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By C. Ortuglio

The effect of cracking by increasing the free space above the charge on the composition and yields of the volatile products from carbonization of Pittsburgh-bed coal and one industrially used blend from Eastern United States and one from Western United States was investigated with the BM-AGA carbonization apparatus. Increasing the free space above the charge from 1 inch to 3 inches, to 6 inches, and to 9 inches resulted in lower tar yields and increased gas and light oil yields. Anthracene and naphthalene yields were increased; quinoline and benzene insoluble fractions of both the tar and pitch increased considerably with increased free space, although the carbon content of the tars and pitches increased only slightly. Increased cracking, occasioned by the increase in free space, resulted in a decrease in the yields of tar acids, tar bases, neutral oils, olefins, aromatics, and paraffins and naphthenes. Gas composition was relatively constant; hydrogen and methane tended to increase and ethane decrease. Results of the investigation are being used to design a unit to upgrade the volatile products of carbonization by cracking the hot products as they leave the carbonization chamber.

Jan 1, 1970

By Noel N. Moebs

The Bureau of Mines measured surface subsidence above four small coal mine room-and-pillar sections in southwestern Pennsylvania, to obtain preliminary information on the magnitude and character of selected parameters, such as angle of draw and maximum subsidence, which are essential to the development of subsidence prediction methods. Data varied widely at the four sites; this is attributed to local geologic and mining conditions. Surface deformation at each site was of a magnitude normally associated with severe structural damage.

Jan 1, 1982

By A. J. Kraemer, O. C. Blade

This report on the properties of motor fuels sold through service stations in the United States is a continuation of a series of reports made in accordance with a cooperative agreement between the Coordinating Fuel Research (C. F. R. ) Committee of the Coordinating Research Council (C. R. C.) and the Bureau of Mines of the United States Department of the Interior . The first of these reports contained data on motor gasolines sold during the winter of 1935-36 and further reports on motor gasolines sold during the succeeding summers and winters to the summer of 1941

Dec 1, 1943

By Walter T. Lewiecki

Bauxite was first discovered in-the United States near Rome, Ga., in 1887, Approximately 400,000 tons of bauxite ranging from 46 to-62 percent alumina were mined in the area from 1888 to 1930. In February 1943, The Republic Mining & Manufacturing Co. installed a dryer and began mining and reworking dumps from the old bauxite mines. Some 3,000 long tons were dried and shipped to the chemical industries from March 1943, to June 30, 1943. In 1941 and 1942, representatives of the Bureau of Mined and the Federal Geological Survey/ visited this area and proposed an exploratory project that at first was to be confined to the Heritage district northeast of Rome (see fig; I). The Bobo district, southwest of Rome, was to be explored after work .1n the Hermitage district was completed. The Hermitage district comprises an area of about 50 square miles in the northwest quarter of Bartow County and the adjacent portion of Floyd County. It is bounded on the north by the Gordon County line, on the east by U. S. Highway 41, on the south by U. S. Highway 441, and on the west by State Highway 53.

Jan 1, 1949

By A. T. Coumbe

During 1953-55, 31,105 miles of pipe for transporting crude petroleum and refined products was laid in the United States, a total slightly below that of the prior 3-year period, according to data compiled by the Bureau of Mines, United States Department of the Interior. The added mileage consisted of 22,571 miles of new pipe, representing about 2,163,807 tons of steel, plus 8,534 miles of secondhand pipe, equivalent to about 419,849 additional tons of steel. During the 3-year period, 13,069 miles of pipe was taken up. By January 1, 1956, the Nation had 188,540 miles of pipeline, an 11-percent gain over the 1952 total of 170,504 miles. The greater use of larger diameter pipelines indicated in recent surveys has continued, as the mileage for sizes 12 inches and over increased from 13 percent of the total mileage at the close of 1952 to 16 percent 3 years later. Crude-oil trunklines 12 inches and over in diameter gained 24 percent during 1953-55, and these larger lines represented 30 percent of the total mileage compared with 25 percent at the close of 1952. Furthermore, the mileage for crude-oil lines less than 12 inches in diameter declined 2 percent and made up only 70 percent of the 1955 total against 75 percent n the previous survey. Product Lines 8 inches and over increased 43 percent from 1952 through 1955 and composed 70 percent of the total mileage compared with 66 percent in 1952.

Jan 1, 1956

By B. W. Gandrud, G. D. Coe

"INTRODUCTION The Southern Experiment Station of the U.S. Bureau of Mines, cooperating with the University of Alabama and Alabama coal producers, has made a series of investigations of the washability of coal from commercially important bens of Alabama. The results of 13 investigations pertaining to the Mary Lee, Clark, Black Creek, Jefferson, Pratt, Corona, Carter Brookwood, Blue Creek, Thompson, and Woodstock beds have been published. 4/ This report, the fourteenth of the series, deals with run-of-mine coal from the Henry Ellen bed at the Acmar No. 5 mine of the Alabama Fuel & Iron Co.The Acmar mine is 1/2 mile west of Acmar, Saint Clair County, in the northern part of the Cahaba field. Present production at the mine is about 800 tons per day, all of which, accept the lump coal, is treated in jigs. The washability data were obtained by means of screen-sizing and float-and-sink tests. There are included, also, tests showing the extent of liberation of impurities by recrushing the coarser sizes of coal from the top bench and tests showing the flakiness in selected sizes.SAMPLING AT THE MINEThe Henry Ellen bed at Acmar consists of two benches separated by a shale parting. At the point of sampling the top bench was 6 feet 3 inches thick and contained a 1-inch and a 1 1/2-inch band of bone. The bottom bench was 5 feet thick and was separated from the top bench by 20 inches of shale. In taking the samples for the washability study the working face was squared up, and a representative 2-ton section was out from each bench. The shale parting was discarded, according to usual mining practice."

Nov 1, 1936

By William O. Vanderburg

Some mines after passing through the prospecting stage and becoming sizable enterprises still adhere to the development program of the prospect, extending their workings without definite plans. In mining operations where definite structural conditions do not exist, a prearranged layout of mine development is not feasible; but where exploration and preliminary development have indicated the extent and probable limits within which the ore is expected, careful planning of development will result in a lowering of mining costs and a consequent increase is profits. A lack of definite plane for laying out mine workings is one of the contributory factors to unnecessarily high costs. Although this paper deals primarily with the influence of level spacing on mining costs, still other phases of mine development, such as the proper spacing of ore chutes and raises, can be analyzed on a cost basis in a similar manner, as shown herein. LEVEL SPACING The problem of establishing a new level or levels in order to exploit steeply dioping ore deposits and prospect the ground at depth recurs at intervals during the active life of mines. Driving levels is largely "dead work" and therefore costly. By the judicious selection of the proper level interval after balancing the opposing factors involved in the problem, a considerable saving in mining costs can be effected. Although much has been written in regard to the various methods employed in ore extraction, mining literature is still incomplete in regard to the factors-influencing level spacing at various mines. Level spacing involves procedures not lending themselves readily to description, and, moreover, it is a phase of mining operations that is apt to escape criticism, because only those in close contact with the operations are equipped with the necessary familiarity with the conditions to pass judgment.

Jan 1, 1932

By Henry E. Blake

Defluorination studies on refractory fluoride - bearing compounds and minerals , particularly on partly defluorinated residues from high - temperature pyrohydrolysis , required a dependable and reasonably accurate analyticalcontrol method for the analysis of fluorine . The difficulty in liberating fluorine from the fluorides of metallic elements such as aluminum, zirconium , and rare earths by steam- distillation can be largely overcome if the distillation is made from a sulfuric - phosphoric acid solution of a sodium carbonate fusion of the sample material and if the distillation temperature is maintained at about 155 ° C. The data presented in this paper show that liberation of fluorine by this method is more complete and proceeds more rapidly than by usual distillations from perchloric or sulfuric acid alone or a mixture of phosphoric and perchloric acids . Fluorine in amounts ranging up to about 140 mg can be recovered by collecting only about 300 ml of distillate . Determination of fluoride in the distillate is made by the usual thorium nitrate titration .

Jan 1, 1963

By NIOSH NIOSH

This work explores application of a double alkaline leach method to extraction of alumina from Oregon ferruginous bauxitic materials. The process recovers a greater proportion of alumina from high-silica ores than is possible by a conventional single-leach method. This recovery is accomplished by calcining the ore, removing reactive silica in a preliminary dilute caustic soda leach, and then applying a second leach to dissolve alumina. Ores containing up to 15 percent Si~) 35 percent AI;:) Os, and 30 percent Os were examined. Under conditions of treatment established by experimentation, more than BO-percent alumina extraction was demonstrated. When and if conditions demand the use of low-grade materials, the double-leach process is capable of providing millions of tons of alumina from Oregon ferruginous bauxite.

Jan 1, 1963

By M. E. Tyrrell

Despits its high melting point (2,135° C.), resistance to attack by molten metals, and its hardness (8), spinel (MgO?Al203) synthesized by the fusion of alumina (Al 2 0.) and magnesia (MgO) is not used on a large scale as a commercial furnace lining, mainly because of the prohibitive cost. This investigation by the Federal Bureau of Mines was prompted by the possibility of producing synthetic spinel from inexpensive raw materials by methods outlined in U.S. Patent 2,029,773, "Process for Obtaining Products Containing Spinets," dated February 4, 1936. In this patent Ture B. Haglund described a process for recovering crystalline spinels from melts in the system Mg0?Al203-2CaO-SiO2, a system well suited to the use of starting materials such as dolomite CaMg(C03)2, olivine [2(Mg?Fe)0.Si02], and bauxite (Al203?2H20) which are abundant in the southeastern United States. Compositions, ranging from a low content in the eutectic mixture of 35 percent spinal and 65 percent dicalcium silicate (2 CaO?SiO2) to a high of 75 percent spinel and 25 percent dicalcium silicate, were fused in electric furnaces of the arc-resistance and internal-resistance types. So long as members of the system were in proper chemical balance, "dusting" slags could be produced over the entire range of spinel concentration.

Jan 1, 1961

By James W. Miller

An investigation was begun by the Bureau of Mines in 1948 to determine the preparation characteristics of American coals. Results of the investigation were planned to be reported on a county basis and from the data developed, to determine: (a) Which coals either as mined or after beneficiation by conventional preparation are chemically suitable under present standards for producing metallurgical coke; (b) Which coals require special and more intensive treatment in preparation than is now practiced; and (c) Which coals cannot be considered potential sources of metallurgical coke, regardless of preparation. This report is one in this county series that describes the preparation characteristics of the coals of Perry County, Ky.

Jan 1, 1956

By Murray Greyson

A number of tests were made with various methanation catalysts in fixed-bed, conventional fluidized-bed, and multiple-feed, fluidized-bed equipment to develop catalysts and processes for methanation of synthesis gas. The results show: 1. Methanation reactions may be carried out in 1-inch, bench-scale equipment at high synthesis-gas throughputs with good temperature control of the reactions if a multiple-feed type of fluidized-bed design is used. 2. Nickel is superior to iron as a catalyst for the methanation of synthesis gas, unless the process is considered in terms of a combined operation that produces both gaseous and liquid products. 3. Techniques of catalyst preparation determine, to a large extent, the process life of nickel catalysts, and these techniques must be thoroughly investigated before any conclusions can be reached. 4. Enough data are available to indicate that the sulfur concentrations in synthesis gas that is used for methanation are extremely critical, and maximum process limits should be carefully evaluated.

Jan 1, 1955

By Jonnie M. Estes

A two-constant equation is presented for helium from 30° = T = 1,473° K. This equation is developed by modifying a generalized equation of state originally presented by Redlich and Kwong (20).3 The modification consists of setting B = 0.06372 Tc/PeT. This modified equation represents the compressibility factors of each of 80 isotherms tested in this temperature range to less than 1 percent average deviation.

Jan 1, 1967

By H. Tomlinson

This circular is one of a series of papers on coal mining methods and costs which being prepared by the United States Bureau of Mines for the purpose of making available to those interested in the industry a knowledge of the mining methods employed, the places here mechanical and hand loading are practiced, and coat data on the several operations pertaining to the removal of coal from the working faces and its transportation to the tipple for loading into railroad cars. Mining costs are governed by the relative efficiency of the mining method employed. The method is selected for Its adaptability to the local natural physical conditions such as the nature and thickness of the coal bed, its dip, the character of the coal, and the thickness of the overlying strata.

Jan 1, 1930

By R. V. Lundquist

The compound 2Na2O?3CaO?5Al2O3 occurs as a minor phase in lime-soda sinters prepared for extracting aluminum from siliceous aluminum-bearing materials. About 99 percent extraction of sodium and aluminum from synthesized 2Na2O.3CaO.5Al2O3 was obtained in solutions of NaOH-Na2CO3 at leaching temperatures of 50° C and above. Extractions in water were low because insufficient NaOH was generated by hydrolysis. Extractions in NaOH solutions were limited to about 80 percent owing to the precipitation of hydrated calcium aluminates. Rapid extractions of 100 percent were obtainable in NaaC03 solutions, but the subsequent rapid precipitation of alumina trihydrate caused losses in alumina recovery.

Jan 1, 1965

By H. Kenworthy

Laboratory experiments were conducted on several materials to determine their suitability for the production of mineral wool. By blending raw charges in the proper proportions and in some instances by adding lime, acceptable wools were made from samples originating in Alaska, Florida, Texas, and Virginia. It was shown that satisfactory wools can be produced from many kinds of raw materials if the ratios of acidic and basic constituents are properly maintained. INTRODUCTION The Federal Bureau of Mines has facilities at the Mississippi Valley Experiment Station, Rolla, Mo., for examining and testing mineral-wool raw materials. Samples are evaluated through small-scale wool-blowing experiments, aided by petrographic, chemical, and physical analyses of the raw materials and finished wools. When enough experimental data have been accumulated they are made public through Government reports and periodicals. This report of investigations follows that published in 19513/ and presents test data on samples received and examined since 1951.

Jan 1, 1956

By E. C. Lane

This paper is a preliminary report of the results of the Bureau of Mines' twenty-second semiannual survey of motor gasoline marketed in the United States. A more detailed discussion of the whole survey is in preparation and will be published as a companion, report. The second paper, in addition to giving a more complete summary of the data included in this report, will present results of the determination of copper-strip core lion (method 530.22), color (method 10.11), sulphur content (method 520.11) evaporation residue (method 530.1), and gum content as given by the Bureau of Mines steam oven method.9 The retail price at the time the sample was taken and tax will also be stated for each sample. The present paper deals specifically with data relating to gravity, vapor pressure, and distillation. It has been the feeling of some investigators that the practice, followed in previous semiannual surveys, of grouping all types of motor fuel together without discriminating between "competitive price gasoline," benzol blends, Ethyl gasoline, "high-test" fuels, etc., has detracted from their usefulness because the data did not permit drawing conclusions in regard to any one type of fuel, and tended to obscure differences between fuels of the various types. Therefore, in order to remedy this condition, the samples of the present survey have been divided into two groups; one called "competitive-price gasoline" and a second group called "premium-price motor fuels."

Jan 1, 1930

By R. D. Leitch, C. A. Taylor

Trinitrotoluene is made by the direct nitration of toluene by a mixture of nitric and sulphuric acids . The exact procedure varies , but the product , where Grade I of TNT is desired , is similar , and consists largely of material that has a melting and setting point of 80.6 °c . The purification consists of draining off the liquid portions , including the acid and liquid nitro compounds . The mass is crushed and washed until the TNT is acid - free . It may still have a low-melting point due to the presence of material of lower nitration. Other isomers also have the same effect . The crystal mass may be washed with a solution of sodium sulphite , thiosulphate , sulphuric acid , or with an organic solvent such as alcohol , benzene , or carbon tetrachloride , Where a very pure product is desired , the TNT is separated by fractional crystallization from solution in organic solvents . The TNT is If it forms In some cases the material is melted during purification . agitated as it cools to prevent solidification in a solid mass . in a solid mass , this is broken up and screened . There has been some question as to the effect of the different methods of purification on the strength and sensitiveness of TNT , although all methods left a product that would give satisfactory tests .

Sep 1, 1923

By John Soule

The Torpedo copper mine in the Organ Mining, District, Dona Ana County, N. Mex., was discovered in 1899, and production of copper from oxidized-ore deposits was begun in 1900. Production continued through 1907, but operations were only intermittent frown 1907 through 1921. The production of copper during these periods amounted to about 3,500,000 pounds. Reserves primary sulfide copper ore were believed to occur below the old workings, and after a detailed examination of accessible workings and a study of drilling records of several private companies by an engineer of the Bureau of Mines, a development program of diamond core drilling was initiated. This investigation was started October 3, 1949; and completed April 30, 1950. Four holes totaling 2,122.3 feet wore diamond-drilled, and 70 samples were analyzed. All drilling was done with a Government-owned hydraulic-feet drill having special rods and core barrels to increase the recovery of core in critical zones. This report describes the location, history, ore deposits, and factual data obtained by the Bureau of Mines from the drilling.

Jan 1, 1951

By R. V. Lundquist, H. Leitch

Sodium aluminate is the principal aluminum compound formed in the sinters prepared by the lime - soda sinter process for recovering aluminum from silicate source materials . The properties and characteristics of this compound were studied to improve the efficiency of the process . Crystalline sodium aluminate was prepared by sintering stoichiometric quantities of soda ash and calcined alumina for 1 hour at 1,250 ° C. The extent of aluminum extraction from sodium aluminate was determined in water and in solutions of NaOH and Na₂ CO3 . Nearly complete extraction of aluminum from sodium aluminate was achieved only in solutions containing free NaOH in excess of that supplied by the salt through hydrolysis . About 42.2 to 68.8 percent of the aluminum was extracted in water or in solutions of Na₂ CO . The precipitation of alumina trihydrate from sodium aluminate solutions was shown to be part of a continuous , reversible reaction according to the equation Al (OH ) A1 (OH )3 + OHThe reverse reaction dissolves alumina trihydrate in NaOH solutions to produce sodium aluminate . Approximate equilibrium concentrations were determined for the reaction at 30° , 50 ° , and 70 ° C. False apparent equilibrium conditions for the dissolution reaction appear when only a small excess of alumina trihydrate is present in the NaOH solutions . A large excess of alumina trihydrate must be present before the true equilibrium point is assured . The engineering significance of the data is summarized , showing controls that should be exercised for a successful and efficient process .

Jan 1, 1964