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By G-L. Wu, X-B. Liu, C-Y. Zhou

"The static recrystallization behaviour of Ti-Nb microalloyed high-strength steel during hot deformation was studied by conducting double-hit hot compression experiments using a Gleeble-3500 thermomechanical simulator. The effects of deformation temperature, strain rate, strain, and initial austenite grain size on the static recrystallization fraction are discussed. The static recrystallization kinetics were modelled, and the results show that the static recrystallization fraction increased with deformation temperature, strain rate, and strain and interpass time. The static recrystallization activation energy Qs was 326.05 kJ mol-1. Comparison of the experimental results and predicted results indicates that the effects of deformation parameters on the static recrystallization in multistage hot deformation are significant. The predicted results are in good agreement with the experimental results. IntroductionIn hot-forming processes, complex microstructures are often induced by multiple hot deformation mechanisms (Zhang et al., 2014; Liang et al., 2015). The softening behaviour during hot processing has generated considerable interest because component properties are influenced significantly by the corresponding microstructural evolution (Wu et al., 2010). It is well known that dynamic recrystallization (DRX); metadynamic recrystallization (MDRX), which occurs by the growth of DRX nuclei during intervals of deformation; and static recrystallization (SRX), which occurs by nucleation and growth during the intervals of deformation, can significantly alter the austenite grain size (Chen et al., 2015. Chen, Sui, and Cui, 2014; Mao et al., 2014). The long interpass times allow complete SRX to take place if the steel is being rolled above the interpass recrystallization stop temperature (Tnr), i.e. in the absence of carbonitride precipitation (Siciliano, 2000). In recent research, microalloying technology coupled with new-generation thermomechanical control processing (NG-TMCP) has proved efficient in achieving the proper balance between strength, toughness, ductility, and formability by means of a suitable combination of chemical composition and thermomechanical treatment parameters (Shukla et al., 2012; Bandyopadhyay et al., 2011). The alloying elements Nb, V, Ti are widely used in high-strength low-alloy (HSLA) steel to achieve the desired strength and toughness properties with solid-solution strengthening, precipitation hardening, grain refinement, and dislocation strengthening (Opiela, 2014; Chen and Yu, 2012). The wide applicability of alloying elements in HSLA steel is due to the fact that heat treatments are not required after forming of the parts, which results in time and cost savings."

Jan 1, 2017

By K. C. Corin, M. Tadie, N. Ndamase

Fresh water conservation efforts and strict environmental regulations have forced the mining industry to reduce freshwater consumption and effluent discharge. This is achieved by recycling process water back to mining processes. The performance of flotation circuits depends on the pulp chemistry. When process water is recycled to flotation cells, organic and inorganic species that have accumulated over time alter the pulp chemistry. The presence of accumulating ionic species such as SO4 2- and S2O3 2- has been found to hinder the adsorption of collector ions onto mineral surfaces. Sulphide minerals are semi-conductors; electrochemical reactions take place on their surfaces. The adsorption of collectors onto mineral surfaces takes place via electrochemical reactions. This study, therefore, aims to investigate how the presence of accumulating ionic species at varying ionic strengths affects the adsorption of sodium ethyl xanthate onto chalcopyrite from an electrochemical perspective. Synthetic plant water comprised of single salts with varying ionic strengths was used. Rest potential measurements were conducted to investigate collector-mineral interactions in the presence of these ionic species. Microflotation tests were performed to determine whether the presence of these ionic species affects mineral floatability. Higher chalcopyrite recoveries were achieved in the presence of SO4 2- than in the presence of S2O3 2-. Rest potential measurements were found to successfully predict microflotation performance in the presence of the ions of interest. Keywords: Flotation water quality, electrochemical adsorption; xanthate collectors

Jan 1, 2020

By H. Karabulut, S. Gündüz, K. Karacif, M. A. Erden

The corrosion properties of iron-based composite materials containing graphite and silicon carbide (SiC) reinforcement were investigated. The effects of silicon carbide reinforcement were investigated by adding 0.5% graphite and 1%, 2%, and 4% SiC. A powder metallurgy method was used to produce the composite samples. Iron, graphite, and silicon carbide powders were blended for one hour with a threeaxis mixer and then unidirectionally pressed under a pressure of 750 MPa. After pressing, the composite materials were sintered at 1100°C for one hour. The corrosion properties and microstructure, density, and hardness properties of the composite materials that can affect the corrosion properties were also investigated. It was determined that the pore ratio and hardness of the composite material increased, and corrosion resistance decreased, with increasing silicon carbide content.

Jun 2, 2022

By A. V. Rasskazova

Theoretical substantiation of leaching of clustered ultra-fine gold by the electro-photo activated cyanide and chloride solutions is given in the paper; and processes of activation of leach solution by electrolysis and photo-activation are described. Comparative experiments on electro-photo activated leaching of ultra-fine gold from refractory ores by cyanide and chloride solutions were carried out. The material for research is primary ore of the Pogromnoe deposit (Russian Federation, Trans-Baikal Territory). The ore is characterised by the minimum sulfide minerals and the organic carbon content. Gold in ores of this deposit is presented as mainly ultra-fine. Gold inclusions in quartz and silica-alumina minerals (metasomatic minerals) are ultra-fine. Sulfide minerals (2.5-3%) are presented in ore generally by pyrrhotine (gold content does not exceed 10 g/t). Standard cyanide technology provides 49.5% gold recovery. Photo-electro activated air saturated NaCN provides 69.9% gold recovery. Laboratory research of chloride-hypochlorite column leaching demonstrated that the electro-photo activated method provided 78.9 % gold recovery to pregnant leach solution. Chloride-hypochlorite photo-electro activated solution can provide higher level of gold recovery with shorter process duration (10 days) in comparison with cyanide (40 days). The final decision regarding the choice of leach solution has to be done on the basis of technical and economic calculations. Keywords: Ultra-fine gold, cluster chemical reactions, active clusters, leaching, electro-photo activation of leach solution

Jan 1, 2020

By E. Schoeman

Ion exchange resins were investigated for the effective recovery of platinum, palladium, and gold from a pregnant cyanide heap leach solution. Screening results indicated that strong-base anion exchange resins proved to be most effective in the recovery of these metal cyanides. Gold was selectively recovered with the use of Minix, while effective recovery of gold, platinum, and palladium over the base metals, copper, and iron, was achieved with Amberlite PWA-5. Successful elution of these metal cyanides was possible from both Minix and Amberlite PWA-5, using a 2M potassium thiocyanate solution at ambient temperature. Acidic thiourea was unable to elute platinum from either Minix or Amberlite PWA-5. Effective elution of palladium and gold were, however, achieved with use of acidic thiourea. Using these results, two conceptual flow diagrams for the recovery of these metals from cyanide solutions are proposed.

Jan 1, 2012

By V. E. Cogho

Optimum Coal Mine comprises numerous defunct, active, and future mining sections. The mine is primarily a large opencast coal mine; however, underground mining activities will be increasing steadily over the next five years. Opencast and underground mining activities have a significant impact on surface and groundwater resources. To ensure that the mine will be able to continue with its mining operations in the catchment, the extent of this impact requires that substantial intervention and mitigation measures need to be implemented to ensure the environmental integrity and economic use of the catchment's water resources. In developing a sustainable long-term mine water management strategy, numerous scenarios had to be analysed. The various scenarios are a combination of water and land management activities. The main components of the mine's integrated water management strategy include: ? Management of water recharge by continual and appropriate rehabilitation of disturbed land ? Beneficial re-use of impacted mine water for coal plant process water and mining operations ? Reclamation and desalination of remaining excess impacted mine water to potable standard. From the mine's long-term water balance, it is evident that the continued implementation of numerous water management actions is required to mitigate the water resources impact in a sustainable manner. In addition, the installation of a water reclamation plant at Optimum Coal Mine (15Ml/day) is a key step for the mine to achieve a zero impact target.

Jan 1, 2012

A very successful banquet was held in the Ballroom of the Carlton Hotel on 7th March, 1986. The Institute thanks the Organizing Committee and the sponsors (listed on this page), without whose generous support the banquet would not have been possible.

Jan 1, 1986

By J. W. Neale

Mintek was a leading participant in the BioMinE project between 2004 and 2008. This project, which was funded in part by the European Commission, was aimed at the development of biotechnology for the minerals industry in Europe. Mintek?s research programme focused mainly on the development of integrated bioleach-based processes for the recovery of base metals from complex, low-grade sulphide concentrates. Specific European mineral resources were targeted and used in integrated piloting campaigns involving bioleaching, solution purification, and metals recovery. This paper describes the use of thermophilic bioleaching for the recovery of nickel and copper from a low-grade nickel-copper concentrate produced at the Aguablanca Mine in southern Spain. Currently, the Aguablanca Mine produces a bulk nickel-copper concentrate for sale to a smelter, and the proposition is to increase the profitability of the operation by the on-site production of metal or metal intermediate. Initially, bench-scale bioleach tests were conducted to determine the bioleach operating conditions. These tests included an evaluation of mesophilic, moderately thermophilic and thermophilic microorganisms. In order to achieve sufficiently high levels of both copper and nickel extraction, a thermophilic process was selected?this was necessary for leaching of the refractory chalcopyrite that occurs in this concentrate. Additional bench-scale test work was carried out to derive a conceptual process flowsheet for the solution purification and metals recovery circuit. The results of the bench-scale tests were used to design, construct and commission an integrated pilot plant, which was subsequently operated at Mintek for over seven months. During this time, the solution purification and metals recovery processes were optimized, and all recycle loops were closed. The final process flowsheet included the following unit operations: concentrate regrinding, thermophilic bioleaching at 70°C, primary iron removal using limestone, copper solvent extraction and electrowinning, secondary iron removal, nickel hydroxide precipitation using magnesia, and final solution purification using lime. Where applicable, process solutions were recycled to preserve water. The process design data derived from this pilot-plant campaign formed the basis for a conceptual engineering study for the developed process. In the study, mass and energy balances were derived, and a process flowsheet was developed and used as the basis for estimating the capital and operating costs of the process. This enabled a preliminary economic analysis of the process to be undertaken. The findings of this study are discussed.

Jan 1, 2009

By S. Soren, K. Deo Mehta, G. Jha

The paper aims to find a sustainable sintering process through cleaner means, in order to achieve the desired outputs with zero environmental impact. At present, sintering has no control over its environmental impacts. These impacts occur when fossil fuels such as coal and coke are used in metallurgical sintering. These fossil fuels are undoubtedly effective in their assigned reducing task, but simultaneously emit about 220 kg of GHGs (greenhouse gases) per tonne of sinter produced. The current attempt has focused on reducing these emission levels by switching from coke to a renewable fuel source such as biomass. Biomass is a cleaner fuel source with a significantly lower emission footprint compared to coke. In the experimental campaign, sawdust and wood-charcoal were used in substitution for coke. Experiments were designed in a progressing substitution to obtain the maximum substitution ability without compromising the sinter properties. Sawdust as raw biomass source optimally substituted 10% of coke. The substitution levels were remarkably higher (30%) for wood charcoal due to its low moisture and high calorific values. A fuel blend with 30% biomass and remaining coke succeeded in producing a sinter with acceptable quality indices. Sinters prepared with or without biomass contribution shared an identical phase transformation and microstructures. In order to to maintain consistency in the process, every effort was made to maintain all operational and process parameters identically, except for the fuelling framework. Keywords: Sintering, sustainable, biomass, GHGs, fuel substitution

Jan 1, 2020

By J. Petersen, T. Moyo

Waste Printed Circuit Boards (PCBs) are a metals-rich fraction of electronic waste (e-waste) streams, and globally it has been demonstrated that they can be recycled gainfully to recover the metals. Reported successful cases of PCB recycling are carried out in large volumes, using high-level technology and high capital investment smelter house operations. This presents entry barriers for recyclers in developing economies where capital may not be accessible, and the waste volumes are not sufficient to warrant large scale operations. Hydrometallurgical processes have the potential to provide an option for the scalable processing of smaller volumes of PCBs and can be set up at relatively lower capital costs. However, to date, the hydrometallurgical treatment options available rely on precursor communition and classification processes that also require high capital and energy costs. This paper presents an overview of the work done under the Minerals to Metals signature theme towards understanding e-waste recycling processes and developing pre-processing and characterisation of PCBs in order to unlock potential for local end processing in developing economies, using South Africa as a case study. The structure of PCBs is reviewed, and the current size reduction techniques and the subsequent leaching processes are discussed. Keywords: Printed circuit boards (PCBs), PCB structure, pre-treatment, liberation, ammoniacal leaching

Jan 1, 2020

Infacon 74 Members are reminded of the International Ferro-Alloys Congress that is to take place in Johannesburg between 22nd April and 1st May, 1974. The Congress is being held jointly by the National Institute for Metallurgy, the Ferro Alloy Producers' Association of South Africa, and the South African Institute of Mining and Metallurgy. Correspondence and enquiries should be addressed to The Secretary, Organizing Committee, INFACON 74, Private Bag 7, Auckland Park 2006. The gold deposits of the farms Lisbon and Berlyn in the Eastern Transvaal by v. c. H. R. BRERETON. Published in the Journal November 1973. AUTHOR'S CORRECTIONS The following amendments should be made.

Jan 2, 1974

By C. O. Aksoy, G. G. U. Aksoy, A. Fisne, I. Alagoz, E. Kaya

Coal produced in underground mines is transported to the surface by means of conveyor belts throughout long roadways. The combustion of belts puts a large number of employees at great risk. Underground collieries differ from other underground mines -due to the combustible nature of the product. The most prevalent cause of belt fires in underground coal mine is spontaneous combustion due to oxidation of the coal, which also enables the conveyor belt to burn over time. In 2014, a belt fire in an underground coal mine in Manisa-Soma, Turkey caused 301 fatalities. A study has been conducted on this accident for approximately 3 years, consisting of combustion tests in a purpose-built research gallery, comparison of the test results with mine records of the accident, and CFD modelling of the mine environment. The intensity of the fire was sufficient to redirect the air flow underground, causin large amounts of toxic gases to fill almost the entire mine in approximately 15 minutes. It is recommended that CFD analysis be used in planning emergency action strategies in underground mines.

Dec 13, 2023

By H. Brüggemann

The exploration of deposits generates geological data which are suitable for creating a preliminary tectonic and stratigraphic model. Linked with the topographical map and analysis data from exploration drillings, this information forms a numeric representation of the deposit. The following example demonstrates an expert system which connects chemical quality requirements and quarrying criteria, and develops a quarrying strategy based on the calculated model. Additional constraining factors like process technology, quarrying methods, landscape protection regulations, etc. are included. The goal is to guarantee a long-term, homogeneous material flow from the quarry at acceptable production costs - even in the case of an extraordinarily inhomogeneous deposit. In order to fulfil this requirement it is necessary to consider a large number of rules, criteria and instructions which can be structured as an expert system and programmed with LISP at a comparably low cost. The chosen strategy is not necessarily final, but can be changed any time by altering or varying the framework of conditions. The output consists of a block-working sequence which best satisfies the set requirements for appropriate points of quarry opening.

Jan 1, 1987

By N. Naude, W. P. Roux, O. Kaba

Ceramic filtration plates are used for dewatering slurries with high solid concentrations and particles in the size range of 30 μm to 150 μm. After extensive operating times, the ceramic filter plates at Minas Rio in Brazil begin to blind due to the precipitation of barium sulphate on the surface of the ceramic filter plate, which reduces the overall efficiency of the filtration process. Further research is needed to identify the barium precipitate phases on the blocked filter plates and its thermodynamic and kinetic behaviour in the system. A crystallography analysis was performed on the sample and the results showed that there are two different sets of precipitates formed on the filter plate: grey crystals which were large and scatted on the filter plate and red micro crystals that covered the entire surface of the filter plate. The red microcrystals on the sample were identified with XRD, which indicated that the sample contained barium sulphate in the mineral form barite. Experiments were conducted to determine the optimum conditions under which barium precipitation will occur. The conditions tested as a possible driving force for barium sulphate precipitation were the effect of temperature, pH and concentration. The pH and temperature ranges were pushed to both the lower and higher boundaries. The effect of temperatures as low as 15oC was studied and pH levels of 7 and upwards. The first nuclei started appearing at a pH of 7 but significant growth is promoted at higher pH levels. The X-Ray diffraction analysis confirmed the phase of the precipitates formed, and the orthorhombic crystallographic structure formed is a characteristic of barium sulphate. Keywords: Iron ore, barium sulphate, temperature, pH, concentration, morphology, and ceramic filter plate

Jan 1, 2020

By C. Dechert, J. Norwood

Compañia Minera Antamina, Peru has recently completed a fifth year of operation of their 301-km concentrate pipeline. The pipeline was commissioned by PSI in May of 2001. The Antamina pipeline is generally accepted as one of the most complex slurry pipeline operations worldwide. The pipeline transports an average of 1.6 million tonnes of copper and zinc concentrates from the Yanacancha mine site at an elevation of 4 155 metres above sea level (masl) to the port of Huarmey at an elevation of 62 masl. Currently ten different types of concentrates are being transported as separate batches. The pipeline traverses oneof the most rugged areas in the world. It utilizes three different pipe diameters, and four remote valve stations to optimize the hydraulic design. PSI has recently completed an overall operational audi tof the Antamina pipeline. This paper evaluates the operational effectiveness of specific design features and operating philosophies, implemented during the engineering phase, over the last five years of operation.

Jan 1, 2007

By C. van Buuren, R. F. Sandenbergh, P. J. Pieterse

Gold extraction from double refractory ores using conventional cyanidation has proved challenging due to the presence of carbon within the ore. Carbon particles may adsorb leached gold resulting in gold losses to tailings, i.e. preg-robbing the gold. Some of the preg-robbed gold may be recovered by the application of the HiTeCC process on CIL tailings. The process developed by Metso Outotec involves caustic conditioning of the tailings followed by high temperature desorption and simultaneous adsorption onto virgin activated carbon of the aurodicyanide. The aim of this paper was to develop a model for the HiTeCC process which could be used to support design and optimisation of the process, based on the adsorption characteristics of the preg-robbing and activated carbons. It was found that accurate experimental isotherms can be used to predict the behaviour of preg-robbing adsorbents. Comparing the sorption isotherms for preg-robbing ores and activated carbon indicated similar dependencies on temperature and ionic composition. Applying boundary layer diffusion models coupled with experimentally determined isotherms for preg-robbing ore and activated carbon, the HiTeCC process was successfully simulated at experimental and plant scale. Gold recovery of the HiTeCC process is most sensitive to the temperature of desorption and gold loading of the activated carbon, with increased temperature improving recovery. The gold loading of the activated carbon in the process should always be maintained lower than that of the normalised pregrobbing carbon gold loading to ensure favourable conditions for adsorption onto the activated carbon. Caustic conditioning stabilises adsorption and is therefore not necessary during the desorption stages of the process, but potentially improves recovery during adsorption. Keywords: Preg-robbing, refractory gold ores, HiTeCC, aurodicyanide

Jan 1, 2020

The relationship between the aspect ratio and physical fields in aluminium reduction cells wase studied numerically. The aspect ratio was firstly defined and 7 kinds of 320 kA cells with different aspect ratios were put forward. By using numerical simulation, the relationship between the aspect ratio and the electric-magnetic flow fields, magnetohydrodynamic stabilities, and thermal stability was discussed. It is concluded that the electric-magnetic flow field distributions are greatly affected by the aspect ratio. From the perspective of magnetohydrodynamics stability, the larger the aspect ratio is, the more stable the cell will be. A larger aspect ratio is more beneficial for the thermal stability under the same current density.

Jan 1, 2011

By G. Akdogan, C. Bergmann, C. J. Coetzee, Q. G. Reynolds, S. J. Baumgartner

Submerged arc furnaces (SAF) are used extensively in the production of ferrochrome, where charge material – consisting of mixtures of carbonaceous reductants, fluxes such as silica, and ore in the form of pellets – is fed through chutes into the vessel. The feed typically forms a thick bed or ‘burden’ of solid particulates above a bath of molten material below. This burden layer surrounds three electrodes, which are typically arranged in a triangular configuration in circular SAFs. A major challenge in the industry is the availability of sought-after reductants, volatile market conditions, and increasing electricity tariffs in South Africa. A good understanding of the physical properties of the raw materials in the charge is therefore of great value in order to best deal with the reductants available at any given time, and thereby maximising furnace throughput. This paper presents a study of the effects of different particle properties on particle flow behaviour relevant to SAF operations. Discrete element model (DEM) simulations were used to estimate the sensitivity of the particulate flow of beds of charge material to properties such as the coefficients of friction, particle shape and size, and others. The present study lays the groundwork for the development of full DEM models of the SAF that will greatly improve understanding of the flow of complex mixtures of solid particles in the submerged arc furnace, and how the relative physical properties of each component in the charge can influence electrical behaviour of the burden.

Sep 1, 2021

By J. Zwartendyk, A. Azis

"Every nation must decide how it should exploit its mineral resources so as to contribute most to its national objectives. It is argued that the present value of the future corporate income tax flow derived from mineral exploitation may serve as a useful indicator in moving toward a taxation policy that would contribute optimally toward the greatest public benefit.The future stream of corporate income taxes depends largely on the mineral endowment, consisting of deposits now being mined, known unmined deposits, and unknown deposits.Unknown deposits may be estimated by geological inference. Both known and unknown deposits can be categorized according to grade and size, and divided into economic and uneconomic deposits on the basis of certain prices, costs, rate of return and taxation levels.Computer simulations can be run of discounted cash flow models at various taxation levels to show the impact of taxation changes on future tax revenues."

Jan 1, 2014

By M. Tang, X. Tong

"SynopsisSlime coating is one of the most common ways for serpentines to contaminate metallic mineral concentrates during traditional flotation of coarse sulphide particles. This could pose quite a complicated and challenging problem in the case of some types of low-grade and finely disseminated Cu-Ni ores bearing high serpentine contents. This is the case for the copper and nickel sulphides from the Yunnan Mine, China. Previous batch flotation tests of this ore resulted in satisfactory recoveries of 86.92% Cu, 54.92% Ni, and 74.73% Pt+Pd, and concentrate grades of 4.02% Cu, 3.24% Ni, and 76.61 g/t Pt+Pd. However, the MgO content in these concentrates was more than 19%. In the current study, microflotation tests and settling rate tests were introduced to investigate the effects of a combination of strong collectors (a 2:1 weight ratio of butyl xanthate and butyl ammonium dithophosphate) on entrainment of serpentines in metallic mineral concentrate, as well as visual observations of the concentrates in suspension using still photography. All test results indicated the presence of serpentines entrapped in the hydrophobic flocs that resulted from these collectors, even with the use of effective gangue depressants. These strong collectors are used to flocculate the ultra-fine sulphides by forming loose and ‘fluffy’ hydrophobic flocs. However, these hydrophobic flocs may also be able to load or entrap some serpentine slimes into the concentrate, and this entrained serpentine could be harder to remove by using depressants or intensified conditioning than serpentine slime coating on the particle surfaces.IntroductionSerpentine minerals, which have the generalized composition (Mg,Fe)3Si2O5(OH)4, can be easy to crush and grind due to their convoluted and bent layered structures. These serpentines can hinder the enrichment of some metallic minerals and dilute their concentrates by entrainment during flotation. The resulting high pulp viscosities, slime coatings, and high content of dissolved ions adversely affect the flotation recoveries of copper and nickel sulphides, and high levels of MgO entrained in the concentrates lead to heavy penalties from smelters. Since the quality of nickel flotation concentrate depends heavily on its MgO content (generally less than 6–7% for No.1 or 2 grade nickel concentrate according to the standard requirement from National Nonferrous Industry), reducing the entrainment of serpentine during flotation is becoming more and more pressing. Previous research has focused on the collectors and depressants that are commonly used in copper-nickel flotation, as well as their interaction mechanisms."

Jan 1, 2015