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By C. H. Riggs

This petroleum-engineering report of the Atlanta oil field in BO them Arkansas reviews reservoir conditions and pressure-production history of one of the important Smackover limestone fields in southern Arkansas. The study of the field was made and the report prepared to aid operators in this and similar fields to increase the efficiency of recovery through the application of better engineering practices. A similar study of the Magnolia field in Arkansas by Carpenter and Schroeder was the first of these reports prepared under a joint agreement between the Arkansas Oil and Can Commission and the Bureau of Mines. The increasing demands for petroleum and its products and the steadily increasing cost of discovering and developing oil field; emphasize the importance of conserving known reserves of oil and gas. In recent years vast improvements have been made in the technique of oil recovery, both by better utilization of the natural energy stored in the reservoir and by improved methods of applying external energy to the reservoir system. This report may aid in oil conservation by careful evaluation of the several factors that did or did not contribute the greater recovery in the Atlanta field and by suggesting improvements in production methods and applications.

Jan 1, 1949

By Thoms L. Chapman

The San Manuel is a deposit of low-grade disseminated copper ore. It was brought to the attention of the government in October 1942 through an application to the Reconstruction Finance Corporation for a development loan, supported by a report by Henry W. Nichols. Nichols’ sampling of two outcrops containing copper silicate and his geologic map indicated that a minable body of copper ore might be developed. The Federal Geological Survey was requested to examine the property. The Survey mapped the geology in March 1943 and cut a few check samples, which substantially confirmed Nichols’ sampling of the outcrops and a few shallow workings. The geologists of the Survey recommended some test drilling by the Bureau of Mines. The property was examined by the author and W. D. Hughes, associate engineer of the Bureau of Mines on March 22 and 26, 1943, and a preliminary drilling campaign was recommended. Five shallow churn-drill holes totaling 1,480 feet were put down under the supervision of Chas. A. Kumke, one of the Bureau’s engineers, from November 23, 1943 to January 15, 1944. This work indicated that the deposit extended deeper than the 350-foot depth attained in the deepest hole and might have very considerable areal extent. Additional funds were allotted, and the drilling contract was extended twice to a final maximum of 17,000 feet with 2,000 foot maximum depth of hole. Drilling was continued by the Bureau of Mines until February 2, 1945, when 15,844 feet of hole had been drilled. The Magma Copper Co. took options on this and adjoining property in September 1944 and commenced drilling with two machines. It also engaged the two contract drills used by the Bureau after it stopped drilling. It exercised its options in August 1945 and organized the San Manuel Copper Corp. to operate the property. That company is continuing to explore the ore body with six churn drills. Thomas Lyon took options early in 1945 on holdings adjoining the San Manuel property on the east and is operating two churn drills. Exploration up to the completion of the last holes started by the Bureau of Mines indicated a block of ore 5,100 feet long, 400 to 800 feet wide, and 500 to 900 feet thick, and averaging about 0.8 percent copper. Subsequent drilling showed that the ore body extends considerably beyond this block. The axis of the ore body strikes about N. 61º E. Copper minerals are disseminated in hydrothermally altered quartz monzonite and monzonite porphyry. Ore outcrops in two small areas over the northeast part of the block. Elsewhere the copper-bearing rocks are capped by Gila conglomerate, which thickens toward the west and south. Drilling showed that the ore is in a thick, tabular body with a steep dip to the south. The ore body lies near the surface in the northeastern part of the block. The south side of the block is much farther below the surface than the north side. There the upper part of the copper-bearing rocks is lightly mineralized, so that the hanging wall of minable ore lies deeper than the base of the conglomerate cap, which thickens southward.

Aug 1, 1947

By Irven A. Jacobson

This literature survey consists of references dealing with gaseous state thermal decomposition reactions of organic nitrogen and sulfur compounds. The reference source for the survey was the Chemical Abstracts from 1930 to 1956, inclusive. Original articles were not studied. The starting date was set at 1930 because previous to this time much of the work is questionable. This report is in three parts: Part I lists nitrogen compounds; Part II, sulfur compounds; and Part III, compounds containing both nitrogen and sulfur. The organization of the classes of compounds is alphabetical: Part I - amides, amines, amino acids, ammonia, azides, azines, azo compounds, heterocyclic nltrogen compounds, hydrazine, nitrates, nitriles, nitrites, nitro compounds and miscellaneous nitrogen compounds; Part II - disulfides, sulfides (including double and triple sulfides), thiols, thiophenes and xanthates; Part III - thioacid amides, thiazoles, thiocyanates and thiuram disulfides. A class formula is included with each class name. The R's used in these class formulas may refer to hydrogen or to the same or different radicals when more than one R appears.

Jan 1, 1960

By G. R. Hopkins, E. M. SEELEY

The number of natural-gasoline plants has shown a consistent decline in recent years, but the total capacity has increased steadily. The number of completed plants, as determined by a survey as of January 1, 1932, amounted to 959. Previous surveys of January 1, 1928 and 1930 showed 1,155 and 1,035 plants, respectively. Of the total plants on January 1, 1932, 859 were operating and 100 were shut down, compared with 999 operating and 36 shut down on January 1, 1930. The material gain in the number of inoperative plants in the last two years was probably due to the severe decline in prices of 1931. The low prices of 1931, which were approximately 40 per cent below 1930, made it virtually impossible for the majority of the independent plants, or plants not owned by a large integrated company, to operate at a profit. Accordingly, the majority of the plants removed from the list in 1930 and 1931 were owned by companies which were engaged solely in the manufacture of natural gasoline. The total daily capacity of the plants on January 1, 1932, amounted to 11,387,000 gallons, an increase of 871,000 gallons, or 8 per cent, in the two years 1930 and 1931. That the total capacity of the plants has increased while the number of plants has declined is due to the fact that nearly all the plants constructed in the last five years have been large plants. During 1931 the average total daily capacity of the operating plants was approximately 10,600,000 gallons, while the average daily production amounted to 4,944,000 gallons. This indicates that the plants operated during 1931 at 47 per cent of their capacity, compared with 58 per cent in 1930 and 61 per cent in 1929. Although more plants have been dismantled in Oklahoma in recent years than in any other State, it continues to rank first in number of plants. On January 1, 1932, there were 238 plants in Oklahoma, compared with 145 plants

Jun 1, 1932

By J. L. Holman

In conjunction with its research program on separation, recovery, and recycling of metal, mineral, and energy-based materials in urban refuse, the U.S. Bureau of Mines is developing means to reuse and recycle plastics discarded in raw municipal waste. Experimental work on plastic waste from a community collection has produced some guidelines for systematic methods of processing, including air classification, cleaning, separation, and use or disposal. Sink-float methods are a practical means of separation into types. Methods for final disposition of the plastic waste include refabrication, thermal decomposition, and incineration.

Jan 1, 1972

By Robert M. Busche

[Recent developments in the gasification of coal, both by the Bureau of Mines and American industry, have intensified interest in the thermodynamic and kinetic principles necessary for understanding the reaction mechanism and rates and the physical changes that take place. In the course of a Bureau of Mines study of the kinetics of coal gasification at the Synthetic Liquid Fuels Demonstration Plant, Louisiana, Mo., a bibliography of approximately two references was compiled. They are listed n this publication and refer both to American and foreign sources.]

Jan 1, 1952

By J. L. Reuss

The Bureau of Mines investigated the technical feasibility of smelting copper concentrates containing chalcocite (Cu2S) and native copper using nonpyritic sulfur-bearing materials to aid matte formation. The procedure consisted of combining various proportions of commercial chalcocite concentrate, smelter slag, fluxes, and matte-forming constituents to produce charges of comparable compositions. The mixtures were charged in fire-clay crucibles and smelted in an induction furnace at 1,300° C. The research proved that either sulfur or gypsum can replace pyrite as a matte-forming material, and that gypsum produces an exceptionally high-grade copper matte. The addition of small quantities of metallic iron to the nonpyritic smelting charge furthers the removal of sulfur, improves the recovery of copper, and makes it possible to utilize gypsum as the exclusive flux and matte-forming ingredient, thereby eliminating the necessity of adding limestone.

Jan 1, 1968

Case 1: A driller-helper was pulling a winch cable toward a stack of drill steel when the cable contacted a 12,000-volt power line. The helper was killed, and the driller at the rig controls was severely injured. [ ] Case 2: A crew was preparing to remove a pump from a well when the hoist boom contacted a 4160-volt power line. The hoist operator was electrocuted. [ ]

Jan 1, 2005

By D. J. Bauer

The Bureau of Mines has conducted extensive studies on the recovery of alumina from kaolinitic clay by a HCI leaching-HCI sparging process. The current study reports a modification of the process, which involves a double-leaching system. The first leach of the calcined clay is made at as high a HCI acid strength as possible so that the dissolution of aluminum chloride hexahydrate (AlCI3*6H20) is suppressed, Most of the impurities, but very little aluminum, are soluble in the strong acid. After liquid-solid separation and washing, the solids are leached with recycled weak HCI, which dissolves the AICI3'6H2O. The pregnant liquor is separated from the gangue, and AICI3'6H2O is crystallized from solu-tion by injecting HCI gas. A proposed flowsheet is presented, and the effect of bleedstream size on AlC13'6H20 purity is discussed.

Jan 1, 1984

By D. E. Shanks

As part of its goal to help maintain an adequate supply of minerals to meet national economic and strategic needs, the Bureau of Mines, U.S. Department of the Interior, is investigating a fused-salt electrolytic procedure for producing zinc metal. A previous report described preliminary, small-scale work on the fused-salt electrolysis of ZnC12. The present report covers a more detailed investigation of the properties of ZnC12-alkali metal chloride electrolyte systems in relation to the production of zinc metal and also discusses electrolysis in largescale, internally heated cells. The effect of composition on bath stability, current efficiency, cell voltage, and liquidus temperature was determined for the ZnCla-NaC1-KC1, ZnC12-NaC1-LiC1, and ZnC12-KC1-LiC1 electrolyte systems. An electrolyte com-posed of 38 mole-pct ZnC12, 31 mole-pct NaC1, and 31 mole-pct KC1 gave the best overall results. Sludge (ZnO) formation in the ZnC12-NaC1-KC1, ZnC12-KC1-LiC1, and ZnC12-KC1 systems was investigated during prolonged electrolysis. The ZnC12-KC1-NaC1 electrolyte showed the least sludge formation. A 1,500-amp cell was operated using the ZnC12-NaC1-KC1 electrolyte at 500° C. Zinc metal was produced at the rate of 4.0 lb/hr with a current efficiency of 95 pct.

Jan 1, 1979

By R. G. Knickerbocker, C. T. Baroch, A. W. HACKWOOD

The difficulties inherent in the production of alumina by the formation of potassium alum and its subsequent thermal dehydration and decomposition have been overcome , to a large extent , in a process developed at the Boulder City Station of the Bureau of Mines . This process is applicable to the reserves of alunite known to occur in several Western States and , possibly , to certain clay and low-grade bauxite deposits known to exist in this country . The operations sequence of the process is shown in the flow sheet (fig . 1) . Only those steps included within the heavy line are considered in this report . Four different procedures for dehydration of alum were investigated ; ( 1 ) Spray drying , ( 2 ) rotary - kiln drying , ( 3 ) dry grinding in a thermal ball mill , and ( 4 ) dehydration in the vertical- column flash dehydrator . Based upon fuel requirements and other practical considerations , the vertical- column dehydrator , or some modification of its operating principle , offers the botter possibility for commercial use .

Feb 1, 1946

By E. L. Singleton

The electrochemical reduction of aluminum chloride to aluminum was investigated in a closed, two-compartment cell utilizing a molten chloride electrolyte. The externally heated cell was divided into a reduction compartment and a combination AICl3 feed and metal removal compartment. Aluminum was deposited at 700° C on a molten aluminum catbode from a KCI-NaCI-AICI3 electrolyte. The AICl3 content of the electrolyte was replenished by either vapor or solid additions. The chlorine evolved was collected and measured to give a quantitative evaluation of AICl3 reduction. The effects of anode and cathode current densities and AIC13 concentration on anode current efficiencies were studiedo A range of 64 to 84 percent anode current efficiency was obtained with the 25-pound electrolyte capacity cell and related auxiliary equipment.

Jan 1, 1968

By Henry Kreisinger, L. P. BRECKENRIDGE, WALTER T. RAY

The investigations of fuels conducted by the technologic branch of the United States Geological Survey had their inception at the Louisiana Purchase Exposition in 1904. By an act approved Febru- ary 18, 1904, Congress authorized the work of analyzing and testing at the Louisiana Purchase Exposition the coals and lignites of the United States, under the supervision of the Director of the United States Geological Survey. An appropriation of $30,000 was made for this purpose. In the general deficiency bill dated April 27, 1904, the sum of $30,000 was added to the appropriation. To carry out these investigations the Director of the Geological Survey appointed a committee consisting of E. W. Parker, statistician of the Geological Survey; Joseph A. Holmes, State geologist of North Carolina; and Marius R. Campbell, a geologist of the Geological Survey. Under the first act authorizing this work all of the machinery and coal for the tests was to be furnished the Government free of charge. The buildings containing the testing apparatus were all paid for out of the first appropriation. After the close of the Louisiana Purchase Exposition every Congress made an appropriation for continuing these fuel tests. These subsequent appropriations permitted the purchase of appliances better adapted for the testing work.

Jan 1, 1912

By J. L. Holman

The Bureau of Mines is conducting research to recover strategic and critical metals such as Ni, Co, and Cr from mixed contaminated super-alloy scrap. One approach being studied involves melt refining of superalloy scrap to produce anodes for electrolytic deposition of Ni-Co alloy. This melt refining of superalloy turnings is described based on melt-oxidation and oxidation-carburization experiments, using roasted superalloy grinding sludge to supply the 0 needed to oxidize Cr and other readily oxidized elements to the slag. Controlled melt-carburization subsequent to oxidation improved the metal phase recovery of Ni and Co to well over 90 pct and decreased electrolytic solubility of Cr, Mo, and W by carbide formation. Electrolytic refining experiments were conducted using a controlled-potential mode (preset cathode potential). Data show effects of Fe and Cr impurities, cation concentration, electrolyte pH, S04-Cl electrolyte ratio, temperature, cathode potential, and cation-selective membrane use on current efficiency, current density, and deposit composition. Disposition of Ni, Co, Cr, MO, W, and Fe is compared for melt-oxidized versus oxidized-plus-carburized anodes. Deposits containing >97 pct Ni + Co (major impurity Fe) have been routinely obtained from scrap anodes. Research is continuing to improve deposit quality in sustained deposition and to recover Cr and other metals from refining slags and anode sludges.

Jan 1, 1986

By W. G. Hopkins

The development of systems for location of miners who have become entrapped following a mine disaster has been one of the major research goals in the Bureau of Mines. This study details the preliminary development of such a system. Current technologies for locating trapped miners from the surface are either simple direction finders or time difference pulse systems that have accuracy limitations. Developing technologies using full vector field measurements at several receiving points are currently being studied. The necessity of measuring field strength with great accuracy can be a drawback in these systems. A system that operates with continuous wave radio signals, whose phase differences can be measured accurately even in weak signal conditions, greatly improves the location accuracy. A microcomputer would be used in conjunction with the system, to gather and manipulate the data to automatically pinpoint the location of the trapped miner. Comparison of this system with existing technology indicates a favorable accuracy/complexity ratio for the phase difference of arrival technique.

Jan 1, 2011

By P. G. Kovalchik

Safe electrical operation of shuttle cars depends upon maintaining the trailing cable's conductor temperature below 90° C. However, trailing cables are wound on and off reels, which changes the heat transfer characteristics of the cable-reel system. Derating factors for trailing cables are an attempt to adjust for this changing heat transfer mechanism in a practical way. The U.S. Bureau of Mines conducted research to determine acceptable derating factors for reeled mine trailing cables, using four cable-reel combinations, representative of industry usage. Cables were continuously and intermittently loaded at different duty cycles with direct currents of different magnitudes. Relationships between the average temperature rise and current load were established for each layer of each cable. Two models were constructed; one used empirical data from the continuous and intermittent load tests, and the other was based on thermodynamic theory. Results obtained from the theoretical model were compared with those from the empirical model for the rated temperature rise of the cable. Both models can be used to simulate a variety of test conditions including those that normally cannot be conducted in the laboratory. This information was used to determine acceptable derating factors for each layer of these cable-reel combinations.

Jan 1, 1994

By J. R. Nettle

A method has been developed in the laboratory for successfully electro-refining titanium metal. Refining is accomplished in e fused-salt electrolyte using offgrade metal as the anode and collecting the purified metal at the cathode. The characteristics and requirements of the various alkali chlorides tested as electrolytes are discussed in relation to relative ease of purification and serviceability. The various types of cells designed and tested for electrorefining are illustrated and their method of operation discussed. The individual advantage of each cell and the purpose for which it was designed are reviewed. The magnitude of the cathode current density was found to depend largely upon the quantity of soluble titanium chloride in the electrolyte. The physical condition of the anode also greatly affected the cathode current density.

Jan 1, 1957

By Gregory J. Chekan

The U.S. Bureau of Mines is investigating longwall panel and gate road layouts to increase coal recovery and reduce multiple-seam interactive problems. This report presents design practices for longwall mining multiple seams to provide mine planners and operators with practical guidelines for designing productive longwall mines. Key aspects of mine design that control longwall interactions are examined, including sequencing of seams, design of gate road pillars, and orientation of gate roads and longwall panels. Theories that describe stress transfer between multiple scams and the mechanics of interaction are addressed in relation to geology. Common longwall designs were further investigated using a boundary element model, MULSIM/NL. The model provided insight into relative stress transfer and distribution that occurs between longwall operations in multiple seams. Findings from the model show that (1) a longwall panel should be mined from the gob to the solid coal of an overlying mine, because the stress concentrations are lower; the approach angle should be kept under 30°; and (2) when mining in descending order, superpositioning gate roads usually produces the worst stress condition. To prevent this, the overlying isolated gate roads should be positioned from the centerline toward the headgate side of the underlying panel.

Jan 1, 1993

By McHenry Mosier

This paper describes come mechanical raid electrical signal systems in common use in Metal-mine shafts, together with several distinctive systems that indicate or control the origin of the signal. The latter systems remove the hazard of the movement of the cage from one level in response to signals from another. Previous publications of the Bureau of Mines have covered several meritorious installations One of the best signal systems for deep shafts is at the Homestake mine4/. A successful installation of an induction system in the Lake Superior mining region permits signaling as well as telephoning from cages at rest or in motion5/. El Potosi mine uses a variation of the three-wire electric system6/. A mine in Utah has developed a system of the double trolly-wire type, in which the cage attendant may signal from a moving cage7/. At present no system of the sine-shaft signaling employing radio is available.

Jan 1, 1939

By Will H. Coghill, C. O. Anderson

In July 1921 , we were assigned by the U. S. Bureau of Mines to an investigation of milling methods in the Tri - State zinc district ( Missouri -Kaneas- Oklahoma district ) . The work has progressed without interruption , and about onehalf of the funds allotted for it has been expended . This preliminary statement abcut the nature of the work and the results so far obtained , has been prepared for the information of the operators , and through their assistance to insure the greatest possible progress during the remainder of the work . A general survey of the district was made , and many of the mining companies cordially offered the facilities of their plants for the investigation . The work was finally centralized at the plant of the 0. M. Bilharz Mining Co. Its manager , F. H. Gartung, and his successor , O. W. Bilharz , have been especially helpful , also the millmen at this plant and elsewhere have rendered assistance without which the work could not have advanced . The Missouri School of Mines and Metallurgy , Rolla, Mo. , and the Miami School of Mines , Miami , Okla . , have given hearty cooperation . The Webb City Iron Works and the Joplin Supply Co. donated some necessary apparatus .

Jan 1, 1922