Search Documents

By M. A. Barakat

"Adsorption of heavy metal ions specifically, Cu(II), Zn(II), Mn(II), and Cr(VI) from aqueous solution on synthetic 4A Zeolite was evaluated. The 4A zeolite was synthesized previously by dehydroxylation of low grade Kalabsha Kaolin at 800 °C, and reacted hydrothermally with 2-4 M NaOH solution at 100 °C for 2h. The adsorption capacity of the metal ions were found to be strongly dependent on pH and initial metal ion concentration. At the optimium conditions the adsorption capacity decreased in the order Cu(II) > Zn(II) > Mn(II) > Cr(VI) ions. Almost complete adsorption was achieved for both of Cu(II) and Zn(II) ions at pH > 6, while the adsorption capacity for both Mn(II) and Cr(VI) was 96, and 55.3 % at pH 11 and pH 3, respectively. The results also showed that the grain size of the 4A zeolite has a little effect on the adsorption capacity. The experimental data was compared with two adsorption isotherms, Langmuir and Freundlich isotheroms. The results showed a good agreement of the Langmuir plots with the experimental data.1. IntroductionSeveral industrial wastewater streams may contain heavy metals such as Cr, Cu, Pb, Zn, Co, Ni, Mn, etc. including the waste liquids generated by metal finishing or the mineral processing industries. Heavy metals are considered hazardous pollutants due to their toxicity, even at low concentration, and nonbiodegradability. Increasing level of heavy metals in natural water bodies poses a serious threat to all living species including humans. It is, therefore, essential to reduce the heavy metal concentration in effluents/wastewater before it is discharged into the water bodies [1]."

Jan 1, 2008

By Olga Frank-Kamenetskaya

The experimental results of study of atmospheric corrosion processes on Saint-Petersburg bronze monuments surface, received in situ and by means of simulating experiments, have been discussed. Influence of the time factor on corrosion film (patina) mineral composition has been analyzed. Direct dependence between patina mineral composition and environmental conditions has been proved. The sequence of patina phases crystallization has been established. Effect of the chemical composition and heterogeneity of artistic bronze and also monument surface structure on the rate of corrosion process has been regarded. The time variations of mass of the crystallized in the hydrochloric acid vapor phases have been investigated. The kinetic laws of their development at the initial stage of formation, indicating simple (non chain) reactions, have been revealed.

Jan 1, 2006

By Y. Zhoa

The surface morphology of materials is of fundamental importance to many surface related applications, such as wetting, friction, reflection, drag, and adhesion. Various approaches for micro/nano patterning atop polymer surfaces have been proposed in recent years. However, a cost effective technique is still highly in demand. In this paper, we demonstrate a novel but rather simple and generic approach for surface micro/nano patterning using shape memory polymers (SMPs). Different types of novel patterns are realized and their 3-D surface features are quantitatively analyzed by a PLµ Confocal imaging profiler.

Jan 1, 2010

By Marilia S. de Magalhaes

Keywords: sinter, characterization, agglomeration, iron ore Iron ore sinters are the main burden of blast furnaces for pig iron production. The evaluation of these agglomerates is very important due to their properties affect indirectly the productivity and costs of production of the steel industry. In the sintering plants, the standard procedure of sinter assessment has been carried out by particle size control, bulk chemical analyses, tumbler and/or shatter tests and determination of reduction degradation and reducibility indexes. Microscopy techniques have just been applied to characterize sinters produced in pilot conditions, however, these techniques, the classical ones and the less traditional, allow enhancing the industrial sintering process assessment. For investigation of the phases, microstructures and fabric, reflected-light and scanning electron microscopy(backscattered electrons images) were used; for micro analytical chemical examination, energy-dispersive X-ray spectrometry; for Kikuchi patterns registers, electron backscattering diffraction. In addition to the microscopy techniques, the magnetic behavior was depicted by means of magnetic susceptibility measurements. Iron ore sinters are made up by hematite, magnetite, silicoferrite of calcium and aluminium and silicates. These phases develop either during sintering or, in some proportion, represent remnants of ores and fluxes; this is the case of some hematite and Mg-bearing silicate, respectively. From the magnetic susceptibility results, three different behaviors were determined, which are directly related to the magnetiteproportion in the samples. The phase association and proportion, the sintering conditions andthe quality assessment are some features appraised by such procedures, which reveal themagnitude of this proposal in sintering plants.

Jan 1, 2005

By Wen-Ming Chien

Keywords: AN-KN Phase Transition, Lattice Parameters of AN-KN, X-ray Diffraction The lattice parameters of the low and high temperature phase of KNO3-rich (in NH4NO3) solid solutions have been determined by the X-ray diffraction method. The low temperature single KNO3 phase (KN II) are from 92%-100% KNO3 in NH4NO3 composition range and from room temperature to 393 K showing in X-ray diffraction patterns. The high temperature KNO3 phase (KN I) showed very broad composition range between 20% to 100% KNO3. The lattice parameters of KNO3-rich (KN II and KN I) solid solutions have been calculated at different temperature range. The volumes of orthorhombic KN II phase decrease from 0.3208(3) to 0.3195(3) nm³ at the room temperature as the compositions increase from 95% to 100% KNO3. The lattice constants of the hexagonal KN I phase show that there is no significant change in a-direction when the temperature increases. Details X-ray results and lattice expansion equations during heating will be presented.

Jan 1, 2005

By Liang Sha

In this study, adsorption of copper by chemically modified orange peel was investigated. A conspicuous change occurs in the surface morphology of the biomass due to modification, which is depicted by SEM images. Equilibrium isotherms and kinetics were obtained and the effects of various factors, including solution pH, contact time, initial metal ions concentration and temperature, were studied by batch experiments. Kinetics was found to be best-fit pseudosecond- order equations. Equilibrium was better described by Langermuir isotherms rather than Freudlich isotherms. At 25?, pH5.30, the maximum adsorption capacity was 70.67mg?g-1 . With increase of temperature, adsorption efficiency decreased. The biosorbent was suitable for repeated use for more than five cycles.

Jan 1, 2009

By Pengfu Tan

Xstrata Copper at Mount Isa in Australia has operated one copper Isasmelt furnace and four P-S converters. The phenomena of foaming occur in above 10% of converter operations. A thermodynamic model of copper P-S converter and a viscosity model of converter slag have been developed to simulate the slag blow and copper blow. The model predicts the chemistry and viscosity of copper skims during copper blow. The effects of oxygen potential, charge of dirty materials, slag carry-over, under-blowing, over-blowing, and temperature on the foaming and viscosity of copper skims have been discussed. Some improvements of the industrial operations have been presented.

Jan 1, 2006

By S. Prasad

The effectiveness of ultrasonic velocity measurements and attenuation of the propagating pulse was evaluated as a means of Non-Destructive characterization of cold worked and annealed copper. Commercial copper is subjected to mechanical working such as forging, rolling and thermal treatment to induce re-crystallization. The microstructural changes that occur in copper and a variation in its mechanical properties are subjected to analysis using the ultrasonic technique. The signal processing is carried out using the wavelet analysis technique. The features of wavelet analysis namely, localization in space and the presence of an infinite set of basis functions allows removing noise from the time series and components of a non-stationary signal to be analyzed. This is seen to improve the accuracy of the results obtained from the ultrasonic technique in the case of copper, which has distinct coarse grains that are difficult to inspect due to backscattering from the grain boundaries.

Jan 1, 2010

By Sergio Neves Monteiro

In the present work, a ceramic foam elaborated with illitic clays was characterized. Properties related to density and compression strength were determined in samples fired at 1300oC, a temperature that permits the clay structure to generate and retain gases that will produce the foamy structure. The microstructure of the ceramic foam was studied by X-ray diffraction, scanning electron microscopy and mercury porosimetry. The results showed that the ceramic foam presents a bulk density of 0.38 g/cm3. The microstructure is formed by large open pores, quartz particles and vitreous phase.

Jan 1, 2006

By Tianjiao Luo

Some literatures discussed on how to recycle the various reagent, but the discussion on how to reuse the waste liquid directly is very little. How to reuse the waste liquid directly was researched in this paper. Firstly, the waste liquid should be filtrated to remove the impurity; then some quantity of H2O2 solution was dripped into the waste liquid to pretreat it; finally, CuSO4solution was added into the treated waste liquid and the pH was adjusted to about 12, then some HCHO solution was added into the waste liquid, in which the treated carbon fiber can be plated. The morphology and composition of coatings were investigated by means of Scanning Electron Microscopy (SEM) and Energy Dispersive X-ray Spectroscopy (EDS), the deposition rate was mensurated by the way of dissolution. The results indicated that, the plating effect was basically identical with new plating solution, and the solution is stable, and the plating rate is still about 0.8µm/h, and the copper coating is even and combines closely with carbon fiber. According to this way, the waste liquid can be reuse 5~7 times.

Jan 1, 2006

By Hugo Cabrera-Real

This work investigated the chemical and mineralogical properties of CaO-SiO2-CrOx-CaF2- MgO slags. Synthetic slags were prepared and the effect of the slag basicity (CaO/SiO2) and MgO contents on the stability of the mineralogical species formed was analyzed. The morphology and composition of the slags were analyzed by XRD and SEM-EDS, whilst their chemical stability was evaluated by leaching with an aqueous acetic acid solution. It was found that in slags with CaO/SiO2 = 1, the main Cr-compound was MgCr2O4 spinel, which forms octahedron crystals. Small amounts of CaCr2O4 and CaCrO4 were also observed. It was found that increasing the slag basicity from 1 to 2 the compounds MgCr2O4 and CaCr2O4 were formed together with the Cr(V)-containing compound complex Ca5(CrO4)3F which forms hexagonal crystals. The results showed that the highest chromium concentration levels in the leaching liquors corresponded to slags with CaO/SiO2 = 2, probably owing to the formation of Ca5(CrO4)3F.

Jan 1, 2010

By Qingwei Wang

This study focused on acidic wastewater from producing sulfuric acid system in zinc smelter containing mercury 21.48mg/L, zinc 55.85mg/L, lead 38.50mg/L, copper 1.68mg/L, cadmium 10.25mg/L, As 29.86mg/L treated by biologics. The factors of pH value, the ratio of biologics to mercury, complexing time, hydrolytic time and temperature were studied in this paper. Experimental results indicated that at pH value 10, quantity of biologics to mercury ratio was 16, complexing time 30min, hydrolyzation time 20min, temperature at 40?, concentration of mercury in treated water was removed to 22.15µg/L. At same time heavy metals such as Zn, Pb, Cu, Cd, As was removed by biologics, the remained concentration in treated water was Zn 0.53mg/L, Pb 0.12mg/L, Cu 0.01mg/L, Cd low to 0.01mg/L and As 0.023mg/L. According to EDAX analysis, mercury content in complexing sediment reached 28.49% easily to recycle as raw material and low concentration of heavy metals in hydrolytic sediment easily to dispose and treat.

Jan 1, 2009

By Othon do Rêgo Monteiro Neto

[The present study has investigated the extraction of copper from a chalcopyrite flotation concentrate using an adapted strain of Thiobacillus ferrooxidans and shake flasks, tank leaching and Warburg respirometer techniques. From the shake flask experiments, the activation energy and the frequency factor have been determined to be ?ka = 59.4 kJ and A = 3.3 x 105 S-1, respectively. The temperature coefficient was found to be Q10 = 2.2 in the range of 20 to 35°C. It was suggested that the reaction mechanism of chalcopyrite leaching by T. ferrooxidans involves the formation of an activated complex. whose thermodynamic values have been calculated to be ?G? = 92.1 kJ, ?S? -148.8 J K-1 and ?H$ = 47.8 kJ. The maximum volumetric oxygen mass transfer coefficient for the reactor leaching was found to be achieved by using an optimum air flow rate of 1970 cm min l at a rotational frequency of 1000 min-1. The highest copper extraction in tank (reactor) leaching experiment was 86.8% after 17 days of leaching, while in the sterile runs the corresponding copper extraction was only 40.1%. The copper extraction was suggested to be diffusion controlled. The power requirement of the aerated reactor was calculated to be Pg = 2.02 watts. During leaching, the oxygen saturation concentration was found to be C* = 6.70 mg dm-3. Using the gassing out method the critical oxygen concentration was assessed to be CCrit 0.05 mg dm 3. From the Warburg experiments, the kinetic parameters of the Monad equation were derived with a new evaluation technique to be Vmsp = 9.0 µm3 02 min-1 mg protein-1 and K = 7.4% pulp density for the effect of substrate concentration. The order of reaction and the overall reaction rate constant were determined from the modified van't Hoff plot to be n = 0.0 and k = 1.49 p dm3 02 min-1 mg Protein -1 for the chalcopyrite concentrate oxidation by T. ferrooxidans. On the basis of this experimental work, a preliminary flow sheet has been proposed for the bioextraction of copper from flotation concentrates.]

Jan 1, 1985

By M. Potesser

One of the main targets in the automotive mass industry and supplying industry is the weight reduction of the vehicle for decrease of the fuel consumption. For that reason combinations of different kinds of materials and connections of, for example, steel and aluminium are developed or are already successfully field-tested. A determining factor concerning the quality assessment of the welded joint during hybrid welding is the characterization of the intermetallic Fe-Al layer regarding strength, hardness, morphology and mainly the different phases in which Fe occurs together with the Aluminum (FeAl, Fe2Al5, FeAl3.). A combination of conventional light microscopy, SEM - EDX - analysis, the usage of an atomic force microscope including a Nanoindenter and theoretical thermodynamic calculations turned out to be highly effective. Based on the attained results, the constitution of the intermetallic FeAl layer, influenced by silicon, manganese and zinc, can be predicted.

Jan 1, 2006

By S. N. Lekakh

Phosphorous segregated at grain boundaries during solidification and heat treatment dramatically decreases low temperature toughness of precipitation hardened Fe-Mn-Al-C austenitic steel. A thermodynamic analysis was performed to evaluate the possibility of decreasing P and subsequent segregation by Ca- and Ce-additives in the melt. It was shown that the predicted probability of forming a P containing compounds depends on melt composition and treatment sequence. Experimental heats were performed and several micro- and macro-structural effects of Ca- and Ce-additives were recognized by using an automated inclusion analysis technique.

Jan 1, 2010

By WU Jian-hui

Keywords: metallic material; nickel powder; thermal decomposition; precursor; fibrillar powder; nanometer scale; passivation treatment The precursor thermal decomposition process of fibrillar nanometer scale nickel powder and passivation treatment of obtained powder are investigated, and the composition and morphology of the products are characterized by use of IR, TGA/DTA, XRD and SEM. The results show that the precursor morphology is a decisive factor to the product morphology of the nickel powder. The morphology of the product derived at low decomposing temperature is irregular. The nickel powders produced at the temperature higher than 480 coheres seriously. The product particles are reunited with the decomposition time prolong. The powder prepared under the optimal condition is fibrillar like woolen yarn; the grain diameter is less than 50nm.

Jan 1, 2005

By Neil E. Ryan

Because of their chemical reactivity and affinity for oxygen, rare-earth elements are difficult to extract, and due to their close chemical similarity, it is an exacting task to separate one from the other. Nevertheless, these same characteristics can be used to benefit other metals by enhancing their resistance to high-temperture oxidation/corrosion and by inhibiting their corrosion in aqueous environments. This paper gives an overview of the use of rare-earths: [a] as alloy additions, [b] in coatings, and [c] when added to hostile environments, to retard rates of high- temperature oxidation and inhibit aqueous corrosion.

Jan 1, 1992

By Alicia Esther Ares

The family of Zn-Al (ZA), Zn-Ag and Zn-Al-Ag (ZINAG) alloys offers high mechanical properties, ease of finishing, the advantage of low energy and pollution-free melting. Also, present alternatives to the well developed alloy systems, such as brasses, bronzes, cast irons and aluminum alloys. The main objective of this paper is to measure thermal parameters in ZA, Zn-Ag and ZINAG hypoeutectic and hypereutectic alloys directionally solidified which present columnar, equiaxed and columnar to equiaxed transition structures (CET). Also, estimate the mechanical properties, such as microhardness and tensile parameters and correlate these with the thermal (cooling rate) and structural parameters (grain size and dendritic spacing). The different types of structures were analyzed with optical and scanning electron microscopy. The results showed the influence of concentration, microstructural arrangement and thermal conditions during solidification on the mechanical properties. The results of the present investigation are compared with previous experiments.

Jan 1, 2010

By S. Uddin

An integrated device has been developed to measure sedimentation potential, conductivity and pH simultaneously of particulate systems. Maxwell?s model was used to calculate volume fraction of solid from the conductivity data. In this approach, all system variables are known and zeta potential can be calculated from Smoluchowski?s equation. The technique is validated by comparing zeta potential vs. pH for alumina and silica suspensions with electrophoresis measurements. The technique was extended to mixed alumina/silica systems. Sufficient column height along with size difference between the two minerals allowed gravity fractionation during settling. Sedimentation potential measured over time identified the transition from one mineral to the next. Using XRD analysis the results supported the correlation between surface charge and sample composition. This is a step towards characterizing surface charge of mixed systems of interest in mineral processing.

Jan 1, 2010

By Jae R. Lee

Keywords: Self-propagating high temperature synthesis, AlN, Powder synthesis The particle size and shape effects of starting raw powders on the synthesis of aluminum nitride by self-propagating high temperature technique under high nitrogen pressure were investigated with various AlN diluents and Al reactants. It was found that the structure of beds of the starting raw particles largely affected the pore channels for nitrogen gas infiltration as well as the passages for combustion propagation before and during the reaction, resulting in the morphology and purity changes of the synthesized products. The AlN product of purity over 98% with about 30 microns was obtained.

Jan 1, 2005