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By Seth C. Schaefer

The Bureau of Mines studied the standard free energies2 of formation of ferrous fluoride (FeF2) and ferric fluoride (FeF3) with high-temperature galvanic cells employing calcium fluoride doped with 1 mole-pet yttrium fluoride as the electrolyte. A free-energy change for the cell reaction Fe (s) + NiF2 (S) = FeF2 (S) + Ni (s) together with the standard free energy of formation of nickel fluoride yields a standard free energy of formation of ferrous fluoride from the elements of ?GF° = -168.74 + 30.63 x 10-3T ± 0.41 kcal/mole (897-1,098 K). (2) Combining the standard free energies of formation of magnesium fluoride, ferric oxide, and magnesium oxide with the free-energy change for the overall cell reaction 3MgO(s) + 2FeF3 (s) = 3MgF2 (S) + Fe2 03 (S) (3) gives a standard free energy of formation of ferric fluoride from the elements as ?Gf° = -281.45 + 90.46 X 10-3T ± 0,67 kcal/mole (880-935 K). (4) Free energies and equilibrium fluorine pressures for the two univariant equilibria of the Fe-F system are tabulated and illustrated.

Jan 1, 1975

By David A. Monaghan, Kenneth R. Maser, Adi R. Gurdar, D. Randolph Berry

9. Remote Sealing System Sensitivity 9. 1 Introduction In the previous sections a description of the overall system has been presented along with detailed descriptions of the equipment and techniques employed with the preliminary probing system, the seal em¬placement system and the seal checking system. In addition, the use of these subsystems in a specific mine application has been described in considerable detail. A broad range of parameters of interest was specified in the contract, as summarized in Section 1. 3. Most of these are a function of the general location; i. e. , the location of the mine, and the specific location; i. e. , the location of the boreholes. These parameters of interest include passage size, shape, depth, slope and water con¬ditions. The length, diameter and location of the boreholes within the mine passage and on the surface are critical parameters as well. A few additional parameters may affect one or more of the remote sealing subsystems. These include temperature, topography, rock and soil conditions, and underground water. While variation in these parameters will not render the system inoperative, consideration of them in the planning stages will simplify and expedite the field operation. In the following sections the effect of the various parameters on the remote sealing operation will be discussed. For clarity, the several tasks, borehole drilling and casing, preliminary probing, fly ash delivery, foam topping and seal checking, will each be considered separately.

Jan 1, 1973

By W. K. Sawyer

In this Bureau of Mines investigation, one-and two-dimensional gas reservoir simulators were combined in such a manner that pressure distributions both in an induced vertical fracture and in the surrounding formation, could be determined as a function of time for any specified well production rate. The technique used consisted basically of the alternate ust of one-and two-dimensional algorithms for obtaining new pressure distributions in the fracture and in the reservoir, respectively. The pressures at adjacent reservoir and fracture nodes were used to calculate flow rates from the formation into the fracture, which provided source terms for both algorithms. The combination model developed provides the only known means of simultaneously simulating transient gas flow in a vertical fracture and the surrounding formation. Thus, the technique developed would be useful in locating wells in a gas storage field in that the effects of both fracture length and conductivity could be considered prior to drilling and fracturing operations. In addition, it will be helpful in analyzing pressure drawdown tests in a vertically fractured gas well since the entire test can be readily simulated for a wide range of reservoir and fracture properties.

Jan 1, 1974

By C. P. Fang

"For lower stages of multinozzle micro-orifice impactors, as many as two thousand nozzles are uniformly arranged within a cluster diameter of 1.06 inches. In the impaction region the mass flowrate of the spent air increases along the radius and reaches a maximum at the periphery. This crossflow can significantly deflect the air jets of the outer nozzles, hence the characteristics of impaction changes.Investigators in heat transfer and fluid mechanics have studied the influence of crossflow on jet deflection and found the dimensionless deflection of the jet centerline X/Dn is a function of (S/Dn)(l/m) . only, here X is downstream coordinate measured from the center of the jet orifice, Sis the jet-to-plate distance, Dn is the orifice diameter and m is the jet/crossflow mass flux ratio defined as:"

Jan 1, 1989

By J. A. Organiscak

Two types of airflow splitting methods for improving longwall dust control were investigated by NIOSH's Pittsburgh Research Laboratory. These methods included a translucent mesh barrier and a staged spray barrier system to confine the shearer-generated dust to the coal extraction side of the longwall face while maintaining a cleaner split of airflow on the opposing worker walkway side of the longwall face. The translucent mesh barrier was shown to provide notable dust control effectiveness up to 60 m downstream of the shearer in both the laboratory experiments and a longwall field evaluation, provided the mesh barrier remains relatively parallel to the airflow. The staged spray barrier system showed marginal dust control effectiveness in the laboratory and subsequently was not field tested.

By F. N. Kissell, H. K. Sacks

This study examines the accuracy of area sampling for measuring the dust exposure of mining machine operators in coal mines. The specific objective of this research was to find locations where an area sampler might work better than earlier studies have indicated. The results show that fixed-location area sampling cannot accurately predict the dust exposure of a machine operator, even when the best fixed location is sought, the fixed location is quite close to the operator and the bias due to the dust concentration gradient is corrected. Industrial hygienists have known for many years that area sampling is unsuitable for measuring air contaminant exposures in the workplace. Near contaminant sources, the dilution air and the contaminants are not evenly mixed. Therefore, when workers are near contaminant sources, exposure measurements must be taken from the worker's breathing zone to be accurate

Provide minx operators with means for evaluating dust generation and bit wear effects on Production without costly and extensive underground testing. Approach Develop personal-computer-based cutting system models that will simultaneously evaluate machine, Coal seam, and mine-operator-controlled parameters for their interactive effects on dust generation, bit wear, and Production by either a longwall shearer or a continuous miner. How It Works CSM Programs have been developed to analyze relative dust generated by a double-drum, ranging arm, longwall shearer and a continuous miner. These interactive programs Provide relative dust, culling forces, and production values for any given set of mining machine parameters, specific seam conditions, and operator-controllable parameters. Expanded versions of each program provide a dynamic evaluation of the effects of bit wear, over time, on production.

Jan 1, 1989

Utilize innovative processing technology to prepare high-purity, ultrafine advanced ceramic powders with little or no contamination occurring during the milling process. Advanced ceramic materials made from these powders could substitute for high-temperature alloys containing critical materials such as chromium, cobalt, and nickel. Approach Modify and evaluate the Bureau's turbomill, developed earlier to grind a variety of ceramic raw materials (clay, mica, and talc), as a milling or size-reduction technique for hard and abrasive advanced ceramic powders, such as silicon carbide. Background Powders for producing ceramic materials, such as silicon carbide. silicon nitride, alumina, and zirconia, which arc being considered for use in severe applications requiring high-temperature and/or corrosion resistance, are very difficult to reduce to fine sizes for processing into finished parts. Traditional techniques of particle size reduction, such as ball milling and jet milling, are very energy intensive and/or slow. These traditional techniques often produce materials that have a nonuniform particle size distribution and are contaminated by the milling media or container.

Jan 1, 1989

By Harold F. Unger

The Bureau of Mines conducted drilling experiments in the laboratory with a commercially available percussive drill that has an independent rotational system. Eight rock types with a wide range of physical properties were drilled under several combinations of rotational speed, drilling thrust, and operating pressure. Penetration rates and energy per unit volume correlated well with the coefficient of rock strength as shown graphically. Size-distribution analyses of some of the drill cuttings show how particle size varies with rotation speed and rock hardness. In general, changing the rotational speed has a greater influence on the penetration rate in softer rocks, with penetration rate increasing with increasing rotational speed.

Jan 1, 1972

By Benjamin W. Haynes

The Bureau of Mines conducted research to devise technology for increasing the Nation's mineral supply by recovering valuable constituents from currently discarded waste materials. Municipal solid waste (MSW), presently a major disposal problem, represents a significant source of metals, glass, and a combustible fraction that can be used to supplement coal in generating heat and electricity. As part of the total metallurgical system to treat MSW, this study evaluates the combustible fraction of MSW to characterize the various combustible components and to identify the principal sources of elements that eventually may be objectionable from corrosive or environmental considerations. Several possible sources for cadmium, chromium, cobalt, copper, lead, nickel, and zinc have been tentatively identified. These sources are pigments, inks, paper stock, and additives to plastics. A correlation between industry consumption values and measured concentrations in MSW was found for several elements.

Jan 1, 1978

By Charles E. Whieldon

This report presents the results of a study on part of the Smithfield oilfield, Wetzel County, W. Va. The primary purpose of the investigation was to determine the original and the present volume of stock-tank oil in the formations and to investigate the feasibility of waterflooding the Gordon Stray, Gordon, and Fourth sands underlying the I. D. Morgan lease. The study was based on laboratory core analyses, geophysical well logs, geologic considerations, and various field prediction data from the I. D. Morgan lease. The Bureau found that, of the three sands cored, the Gordon Sand was the best prospect for waterflooding, and that a properly engineered water flood should recover 136 to 230 barrels of oil per acre-foot from this formation.

Jan 1, 1967

By A. A. Afshari, D. G. Frazer, C. F. Stanley

"INTRODUCTIONThe primary function of the lung, i.e. gas exchange, occurs in peripheral units termed alveoli• Diagnosis of lung dysfunction ls therefore dependent on techniques to evaluate the status of the peripheral airways. Since these airways and alveoli are very small, it is difficult to determine directly how they function or how the function is changing due to disease. Yet this unde1·standing is critical to the design of instrumentation to detect early changes in lung function due to disease.An interesting hypothesis describing one aspect of small airway function has been proposed by Frazer (1) as gas trapping due to the formation of menisci in the airways. An additional study (2) proposes that the breaking and possibly the formation of these menisci could generate lung sounds, i.e. crackles. These lung sounds were recorded by placing a microphone at the trachea of an excised rat lung. The lung was degassed and then inflated and deflated. At points along the path of inflation, lung sounds were recorded. However, determination of the origin of the sounds was not attempted due to the difficulties induced by contacting the lung st1rface with a microphone.The purpose of this paper is to describe a non-contacting, whole field technique to monitor and describe the movements of the lung surface during inflation - deflation cycles.HOLOGRAPHIC INTERFEROMETRYHolographic interferometry is a full field, non-contacting and non-destructive technique that measures deformations of an object with a sensitivity in the order of the wavelength of light. A laser beam is split, with one beam reflected from an object and the other used as a reference beam. Both beams combine to produce a hologram of the object on a photographic plate. The process utilizes the concepts of interference, i.e. the two wave amplitudes will add at the points where the difference in optical path lengths over the exposure period is zero or a whole number of wavelengths and will subtract at other points."

Jan 1, 1989

By W. H. Ode, W. A. Selvig

Investigations have shown interesting relationships between primary-tar and light-oil yields and chemical analyses of coals. These studies have been based largely upon results published by the Bureau of Mines in connection with its survey of the gas-, coke-, and byproduct-making properties of American coals. This paper gives the results of a similar correlation in which the range in rank and type has been extended to include nearly all classes of coal, the object being to determine relationships that are significant in predicting tar and light-oil yields from chemical analyses of coals. The yields of primary tar and light oil are important in two fields of coal utilization, namely, combustion and carbonization. It is generally recognized that the principal cause of smoke produced upon burning coal is incomplete combustion of tar and light-oil vapor released during burning. The greater the tar and light-oil yields of a coal, the greater is its potential smoke-producing property. During the present war, development of new sources of fuel oil has been emphasized, especially where the supply of petroleum products is limited. One possible source of a substitute fuel is the tar and light oil that can be obtained by low-temperature carbonization of coal. In both England and Germany large quantities of low-temperature tar and oil are being processed as a source of liquid fuels. It is obvious that primary-tar and light-oil yields are of paramount importance in the selection of coals for such use.

Mar 1, 1944

By McHenry Mosier

The Bell mine operated by the Warner Co. at Bellefonte, Pa., has an annual production of about 600,000 short tons of high-grade limestone. Since 1924, shrinkage stoping has been the mining method. Horizontal, long-hole diamond-drilling for production in stopes was started with one machine in July 1946. It is now standard practice. The burden on the holes is 10 feet. Diamond bits are noncoring EX-size in both concave and pilot types. The two types have little difference in drilling speed at the Bell mine. The diamond drills are mounted on 3-inch single-screw columns. Diamond drilling shows a marked increase in efficiency at the Bell mine, compared to percussion drilling, with respect to tons broken per drill shift, tons broken per foot of hole, and tons broken per pound of explosive. The advantages of diamond-drilling blast-holes also include (a) improved safety, greater footage per drill shift, (c) better frag- mentation of the broken, stone, and (d) reduction in amount of barring down required in stopes because the working places are limited to slots which have a relatively small area.

Feb 1, 1948

By C. H. Elder

An experimental degasification program using a vertical borehole and vacuum pump to drain gas from the gob area of a longwall panel was successful at Bethlehem Mines Corporation, Cambria Division, No. 33 coal mine. Sixty-one million cubic feet of methane has been exhausted during a 9-month period. Daily production time in the panel increased as a result of lower methane levels in the returns. Removal of large quantities of methane in this way and the exclusion of it from the ventilating system will provide reduced cost in mine ventilation and provide a safer environment for the mine.

May 1, 1969

By Todd M. Ruff

A training software package for new mine employees, called Miner Training Simulator (MTS), has been developed by researchers at the National Institute for Occupational Safety and Health. MTS is a computer-based tool that allows a trainee to enter a simulated mine and interact with his/her surroundings in order to learn basic mining concepts, safety procedures, mine layouts, and escape routes. The training simulator software and instructions for its use are described in this report. Also, each mine using the software will have different requirements with regard to safety training. To customize the simulator for these differences, an interpreted scripting language is used to define interactions between the trainee and the virtual mine and objects in it. The scripting language, called Tool Command Language, uses simple commands to control various actions in the simulation, such as sounds, safety messages, hazards, and movement of objects. The basics of the scripting language are described here, along with many examples and instructions for building a script for MTS.

Jan 6, 2001

By Lewis V. Wade

This Bureau of Mines work was performed to theoretically determine the effects of specimen radius and specimen boundary conditions on the stress state in the rock near the anchor for rock specimens used to investigate expansion anchor behavior. Finite element analyses were performed on mathematical models of varying radius and boundary conditions. A review of the results of these analyses revealed a definite convergence of all stress measures considered as the specimen radius increased. There was, however, a significant variation in all stress measures as the specimen diameter increased from 8 to 12 inches.

Jan 1, 1973

By Andrew B. Cecala, Robert J. Timko, Alexander D. Prokop

Bag loading and stacking processes are the highest dust-exposure job categories in the metal/nonmetal mining industry.1 To cost-effectively decrease respirable dust levels, the Pittsburgh Research Center of the National Institute of Occupational Safety and Health (NIOSH), formerly of the U. S. Bureau of Mines, designed and tested a system called the Bag and Belt Cleaner Device (B&BCD). [ ]

By C. Stephan, E. Weiss, J. Trackemas, M. Sapko

The National Institute for Occupational Safety and Health (NIOSH), Pittsburgh Research Laboratory (PRL), in collaboration with the Mine Safety and Health Administration (MSHA), the mining industry and seal manufacturers, conducted a series of full-scale experiments within the underground experimental mine at PRL's Lake Lynn Laboratory. The purpose of the experiments was to evaluate the explosion-resistant characteristics of several new seal designs for rapid deployment during mine emergencies. These seals can be deployed in less than 12 hours and are capable of withstanding explosion overpressures in excess of 140 kPa (20psi). These novel seal designs use available mine materials, do not require conventional rib hitching and, most importantly, can substantially reduce exposure time for coal miners during sealing and mine recovery operations.

Provide low-cost fire protection for big bulldozers. Approach A fire protection system, previously used on mobile logging equipment and adapted to surface coal augers, has now been adapted for use on large mining bulldozers. How It Works Heat sensors mounted in the engine compartment and hydraulic hose areas detect the fire, usually before the operator does. This causes the system to automatically discharge A-B-C class dry chemical extinguisher through a fixed piping system. The system can also be manually activated from either the opera-tor's cab or ground level. Location of the principal components of the system are shown in the drawing The heat sensors of the sys-tem consist of bimetallic strip switches which operate at about 10000F temperature. Switch operation results in release of compressed gas from a small storage cylinder. The gas expands to blow the dry chemicals out of the nozzles, in a spray that lasts about 15 seconds. The compressed gas used is usually nitrogen, although carbon dioxide is also used.

Jan 1, 1978