphyries.The whole of the rock assemblage has been subjected tG a considerable amount of folding, faulting, shearing and fracturing, the greater part of which took place before the formation of the lodes.

Jan 1, 1941

By M. R. TECK, N. Rudd, L. K. Thomas, D. L. Katz

The authors are to be congratulated for presenting the first comprehensive paper on the theory and practice of threshold pressure determination in connection with underground gas storage. It is of particular value since most previous experimental work on this subject has been proprietary to the commercial laboratories engaged in such testing and to their clients. This dlscussion is presented in amplification of the subject paper, not in criticism, and is based upon our experience with approximately 5,000 threshold pressure determinations. Our comments are directed primarily to the experimental procedures as described by Thomas et al. It should be noted that, while clay mineral-rich lithologies are the most common caprock materials, the samples used (Table 1) include low permeability sandstones and carbonates, but do not include shales or other formations in which clav minerals exert a dominant effect. While our experience on samples analogous to those investigated by the authors generally confirms their findings, we have found that even more rigorous experimental conditions must be imposed where clay minerals are the controlling factor. These additional conditions result from the well-known molecular character of the clay minerals themselves in which water is interlaminated with, and bonded to, silicate sheets, thus becoming an essential component of the molecule. In many clay minerals the character of the intersheet bonding, and thus the dimension of the lattice, is strongly affected by variations in the identity and concentration of cations present in the intersilicate water. On a supermolecular scale, adsorbed water films on particle or "flakes" of shale provide much of the cohesive force necessary to maintain mechanical strength. The thickness of these films is variable and inversely proportional to intergranular pressure within the dimensional limits involved in caprock investigation. The thickness of the intersilicate water layers may also be subject to pressure under some conditions. These considerations are reflected in several necessary modifications of the experimental procedures described by the authors. Two of these are, in our judgment and experience, of such importance that they cast real doubt on the validity of data obtained on argillaceous materials without their application. The very careful resaturation procedures proposed by the authors should give good results in connection with the relatively "inert" lithologies used in their experiments. Our experience suggests, however, that they would create more problems than they would eliminate if applied to argillaceous materials. 1. Drying of the sample at the temperature and for the duration indicated by the authors not only will dessicate the sample with consequent shrinkage cracking, parting along bedding planes, and even total disassociation in the case of fissile shales, but it may also alter the character of the clay minerals themselves — in some cases irreversibly. 2. Prolonged evacuation to 2 microns Hg further dessicates the sample and is even more effective in reducing the intersilicate water content. 3. Resaturation with water differing in pH or chemical content from that existing originally in the sample also serves to alter the nature of the sample, particularly its structure and strength. 4. Our experience has been that, even with the thorough precautions proposed by the authors, complete resaturation of very fine grained materials is rarely obtained. Yet our experience confirms the

Jan 1, 1969

By H Matsuno, N Oyama, T Yamamoto, K Nakajima, Y Iwami, N Saito

Recently, the quality of sinter feed ore used in sintering process has deteriorated. In particular, Fe has decreased and gangue component has increased in the sinter feed ore. Increase of gangue is not only the factor to influence sinter qualities, but also the factor to increase coke ratio in the blast furnace operation as the increase of slag ratio. Therefore, to cope with the deterioration of iron ore qualities, studies on alternative iron ore resources and development of its utilisation technology have been required.In that kind of new iron ore resources, authors focus on high-grade magnetite fine. High-grade magnetite fine decreases sinter productivity by the decrease of permeability of sintering bed. Therefore a new study for using large amount of magnetite fine is required. In the past, there are some studies about the effect of mixing ratio and size of magnetite fine on productivity and quality, but there are few studies about magnetite fine segregation in charging.In this research, the melting behaviour and interfacial reaction calcium-ferrite, which has important role as bonding agent among iron ores, melts into hematite substrate and magnetite substrate was studied. As the results, it was defined that upper segregation of high-grade magnetite fine is suitable for productivity of sintered ore. Based on this knowledge, the control method of high-grade magnetite fine segregation by magnetic force at charging was studied with DEM (discrete element method) and its verification experiments for magnetic segregation control was conducted in the laboratory.CITATION:Iwami, Y, Yamamoto, T, Oyama, N, Matsuno, H, Saito, N and Nakajima, K, 2017. Improvement of sinter productivity by control of magnetite ore segregation in sintering bed, in Proceedings Iron Ore 2017, pp 61–68 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 24, 2017

CrusherMapperTM - A New Tool for Crusher Condition Monitoring The efficiency of mineral processing plants is entirely dependent on the availability of the plant equipment critical path. This typically concerns comminution circuits consisting of primary crushers and primary grinding mills. Crusher and mill availability are determined by the frequency and duration of maintenance shutdowns, which are primarily driven by the need for replacement of sacrificial liners. The change of crusher and mill liner shape over respective life cycles also strongly affects plant efficiency. It is therefore highly desirable to accurately monitor the condition of mills and crushers in order to optimise plant efficiency through maximised availability and targeted liner shape. Traditional comminution liner and other production parameter condition monitoring has been attempted through ineffective methods which prevent satisfactory management of crusher and mill maintenance and reduce operational control. This situation has recently dramatically improved for grinding mills through the development and commercial deployment of MillMapperÖ, a technology based on three-dimensional laser scanning data and dedicated software (Franke, Lichti and Stewart, 2006; Franke and Lichti, 2007; 2008; Franke, 2008; Franke, Redman, Johnson and Michalek, 2009). At the time of writing in late 2009, MillMapperÖ is in successful use at a rate of approximately 170 surveys and associated reports per annum at processing plants in Australasia, South America, North America and Africa. This paper presents the introduction of CrusherMapperÖ, the MillMapperÖ equivalent for crushers. CrusherMapperÖ also utilises high density, high accuracy laser scanning data, and features dedicated algorithms for three-dimensional monitoring of wear on crusher concaves and mantles. This facilitates the detection of wear hot spots or zones or localised liner failures, and accurate forecasting of reline tonnages and dates. It also for the first time provides the means to establish optimised concave and mantle shapes in order to achieve production targets. In contrast to any other currently utilised condition monitoring method, CrusherMapperÖ data collection can occur remotely and does not require any shutdown or crusher isolation. This method therefore does not interrupt crusher production while at the same time eliminating any confined space risk normally associated with taking measurements inside the crusher cavity.

Sep 13, 2010

By L. S. Hansen

Organized efforts toward the prevention of injuries and occupational diseases have been of comparatively recent origin in the mining industry, dating generally from the beginning of this century. Mining-and particularly underground mining- is more hazardous in many respects than most other major industries, and continual and increasing attention has been given to its health and safety aspects. The importance of the physical well-being of those engaged in mining was recognized by Agricola, who, after describing the hazards encountered in 16th century mining operations, stated that "Some of these evils, as well as certain other things, are the reason why pits are occasionally abandoned." In the past 50 yr particularly, mine managements and labor organizations, separately or collectively, have mounted productive efforts toward the prevention of accidents and industry-associated diseases and illnesses. A statistical study of this period indicates that increasing awareness coupled with the endeavors of all concerned agencies has resulted in decreasing frequency of occurrences of injuries and illnesses. In recent years particularly the mining industry has used the services of safety engineers, industrial hygienists, inspectors, ventilation engineers and other specializing in locating and correcting deficiencies affecting the welfare of employees. Concurrently, the labor movement has incorporated into its organization individuals working in the fields of health and safety, many devoting full time to these responsibilities. Others serve in behalf of their fellow workmen as on-the-job safety representatives. Most authorities agree that accidents are caused by (1) unsafe acts, (2) unsafe conditions and, exceptionally, (3) Acts of God. The "unsafe act" often is cited as the prime cause. but many accidents, and attendant injuries, are the result of a blend of "unsafe acts" and "unsafe conditions," with each chargeable in varying proportions. It therefore is necessary to consider both the physical elements of the mine plant and the training, mental attributes and actions of all personnel involved. Analysis of an accident, if based on hasty reconnaissance and unduly hurried questioning, seldom will disclose more than surface causes and consequently will result in inadequate measures to prevent repetition. Mining involves unavoidable and calculated risks, as in all facets of life. It is most important then that men employed in mining be schooled in the hazards and develop fully the ability to evaluate and minimize risks. The environment, of underground mining often is harsh and strange compared to the more natural surface conditions man has learned to cope with as a part of established life patterns. The miner. therefore, must adapt to unusual situations and conditions and must develop a mental attitude permitting acceptance of change. 3.1-INDUSTRY-AFFILIATED SAFETY AGENCIES L. S. HANSEN There are many organizations primarily interested in health and safety. In addition to industry and labor groups, there are many private and governmental

Jan 1, 1973

By F. D. Ford, Z. Dai

"Vale’s Ontario Operations re-introduced Cu/Ni separation at Clarabelle Mill in 2006. The mill processes ores from a number of mines in the Sudbury basin. A saleable Cu concentrate is produced at 30-60% Cu recovery from mill feed, which has to meet the quality specification. In particular, Ni content in Cu concentrate must be less than 0.6%, otherwise, penalties will apply and diminish the value of Cu concentrate, in addition to the lost Ni value. Generally, a Ni grade of less than 0.4% is obtained in Cu concentrate. More recently, while processing Cu-rich ore, Cu concentrate contained more than 0.6% Ni which is abnormally high. Detailed mineralogical investigation shows that Cu-rich ore contains more millerite in comparison to typical Sudbury Ni sulphide ore. Millerite is found to be more floatable than pentlandite and is much more difficult to depress using high-lime aeration conditioning, which is the standard practice in Cu/Ni separation to float chalcopyrite while depressing pentlandite. The current operation uses sodium cyanide at 20 g/t to depress pentlandite and pyrrhotite. However, it is found that a high dosage is required to depress millerite. It is also shown that starch and dextrin are promising in millerite depression.INTRODUCTIONPrior to bulk smelting in 1991, Cu/Ni separation was carried out at Vale’s Copper Cliff Mill, Ontario Operation. The typical Cu concentrate grade was around 30% Cu and 1% Ni. This is very high in comparison to today’s value of 0.4% Ni and would not be acceptable for external processing. However, the Cu concentrate was processed internally at the Copper Cliff smelter/refinery, so the Ni contained in Cu concentrate was not lost and no actual penalties applied. During the SO2 abatement initiative, bulk smelting was chosen because of the perceived simplicity and consequently, Cu/Ni separation was eliminated (Agar, 1991) and the Copper Cliff mill was subsequently demolished. In 2005 and after more than one decade of bulk smelting, business changes required the removal of some Cu concentrate from Clarabelle Mill bulk concentrate to provide smelter capacity for Voisey’s Bay concentrate in the Copper Cliff smelter. In essence, this strategy calls for Cu removal at Clarabelle Mill (Lawson, 2006). In this case, Cu concentrate is sold externally and it must meet the quality requirement of less than 0.6% Ni."

Jan 1, 2011

By Lloyd Williams

1. The investigation shows that the Poplar Creek and Big Mary beds contain the largest known recoverable reserves of coal in Morgan County, Tenn. The Poplar Creek bed has been the most productive. 2. Known measured and indicated reserves of coal, based on a minimum bed thickness of 14 inches and on 1,800 short tons per acre-foot of coal in place, are estimated to be 96 million tons, as of January 1, 1954. Of this total, 59 million tons is in beds 28 inches and more thick. Areas in each bed were omitted from the estimate because available data relative to the bed characteristics were too meager to make an estimate that conforms with the definitions of measured and indicated coal adopted for this study. Should future drilling or development prove reserves in these areas, such reserves should be added to the total estimated reserves.

Jan 1, 1956

By A. Eslami

In recent development of piled raft design, the contribution of both raft and piles to tolerate the loads is taken into account, depending on the stiffness and contributions of involved elements i.e.; piles, raft and surrounding soil. The piles are usually required not to ensure the overall stability of the foundation but to act as settlement reducers. One alternative method of foundation design is therefore to introduce piles purely as a means of improving or enhancing the stiffness of the base soil by structurally disconnecting the piles from the raft. In this paper, two and three dimensional finite element analysis of disconnected pile-raft systems are performed on three case studies including a 12-storey residential building in Iran, a 39-storey twin tower in Indonesia, and the 256m height of Messeturm tower in Frankfurt, Germany. The analysis include different geometrical parameters, e.g., pile spacing and embedment length, arrangement and raft thickness for foundation system to obtain the optimized design functions and to clarify the role of each parameter and method of analysis. The parametric study results and comparison to a few field measurements indicate that by concentrating the piles in the central area of the raft foundation leads to the optimum design with the minimum total length of piles. This achievement can be considered as a criterion for project cost efficiency. On the other hand, disconnected piled-raft systems can significantly reduce the settlements and raft internal bending moments. Finally, the comparison indicates that simple and faster 2D analysis has almost the identical results to 3D analysis which is complicated and time consuming.

Jan 1, 2008

By F. P. Haver

Primary lead is produced in the United States by the pyrometallurgical smelting of lead sulfide (galena, PbS) concentrates, which poses sulfur dioxide and lead air pollution control problems. The Federal Bureau of Mines has investigated an alternative hydrometallurgy procedure that does not generate gaseous sulfur oxides and diminishes the potential for the escape of lead into the atmosphere. The procedure involves leaching galena flotation concentrates with ferric chloride (FeC13) solution to obtain lead chloride (PbC12) and elemental sulfur as expressed by the following chemical reaction: PbS + 2FeC13 ? PbC12 + 2FeCl2 + S°. At 100° C, over 99 pct of the PbS in the concentrate is converted to PbCl2 in less than 15 min. The leach solution, composed of brine (NaCl) containing slightly more than the theoretical required amount of FeC13, dissolves the PbC12 as it is formed, leaving a residue of elemental sulfur plus gangue. High-purity PbC12 (>99.9 pct) crystallizes from the leach filtrate on cooling and is electrolyzed in a low-temperature, fused-salt cell to obtain corroding-grade metal (>99.94 pct Pb). Spent leach solution (FeC12) is regenerated for further use by reaction with the chlorine obtained in the electrolysis of lead chloride. Other values, such as Ag, Cu, Zn, and S°, are recovered by additional treatment of either the leach solution or leach residue.

Jan 1, 1976

By P. P. Sinha, D. N. Bhatia, B. R. Ghosh, R. K. Gupta

Medium carbon, low alloy, high-strength steels containing Ni, Cr, and Mo are used for the fabrication of various types of high-strength fasteners required for launch vehicle structures. Cold heading properties and response to hardening and tempering are the essential requirements of the material for fabrication and application, respectively. Combining these two requirements is essentially warranted in high-strength fastener-grade steels. Cold heading properties require ductility, which can be achieved through spheroidizing treatments. In the absence of a suitable spheroidizing cycle for medium carbon 3.8 Ni, 1.8 Cr, 0.3 Mo steel, experiments were carried out with a theoretical understanding of the alloy system. This paper presents the experiments and results obtained after a spheroidizing treatment, which was carried out to optimize the process. Hardness measurements were carried out and microstructural studies were conducted to assess the spheroidization process and to determine the optimal spheroidization parameters.

Jan 1, 2007