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By L. A. Haas

Hydrogen sulfide was decomposed to elemental sulfur in an electrical discharge. With He, N., or Ar diluents, a threshold voltage between 1 and 3 kV was required for the decomposition reaction to occur in a laboratory ozonizer. Above the threshold voltage, the HAS decomposition rate increased with increasing voltage, but the increase was more pronounced with argon diluent than with either nitrogen or helium. In common with other reactions in an electrical discharge, the B2S decomposition decreased with increasing temperature in the range of -410 to +61° C. The reaction did not appear to be rate-controlled by a solid-gas sorption step because the introduction of activated charcoal into the electrical discharge zone did not significantly affect the decomposition yield. In the presence of polymeric chlorofluoro-carbon oil, 90 pct conversion of the 3 pct H2S in helium was obtained at 14 kV, 60 Hz, a 2-mm electrode gap, and a gas-residence time greater than 1 min. Under the same experimental conditions in the absence of oil, the conversion was only about 50 pct.

Jan 1, 1973

By R. V. Ramani, R. Srikanth, R. Zhao

"A two-pan study was conducted to understand the factors affecting respirable dust generation potential or dustiness of coal seams. In the first part, the data from three prior comprehensive laboratory studies was analyzed to establish quantitative relationships between respirable dust generation potential and coal characteristics. This analysis indicates that respirable dust generation rate is positively correlated with Hardgrove Grindability Index (HGI), fuel ratio (fixed carbon/volatile matter), Vitrinite Reflectance (VR), and Level of Organic Metamorphism (LOM). In the second part, specially-designed single breakage experiments were conducted to determine the primary dust generation potential of 17 coal samples obtained from four continuous miner sections, three longwall sections, and the Penn State Coal Data Bank. The single breakage study indicates that primary dust generation rate is positively correlated with fixed carbon content, fuel ratio (fixed carbon/volatile matter), VR, and LOM. Since VR and LOM are strongly influenced by the process of coalification, differences in respirable dust generation rates in different coal seams may be explained by the thermal metamorphism of sedimentary organic matter during subsurface burial.Mineral particles in the range of one to five microns, if inhaled in sufficient amounts, lead to a number of lung diseases generally referred to as pneumoconiosis. A priori knowledge of the mechanisms and rates of fine particle generation during mining can aid in the development of more effective technology for controlling primary dust generation. Unfortunately, the data and knowledge currently available are not adequate for this purpose. In fact, a committee of the National Academy of Sciences on the measurement and control of dust concluded that the knowledge of the fundamental mechanisms by which coal mine dust is generated and a part of it is entrained in the mine atmosphere as respirable dust is not sufficient to clarify, let alone control, the processes involved (Anon., 1980). Under a research contract from the U.S. Bureau of Mines, Stecklein et al. (1982) have identified a number of fundamental research issues for understanding the coal fragmentation and entrainment processes.Reduction of dust generation is the best means of control since fine particles are difficult to control once they become airborne. Therefore, considerable research efforts have been directed to understand the factors influencing dust generation and entrainment, including machine design, water sprays, and ventilation. Laboratory studies have been conducted on the mechanical action of bits and machine power requirements (Evans and Pomeroy, 1966; Roepke, 1984). Since the physical characteristics of coal play an important role in the process of breakage, a number of laboratory studies have been conducted to study the relationship between coal characteristics and respirable dust generation (Baafi, 1977; Moore, 1986; Polat, 1990; Thakur, 1971). Several studies have been conducted on the relationships between coal characteristics and airborne dust concentrations (Hamilton and Knight, 1958; Khair and Xu, 1991; Organiscak and Page, 1993; Page et al., 1993). A limited number of studies have also been conducted on the relationships between coal characteristics and airborne dust concentrations in mines (Organiscak et al., 1990). Yet, no reliable method has been developed to rank coal seams according to their respirable dust generation potential. The conclusions derived from previous studies can be summarized as follows:"

Dec 1, 1996

By G. F. Friel

A series of experiments in the U.S. Bureau of Mines Safety Research Coal Mine at the Pittsburgh Research Center evaluated the effects of crosscuts on the travel time of carbon monoxide (CO) along an entry to improve the accuracy of a mine-fire locator program. Three entries, ten single crosscuts, and three double crosscuts were instrumented with CO sensors. One-percent CO in nitrogen was released and monitored as it traveled the entries. In addition to dispersion of CO at the front of the CO wave, CO was entrained from the entry into the crosscuts. It was determined for an entry and single-crosscut configuration that the measured travel time for a concentration change of 5 ppm was 27% greater than the predicted time based upon entry volume only, but 13% less than the predicted time based upon entry and crosscut volumes. For an entry and double-crosscut configuration, the measured travel time for the same concentration change was 25% greater than the predicted time based upon entry volume only, but 10% less than the predicted time based upon entry and crosscut volumes. An effective dispersion coefficient for CO dispersion along one of the entries was estimated to be 1.5 m2/ s.

Jan 1, 2010

By Lindsay D. Norman

Four chloride and seven fixed-nitrogen processes for recovering manganese from domestic resources are described. The chloride processes are divided into two classes (leaching and chloridization) depending upon the major operation responsible for converting the manganese minerals to the chloride from which manganese oxide products are obtained. The fixed nitrogen processes, all of which yield high-grade manganese oxide products, are essentially either leaching or roasting processes. The 11 processes include HC1 leach, HC1 chloridization, HC1 chloride volatilization, CaC12 chloride volatilization, NO2 leach, HNO3-NO2 leach, NH3-CO2-H2O system leach, (NH4)2SO4 leach, (NH4)2SO4 roast, and ammonium salt roast.

Jan 1, 1963

By Robert M. Becker

The evaluation of existing rock stresses from measurements of the change in diameter of a borehole that is stress relieved by overcoring has become a common practice, The stress evaluation has been generally based ,on isotropic relations whereas rock in varying degrees is anisotropic. A plane elasticity solution for a circular hole along one axis of an orthotropic medium is adapted for evaluation of in situ stress from borehole deformation measurements. A consistent triaxial testing approach for determining elastic properties of the overcore is also outlined. Comparison of isotropic with anisotropic interpretations of the state of stress show that large errors in evaluation may occur if the anisotropic character of the rock is neglected.

Jan 1, 1967

By Lindsay D. Norman

Four chloride and seven fixed-nitrogen processes for recovering manganese from domestic resources are described. The chloride processes are divided into two classes (leaching and chloridization) depending upon the major operation responsible for converting the manganese minerals to the chloride from which manganese oxide products are obtained. The fixed nitrogen processes, all of which yield high-grade manganese oxide products, are essentially either leaching or roasting processes. The 11 processes include HC1 leach, HC1 chloridization, HC1 chloride volatilization, CaC12 chloride volatilization, NO2 leach, HNO3 leach, HNO3 ?NO2 leach, H3 ?CO2-H2O system leach, (NH4)2SO4 leach, (NH4)2SO4 roast , and ammonium salt roast .

Jan 1, 1963

By D. Montagna

This Bureau of Mines report describes a salt-free, fluxless method for reclaiming metallic aluminum from aluminum dross. The dross is smelted under argon, nitrogen, or carbon dioxide, instead of a salt flux, in an externally heated pot furnace. Aluminum recovery, using argon, is equal to recoveries reported from commercial smelters that process dross in rotary-type furnaces This salt-free method could offer a reduction in air pollution, lower energy requirements by elimination of salts, and the production of up to 60 percent less solid waste for disposal than the salt method.

Jan 1, 1978

By G. W. Birge

Carbonizing properties of the principal coalbeds of Elk, Clarion, Jefferson, Clearfield, and Centre Counties, Pa,, are described in this Bureau of Mines report, Twenty-six samples, representing the Upper Freeport, Lower Freeport, Upper Kittanning, Middle Kittanning, Lower Kittanning, and Brookville beds, were carbonized by the Bureau of Mines--American Gas Association (BM-AM) method, and yields of products and physical properties of cokes were determined. Expansion or contraction of the majority of the samples was measured in the Bureau of Mines sole-heated oven. Chemical analyses, agglutinating values, and free-swelling indexes are given for all samples. In this area the coals generally are characterized by high sulfur and moderately high ash content, and their suitability for metallurgical use would depend largely upon satisfactory cleaning. The samples from Elk, Clarion, and Jefferson Counties were high-volatile A bituminous In rank, whereas, most samples from Clearfield County and all those from Centre County were of medium-volatile rank. Coals from Clarion County had dry, mineral- matter-free fixed-carbon contents ranging from 56.5 to 60.3 percent and were weakly coking. With the exception of two samples which contained excessive ash, the medium-volatile coals of Clearfield and Centre Counties were strongly coking and, as indicated by sole-oven expansion results, would require blending with lower rank coal to avoid oven damage.

Jan 1, 1963

By X. C. Shi

Bacterial mutagenicity and mammalian cell chromosomal and DNA damage in vitro assays were performed on a diesel exhaust particulate material (DPM) standard in two preparations: as an organic solvent extract, and as an aqueous dispersion in a simulated pulmonary surfactant. U.S. National Institute for Standards and Technology DPM SRM 2975 expressed mutagenic activity in the Salmonella reversion assay, and for in vitro genotoxicity to mammalian cells as micronucleus induction and as DNA damage in both preparations: as an acetone extract of the DPM mixed into dimethylsulfoxide, and as a mixture of whole DPM in a dispersion of dipalmitoyl phosphatidyl choline. Dispersion in surfactant was used to model the conditioning of DPM depositing on the deep respiratory airways of the lung. DPM solid residue after acetone extraction was inactive when assayed as a surfactant dispersion in the micronucleus induction assay, as was surfactant dispersion of a respirable particulate carbon black. In general, a given mass of the DPM in surfactant dispersion expressed greater activity than the solvent extract of an equal mass of DPM.

Jan 1, 2009

In spite of advances in measurement techniques and an explosive increase in the volume of research, our understanding of human strength remains in its introductory stages. It is clear that muscle strength is a highly complex and variable function that depends on a large number of factors. It is not surprising, therefore, that large differences in strength exist not only between individuals, but even within the same individual tested repeatedly on a given piece of equipment. The issue is compounded by the fact that correlations of strength among different muscle groups in the same individual are generally low, and tests of isometric strength do not necessarily reflect the strength an individual might exhibit in a dynamic test. As a result of these and other influences, great care needs to be exercised in designing, evaluating, reporting, and interpreting muscular strength assessments. Traditionally, tests of muscular strength were in the domain of the orthopaedist, physical therapist, and exercise physiologist. Such tests are also an important tool for the ergonomist, however, because of the high strength demands on workers in manual materials-handling tasks. In some cases, task demands may approach or even exceed the strength that an individual is voluntarily willing to exert in a test of strength. In such cases, evidence suggests that the likelihood of injury is significantly greater than when the task demands lie well within an individual's strength capacity. Because the relationship among strength capabilities, job demands, and musculoskeletal injury has been established, it is apparent that tests of muscular strength may benefit the ergonomist both in designing jobs and in ensuring that individuals have sufficient strength to safely perform physically demanding jobs. Several strength assessment techniques have been employed for these purposes, each possessing unique characteristics and applicability to job design and worker selection procedures. Our main purpose has been to elucidate these strengths and weaknesses, so that tests of strength may be properly applied in designing jobs and selecting workers. One of the crucial points we have emphasized is that any test of strength used in job design or worker selection must be directly related to the demands of the job.(1) For example, if an occupational lifting task has a high dynamic component, a test of isometric strength is not likely to provide the data necessary for proper design of the job. Of course, dynamic strength tests would also be misapplied in assessing a job requiring isometric exertions. Another potential pitfall is using tests of strength on isolated muscle groups and assuming that they are indicative of whole-body strength. For example, one might mistakenly assume that dynamic trunk extension strength represents a person's capability to perform a lifting task. However, an individual's lifting capacity may be entirely unrelated to trunk extension strength. It may, instead, be limited by an individual's arm or leg strength, depending on the task being performed. A final point on strength assessment should be made. An individual's strength capability cannot be considered a fixed human attribute. Strength training regimens can increase an individual's strength capability by 30%-40%. Whether

Jan 1, 1998

By Richard G. Sandberg

The Bureau of Mins, U.S. Department of the Interior, is investigating a hydrometallurgical procedure to conserve cobalt, nickel, and copper by recovering the metals from the matte byproducts of smelting Missouri lead ores. For want of adequate processing technology the mattes are now either unmarketable or marginally so. The procedure involves leaching with manganese dioxide and sulfuric acid to obtain copper, nickel, cobalt, lead, and manganese sulfates, and elemental sulfur as expressed by the following reaction: MS + MnO2 + 2H2SO4 ? MSO4 + MnS04 + S° + 2H2O, where M = Cu, Ni, Co, and Pb. The leach solutions, containing near theoretical amounts of sulfuric acid and manganese dioxide at 85° to 100° C, convert up to 98 pct of the cobalt, nickel, and copper in the mattes to sulfates in less than 2 hr. As they are formed, the cobalt, nickel, and copper sulfates are dissolved leaving a residue of lead sulfate, lead, sulfur, and gangue. The soluble metals are recovered from the leach solutions by caustic and sulfide precipitation, and the residue returned to the smelter for lead recovery. The manganese can be reclaimed from the spent leach liquor as manganese oxide and recycled to leaching.

Jan 1, 1979

By R. E. Cerullo

Many computer programs have been written which are capable of performing a least squares fit, both linear and nonlinear, to data gathered by the petroleum researcher. However, when the petroleum engineer tries to program methods of analysis he has used manually in the past, such as forecasting production by decline-curve analysis, more than a knowledge of the use of existing least squares programs becomes necessary. It is the intent of the authors to report the techniques used in the development of such a decline-curve program.

Jan 1, 1970

By John B. Knaebel

Hammer machines are now widely used for underground sampling and exploration. Their application to such work can be divided into two classes - sampling and testing with ordinary drilling equipment to shallow depths of 22 feet or less, and "long hole" drilling with heavy machines and special equipment to depths of as much as 250 feet or more. In the first category hammer drills are employed for either of two distinct purposes: first, as a means of checking the results of grab or cut samples or, in certain types of ore deposits, as a substitute for these methods; and second, as a method of sampling the ground 5 to 20 feet beyond existing faces and thus aiding in the control of stoping operations or in the direction of development headings, as the case may be. The deep-hole drill, in the second category, has proved to be a valuable adjunct to the old established methods of exploring, end developing ore, provided it is employed under natural conditions to which it is suited, handled by men thoroughly familiar with the technique of its operations, and used with its possibilities and limitations clearly understood.

Jan 1, 1932

By W. I. Nelson

This paper which describes the milling practice of the Engels Copper Mining Co., is one of a series on milling methods being prepared for and published by the United States Bureau of Mines. ACKNOWLEDGMENTS Acknowledgment is made of the assistance rendered by J. Casagrande, mill foreman of the Engels concentrator, in collecting much of the data presented in this paper.

Jan 1, 1932

By Richard W. Watson

Card-gap and projectile impact sensitivity data are presented for a wide variety of explosive compositions tested at the Bureau of Mines in more or less standard test geometries. The results of both tests are in good agreement in that they provide the same sensitivity ordering for different subclasses of explosives. Least sensitive were homogeneous liquids that did not exhibit a tendency to undergo low-velocity detonation, ammonium nitrate-fuel oil, and most cast military explosives. Of intermediate sensitivity were pressed and powdered military explosives, cast pentolite, permissible and non- permissible water-based explosives, and one commercial two-component explosive. The most sensitive were permissible and nonpermissible dynamites and explosives susceptible to low-velocity detonation.

Jan 1, 1973

By James A. Wasson

The Mitchell and Berea sands were cored and logged in Fred Link well K-l, Lower Newport field, Washington County, Ohio. Core and reservoir fluid analyses and available field data were studied to determine if these sands could be successfully waterflooded. The results of the study indicate that there is insufficient oil in place to form an oilbank in either the western Mitchell pool or the Berea sand, and that no commercial recovery of oil by waterflooding can be obtained in these reservoirs.

Jan 1, 1967

By R. Hogg

"The basic population balance models for agglomeration processes are reviewed and procedures are described for extending their applicability to systems with size-dependent rate constants and to the formation and growth of porous agglomerates from rigid, solid particles. Simplified procedures for the further extension of the models to include simultaneous agglomerate growth and breakage arc also described. IntroductionThe association of small particles into clusters or agglomerates is a significant factor in many facets of particle processing. Agglomeration processes are widely used to facilitate handling, storage and utilization of fine powders. Processes such as coagulation or flocculation are used to aid solid-fluid separation in dispersed particulate systems. Agglomeration also occurs as an accompaniment, often unwanted, to other particulate processing operations such as fine grinding, mixing and blending, transport and flow.Reliable agglomeration models are needed for improved understanding of the processes in general and of the complex role of numerous, interacting variables as well as for direct application to the design and control of industrial processes such as flocculation, granulation and pelletization. Ideally, the models should account for the primary forces responsible for agglomerate ·formation and growth, the effects of external forces on process dynamics, the development of agglomerate structure and its role in the process itself, and the effects of concurrent processes such as structure modification (e.g. compaction) and agglomerate breakage or degradation.In its most general form, the process of agglomeration involves taking discrete, independent particles, bringing them into contact with one another, promoting (or allowing) interparticle adhesion to occur and then causing structure rearrangement, usually under the action of external forces. The relative importance of these steps varies with the nature of the particulate system being agglomerated and with the kinds of agglomerates being produced. Coagulation or flocculation of particles dispersed in fluids is generally dominated by the contact and adhesion steps. In the granulation of powders, on the other hand, particles are already in contact so that structure rearrangement is the principal step."

Mar 1, 1992

By W. H. Oppelt

To provide a relatively structurally stable form of dried lump lignite, two North Dakota lignites from Mercer County were dried by the Fleissner process in an atmosphere of saturated steam at 200, 300, and 370 p.s.i.a. pressure, corresponding to steam temperatures of 382°, 417°, and 437° F., respectively. Two series of experiments were made at each test pressure with the individual lignites. In one series, the autoclave was preheated to the processing temperature before charging the lignite; in the other the lignite was charged into the autoclave at room temperature. In each case, heat losses were determined by blank tests of steam consumption over a similar operating cycle with the empty autoclave. The degree of moisture removal and net steam consumption were calculated from material balances. The amount of water removed as a liquid from the two North Dakota lignites during the heating and steaming periods was compared with results calculated from previously published data on drying Austrian lignite and Australian brown coal. These lignites, covering a wide geographical area, had original moisture contents ranging from 35 to 49 percent. The Austrian lignite and Australian brown coal are considered to be of Miocene Age, and the Dakota lignites belong to the Paleocene.

Jan 1, 1955

By Ralph H. Espach

In the spring of 1943, when it was evident that the Tensleep sandstone in the Elk Basin field, Wyoming and Montana, held a large reserve of petroleum, Bureau of Mines engineers obtained samples of oil from the bottom of nine wells and analyzed them for such physical characteristics as the volumes of gas in solution, saturation pressures or bubble points, shrinkage in volume caused by the release of gas from solution, expansion of the oil with decrease in pressure, and other related properties. The composition of the gas in solution in the oil was studied. The pressures and temperatures existing in the reservoir and the productivity characteristics of the oil wells were determined. The data obtained indicate that the oil in the Tensleep reservoir of the Elk Basin field has unusually varying physical characteristics, such as a saturation pressure of 1,250 pounds per square inch absolute and 490 cubic feet of gas in solution in a barrel of oil at the crest of the structure, and a saturation pressure of 530 pounds per square inch absolute and 134 cubic feet of gas in solution in a barrel of oil low on the flanks. The hydrogen sulfide content of the 6a r; in solution in the oil varies from 18 percent for oil on the crest to 5 percent for oil low on the flanks of the structure. Of even greater significance is the fact that these and other variable characteristics of the reservoir oil are related to the position of oil in the structure. Many geologists and petroleum engineers have considered all the oil in a petroleum reservoir to have uniform physical characteristics and that equilibrium conditions prevailed in all underground accumulations of oil and gas. That such is not always so is borne out by the results of the study made by the writers.

Jan 1, 1951

By L. R. Burdick, R. Wiggers, J. F. Berkley

"INTRODUCTION On February 23, 1944, Solid Fuels Administrator Harold L. Ickes stated that the existing fuel shortage made it necessary to utilize a great surplus of freshly mined anthracite ranging in size from Barley (No. 3 Buckwheat) downward through the smaller sizes. As a part of the program to increase the use of such coal, field trials of mixtures of bituminous slack coal and anthracite Barley were made on industrial-size stokers at many fuel-burning plants. The following covers the test information it was possible to accu-mulate during the work of initiating the use of these mixtures at the plants.SUMMARY AND CONCLUSIONSField tests of various mixtures of bituminous slack coal and anthracite Barley on industrial-type stokers show that the use of such mixtures is very practicable and that it is possible to change and usually to adjust to an improved condition the characteristics of a fuel bed of eastern bituminous slack coal by the addition of proper amounts of anthracite. The improved uniformity of the fuel bed of single-retort stokers makes possible less manual attention to the bed. Air flow through the fuel bed is affected.Smoke is decreased. In general, the fly ash and also the unburned combustible in the fly ash and refuse are increased. Clinkering in the fuel bed is generally lessened. The peak-load carrying capacity of the stoker is definitely affected, usually adversely for the higher percentages of anthracite."

May 1, 1946