Search Documents

By Robert L. de Beauchamp

The Bureau of Mines reviewed aluminum chloride technology to determine the problems associated with its preparation from minerals, and to ascertain the best areas for research to solve these problems. Commercial AlC13 production processes are described and the ?state of the art? for the preparation of AlC13 from aluminous materials is evaluated. Areas for further research are indicated.

Jan 1, 1969

By Raja V. Ramani, Sachin Shankar

"Re-entrainment refers to dislodgement of particles deposited by both atmospheric and nonatmospheric processes and their subsequent insertion into a flowing field. Formation of sand dunes, snow drifts, soil erosion and fugitive dust emissions are a few examples of the natural occurrence of re-entrainment. Re-entrainment studies have been done for the estimation of potential hazards from nuclear fallouts. The phenomenon of re-entrainment has been utilized for the cleaning of wafers and filters. Re-entrainment is associated with both surface and underground mining activities. However, studies on dust re-entrainment in mine atmospheres are limited. Understanding the re-entrainment phenomenon is important because dust particles lying seemingly harmless on the ground and adhering to numerous surfaces can get re-entrained and become a health and safety hazard.There are significant differences in the kind of re-entrainment encountered in underground mines and those in other fields of interest. These major differences are air velocity, direction of air flow, particle size, amount of particles, and time of exposure. While numerous studies have been done in other fields to identify the role of interacting variables and their contribution to the mechanisms of re-entrainment, no similar reported work is available for dust in mine atmospheres.In this paper, recent research efforts on re-entrainment are reviewed. The most suitable form of representing re-entrainment in underground coal mine atmosphere is presented. Various approaches to studying re-entrainment phenomenon in mines are also outlined.In the mineral industries, formation of dust particles of widely varying sizes is a natural outcome of the fragmentation required in mining the solid resources. Fine particles in mine atmospheres, particularly in the respirable size range, are a threat to the health and safety of the miners when present in high concentrations. In 1980 the National Academy of Sciences (NAS) Committee on the Measurement and Control of Respirable Dust in Mines recommended that the spatial and temporal characteristics (of fragments produced in coal mining) need to be understood so that the exposure of workers to the dust can be controlled. Recently several studies have been performed to understand the fundamental behavior of the airborne respirable dust in mine airways (Bhaskar, 1987; Qin, 1988; Polat, 1989; Bode, 1990)."

Mar 1, 1992

By D. G. Collins

As part of its effort to develop ways to maximize resource recovery, the Bureau of Mines investigated the extraction of vanadium from Western phosphate beneficiation tailings with H2S04 and/or H3P04. Dissolution of the vanadium was accomplished by digesting a mixture of acid and a 50-pet-solids, tailings-water slurry. In the most effective method investigated, vanadium and phosphorus were leached by digesting the slurry at a constant boiling temperature (1000-1100 C) in a stirred reactor. In batch tests, maximum vanadium dissolution was 95 pet. In continuous-circuit tests designed to further evaluate vanadium dissolution at con-stant boiling temperature in a continuously stirred reactor, vanadium dissolution ranged from 70 to 85 pet. An economic evaluation of the process demonstrated that H2S04 consumption is the major cost factor. Based on the value of the vanadium product with no allowance for a phos-phate product, the cost of producing the V205 is more than twice its value. The potential for profit would depend upon the value of the phosphate fertilizer produced from the impure H3P04 remaining after vanadium extraction.

Jan 1, 1985

By D. Harrington

More or less unconsciously and from sheer force of habit human beings do many things they probably would not do if the possible consequences of their acts were fully recognized and appreciated. Such carelessness ordinarily could be condoned if human life were not at stake, but it is difficult to understand why intelligent men engaged in the hazardous occupation of mining indulge with the utmost indifference in some habit or continue some custom in violation of State leas and company regulations and under circumstances that may jeopardize not only their own lives but those of scores, even of hundreds, of their fellow workers as well. The old adage that stolen sweets are the best may or nay not have some foundation, but when applied to the practice of smoking surreptitiously in a coal mine, more especially a gassy mine, it is without even remote justification. Although a relatively harmless habit in the proper environment, smoking has been the cause or suspected cause of many gas explosions and black-powder ignitions and has resulted in numerous instances of bodily injury, loss of life, and destruction of property. Likewise, many fires in both coal and metal nines, causing loss of life, have been started by smoking.

Jan 1, 1941

By Michael G. Pojar

This Bureau of Mines report estimates the population of the principal types of machinery in use by the coal mining industry during 1982 in surface and underground mines. Estimates were arrived at using 1976 coal equipment population estimates as baseline data with modifications made for new mine development, expansion, and closure occurring during 1976-82. Estimates were broken down into 3 regions which included all 26 coal-producing States. Modifications made to the baseline data were computed using (1) actual equipment information when available, plus (2) equipment information hypothesized from representative generic mine models, which were predicated on mine size and mine method. Roughly half of the equipment fleet at new or expanding coal operations was known; the remainder was hypothesized. The mine models used to generate equipment information are included in this report, along with the hypothesized equipment use data. The equations and various factors used to determine the equipment adjustments for mine closings, new mine openings, and small coal mine operations are also identified.

Jan 1, 1986

By J. E. Schiller

The Bureau of Mines is investigating methods to treat waste water that contains cyanide. This report describes a new method that removes heavy metals and all forms of cyanide. In the first step, hydrogen peroxide and sodium thiosulfate are added at pH 7 to 9 in a 1:2 molar ratio to convert free and weakly complexed cyanide to nontoxic thiocyanate. Then steryldimethylbenzylammonium chloride is added to precipitate ferro-cyanide, and finally, ferric sulfate is added as a sweep floc and sequestrant for heavy metals. After the suspended solids settle, the water is polished by filtering. The water initially contained 1 to 5 mg/L Fe, 1 to 5 mg/L Cu, and 10 to 30 mg/L total cyanide; the level of each of these constituents was reduced to less than 0.02 mg/L.

Jan 1, 1983

By A. J. Barry

To determine the torque-load relationship for SIB-inch (nominal)-diameter roof bolts, the Bureau of Mines tested 5 makes of expansion shells and 2 types of bolts (regular and high-strength) in 2 sandstone and 2 shale mine roofs. Unused flat-steel bearing plates in as-received condition were used in these tests. The relationship between torque and load was found to be approximately 50 pounds of load per foot-pound of torque for both the regular and high-strength bolts. This relationship is valid up to 130 foot-pounds for the regular bolts and up to 175 foot-pounds for the high-strength bolts. A torque of 130 foot-pounds on a regular bolt will produce a load of 6,150 ± 1,910 pounds 90 percent of the time, and a torque of 175 foot-pounds on a high-strength bolt will produce 8,050 ± 2,750 pounds 90 percent of the time. Above these values, the torque-load relationship tends to be erratic due to binding between the bolt and plug threads. Binding causes excessive torque to be expended in producing torsion in the bolt rather than tension. This torsion adversely affects the yield load of the bolt. Therefore, the installed torques should not exceed the 130-and l75-foot-pound values. A statistical analysis of the data showed that the torque-load relationship was not significantly affected by the type of bolt or expansion shell unit but might have been affected by the type of rock.

Jan 1, 1956

By MINE SAFETY BOARD

Mining men and State officials in their efforts to make mining safer are confronted from time to time with various complicated questions . In recent years these questions have tended to increase with the use of mechanical appliances . Twenty- five years ago electricity had hardly been used in mines . To - day there is practically no other means of transmitting energy employed in American mines , except in metal mines where compressed air is used for drilling and small portable hoists . In coal mines there has been a great increase in mechanization and a tendency to concentrate the mining operation , which has resulted in attendant difficulties of ventilation and intensified the danger of coal - dust in bituminous and subbituminous mines . The answers to the questions which arise are not always obvious , as is shown by the fact that even able , experienced men differ in their opinions of the best way to overcome a particular mining hazard . The difficulty of solving the problems is also demonstrated by the varying provisions in mine safety rules , both in official regulations and in the rules of those mining companies who are endeavoring to do more than follow the letter of the law . Such differences of opinion on the best way of meeting a difficult situation are often found within the same mining organization , and so it has been in the Bureau of Mines .

Nov 1, 1929

By Craig M. Jensen

A laboratory assessment of prompt and delayed neutron activation analysis with 252Cf and 14MeV neutron sources, for use as an in-situ method of determining low-level copper concentration has been performed. A simulated borehole using porphyry ore was constructed and varying copper concentrations were simulated using copper rods. Prompt neutron activation analysis experiments were consistant with earlier work and do not appear to be feasible fur copper concentration of 1.5% or less. Delayed neutron activation analysis experiments indicate that copper ore concentrations of less than 0.1% are detectable using either the 511-KeV gamma-ray of copper-64 or the 1039-KeV gamma-ray of copper-66, with high resolution detectors such as Ge (Li) or intrinsic germanium.

Jan 1, 1977

By K. L. Paciorek

The aim of the present study was to determine the thermal oxidative behavior of materials used in coal mines, with emphasis on the type and relative concentration of the products, in particular the toxic species formed. To supplement this work and to gain understanding as to the type of products possibly formed and also to assess the limitations and advantages of the various analytical methods used a literature survey of the past investigations performed on the compositions of direct interest to the subject program was conducted. The compositions thus covered were cellulose, polyvinyl chloride, neoprene, urethanes, polyamides, polyesters, polyethylene, epoxy, phenoxy, urea-formaldehyde and melamine formaldehyde resins. The results of this review are compiled in the Appendix. The experimental work consisted of thermal oxidative degradation of 36 materials and 4 composites using a stagnation burner apparatus developed in these laboratories which affords a dynamic system approximating somewhat the conditions encountered in underground coal mines. This technique as employed during this program gave only the relative product concentration at specific periods of the decomposition process, The advantage of this approach is that in this manner screening of materials can be accomplished in conjunction with some assessment of the decomposition rate as influenced by temperature and material composition. Limited static tests were performed using a sealed tube method. The materials studied were grouped according to their compositions. The following were the main groups: (a) polyvinyl chloride-containing materials, (b) neoprene compositions, (c) rigid foams (urethanes, isocyanates), (d) miscellaneous materials (including jute, fiberglass, polyethylene and some articles of unknown composition), (e) coal and fluids (phosphate esters, organic esters, oil-water emulsions), and finally (J) composites. The latter comprised a mixture of a phosphate ester fluid with (a) coal, (b) a representative polyvinyl chloride sample, and (c) a neoprene type composition.

Jan 1, 1972

By Jos. R. Guiteras

The present discussion first presents data to justify the fireproofing of mine shafts. This is followed by a brief outline of fireproofing methods with examples from practice. A summary of authoritative recommendations on fire prevention concludes the discussion. Acknowledgment is made to D. J. Parker, district engineer, Mine Safety Station, Salt Lake City, Utah, for his valuable criticism of the paper. Fireproofing a mine shaft implies lining the shaft with fireproof material or rendering fireproof the material already composing the shaft lining. A brief study of the part mine shafts and shaft stations have played in disastrous end tragic underground fires furnishes convincing evidence that every possible effort to make all mine shafts fireproof is amply justified. The fire hazard in coal minus obviously is much greater than in metal mines. In this discussion the point of views is mainly that of the metal miner; it is tine opinion of the writer that all fires in metal mines are preventable.

Jan 1, 1939

By H. B. Hill

The discovery of the Oklahoma City field and its .rapid development into one of the major oil-producing districts is an outstanding epoch in the history of the petroleum industry not only of .Oklahoma but also of the United States. The relatively great depth to which the wells were drilled and the large initial production of high-gravity oil are of special significance. The field has boon under proration almost from the time that its development began, and many new production problems have developed out of the changed conditions of operation. The discovery well was first tested in December 1928 at a depth of 6,402 feet, with an initial production of 4,847 barrels of 38.5° A.P.I. gravity and several months later was completed at a depth of 6,624 feet. The large initial production, the high pressure, and the large gas volume in the different horizons of the discovery well suggested the potential possibilities of gas and oil, production in formations of Pennsylvanian and pre-Pennsylvanian age.

Jan 1, 1933

By Roger G. Long

This final report reviews installation, maintenance and inspection of mine pager telephone installations. A Technical Handbook was developed and distributed. Certain commercial telephone test equipment was modified and a tone source and switching circuit were developed for use in the testing of mine pager phone systems. Descriptions are included of the modifications to a commercial test set and of a tone source/ switching unit.

Jan 1, 1975

Between 1985-1986, the Bureau of Mines reviewed the mining history and minerals information for areas in and near the San Isabel National Forest to appraise the mineral resources present and determine the types of deposits, and their location in the Forest, that could be mined economically if sufficient demand and metal prices existed. The two major metallic deposit-types that are of national mineral resource significance within the Forest are stockwork- molybdenum (with tungsten and tin) and carbonate-replacement zinc-lead-silver deposits. Historically, small gold placers, gold-quartz veins, silver-quartz veins, skarn iron and copper deposits, volcanogenic copper-zinc-precious metal deposits, and base- and precious-metal veins have been mined. Barite, carbonate rocks, gypsum, other non-metallic deposits, and pegmatites, have also been mined. Sand and gravel, present in large volumes, occurs along and has been mined outside the Forest along the upper Arkansas River valley. Turquoise and gemstones are present in small amounts and are of interest to collectors and jewelers. Geologically, sediment-hosted uranium and copper are present in small occurrences but no resources have been identified. Geothermal resources are related to the Rio Grande rift which parallels the central part of the Forest. Four hot spring areas are present - two of these are within the Forest. Because of the low power requirements of the region, and the presence of other generating facilities, these geothermal resources have had only limited local use. Evaluation of mine models that may be found in the region show that base-metal deposits require a high precious-metal component to be economic. Although molybdenum can be produced at economically competitive prices, there is little demand for the product. Capital costs to start new molybdenum mines would be very high and it is not likely that new mines will be put into production in the near future.

Jan 1, 1989

By R. Hogg, S. Chander

"The distribution of the wettability of coals of different rank was determined by measurements of contact angles for individual particles. The contact angle was estimated from the equilibrium partitioning of a particle at the water/air interface. Using this technique contact angles were determined for a larger number of particles from a given sample and a frequency distribution of contact angle was obtained. The contact angle distribution was broad for all the coals tested with included an anthracite, a hvA bituminous and a sub-bituminous coal. In comparison, spherical particles of polymethylmethacrylaie gave a much narrower distribution. The distribution for irregular polyethylene particles was somewhat broader than that for the polymethylmethacrylate spheres but broader than that for the polymethylmethacrylate spheres but considerably narrower than that for coal. The broader wetting distribution for coal was attributed to differences in surface chemical properties.INTRODUCTIONA knowledge of the wetting properties of coals is very useful in coal cleaning by flotation and other processes in which separations are based on differential surface properties. The various methods available for measuring wetting characteristics include: contact angle, 1-2 time, time, 3-5 bubble attachment, 6 film flotation,7 displacement pressure, 8-9 penetration rate, 10-11 bubble pick-up, 12 induction time, 13 imbibition time, 14 and calorimetry. 15-16 Of all these methods, however, the measure¬ment of contact angle by the sessile drop and captive bubble techniques have been most widely used. Brady and Gauger"" demonstrated through the use of the contact angle method that the natural hydrophobicity of coal varied greatly from sample to sample. Subsequent experiments showed that this difference correlated well with rank, the larger contact angles generally being associated with the higher rank coals. 18-19 More recent studies by Aplan and co-workers' show that the wettability of various ranks of coals as determined by sessile drop and captive bubble methods is a more complex function of rank. The hydrophobicity of coal usually increases with rank up to about 80% fixed carbon (dmmf) and then decreases."

Mar 1, 1992

By Walter Kawa

Bureau of Mines research on the hydrogenation of coal has been concerned with developing processes that could be used to supplement the Nation's petroleum and natural gas resources. Motor fuel was produced in a subsidized coal hydrogenation industry in Europe prior to 1945, but the process used is still not economical and other methods of producing liquid and gaseous fuels from coal are being investigated. As an aid to the planning of coal hydrogenation research, a literature survey was made of processes or methods of hydrogenating coal that differ from the subsidized or conventional process. This report contains a bibliography of unconventional methods of hydrogenating coal and a brief discussion of the economics of the conventional method. A general discussion of unconventional methods is included, and the advantages and disadvantages are pointed out where possible. The survey supplements a previous Bureau of Mines survey3 and a comprehensive review published in 1930.4

Jan 1, 1964

By W. E. Miller, G. S. Scott, G. W. Jones

"An important activity of the Bureau of Mines is the promotion of safety in mining and industry. In connection with these activities, the Bureau determines the explosion hazards of combustible gases, liquids, and solids and investigates means by which explosions may be eliminated or reduced in violence.The limits of inflammability and ignition temperature of combustible gases, vapors, and solids are of practical importance because such materials can be manufactured, transported, and used with greater safety, provided the range of concentrations and temperatures that cause explosions are known.Many organic compounds, which until a few year ago were merely laboratory curiosities, are now being manufactured in large quantities owing to the national emergency, particularly those chemicals entering into the manufacture of synthetic rubber, a product that is playing a major role in the Government program of national defense. This re Jolt gives results relative to the limits of inflammability of styrene and its ignition temperature in air and oxygen. This combustible liquid is now used extensively in the manufacture of synthetic rubber."

Mar 1, 1942

By F. B. Petermann

Two-stage electric smelting tests, using small submerged arc furnaces, were made on high-iron manganiferous materials from the Pioche District, Nev., and the Cuyuna Range, Minn. The object was to reduce sufficient iron in the first stage to give a slag with a favorable Mn to Fe ratio for smelting to ferromanganese in the second stage. The nodulized flotation concentrate from the Pioche District contained 29.2 percent Mn and had a Mn to Fe ratio of 2.3:l. When smelted with coke and silica or alumina as flux, more than 90 percent of the manganese was recovered in slags with Mn to Fe ratios of 10: :24:1. The Pioche slag was smelted to ferromanganese using coke and lime- stone or dolomite as flux. The ferromanganese was high in silicon but other- wise met specifications. Recovery of manganese to ferromanganese in this step was 73 to 78 percent. Overall recovery of manganese was about 70 percent. The sintered flotation concentrate from the Cuyuna Range material contained 12.9 percent Mn and had a Mn to Fe ratio of 0.3:1. When smelted with limestone as flux, about 83 percent of the manganese was recovered in a slag with a Mn to Fe ratio of about 6:1. The Cuyuna slag was smelted to ferromanganese with coke and limestone for flux. Recovery in this step was 61 percent of the manganese in a high silicon ferromanganese. Overall recovery of manganese was about 50 percent.

Jan 1, 1963

By S. Benedict Levin

The Big mine has been a source of mica and high-grade felspar from separate zones in the same pegmatite dike since 1914. In 1943 it became the outstanding producer of strategic mica in New England. The urgent need for sheet mica led to core-drilling by the Bureau of Mines from February to May 1914. Nine diamond-drill hob's aggregating 1,474 feet in length were drilled by the Bureau of Mines with the objective of developing extensions of the known mica shoots. The use of large-diameter bits made it feasible to obtain reasonably reliable results in diamond-drilling this type of deposit.

Jan 1, 1949

By H. A. Doerner

"During the year which has passed since the last progress report on reduction of zinc by natural gas,3 the laboratory experiments on this investigation have been completed. In this concluding report, the whole subject will be reviewed and additional data presented.Chemical ReactionsIn a thermodynamic study of zinc smelting, Maier 4 discussed the use of methane for reducing zinc oxide, and predicted equilibria at various temperatures for the sore important reactions. The study has been extended to include the following list.Maier predicted that 870°C. would be the critical temperature above which reaction (1) would take precedence over reaction (2) and that reaction (1) at equilibria would be substantially complete at or above 927°C. A subsequent papers described experimental verification of these predictions and gave data on reaction rates under various conditions.It methane is passed through a heated bed of zinc oxide at a low enough rate reactions (1), (3), and (4) reach an equilibrium which can be expressed by reaction (10). The equilibrium concentrations for the products of this reaction in the temperature range 900° to 1100°C. were calculated by applying the thermodynamic constants to the stoichiometric relations. 6 The results of these calculations are listed in table 1 and shown graphically in figures 1, A and B. These data have major importance, and experimental work has shown that they are subtantially correct."

Dec 1, 1934