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By R. K. Koch

The vapor pressures of liquid molybdenum and liquid zirconium were determined by the Langmuir free-evaporation method. An electron-beam furnace with a water-cooled copper crucible was used for melting. Temperature was measured with a two-color ratio pyrometer. The vapor-pressure data led to the following equations: [log p (atm) = 5.429 - 28,380 T for liquid molybdenum in the range 2,890° to 2,990° K, and log p (atm) = 6.521 - 30,940 T for liquid zirconium in the range 2,229° to 2,795° K.] Third-law evaluations of each data set gave mean heats of sublimation (298.15° K) of 157.6 ± 1.8 kcal/mole and 148.4 ± 2.4 kcal/mole for molybdenum and zirconium, respectively, where the uncertainties are two standard devia¬tions. Second-law standard heats of sublimation determined from sigma plots and tabulated enthalpies were 143.5 ± 2.7 kcal/mole and 149.2 ± 3.8 kcal/mole for molybdenum and zirconium, respectively. The better agreement in heats of sublimation for zirconium is attributed to the 566° K temperature range studied which permitted a more accurate definition of the vapor pressure curve than could be obtained from the 100° K span for molybdenum. This supposition was verified by making a sigma-prime plot which utilized solid vapor pressure data for molybdenum to extend the evaluation range by 800° K. This gave a standard heat of sublimation of 155.2 ± 1.6 kcal/mole which is in good agree¬ment with the third-law value. The plot also gave a standard entropy of sublimation (298.15° K) of 35.73 ± 0.48 eu.

Jan 1, 1968

By F. W. Wessel

This report summarizes Bureau of Mines laboratory tests of four tungsten¬-bearing materials of various grades, The test work has demonstrated that the dry reaction between sodium carbonate and scheelite is best conducted at 900° C. or a few degrees less. The sodium carbonate requirement, in addition to the stoichiometric equivalent of the scheelite, is in some inverse relationship to the grade of tungsten in the ore. Residence time and particle size exert a definite but minor control on the reaction. Pressure-digestion tests on an impure concentrate indicate the technical feasibility of extraction by this process. INTRDUCTION Over 100 years ago Oxland discovered that tungstic oxide could be removed from wolframite and converted to a soluble form by reacting the mineral with a soluble alkaline salt at elevated temperatures. He patented this discovery, and this patent 4/ since has been the basis for most tungsten extraction. Much literature exists on this process and its modifications, and the characteristics and possibilities of the reaction are quite well defined.

Jan 1, 1956

By F. Fraas, H. H. Storch

"In the second paper 4 of this series, data were presented concerning the decomposi¬tion of polyhalite by saturated salt solutions. It was found that uncalcined polyhalite upon leaching with boiling saturated sodium chloride solutions yielded a brine in which the (K2 Mg) /304 ratio was considerably higher than that obtained from the calcined material, and for this reason appeared more suitable for the production of potassium chloride. It was found, in fact, that the leach liquors from uncalcined polyhalite deposited a mixture of KC1 and NaC1 upon evaporation and subsequent cooling, whereas those from calcined polyhalite yielded mixtures which contained not only potassium and sodium chlorides but also large quantities of glaserite, K3Na (S04)2. Hence it was decided to study the evaporation of the uncalcined poly—halite leach liquor and postpone experiments on the calcined polyhalite liquors until such time as a process for further removal of sulphate was developed.A considerable body of equilibrium data is available in the literature on thesystem K+ Mg++ — Na+ Cl—S04 =,— H20 for temperatures up to 83º C. Owing, however, tothe lack of data other than that corresponding to the invariant points and the complete absence of data for temperatures of 100 to 115°C., and owing to the fact that supersaturation phenomena render unsafe the prediction of the behavior of such a system upon evaporation, it was considered essential to obtain the necessary data by actual evaporation and analysis of the brines thus obtained."

Feb 1, 1931

By Harry E. Tuff

"This paper is based data obtained by the Bureau of Mines from some of the principal mine operators in Pennsylvania, in the course of a study conducted in cooperation with the U. S. Forest Service, with regard to economies that might be effected in the selection storage, and preparations of timber particularly treatment with preservative to prolong its life.The Pennsylvania anthracite region, considered as a single mining district is by far the largest user of mine timber of any mining district, either coal or metal, in the United States, and the bituminous districts of Pennsylvania rank second. The present annual consumption of mine timber by the coal-mining industry of Pennsylvania probably exceeds 100,000,000 cubic feet annually.In 1919, Pennsylvania produced, in round figures, 145,300,000 tons of bituminous coal, 86,200,000 tons of anthracite, and 5,400,000 tons of iron ores. If it be assumed that the bituminous coal mines required 0.33 cubic feet, anthracite mines 0.7, and iron mines 0.9 cubic feet per ton mined the timber requirements were bituminous. 47,950,000; anthracite, 60,340,000; iron mines, 4,860,000 or a total of over 113,000,000 cubic feet.The average cost of round mine timber in the anthracite region in 1905, was, according to the U. S. Forest Service, 6.6 cents per cubic foot, and $15.00 per 1000 board feet for sawed timber. The present cost Las advanced to 27.5 cents per cubic foot for round timber, delivered to the mine, of which cost 57.4, represents freight charges."

Nov 1, 1923

By H. P. Hermance

The Ore Hill zinc-lead mine in Grafton County, N. H., was investigated by the Bureau of Mines from March to July 1943 and from August to October 1944. Fourteen holes with an aggregate bore of 4,899 feet were diamond-drilled, the old workings were unwatered and sampled to an inclined depth of 250 feet, and the tailings dumps were surveyed and sampled. The deposit at the Ore Hill mine comprises a bedding-plane vein of massive sphalerite and galena with subordinate chalcopyrite and pyrite in a series of interbedded metasedimentary and metavolcanic schists about one-quarter mile east of their contact with the intrusive Baker Pond gneiss. The property was first opened about 1850 and was active at times to 1914. Production records are not available, but the output is believed to have been considerable. In 1944, leasers recovered a marketable mica product from mica schist from the dumps and certain outcrops. This report describes the work performed in the Bureau's investigation and presents the data obtained.

Jan 1, 1948

By Frederick W. Horton

With large deposits of low-grade molybdenum ore and a latent market for molybdenum, which with development might perhaps equal that for tungsten, the United States has for years made no pro- duction of molybdenum ore worthy of mention. In fact, during the decade previous to 1914, there was no output of molybdenum ore in this country except in 1905, 1906, and 1907, when a few small lots of molybdenite and wulfenite were marketed." To ascertain why this possible source of economic wealth should remain undeveloped, the United States Bureau of Mines undertook an investigation in 1914, with a view of assisting the establishment of a molybdenum industry in this country. A preliminary review of the situation showed the following conditions: Briefly there was a lack of any considerable demand for molyb- denum for the one known use that might consume any large tonnage of it, that is, for the manufacture to certain alloy steels to which molybdenum imparts properties roughly similar to those produced by tungsten. It was at once evident that the market for molybdenum in alloy steels must be developed, or that extensive new uses for the metal must be created, before the demand would be sufficient to war- rant any extensive mining of molybdenum ore. Investigation showed that one of the chief factors in retarding the development of any demand for molybdenum by the alloy-steel trade was that manufacturers who might use, or might investigate the possibilities of using, the metal were kept out of the market by the fear of not being able to obtain steady supplies. On the other hand, those who might be interested in the development of some of the extensive low-grade molybdenite or wulfenite deposits in this country were prevented from doing so by the small visible demand and the fear that any large production would glut the market. Owing to these conditions the mining of molybdenum has in the past been confined almost entirely to small-scale operations on high-grade streaks of molybdenite ore, and the methods of recovery have been limited largely to cobbing and hand picking.

Jan 1, 1916

By John A. Breslin

Size distributions and concentrations of particulates emitted from diesel engine exhausts were measured with cascade impactors. Samples were taken from the exhaust of two types of engines using three types of fuel and operating under five different engine speed and load conditions. The measured mass median diameters of the diesel particulates were typically about 0.3 um. There was no significant difference in mass median diameter between engines or fuels and only a slight dependence on operating mode. Concentration measurements ranged from 14.2 to 250.9 mg/cu m, and calculated mass outputs, from 52 to 3,443 mg/min. Significant differences in mass output were found between engines, fuels, and especially between different operating modes. The quantity of clean dilution air that would be required to reduce the particulate mass concentration below the 2.0 mg/cu m respirable dust standard for coal mines was greater than the dilution air required to meet the standards for noxious gases for both engines tested.

Jan 1, 1976

By Henry E. Blake

The Bureau of Mines has been engaged in a continuing research effort to develop processes for increasing the recovery and utilization of fluorine from low-grade resources. This current research has shown that over 98 percent of the fluorine in phosphate rock is extracted when the ore is treated with excess phosphoric acid in the presence of water vapor at 150° to 180° C. More than 80 percent of the fluorine can be recovered as fluosilicic acid, which can then be converted to commercially useful hydrogen fluoride or fluorspar by previously developed Bureau processes. Extraction of P205 from the ore was about 98 percent in batch tests and 90 percent in semicyclic tests.

Jan 1, 1974

By R. Hogg, T. F. Dumm

"A procedure for evaluating the size/specific gravity distribution of ultrafine coal and the distributions of sulfur and ash with respect to particle size and specific gravity is described. The procedure is essentially an extension of the conventional coal washability technique in which special precautions are taken to ensure particle dispersion in the heavy organic liquids, centrifuges are used to obtain adequate separation rates, and micromesh sieves are used for size separation at fine sizes. An example of the application of this technique to the evaluation of the extent of liberation of sulfur and ash in a coal sample ground to 90Z passing 200 mesh (74 um) is described.INTRODUCTIONIn order to determine the potential for deep cleaning of coal by fine grinding to liberate sulfur and ash-forming minerals, it is necessary to obtain data on the distributions of these species by size and specific gravity. In conventional coal processing operations, this information is obtained by means of a standard ""washability"" analysis. Attempts to extend this procedure to ultrafine coal, however, have generally been unsatisfactory and have often led to unreliable and inconsistent results [11. The present authors have described a modified washability procedure in which cumulative specific gravity fractionation is combined with sub-sieve size analysis (by laser diffraction/light scattering) to determine the particle size/specific gravity distribution of ultrafine coal [2]. Unfortunately, because this technique does not involve separation of the individual fractions, only limited information can be obtained on the specific distributions of sulfur and ash.The objective of the work described in this paper was to develop and evaluate a procedure for size and specific gravity fractionation of ultrafine coal and to use conventional analyses for sulfur and ash to determine their relative distribution in the coal. The procedure is essentially a simple extension of the standard washability analysis [3] but incorporating special precautions for treating ultrafine particles.EXPERIMENTAL Material The material used in the development and evaluation of the ultrafine coal fractionation procedure was a medium volatile bituminous coal from the Lower Kittanning seam. A sample of the coal (nominally - 1/4 inch), obtained from the Penn State Coal Data Base, was ground to 90% passing 200 mesh by the following two-stage grinding procedure: About 2 kg of the as-received coal were ground to about 30Z passing 200 mesh in a Model 4-E Quakertown mill (""coffee grinder""). About 1 kg of this product was then ground to about 90Z passing 200 mesh in a Holmes Model 300 Pulverizer."

Jan 1, 1989

By H. P. Hermance

The Ely mine, which at one time was the largest producer of copper in the United States, has been idle for the past 30 years. A remarkably continuous ore shoot probably averaging 100 feet wide and 19 feet thick was mined on about a 25° slope for 3,400 feet on the incline. The ore was massive sulfides containing chalcopyrite, pyrrhotite, pyrite, and sphalerite. The estimated production of the Ely mine is 400,000 tons of ore averaging 3.3 percent copper. Because of the critical position of copper during the recent war, a search for extensions and recurrences of parallel ore shoots at the Ely deposit seemed warranted. The Bureau of Mines surveyed selected areas by geophysical methods, diamond-drilled nine holes, and sampled mine dumps during its investigations, which began in 1942 and terminated in 1946. The diamond drilling totaled 5,229 feet. The logs of the holes include chemical analyses of mineralized sections.

Jan 1, 1949

By R. V. Lundquist, H. Leitch

The solubility characteristics of mono calcium aluminate (CaO A₁₂ 0 ) in water and in NaOH , Na₂ CO₂ , and NaOH - Na₂ CO₂ solutions were measured by determining the changes in Al2O3 concentrations in solution over a period of time at a specified temperature . The monocalcium aluminate was synthesized by sintering its starting components for 72 hours at 1,375 ° C. Distilled water and aqueous solutions of technical grades of NaOH and Na₂ CO₂ were used as solvents . The extraction of alumina from the monocalcium aluminate was dependent on the composition of the solvent and partially dependent on temperature for leaching . About 98 percent extraction of alumina from the aluminate occurred in Na₂ CO3 solutions containing 10 to 12 percent NaOH . Other solution compositions produce lesser extractions .

Jan 1, 1963

By Jerry W. Ramsey

The Bureau of Mines examined a low-, a medium-, and a high-volatile Pennsylvania anthracite by densimetric methods using four mesh si.s of each anthracite. Using high-pressure mercury the macropore volumes and distributions of these pore volumes determined, densities in mercury were calculated, and specific pore vo1.r. ware obtained from these mercury densities in conjunction with helium densities. The helium densities were also used with the ultimate analyses of these anthracites in calculating structural parameters by statistical densimetric methods. The effect of 106 or 108 rads of gamma irradiation in the presence of air and in vacuum upon the properties studied with two mesh sizes of each anthracite. Results of the statistical densimetric method seem to show some breakdown of condensed ring structural units at the lower irradiation level, with subsequent polymerization at the longer period of gamma irradiation. The structural parameters obtained also indicated that in going from high- to low-volatile anthracite, either the number of condensed rings per structural unit increased, or the degree of polymerization increased.

Jan 1, 1965

By Fremont T. Johnson

Credited with production of more than 164,000 flasks Of quicksilver from 1876 to 1944, the Oat Hill mine has ranked third in output in the United States. During World War II, when the demand for mercury was high, this property was selected for diamond drill with the purpose of increasing ore reserves so that production could be maintained or, if necessary, increased. Although the existence of marginal-grade ore (fill material) left in the stapes and possibly of virgin ore of good grade had suspected in certain parts of the Oat Hill mine, no factual information to tonnage, grade, or location was available. In close cooperation with the Federal Geological Survey, the Bureau of Mines studied old records and the few available incomplete maps. Diamond drilling began in November 1943 and was completed in December 1944. Twenty-eight holes aggregating 8,121 feet were drilled, in only parts of the promising areas disclosed by the study of the data available. Detailed data on the work done by the Bureau as well as a brief history of the property and some operating details are described in this report.

Jan 1, 1949

By Robert W. Freedman, Robert L. Craft, William G. Humphrey

As part of a continuing effort to reduce the weight and bulk of equipment that mining personnel must carry underground, the Bureau of Mines and the Mining Enforcement and Safety Administration (MESA) investigated accurate and convenient gas samplers for use by mine inspectors in sampling mine atmospheres. The samplers are septum-stoppered glass vials commonly used for routine blood sampling. These lightweight, compact samplers yield results comparable with those obtained with conventional bottle samplers of 250-ml nominal capacity.

Jan 1, 1975

By W. H. Oppelt

A lignite from west-central North Dakota (Mercer County) was dried by the Bureau of Mines by the Fleissner process at saturated steam pressures to 1,500 pounds per square inch absolute (p.s.i.a.). Normally, the process is operated at pressures of 200 to 370 p.s.i.a. At the highest pressure the temperature of the saturated stearn is 596° F. The purpose of the investigation was to evaluate the influence of very high stearn pressure and temperature on moisture removal, steam consumption, and physical and chemical characteristics of the dried lignite. Two drying cycles were used: A normal cycle, corresponding to previously established standard time requirements, and an accelerated cycle, wherein time requirements were determined by boiler capacity and handling speed. Blank tests to determine stearn requirements for heating the empty autoclave were performed for each cycle and each test condition. Moisture removal, final moisture content, net steam consumption, and size stability of the dried lignite were determined.

Jan 1, 1959

By Rogers F. Davis

This publication has been prepared to supply manufacturers and industrial users a listing of mobile diesel-powered equipment and subassemblies approved and certified by the Bureau of Mines for use in noncoal mines. Testing of diesel-powered equipment is one phase of the Bureau's program of health and safety that concerns approval of electrical and diesel equipment designed to prevent explosions, fires, shocks, or toxic hazards in underground mines, when such equipment is used and maintained properly. Manufacturers submit machinery and component parts to the Bureau for study of their design, safety features, and use. Equipment must pass exacting tests and must meet strict requirements established through research and experience and listed in the Bureau's permissible schedules before the Bureau approves it as permissible for safe use in mines.

Jan 1, 1963

By R. H. Bedford, F. T. Johnson

"In California the history of tin mining began in Riverside County in 1853, with the discovery of the Temescal deposit. This deposit remained the only one with a production record until recent small shipments were made from Kern and San Bernardino Counties.According to the California State Division of Mines, Temescal's total output has been about 125 tons of tin, all of which was produced in 1891 and 1892. It was idle from 1892 to 1928.An extensive but unsuccessful development campaign carried on in 1928 and 1929 by the American Tin Corp. produced only half a ton of the metal, and the property again was idle until 1943, when an attempt to resume operations proved unsuccessful. After 1929 no production is recorded from California until 1944 end 1945, when small shipments of sorted ore from Kern County returned about 2 tons of tin and 1-1/3 tons was recovered from sorted ore and concentrates from San Bernardino County. The total output of tin from California has been less than 150 tons, and less than 4 percent of this was produced in the last 50 years, in spite of numerous attempts during that period to promote tin mines,So marked a scarcity of a metal essential in war makes any occurrence interesting. When some prospects were reported to the Bureau of Mines in July 1942, in a new field 10 miles east of Gorman, they were at once examined and the preliminary exploration by the owners closely followed. Eventually one was explored by bulldozing end diamond drilling as a joint project by the Bureau of Mines and the Geological Survey.To supplement this joint project, the authors undertook independently a general survey of tin in California - a survey designed to check reported occurrences and to bring their status up to date. In this work, the 37 places described in the text and spotted on the accompanying map, (fig. 1) were visited end sampled. Although traces of tin were found in many pieces, nothing that suggested a tin mine was found anywhere, and it is difficult to base much hope for appreciable future tin production upon anything found thus far in California."

Apr 1, 1946

By J. H. Field

Results of studies by the Federal Bureau of Mines on a pilot-plant scale for removing hydrogen sulfide and carbonyl sulfide from gas mixtures by the hot carbonate system are given in this publication. Gases containing up to 10 pet. hydrogen sulfide and 48 grains carbonyl sulfide per 100 cu.ft. were treated. In most tests carbon dioxide also was present and was removed simultaneously with the sulfur compounds. Because the rate of absorption of hydrogen sulfide is much more rapid than that of carbon dioxide over a wide temperature range, selective removal of hydrogen sulfide occurred in the bottom section of the absorber near the point of gas entry. Hydrogen sulfide was removed to pipeline specifications with carbonate solutions by using split-stream flows in the absorber and regenerator.

Jan 1, 1960

By J. H. Jacobs

The first authorization, in November 1940, was for a plant of only several hundred pounds capacity at Boulder City, Nev. Improvements in the process and subsequent additions to some sections have enabled the plant to produce more than 2,000 pounds of manganese per day for substantial periods. By the time pilot-plant operations were suspended in June 1945, over 1,500,000 pounds of metal had been produced. The future of electrolytic manganese production obviously depends not only on satisfactory development of methods but on availability of raw material and demonstration of valuable uses. Investigations of manganese-ore deposits in this country, made since 1938 by the Bureau of Mines, have revealed large amounts of ore suitable for making electrolytic manganese. At first the pilot plant was operated on ore from the Three Kids mine near Las Vegas, Nev. After practical features of the process had been worked out, other ores from throughout the United States were tested in the pilot plant. The purpose of this paper is to compare the results obtained on the following ores: Three Kids; Ladd mine, Tracy, Calif.; Chamberlain, S. Dak., nodules; and ore from Metals Reserve stockpiles at Deming, N. Mex.; Cushman, Ark.; and Philipsburg, Mont.

Dec 1, 1947

By Don B. Hunter

The Bureau of Mines investigated the extraction of alumina from calcined kaolin by leaching with boiling RCI in a train of three 50-gal continuous, stirred reactors. Slurry discharged from the reactors con-tained an excessive amount of fines, which impeded solid-liquid separation. Autogenous grinding of coarse solids that accumulated in the reactors was the source of the fines. This report describes modifications to the reactors and to the operations that led to decreased fines generation and improved solid-liquid separation. Modifications to the reactors included custom-made impellers, the addition of a baffle system, a subsurface slurry discharge system, and slower rotation of the impellers. Concurrent testing of a continuous horizontal belt filter showed that the form filtration rates were increased from 350 to almost 1,000 Ib/h+ ft-2 when the modified reactors were used.

Jan 1, 1984