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By B. J. Scheiner

Carbonaceous gold-bearing ores of the type that occur in north-central and northeastern Nevada were investigated by the Bureau of Mines as part of its Heavy Metals Program. Specific objectives were to identify the carbon and organic compounds that prevent adequate gold recovery from the ore by cyanidation and to develop an economical process that would overcome the detrimental effect of the carbonaceous constituents. Activated carbon and long-chain organic compounds containing sulfur and nitrogen were found in the ore. Part of the material consisted of stable gold organic complexes. A mild oxidation technique that allowed gold extraction as high as 96 percent by subsequent cyanidation was developed. A variety of oxidants was shown to be effective in improving gold recovery, including chlorine and sodium hypochlorite (NaOC1). An electrolytic oxidation process was developed that was particularly advantageous from an economic and effectiveness standpoint.

Jan 1, 1971

The instrumentation specification in the National Academy of Engineering (NAE) report of March, 1970, set forth some rather general guidelines that the seismic surface system should follow. The fact that there was no comparable equipment in existence at that time, and the need to produce a system from presently available equipment, was spelled out in that document. The features that the system should include were listed, and included: • Quick and simple deployment • Portability • Battery-powered operation • All-weather operation • Computational simplicity and speed • High reliability and long shelf-life • Dual service for location and communication • Adaptability to widely varying seismic velocities. topography, and geologic structures • Minimum maintenance • Capability of continuous operation for extended periods, and • Reasonable cost Since that report, there has been a substantial amount of field work addressing the trapped miner detection and location problem carried out by Westinghouse Corporation under contract with the Bureau of Mines. Two complete surface systems have been designed, built, and field tested and substantial documentation has been produced on the mine environment and background noise using these systems. These systems, built from off-the-shelf equipment, have been designed with maximum flexibility in mind in order to explore what con¬figuration a field unit should have.

Jan 1, 1974

As technology evolves, accidents may occur because human-system interactions were not considered adequately in the process. A systematic methodology can be used to evaluate the causes of mishaps and to develop recommendations that will enhance safety. A recent trend observed in underground coal mining is used to illustrate this principle because an underground mine is a dynamic work environment. Mining is characterized not only by frequent geologic changes but by technological evolution that can seriously degrade human performance and compromise worker health and safety The case exemplified in this paper involves implementation of remotely controlled equipment for extended cut mining. Extended cut mining technology evolved with minimal ergonomic consideration even though the change from on¬board to remote machine operation dramatically modified the role of the human component. In response to concern that system interactions should be examined more closely. a methodology was developed to identify hazards.

Jan 1, 1998

Provide room-and-pillar operators with practical in- formation and guidelines concerning multiple-seam mine design to reduce ground problems associated with the interaction of adjacent working.

Jan 1, 1994

By Joseph A. Holmes

The perpetuation of the supply of anthracite coal in Pennsylvania is a national as well as a State problem. Any investigation that shows how larger percentages of this coal may be saved in mining, without excessive cost, and without dangerous subsidence of the overlying surface ground, has a national as well as a local interest. Messrs. Conner and Griffith, who conducted the investigations described in this report largely for the city of Scranton, are consulting engineers for the Bureau of Mines for investigations similar to those they have already made in connection with their Scranton work; and this report is published by the bureau in response to numerous requests, because of the fact that the information it contains will prove useful in the general solution of similar problems in many of the country's coal fields. A study of the accompanying maps will show that the city of Scranton is underlain by 11 separate beds of coal, varying in thick- ness from 2 to 24 feet. It is estimated that before mining opera- tions were begun these beds of coal contained underneath the present city limits of Scranton 600,000,000 tons of coal. The 27 collieries operating within the city limits, working independently of each other, had excavated and removed, up to March, 1911, an aggregate of 198,000,000 cubic yards of coal and accompanying rock, or 3,000,000 cubic yards more than the total amount of material excavated and to be excavated by the United States in constructing the Panama Canal. This fact illustrates something of the magnitude of the problem that the city of Scranton, with the aid of these engineers and of a special commission or advisory board, has undertaken to solve. The excavation has included 177,000,000 tons of coal and 44,000,000 tons of rock and accompanying refuse. This leaves about 420,000,000 tons of coal still to be removed. As a result of other investigations and of experience in adjacent anthracite mines, Messrs. Conner and Griffith and the advisory board of engineers have advised that, as far as may be necessary to prevent dangerous surface subsidence, the spaces remaining beneath the city of Scranton from the excavation of the above-described material should be filled with sand and other materials by flushing or other processes. This operation is expensive, but it is believed to be not beyond the reach of what is practicable, nor in excess of the value of the coal that may be removed and the amount of damages that may result from the caving in of the surface if such a plan is not carried out. No one realizes so fully as do the authors of this report the need of additional tests and other investigations before the data now pre- sented by them can be fully accepted as sufficient for all purposes in the solution of the problem; and it is expected that at some early date a more extensive series of similar tests can be made by the Bureau of Mines under the supervision of Messrs. Conner and Griffith on a larger scale and under a greater variety of conditions. The field examinations made for the Bureau of Mines by N. H. Darton, which are described briefly in a chapter of this bulletin and will be discussed at length in a bulletin to be published later, indicate the extent and distribution of the sands, gravels, and other materials in the Scranton-Wilkes-Barre district available for flushing purposes if further tests indicate their relative merits; and it is expected that the relative merits of these different materials will soon be tested under such conditions as will furnish the desired information.

Jan 1, 1912

By Thomas V. Falkie, R. Venkataramani

Proposing A Model In this investigation, a model of the form: n Y = a0 + E a x. A-1 v=l J J was postulated, where the number of independent variables "n" was originally fifteen. The following experimental hypothesis was to be tested: Null Hypothesis: the coefficients a = 0 J Alternate Hypothesis: One or more of the coefficients a 0 J Correlation and Regression To establish the alternate hypothesis and to test how well the proposed model fits the data, the conventional statistical techniques of correlation analysis and multiple linear regression analysis were used. Additionally, factor analysis was employed to investigate the dependency relationships in the data. Correlation and linear regression are well established statistical procedures in science and engineering. References on these procedures include Spiegel (1961), Anderson (1963), and Draper and Smith (1966). A simple example is stated here. If N observations are made of two variables, x and y, and it is desired to test this data to see if a linear relationship exists, then a model of the form: Y = a0 + a 1 x A-2 is proposed. The values of a0 and al may be calculated from the raw data by the "least square normal equations", which are:

Jan 1, 1972

To develop an in-mine water treatment system in which bacterial sulfate reduction and limestone dissolution continuously remove metals and acidity from contaminated drainage. Approach A section of mine tunnel was converted into a water treatment bioreactor by constructing cinder block dams and fang the area between them with a porous substrate mixture of limestone gravel and compost. Readily fermentable materials such as dairy whey, spent brewing yeast, or sugar were periodically added to the reactor. Mine drainage was impounded behind one of the dams and continuously percolates through the reactor substrate at a controlled rate. How It Works The reactor substrate soon becomes anaerobic after it is saturated with mine water. Under anaerobic conditions, sulfate-reducing bacteria consume the organic materials that are added to the reactor and generate hydrogen sulfide (HIS) and alkalinity. The H2S reacts with dissolved iron and heavy metals to form metal sulfide precipitates. The alkalinity raises the pH of the water and induces aluminum to hydrolyze and precipitate as aluminum hydroxide [Al(OH)3]. Additional alkalinity is generated by the continuous dissolution of the substrate limestone. Metal sulfide precipitates and Al(OH)3 are retained within the reactor, and the treated water is discharged. The underground location of the system allows year round operation.

Jan 1, 1994

By John R. Reeves

The principal oil aha.le in Indiana ie known as the New Al'baZ\Y shale. It 11 ot Devonian age, and ia usually correlated with, although not certainly of the 1ame age a,, the Antrim shale of northern Michiga.. the Ohio shale of Ohio, and the Chattanooga shale ot Kentucky. Termescae • a."ld Georgia. The nqtmal thickneaa of the formation 1n Indiana 1e a.bout 100 faet, ltbough 1n the region of its out­ cro;l the tall th!::kne,111 io rarely exposed because cf the general d:.p of the strata, which is 11 about 30 feet per mile to the west. With the exception ot thin local pha1e1, the entire thickness is oil shale,

Aug 1, 1922

By Isaac A. Zlochower, Michael J. Sapko, Eric S. Weiss, Kenneth L. Cashdollar

This paper describes dust explosion research conducted in an experimental mine and in a 20-L laboratory chamber at the Pittsburgh Research Laboratory (PRL) of the National Institute for Occupational Safety and Health (NIOSH). The primary purpose of this research is to improve safety in mining, but the data are also useful to other industries that manufacture, process, or use combustible dusts. Explosion characteristics such as the minimum explosible concentration and the rock dust inerting requirements were measured for various combustible dusts from the mining industries. These dusts included bituminous coats, gilsonite, oil shales, and sulfide ores. The full-scale tests were conducted in the Lake Lynn experimental mine of NIOSH. The mine tests were initiated by a methane-air explosion at the face (closed end) that both entrained and ignited the dust. The laboratory-scale tests were conducted in the 20-L chamber using ignitors of various energies. One purpose of the laboratory and mine comparison is to determine the conditions under which the laboratory tests best simulate the full-scale tests. The results of this research showed relatively good agreement between the laboratory and the large-scale tests in determining explosion limits. Full-scale experiments in the experimental mine were also conducted to evaluate the explosion resistance characteristics of seals that are used to separate non-ventilated, inactive workings from active workings of a mine. Results of these explosion tests show significant increases in explosion overpressure due to added coal dust and indications of pressure piling.

By Doris M. Hyde

Belize remained relatively insulated from the social and political turmoil that affected some of its Central American neighbors. This stability encouraged new foreign investments that assisted the economy, especially in tourism and agriculture. The mineral sector remained limited to construction-oriented materials. Oil exploration efforts continued by the various concessionaires.

Jan 1, 1987

By J. M. Stuve

The standard heats of formation (?Hf°) of holmium trichloride and terbium trichloride were measured by solution calorimetry. Heats of solution of holmium and terbium metals and their anhydrous chlorides were measured in 4.360 molal HCI at 298.15° K. From these measurements ?Hf° for HoC13 (c) was calculated as -240,290 ±1,700 cal/mo1e, and ?Hf° for TbC13 (c) was calculated as -238,330 ±1,500 cal/mole at 298.15° K.

Jan 1, 1967

By L. B. Pankratz

The Bureau of Mines conducted heat-content measurements above 298.15° K for dehydrated analcite (NaAISi2O6) to 1,000°K, kaliophilite (KA1Si04) to 1,800° K, and leucite (KAlSi206) to 1,800° K. Heat content and entropy increments were tabulated, and the heat content data, were given in equation form. A first order transition was noted for kaliophilite near 810° K with a heat absorption of 160 cal/mole. Leucite had a second order transition which became complete near 955° K. In this transition a crystal change occurred from tetragonal (low-temperature form) to cubic (high-temperature form).

Jan 1, 1968

By James J. Hanslovan

Stresses that damage coal mine trailing cables were investigated to obtain a quantified description of cable-stress locations, magnitudes, and frequency of occurrence. Stresses occurring in operating mining sections were measured and observed. Answers to questions that arose during the underground investigations were pursued under controlled conditions, both in the field and in the laboratory. Cable-handling suggestions that minimize or eliminate the stresses are summarized in the form of recommendations to mine operators.

Jan 1, 1979

By F. E. Brantley

Optimum autoclaving conditions were determined for separation of iron and manganese values from pregnant leach liquor produced in extracting manganese from low-grade umber are. The umber was leached with a synthetic anolyte similar to a recycle solution, used in manganese electrolysis cell operations, that had been renewed with ferrous sulfate and sulfuric acid. The equipment used and results obtained are presented for the several conditions employed. The kinetics of the separation were studied. Rate equations were derived for the formation of solid ammonium-manganese sulfate, (NH4)2 Mn2 (S04)3.

Jan 1, 1968

By R. Barany

This paper reports determinations of heats of formation (from the oxides and elements) of crystalline cadmium metasilicate and crystalline lead meta-silicate by hydrofluoric acid solution calorimetry. The results, in conjunction with known entropy values, yield free energies of formation. There are no earlier data of this type for cadmium metasilicate. The results of this investigation for lead metasilicate deviate from the literature values (which are less reliable) in the direction of increased thermodynamic stability. Both cadmium and lead metasilicate are much less thermodynamically stable with respect to their constituent oxides than are the corresponding compounds of the alkaline earth metals.

Jan 1, 1959

By C. I. Pierce

The Bureau of Mines conducted laboratory tests to determine if ultrasonic energy could reduce either the residual water or oil content of petroleum reservoir-rock samples from Appalachian area oilfields. Brine-saturated core samples were flooded with oil to residual brine saturation and subjected to 20 kilocycles per second ultrasonic energy. Then they were flooded with brine to residual oil saturation and again subjected to ultrasonic energy. Additional water displaced as a result of the application of ultrasonic energy to the flow system ranged from 0 to 4.3 percent of the original brine and averaged 1.9 percent. The increase in oil recovery as a result of the ultrasonic energy ranged from 0 to 9.0 percent of the original oil and averaged 3.1 percent. On the basis of the tests, it appears that 20-kcps acoustic waves would not have field application for oil recovery.

Jan 1, 1968

Native asphalt was produced in 1977 by six companies in four States. Leading States were Texas and Utah. Output declined 39% to 1,237,000 tons valued at $18,874,000. Bituminous limestone was produced by Whites Uvalde Mines and by Uvalde Rock Asphalt Co. in Uvalde County, Tex.; by Southern Stone Co. in Colbert. Ala.; and by Barton County Rock Asphalt Co. in Barton County, Mo. Gilsonite was produced by American Gilsanite Co. in Uinta County. Utah, and by Ziegler Chemical and Mineral Corp. in Weber County. Utah. The asphalt was used for streets and roads, and for other purposes.

Jan 1, 1980

By Fred Baldassare, Marcia Harris, Kenneth K. Eltschlager

Surface mine blasting was recently investigated as a potential source of high concentrations of stray gases found in nearby residences of western Pennsylvania. In one incident carbon monoxide was detected in a home and in the other, high concentrations of carbon dioxide were found in a home. Both carbon monoxide and carbon dioxide are by-products of blasting. However, other potential sources of these gases may also exist in a residential setting. In each case, gas chromatography (GC) and carbon isotopic analyses were used to define atmospheric concentrations inside the homes, and to determine the source of a stray gas. Molecular and isotopic analyses provide geochemical evidence as to the origin and source of the stray gas. This paper discusses elements of a stray gas investigation and the analyses necessary to identify the source of a stray gas.

By J. E. Zeilinger

This Bureau of Mines report describes the preparation characteristics of three samples collected from the Kidney seam, in the Northern Field of the anthracite region. Removal of the sink 1.70 specific gravity material from the samples collected would result in greatly reduced ash contents at yields in excess of 90 percent. The Kidney seam, in the locations sampled, proved to be a low-ash anthracite containing an unusually high percentage of float 1.45 specific gravity material.

Jan 1, 1970

Provide a strategy for calculating optimum distribution of selected sensors for detecting underground mine fires. Approach The Bureau of Mines performed research to determine adequate distribution of product-of-combustion (POC) fire sensors within mine entries. This placement strategy would improve the miner's chances for escape by locating sensors where they would most effectively, quickly, and efficiently detect fires resulting from coal or wood combustion. Spacing of Sensors Placement strategy guidelines were based on the performance of 160 F heat sensors with ideal operating characteristics which were placed at intervals of ten feet in underground mine entries. Data obtained from full-scale mine fires were used to estimate fire sizes and alarm activation times for the heat sensors. Various equations were then developed to determine spacing requirements for any fire detection system installed in entries of varying heights, widths, and ventilation rates.

Jan 1, 1983