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By P. Shang

Fly ash and zeolite have strong absorption to cations since their porous microstructure. The porosities of fly ash and zeolite can also be increased by modification, which improves the absorption of the materials. This research showed that the effects of modified fly ash and zeolite to remove ammonia nitrogen from rainwater. The optimal reaction time, additive amount of materials, and pH value of the stormwater to remove ammonia nitrogen were experimentally determined. For modified fly ash, the optimal removal rate of ammonia nitrogen from 100 ml stormwater was 74.41% with the addition of 10.0g fly ash, 1.5 hours of the reaction time, and 8 of pH value. To the modified zeolite, the optimal removal rate of ammonia nitrogen was 51.22% at the reaction conditions of 2.0g of zeolite, 1 hour of reaction time, and 7 of pH value.

Jan 1, 2010

By R. E. Musgrove

At the present time Climax Uranium Company recovers vanadium oxide from carnotite type uranium ores in the mill at Grand Junction, Colorado, The flowsheet of this mill is shown in Figure I. Vanadium is solubilized by a salt roast of the slime fraction of the ore and dissolution is accomplished by a water leach. The metal is precipitated from the pregnant liquor as sodium polyvanadate by heating to boiling and adjusting the pH to 3 with sulfuric acid. The sodium polyvanadate, commonly called, "red caken, is filtered, melted, and cast into thin flakes. This fused flaked vanadium oxide is the material which is packaged for sale. Fused vanadium oxide, marketed by Climax, contains approximately 87% V205, 7% alkali oxide, 0.08% sulfur, 0.03% phosphorus, and less than 0.5% Insoluble. This material is of a lower grade and has a higher alkali oxide content than other vanadium products offered for sale at this time. A typical analysis of a high grade vanadium oxide currently offered for sale by another company is 98% V205, 1 - 2% alkali oxide, less than 0.05% sulfur and less than 0.2% Insoluble. The only reagent consumed in the precipitation of the sodium polyvanadate is sulphuric acid. The total reagent cost is 0.58 cents per pound of vanadium oxide produced.

Jan 1, 1958

By Mark R. Rybak, James Delmonte, Travis Hartman

The City of Phoenix, Arizona designed a 7.2 km (4.5 mi) long water transmission main from the South Mountain Reservoir to the Ahwatukee Foothills Reservoir to address the growing demand for drinking water in the southeast valley. The pipeline design called for a bored tunnel in a very environmentally sensitive area. The Reach3B contract included an 2.44 m (8 ft) diameter TBM excavated tunnel, 1,847 m(6,060 ft) in length. The geotechnical investigation revealed that the tunnel would likely pass through zones of loose to moderately cemented soils (caliche). The primary tunnel support would consist of rock bolts, circular steel ribs, hard wood lagging, and mine straps. A TBM that could handle the ground conditions and allow for efficient ground support installation was required. This paper describes the construction of a small diameter rock tunnel in challenging ground conditions.

Jan 1, 2003

By T. J. Smolik

The Golden Sunlight Mine started full-scale operations in February 1983, with a conventional open-pit mine supplying 4464 tonnes (5000 tons) per day of milling ore. After crushing and grinding, the ore is leached with cyanide solution in large agitation tanks. Soluble gold values are removed from the sand portion of the leached ore with five stages of countercurrent washing cyclones. After thickening of the cyclone-wash overflow slurry, the gold is recovered in activated carbon with a six-stage carbon-in-pulp circuit and a five-stage upflow carbon column circuit. Pressure stripping, carbon reactivation, electro-winning and refining complete the gold recovery process.

Jan 1, 1984

By J. Snowberger III

Rhenium is a valuable and extremely rare chemical element with unique chemical properties. It is extracted commercially as a byproduct from the processing of molybdenite associated with porphyry copper ores. There is a present interest in recovering rhenium from copper pregnant leach solutions (PLS) produced by copper heap and stockpile leaching. These solutions contain rhenium at very dilute concentrations, typically in the 1 mg/L concentration range. This paper describes laboratory column ion exchange experiments to extract rhenium from these solutions using weakly basic anion exchange resins and actual plant PLS from two operating mines. The dynamic loading and elution behavior of Re on Purolite® A170 and A172 is discussed.

Feb 23, 2014

By R. J. Pugh

The surface chemical sites on several fillers (quartz, feldspar, calcite and granite) were studied by the adsorption of well defined acid and basic probe molecules (benzoic acid, benzyl alcohol, ethyl benzoate, pyridine and benzyl amine) from cyclohexane. The results provided a wide variation of adsorption data, emphasizing the extensive range of site heterogeneity on the filler surfaces. In addition, it was shown that the acidic probes were strongly adsorbed on all of the minerals, thus indicating that the basic surface sites dominate the acidic ones. Also, through FTIR studies with vapor-phase probes adsorbed on orthoclase, it was possible to identify the nature of specific sites and the type of bonding occurring between the filler surface and the probe molecule. These types of surface analytical techniques could give useful information for predicting the adsorption functional groups on dispersants, dyes, thickeners, etc. and could lead to enhanced interfacial bonding between the filler and the matrix.

Jan 1, 1993

By Louis M. Schlesinger

KMG Minerals, Inc., a mica-feldspar-quartz producer in Kings Mountain, N.C., uses about 50% of its plant's -200 mesh slimes to manufacture brick. However, the company is unable to market the remaining 50% of this fine mineral mixture. The NCSU Minerals Research Laboratory operated a pilot plant to process these slimes to produce an additional product. The process, consisting of blunging and hydraulic sizing, was designed to separate a kaolin-enriched -270 mesh product from the bulk of the coarser +270 mesh "grit" minerals. Size analysis showed that this product was 80% finer than 20 microns and 50% finer than 6 microns (in equivalent spherical diameter). An evaluation indicated that it is a hydrous aluminum silicate that might be suitable in the filler and extender markets for traffic paint, some types of plastics, joint cements, and dusting compounds. Because of its high viscosity, it will be difficult to use more than a small percentage in cast ceramic bodies. However, it might be possible to use up to 10% in extruded ceramic bodies (i.e., electrical porcelain). The 15.2 cm (6 in,) diameter Linatex Hydrosizer was tested using a range of teeter water flowrates, so that the net rise velocity was varied from 0.10 cm/s to 0.40 cm/s. The solid feed rate to the sizer was maintained at approximately 1.1 t/hr/m2 (0.12 ton/hr/ft2). Tests were run using both "shallow" (i.e., 6 in.) and "deep" (i.e., 15 in. teetered beds. The best overall result was obtained when the sizer was operated with the "deep" teeter bed and a net rise velocity of 0.10 cm/s. About 97% of the +270 mesh material was rejected and approximately 79% of the -270 mesh material was recovered in a 14% solids slurry.

Jan 1, 1994

By G. B. Amicucci

A Denver Autometrics Particle Size Monitor, PSM-400, was installed at Golden Sunlight Mines, Inc. in October 1988. The PSM-400 measures the grind product's particle size and percent solids. The particle size is used to control grind size by automatically adjusting mill feed rate. The PSM's continuous response to ore changes has improved grind product uniformity and mill throughput. Metallurgical testing has shown the PSM's accuracy to be +/-1 % + 150 µm (100 mesh).

Jan 1, 1991

By JIAQI JIN, Joe Milbourne, Maoming Fan

Gold is very important to support the financial system, and to be used in industries of the jewelry, high-tech fields such as electronics and aerospace, etc. Gold is mainly extracted from three types of ores: primary ore (vein gold), placer (alluvial gold) and associated ore. Cyanide was widely used in gold ore flotation to depress gangue minerals and leaching/cyanidation. The process of extracting gold from gold ore, its separation and flotation concentrate, specifically through a technique called cyanidation or cyanide leaching. This method, which has been dominant since the 1970s, utilizes a dilute solution of cyanide to dissolve gold from the ore. While effective, the use of cyanide raises environmental and safety concerns due to its high toxicity. Cyanide spills can have severe environmental consequences. This has led to the exploration of alternative, environmentally friendly reagents. This paper discusses processing results using the alternative flotation depressants such as sodium sulfite (Na2SO3), etc. to produce a goldrich flotation concentrate for sale to a smelter or as feed to an alternative leaching agent. and methods to extract gold from ore without relying on cyanide.

Feb 22, 2026

By R. A. Wyman

"The froth flotation process was patented by E.L. Sulman, H.F.K. Pickard, and John Ballot in 1906 . . . . . . . . . .James M. Hyde installed the first froth flotation process in the U.S., about August 1, 1911, at the Basin Reduction Co. plant, Basin, Montana . . . . . . . . . .By 1914, 42 mining companies were operating or experimenting with the flotation process . . . . . . . . . .The period 1930 to 1960 saw the application of flotation spread to nonsulphide ores and become the key factor in the economic production of many industrial minerals". So states FROTH FLOTATION, 50th Anniversary Volume, published by AIME in 1962. It is interesting, to observe that the Mines Branch, now part of the Canadian Department of Energy, Mines and Resources, was established in 1907 through an act of Parliament entitled, "The Nines and Geology Act". In 1911, a mineral dressing group was formed and a laboratory was constructed. By 1921, an engineer was devoting full time to industrial mineral processing problems.

Jan 1, 1971

By R. C. Bunge

A magnetogravimetric separation is the consequence of two competing forces with opposing directions, i.e., magnetic buoyancy and gravitation (or centrifugal force). While magnetic buoyancy is a function of particle volume, gravitational force depends on particle mass, thus permitting a separation according to specific gravity. Since magnetic buoyancy is not a phenomenon of common knowledge, this chapter is meant to briefly introduce the theory of magnetogravimetric separations. A particle that is suspended in a magnetic fluid which is exposed to an inhomogeneous magnetic field experiences a repulsive force -the so called magnetic buoyancy. In order to illustrate this effect, an analogy with the more familiar hydrostatic buoyancy is drawn. Hydrostatic buoyancy occurs due to unsymmetrical pressure distribution 'above' and 'below' a suspended particle (fig. 1).

Jan 1, 1990

By G. G. O. O. Uwadiale, M. A. U. Nwoke

The flotation of Azara barite tailings was investigated using crude rubber nut oil (RNOc), refined rubber nut oil (RNOR) and oleic acid as fatty acid collectors. Chemical characterization of the rubber nut oils indicated high acidity, high saponification values and high iodine indexes, which are indicative of a high fatty acid compositions. The Azara barite tailings analyzed 64.6% BaSO4 by atomic absorption spectrophotometry. Gravity and magnetic separation techniques yielded a BaSO4 concentrate with a grade of 74.8% and a recovery of 92.5%. Barium sulfate grades of 90.0%, 92.8% and 94.8% with recoveries of 80.3%, 85.4% and 86.7% were achieved with collector dosages of 750g/t crude rubber nut oils, refined rubber nut oils and oleic acid, respectively. Hence, rubber nut oils are effective fatty acid collectors for the flotation of barite tailings.

Jan 1, 1998

By Keith Whitworth

The USSR, over the last 20 years, has continued to increase its out-put year by year and it is now almost four times what it was at the end of the Second World War. In 1975, it exceeded 700 million tons of run-oi-mine coal (all ranks) which amounts to over 20 percent of world output. This rapid progress has been due to modernization of the industry, by means of increased mechanization and automation and the development of new machines and systems for underground workings and by the expansion of open-pit workings and the development and implementation of larger earthmoving machines.

Jan 1, 1977

By D. E. Hinkle

Past surface-mining operations in Appalachia primarily followed mountain con-tours. It is estimated that about 18,000 mi. of highwalls are exposed throughout Appalachia. An evaluation procedure for determining the secondary mining potential (SMP) of these highwalls has been proposed. Sixteen parameters affecting the SMP were isolated. These are grouped in four major categories: geologic conditions, existing infrastructure, site conditions, and environmental conditions. The parameters were then ranked by their impact on SMP and assigned weighting factors. A simple mathematical procedure yields an SMP number (0 < SMP < 100), which may then be used to compare alternative sites and technologies. Determination of limits and ranges while grouping data was aided by field visits to over 40 exposed highwalls in Eastern Kentucky. An interactive program has been developed to rapidly evaluate the SMP for pre-mined sites. The mathematical procedure estimates the relative potential (i.e., techno-logical feasibility) for remining for three predominant secondary mining methods: augering, Hi-wall mining, and underground mining. Other secondary mining methods are briefly reviewed and compared.

Jan 1, 1989

By Ulrich Maidl, Marc Comulada, Janosch Stascheit

"INTRODUCTION Cohesive soils are notorious for causing clogging of the cutter head and the excavation chamber of tunnel boring machines (TBMs). While clogging leads to a drastic reduction in excavation performance, it further induces higher wear of tools and other parts of the cutter head and may even prevent a controlled support of the tunnel face and, thus, lead to face collapse and excess settlements or sinkholes. Employing well-balanced soil conditioning techniques, the clogging tendency can be significantly reduced. The monitoring and control of soil conditioning as well as the timely detection of potential clogging tendencies require a close monitoring of all relevant machine parameters and measurements. To this end, a reliable and powerful Process Controlling software that gathers all machine and process-related information is a prerequisite for successful mitigation of clogging-induced problems. The remainder of this contribution is organized as follows: First, a brief introduction to the Process Controlling system PROCON is given. Afterwards, the mechanisms and mitigation techniques of clogging are discussed. Finally, an example is given how Process Controlling has been employed to soil conditioning in a tunneling project with highly clogging soils.PROCESS CONTROLLING Being both the active part and a huge measuring device, the shield machine represents the core component in mechanized tunneling. This machine comprises a manifold of complex components and devices that require constant supervision and control and, thus, is equipped with a manifold of different sensors that provide a continuous monitoring of the state and condition of the machine (Maidl & Stascheit, 2014). If these data are put into the whole context of the tunneling process, they can provide insight to the assessment and optimization of the performance and to the prediction of potential risks and hazards such as, for example, the tendency of clogging of the cutter head."

Jan 1, 2016

By Hans G. Machel

In low-temperature diagenetic environments (0 c T c 60 - 80°C), elemental sulfur forms by six common processes: via (1) inorganic oxidation of H2S by molecular oxygen, (2) inorganic oxidation of H2S by ferric iron compounds, (3) polysulfide disproportion- ation; and via the microbial metabolic actions of (4) colorless sulfur bacteria, (5) colored sulfur bacteria, and (6) some types of thiobacilli. Economically viable deposits of native sulfur usually are formed by only one process: inorganic oxidation of H2S by molecular oxygen. The amount of elemental sulfur is also limited by three common processes that destroy it in low- temperature diagenetic environments: bacterial reduction, bacterial oxidation, and inorganic oxidation. In high-temperature diagenetic environments (80 - 10o°C c T c 150 - 200°C), particularly in sour gas reservoirs, there are seven common processes forming elemental sulfur: (1) SOdH2S reaction, (2) H2S- hydrocarbon reaction, (3) polysulfide disproportionation, (4) catalytic H2S decomposition, (5) C02-H2S reaction, (6) chlorinification, and (7) exsolution of physically dissolved elemental sulfur. Natural processes that destroy or remove elemental sulfur in such settings are hydrocarbon sulfurization, polysulfide formation, and advection. In most sour gas reservoirs, relatively small quantities of elemental sulfur occur as a free phase (solid or liquid). However, elemental sulfur often precipitates in copious amounts from the reservoir fluids via exsolution and polysulfide disproportionation during production of sour gas reservoirs. By extension, elemental sulfur may precipitate from reservoir fluids in relatively large quantities upon uplift and erosion of deep sour gas reservoirs, or from advection of sulfurous fluids into shallower settings via faults or other high-permeability pathways.

Jan 1, 1992

By R. Q. Honaker

Recent research has shown that enhanced gravity separators provide the opportunity to effectively clean I mm x 37 micron coal. At Southern Illinois University, a detailed experimental program was performed on a continuous Falcon Concentrator, which was found to achieve separations at mass throughput capacity values in excess of 100 tonnes/hour. The apparent particle separation density for I mm x 73 micron coal was about 1.60 with relatively high efficiency (Ep = 0.12). Typical ash and sulfur rejection values of 85% and 70%, respectively, were achieved while recovering 85% of the combustible material. Metallurgical and efficiency data from the evaluation are presented in this publication.

Jan 1, 1998

By Graham Andrews

Experiment shows that the microbial degradation of pyrite does not necessarily proceed stoichiometrically. Under some conditions sulfur is oxidized preferentially leaving something approaching iron in composition; under others, the pyrite is converted almost to elemental sulfur. A kinetic model for the process based on three elementary biochemical reactions can explain these observations. The diffusion of sulfur along grain boundaries and dislocations in the solid pyrite uncouples the oxidation rates of sulfur and iron from the requirements of stoichiometry. This mechanism also explains qualitatively why bacteria adsorb preferentially at dislocation sites on pyrite surfaces, why they form "pits" at these sites, and why amorphous pyrite is more readily degraded than pure crystals. The rate-limiting step for pyrite oxidation is discussed

Jan 1, 1989

By Y. J. Wang

In the mathematical analysis of electrical networks, the electrical devices are often modeled using idealized network elements such as current sources, voltage sources, and resistors. An analogous approach is outlined here for the modeling of mine ventilation networks, which can be considered nonlinear resistive networks. The modeling technique proposed uses five basic (non-reducible) elements: the H element, the Q element, the D element, the R element, and the N element. These elements are characterized by their (a) pressure gain or loss, (b) air quantity, and (c) pressure-versus-quantity relationship, each of which may be known or unknown. In addition to the definition of the basic elements, the necessary conditions for which there exists a unique solution are discussed. This is performed using theoretical developments derived from electrical circuit theory and illustrated in example networks. The proposed procedures are useful in the solution and characterization of mine ventilation networks.

Jan 1, 1996

By Elias Apostolidis

Since 500 B.C. Mt. Penteli has been famous as white marble production site, which provided the birthstones for the construction of Athens Acropolis and Parthenon. The Aloula quarry belongs to ?Dionyssomarble S.A.?, a commercial and industrial marble company, which retreated after 1940. Disturbance in the site was minimal since then. In July of 1994 the reclamation started by a group of quarry workers from Paros, already familiar with traditional marble quarrying techniques, unchanged from antiquity to 1940. The project was complete in 1997. Our main objectives have been to show respect to the area and the art of people, to let nature guide our choices, to use only local stone as a construction means, to imitate the old construction rules and to turn the land use into amenity and civilization. Aloula quarry will become a site restored for amenity and civilisation, including ancient quarrying techniques. The restored quarry is already open to the public, though to a small number of visitors, and soon will become an amenity park and an open space museum of the ancient quarrying art.

Jan 1, 2002