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By Milind Chikhale, Ranjeev Kumar, Keshav Tyagi

Ore characterisation including mineralogy and beneficiation testwork of an ore is very important for determination of possible products and their quality. The results of such study help in ascertaining the beneficiation process route for the ore. The present study deals with ore characterisation study and beneficiation testwork on the samples of hematite iron ore with goethite impurity. The characterisation study reveals that the hematite is under alteration stage to goethite which has become an integral part of hematite. High goethite/limonite content is enhancing the loss of ignition content of the ore and reducing its Fe content. The findings indicate that in case of hematite iron ore associated with goethite and limonite, it is difficult to achieve high grade of concentrate above 65% Fe. It depends on the amount of goethite and limonite minerals and their association with hematite. These minerals contain aluminous impurities and hence, their rejection becomes essential. Separation of limonite and of goethite to limited extent is possible. In case of goethite, effective liberation is not achieved where it occurs as surface alteration product of hematite grains. The gangue mineral reported are clay and gibbsite, and are closely associated with iron minerals. The test work results indicate the grade and recovery of Fe along with alumina and silica content in lumps, sinter fines and pellet feed fines that can be achieved for the different ore types vis-a-vis the percent of available hematite in the ore. The recovery of iron is dependent on the hematite available and the loss of iron values in tailings is more because of rejection of limonite and goethite.

Jan 1, 2014

By D. Pirouzan

It is customary to use more than one stage of flotation to obtain an acceptable level of separation of valuables. Flotation circuit design is usually accomplished by applying empirical rules which usually results in operations not working at their optimum conditions. Given the capabilities of genetic algorithms (GA) in finding an optimum solution in a very disturbed search spaces, they can be used to obtain the desired flotation circuit configuration. In flotation circuit configuration and optimization problem, a combination of metallurgical parameters such as yield and concentrate ash content could be used as the fitness function for the genetic algorithm. The multi-objective nature of the problem justified to use Pareto method to arrive at a set of solutions. The appropriate configuration based on technical or economical considerations could then be chosen. To obtain the fitness function for any given configuration, it is necessary to model every flotation stage. The proposed method was used to find the optimum circuit configuration for a coal washing plant. The objective was to arrive at the highest yield while producing a concentrate with a certain ash content (< 11%). The feed to the flotation circuit was characterized based on the size fractions and their flotation rate constants. Results showed that with a 95% confidence, the absolute difference between the modeled and measured values were 2.9-5.5% for yield and 0.4-1.1% for concentrate ash content. When the proposed GA-based circuit configuration was implemented in the plant, the yield increased from the original value of 57.6% to 65.7% while producing concentrate ash content (10.9%) within acceptable limits. By adding one stage to the current three-stage circuit, it was predicted that the yield could further increase by 3.8% while keeping the quality of the concentrate within the appropriate level. Keywords: modeling, optimizing, flotation circuit configuration, genetic algorithms

Sep 1, 2012

By S. V. Balikov

A close association of fine gold with pyrite and arsenopyrite is observed at many gold ore deposits. Gold forms and gold distribution in sulfides of different deposits were studied. A comprehensive method including optical spectrum analysis, X-ray diffraction analysis, high-temperature X-ray diffraction analysis, scanning electron microscopy and X-ray microanalysis was used for the de-tailed investigation of the defectiveness of the structure of pyrites from different deposits. It was shown that gold content in pyrites varied from 1.5 g/t to 100 g/t compared with 30 g/t to 230 g/t in arsenopyrites. The nature and arrangement of inner inclusions of foreign minerals in pyrites as well as occurrence of fractures and macro- and microdefects were examined. Iron, sulfur and arsenic contents in all pyrite samples were determined. Chemical composition of the detected inclusions was defined. Parameters of submicroscopic structure of pyrite were estimated using X-ray Fourier line shape analysis. Estimation of real structure characteristics with calculation of submicroscopic D-blocks and root-mean-square lattice deformation 2()evalues was performed. Defectiveness of the pyrite structure can be defined by the following parameters: K?1 and K?2 reflection resolution and its intensity within high Bragg angles; S content to Fe content ratio; the arsenic content and the local variation in its concentration within the pyrite grain; the size of submicroscopic blocks and the crystal lattice disturbance value. The performed analysis showed some relationships between these parameters and refractoriness of the pyrite concentrates. It was observed that at S/Fe ratio close to or higher than stoichiometry and at a low arsenic content (less than one per cent) pyrite concentrates were not refractory. The analysis results showed that concentrates of the Beryozovskaya gold plant (0.02~0.07 As%) and concentrates of the Kommunarovskaya gold plant (less than 0.05 As%) as well as some pyrites from the Sukhoi Log gold deposit had the same characteristics. It was found that average arsenic content did not excess 0.2 per cent. Arsenic distribution within the grain of all these pyrites was uniform. At S/Fe ratio lower than or close to stoichiometry and at high arsenic content (more than one per cent) and significant variation in its distribution within a pyrite grain the pyrite concentrates are refractory. Such pyrites are typical for the Sukhoi Log, the Bakyrchik and the Mardzhanbulak gold deposits. Direct correlation between arsenic and gold contents, in particular, in fine grains of pyrite was observed by many researches. This correlation was explained by impregnation of arsenopyrite which normally contains more gold than arsenic pyrites. The analyses results showed that no arsenopyrite impregnation was found: arsenic distribution within the grain was uniform but its concentration varied greatly. Such pyrite concentrates are more refractory. This paper presents the results of analyses of sulfides to determine the amenability of the associated gold recovery by hydro- and pyrometallurgy.

Jan 1, 2014

By Patricio Berrios, David Barriga, Peter Amelunxen, Gerson Sandoval, Roger Amelunxen

Laboratory test equipment and methods have undergone relatively little change since their introduction in the 1950’s. The Denver sub-A cell is still by far the most commonly used laboratory batch cell, but bottom-driven and instrumented cells are beginning to appear. Test procedures have also changed little over the past 60 years, and most engineers continue to rely on empirical models for predicted plant scale performance from laboratory scale tests. This approach is problematic, because changes in the froth phase characteristics in the lab hamper the reliability and reproducibility of the empirical extrapolation to plant scale. In a previous work, the authors reported on the impact of froth recovery at the laboratory cell, showing that variability in the froth recovery can lead to significant error in the modeled kinetic rate constant unless it is properly accounted for in the scale-up model. In this work, we review the role of hydraulic entrainment in the lab cell, and how variability in particle specific gravity, shape factor, and froth residence time can impact the entrainment recovery.

Jan 1, 2014

By Yimin Zhu, Dezhou Wei, Haijun Liang, Zhifu Zhou

It has been fairly well established by many experiments that Thiobacillus ferrooxidans (T. ferrooxidans), also named Acidithiobacillus ferrooxidans(Kelly and Wood, 2000),can depress the floatability of pyrite. However, the mechanisms governing the process have not been known completely. In the present investigation, wettability and electrokinetic studies were carried out to examine the surface chemical changes on pyrite before and after interaction with T. ferrooxidans or its secretions. Attachment of T. ferrooxidans to pyrite was observed using a scanning electron microscope. The results of experiments showed that, under certain conditions, T. ferrooxidans and its secretions would obviously change the surface electricity of pyrite and result in the iso-electric point of pyrite shifting notably. However, the surface wettability of pyrite hardly changed and its hydrophobicity increased little after interaction with T. ferrooxidans and its secretions. Based on the results of the present investigation it can be reasoned that the depression of floatability of pyrite is due to the reduction of surface free energy, rather than the increase of surface hydrophilicity of pyrite. The decrease of surface free energy weakens the attachment of collector to pyrite; during the process bacterial protein plays the most important role and the bacterial chemotaxis strengthens the effect.

Jan 1, 2003

By Vitaly Kretov, Valery Golikov, Vladimir Ryaboy, Elena Shepeta

"The aim of the study was to develop and implement more efficient dialkyldithiophosphate collectors. A hypothesis has been formulated on the action of dialkyldithiophosphates in the flotation of sulphide ores based on the assessment of their complexing properties and surface activity at the liquid-gas border. Dialkyldithiophosphates form weaker complexes with cations of heavy metals compared to xanthates, and are characterized by a large difference in the strength of their complexes with heavy metal cations. It provides higher selectivity of dialkyldithiophosphates in the separation of non-ferrous metal sulphides and iron sulphides from them. To make a quality assessment of the impact of surface activity of the synthesized collectors on their selectivity of action and collecting power, an assessment of the surface tension of their aqueous solutions has been performed using the stalagmometer method. It is well known that a stronger collector is characterized by a greater surface activity, in contrast to a more selective collector which is characterized by a lower surface activity. Based on studies, new dialkyldithiophosphate collectors BTF 163 and BTF 1552 are suggested for use in the flotation of sulphides to increase the recovery of copper, gold and silver. The collector BTF 163 was introduced at a gold processing plant in Kazakhstan and has been undergoing industrial testing in the sulphide cycle of scheelite-skarn-sulphide ores in a factory in the far east of Russia. The collector BTF 1552, which increases the recovery of silver and gold by 3%, was approved for industrial testing in another far-eastern factory. A modification of the reagent BTF 1552, the new reagent BTF 1522, was introduced in the flotation of copper-zinc ore at a factory in Kazakhstan."

Jan 1, 2014

By Bruce Mathema, Steven Huynh, Terry Cheng, Gerry Gomez

"The use of PM40N, a specialty precious metals promoter in conjunction with a standard Xanthate based collector was extensively investigated in the flotation of a complex, silver-bearing, lead-zinc ore containing naturally occurring graphitic gangue. The ore, considered difficult to treat with conventional reagents, was tested at plant scale to determine the impact of the promoter on silver recovery, lead grade and also on the amount of zinc misplaced to the final lead concentrate.Initial laboratory-scale rougher flotation testing implied significant improvements in the recovery of silver and lead with a marginal amount of zinc displaced. Subsequent mini pilot flotation tests further revealed that a gain in selectivity and recovery could be achieved by adjusting PM40N promoter dosage and incorporating a cleaner flotation step, further improving rejection of sphalerite. Plant trials resulted in an improvement of 3% in Silver recovery coupled with a 2% increase in recovered lead whilst maintaining lead grade in the lead circuit.To date, the use of PM40N as a promoter has enabled the processing operation to significantly increase its plant economics. The partial replacement of the standard Xanthate based collector has also reduced the overall quantity of Xanthate required in the standard circuit by approximately 10% - which is a positive impact on the environment. It is envisaged that further optimization of plant parameters will favor stable operation and continue to boost revenues generated by subsequent improvements in silver metallurgy."

Jan 1, 2014

By Elves Matiolo

This paper describes, in detail, results obtained from a research study of a complex iron ore aiming to produce a pellet feed concentrate with at least 65% of Fe and less than 3.5% of SiO2 in the final concentrate. The work includes an ore desliming followed by column flotation at laboratory scale. The ore sample was from Carajás province - Brazil and represents a complex low grade compact itabirite ore, analyzing 35.9% Fe, 45.1% SiO2 and 0.57% of Al2O3. Yet, the feed was treated previously by magnetic separation and grounded to 97% < 20 µm; this sample was named MAG 2. The chemical and mineralogical characterization of the MAG 2 sample showed that Fe and SiO2 grades were 50.7% and 24.3% respectively and was composed mainly by hematite, goethite and quartz. The particle size distribution, using a laser diffraction technique, showed that 90% of the particles were < 18 µm; 50% less than 8 µm and 10% minor than 1 µm. When the cationic reverse flotation without desliming was tested the selectivity of the process was very low and did not meet the concentrate metallurgical goals of the pellet feed product. However, when desliming was applied prior to flotation, a concentrate product with chemical characteristics of the pellet feed was obtained. The best results after desliming and column flotation achieved global iron metallurgical recovery of 72% with Fe grade in the concentrate of 66.5% and 2.1% SiO2 using starch as depressant for the iron oxides minerals at 1200 g/t ? 1500 g/t and an amine as the quartz collector at 100 g/t concentration (pH constant, at 10.5). It is believed that the desliming stage was key in the separation of the iron bearing particles and has a high potential for the flotation process of this type of ores.

Sep 1, 2012

By Andrzej Wieniewski, Cezary Regula, Bozena Skorupska, Krystian Cichy

"In this paper, experiences from Polish non-ferrous metals ores enrichment plants in the copper and blende concentrates quality improvement are discussed. The blende concentrate being produced in ZGH Boleslaw S.A., with Zn content of about 54,5% is characterized by the relatively high magnesium content reaching a level of 1% resulting from the dolomite presence, while for the zinc production by electrowinning a concentrate in which magnesium content should not exceed 0,3% is required. The implemented new technology for the quality improvement of blende concentrate is based on the leaching of zinc concentrate with sulfuric acid aimed at dissolving of the contained dolomite, and then flotation of the leached concentrate. It allows to obtain a concentrate with magnesium content below 0,1% at the simultaneously increased zinc content to about 57,5%. In the paper, laboratory tests results on the development of optimal flotation flowsheet for the gypsum removal and the industrial tests results concerning the process optimization of this flotation are discussed. In turn, the copper concentrate being produced in Polish copper ore enrichment plants KGHM PM S.A., is characterized by the increased organic carbon content - above 8%. It creates problems with the smelting of this concentrate because of difficulties with the heat removal derived from the combustion of organic carbon in the flash smelting process. The implementation of segregating flotation to the industrial practice allows the effective production of two concentrates with the differentiated chemical compositions - a concentrate with increased copper content and reduced organic carbon content for the flash smelting process, and a concentrate with lower copper content and increased organic carbon content for the shaft smelting process. In the paper, conditions of the segregating flotation and the achieved results are described."

Jan 1, 2014

By Irena Grigorova, Tashka Ignatova, Ivan Nishkov, Andrian Valchev

"Feldspars used by ceramic and glass industries as fluxing agents are mainly obtained from high quality feldspar deposits. The demand for feldspar as raw material for industrial applications especially in ceramic manufactures is continuously increasing. However, due to the depletion of those deposits, the research activities related to the recovery of feldspar from the lower grade feldspar deposits and feldspar bearing rocks such as pegmatite, granite, arkosic sandstone and syenite have been intensified in the last two decade. In Bulgaria, the main deposit of arkosic sandstone is located in the area of Shumen town, NE Bulgaria. In Srednya deposit arkosic sandstones are found in Upper Cretaceous sediments (Santonian). In this formation, there are two major industrial minerals - feldspar and quartz. They may be of economic value and possibly suitable for commercial uses. The main purpose of the present study was to investigate the beneficiation and upgrading processes of Srednya deposit arkosic sandstones. In a laboratory scale it was studied the possibility to obtain the feldspar concentrate and quartz sand from arkosic sandstones. Particle size distribution, chemical and mineralogical compositions of quartz-feldspar sands were determined. The bench-scale tests using the KOALIN AD laboratory experimental facilities were conducted. Many processing techniques were tested: disintegration, washing, sizing, carbonate flotation and feldspar flotation. The experimental results show that there are possibilities to obtain the silica sand with low content of Fe2O3 - below 0.02 % and potassium feldspar with content of K2O > 14 %. A new technology for recovery of feldspar and silica sand from arkosic sandstone was developed."

Jan 1, 2014

By M. E. Taranenko, V. A. Krivonosov, S. A. Nemykin

"In concentrating production energy-consuming power installations are wide used, the most powerful of them are the wet autogenous grinding mill operating in closed circuit with a spiral classifier. The analysis of the current state of the automation of the grinding process shows that the reserves for maximizing productivity and minimizing electricity consumption have not yet been exhausted on the existing process equipment. Usage of the achievements of the modern management theory reveals an opportunity for further optimizing of the grinding process. The purpose of the research is to develop an automated control system of complex ""the mill-classifier"" to conduct the grinding process in the most operating efficiency, ensuring the maximization of productivity and minimization of specific electricity consumption. The main idea of this work is to study the specific features of the ore grinding process and creation on this basis of automated control system complex ""mill-classifier"" which allows to find and to maintain the optimal mode of grinding based on identification of the current object parameters, observance and regulating of the object state coordinates. Research methods. We used the methods of system analysis, mathematical statistics, modern automated control theory, theory of systems identification, optimal control, modelling of dynamic processes. Developed scientific provisions: - identification algorithm of the loading sub-system management object of complex ""mill - classifier"" allowing to obtain the unbiased estimators of its parameters according to the data of normal object exploitation; - observing device, which differs from the classic version of the observer Luenberger with possibility of estimating not only the state coordinates of the control object, but also the low-frequency perturbation component; - automated system stabilizing the active power of the grinding mode on the basis of a states controller with Luenberger observer; - structure of the software and hardware that implements the developed models, algorithms, methods of control, management and optimization in the framework of the automation of grinding."

Jan 1, 2018

By B. K. Mohapatra

Small manganese ore bodies in south Odisha, India occurs both as stratiform and stratabound ore bodies. These two ore bodies show contrasting mineralogical, petrographical and chemical characteristics. Stratiform type of Mn-ores consists of manganese, iron and silicate- phases in approximately same proportion. In contrast, stratabound ore bodies contain a high proportion of manganese oxides, silicates and phosphorus phases. Phosphorus is found within apatite in the stratabound ore bodies while in the stratiform ore it occurs as an adsorbed state with iron phase (goethite). Both ore bodies are low-grade (17-23% Mn) therefore do not have a market value. However, the stratabound ores are enriched in phosphorus (P2O5: >1%) compared to the stratiform ores. Both the ore types were processed through gravity, magnetic and roast reduction followed by magnetic separation techniques. The strata bound ore could be upgraded to 33% Mn from a feed of 23% by combination of dry and wet magnetic separation methods. But the phosphorus content also suits up (P2O5: 1.2%) in the processed product making it unsuitable for further use. The stratiform ores do not respond to either gravity or magnetic separation because of close association of manganese with iron phases. However, this could be beneficiated through roast reduction followed by magnetic separation. An ore with 17% Mn content could be upgraded to 40% Mn with a 42% yield and 78% recovery. The goethite, having phosphorus, converts to magnetite and is retained within the magnetic fraction, thereby reducing the concentration of phosphorus in the non-magnetic fraction, which becomes the product. This report demonstrates the influence of ore petrology in determining the up-gradational potential of manganese ore in the southern Odisha, India. Keywords: manganese ore, physical beneficiation, phosphorus rich ore

Sep 1, 2012

By I. A. Agapov, I. S. Anisimov, N. V. Rylov, A. M. Sagitova

"The smelter slags represented silicate crystalline rock with medium to coarse-grained structure with spinifex skeletal network of olivine in hedenbergite matrix. Accessory magnetite, pyrrhotite and copper sulfides chalcopyrite, bornite, covellite, chalcocite and digenite occurred in dissemination in silicate matrix. The sample was studied by optical and electron microscopy with support of quantitative XRD. Modal mineralogical composition included olivine, pyroxene, magnetite, chalcopyrite, quartz, pyrrhotite. Copper deportment showed copper distributed in chalcopyrite (40 %), cuprite (22 %), covellite (21 %), bornite, chalcocite, digenite (5 %), Cu-bearing pyrrhotite (4 %) and spinel (2%). Liberation of copper minerals in the material ground to P80=71 µm was good with over 90 % sulfides in free grains and floatable binaries. The results showed theoretical possibility of 65 % copper recovery by flotation. Conclusion based on mineralogical data was precisely confirmed with flotation tests studies that proved to recover around 60 % of copper to commercial grade concentrate. INTRODUCTION Annual world copper matte smelter slags production is estimated to be millions of tones and contain thousands tones of unrecovered Cu, Zn and significant amounts of Ag and Au. Mineralogical study of one large processing sample of material of historical piles of Cu matte smelter slag was carried out to find possibility to recover copper and define theoretical recovery by flotation. The study of the slag material was aimed to determine possibility of upgrading the material on existing copper flotation plant to develop additional mineral resources. The objectives for mineralogical investigation were to target for best liberation fineness, determine theoretical recovery and possible concentrate quality for sulfide flotation tests. MATERIALS AND METHODS Large representative processing sample was collected by mixing of 120 t of slag material representatively excavated from historical piles of Cu matte smelter slag. The sample was used to define the processing technology to recover copper and gold from the material."

Jan 1, 2018

By T. N. Alexandrova

Results of mineralogical-technological research of carbonaceous rocks of Kimkansky precious metal occurrence are presented, on their basis new typemorphic natural and technological microelement associations were revealed using mathematical statistics methods. Keywords: carbonaceous rocks, processing, microelements, flotation, statistical criteria

Sep 1, 2012

By Jonas Addai-Mensah

Despite the fact that nickel (Ni) laterites accounts for about 60 % of the world?s nickel mineralization, commercial processing of complex, low grade Ni laterite ores by conventional beneficiation (e.g. magnetic, electrostatic and flotation separation) still presents intractable challenges, particularly in heap leaching. Invariably, low grade laterite ores require aggressive hydrometallurgical techniques (e.g., highly acidic lixiviant leaching at ambient or elevated temperatures) for Ni and cobalt (Co) extraction. As a precursor to heap leaching, agglomeration of the multi-mineral phase feed particles into robust and porous granules of 4-10 m permeable bed, is essential. In the present work, several basic and applied studies of the agglomeration behavior of real Ni laterite ores and selected oxides and clay minerals (hematite, quartz smectite and kaolinite) which constitute the predominant host gangue phases of typical laterite ores are performed. Isothermal, batch agglomeration tests involving sulphuric acid solution as a binder were carried out to produce coarse, narrow-sized (5 ? 40 mm) granules which were well characterized. The influential role of feed ore characteristics (e.g., mineralogy/chemistry and primary particle size distribution) and binder composition (30 vs. 44% w/w H2SO4) and dosage (15-25 wt.%) in agglomeration behavior and granule properties were examined through several characterization techniques including granule size, compressive strength, bed percolation and re-wetting stability and 3-dimensional micro-structure analyses. Links between feed mineralogy/chemistry and size, binder formulation, agglomeration behavior, curing conditions and final granule properties and structural characteristics are established. The implications of the findings to Ni laterite plant agglomeration for enhanced heap leaching are discussed. Keywords: nickel laterite, complex low-grade ores, agglomeration, heap leaching, micro-structure

Sep 1, 2012

By Mohammad Noaparast, Hamed Haghi

"In this research work, it was attempted to reduce the iron contents (Fe2O3) in relatively low grade silica sample which was obtained from Shenin silica mine, using magnetic separation. The prepared sample contained 93.75%SiO2, 0.44%Fe2O3, 2.78%Al2O3, and 0.08%TiO2 and the Fe2O3 had to be reduced to less than 0.08%. Mineralogical studies and XRD analysis indicated the presence of Hematite, Pyrite, and Goethite as the major iron impurity phases. Mineralogical studies of polished and thin sections demonstrated that the degree of freedom of silica is more than 80% in -300+212 ?m size fraction. After primary stages including crushing, milling, scrubbing and de-sliming, various methods such as low intensity magnetic separation (LIMS), high gradient magnetic separation (WHGMS) and dry high intensity magnetic separation (DHIMS) were applied to find out that which process would be appropriate for the elimination of iron impurities from this sample. Different experiments were carried out on the product of wet rod mill and scrubber. However the magnetic field intensity of WHGMS was increased down to 2Tesla, and there was not any acceptable result in reduction of Fe2O3 content lower than 0.08%. Thereafter the product of wet rod mill and scrubber were dried and reported to DHIMS. In these experiments, maximum magnetic field intensity was 1.4Tesla. In this case very significant results were achieved, and Fe2O3 content of final product were reduced to less than 0.05% which meets glass manufacturing standards."

Jan 1, 2014

By S. Kelebek, A. Khan, J. Caceres, Beckett. D.

"Pyrrhotite in nickel-copper sulphide ores is nickeliferrous and intimately associated with pentlandite. Due to its low nickel content, pyrrhotite rejection is an important step in processing of these ores. In our laboratory, various reagents were investigated for their effect on pyrrhotite depression. Among these, a combined use of triethylenetetramine and sodium metabisulphite was found highly promising.The work described in this paper has two parts. The firs part is a summary of results obtained on process samples from the pyrrhotite rejection circuit at Falconbridge’s Strathcona Mill. The second part involves simulation of the circuit performance based on the reagent conditions used in the experimental work and the concept of split factors.Two sets of reagent conditions were evaluated. The first one involved baseline conditions, simulating the current reagent performance. The second one simulated the impact these new reagents can have on the circuit performance.The simulation results obtained under baseline conditions indicated a good agreement with the current circuit performance. The simulation results suggest that at practically the same pentlandite recovery and tailing grades, the circuit concentrate nickel grade can be doubled through effective pyrrhotite rejection by these new reagents."

Jan 1, 2003

By S. M. Narbekova, L. V. Semushkina, Zh. A. Aldybayeva, A. A. Mukhanova, D. K. Turysbekov, N. K. Tussupbayev

More complex and heavy-concentrating oxidized and mixed sulphidic oxidized ores are involved in production because of increasing needs for non-ferrous metals. Extraction of the oxidized minerals of non-ferrous metals general in current technologies. The problem is solved to oxidized polymetallic ores the preliminary selective sulphidization is the oxidized surface of the components by means of hydrogen sulphide, sulphide and calcium polysulphide, and also element sulphur, etc. The task was to study details of flotation of the oxidized lead-bearing ore of the Zarechnoe deposit (Kazakhstan) with calcium polysulphide as sulphidation. According to chemical analysis initial samples of the ore contain, %: lead – 4.8; zinc – 0.1; general iron – 0.81. Phase structure lead is characterized by the oxidized form of 57.76-64.5 %; by sulphidic status of 25.5-32.64 %, and by plyumboyarosite of 19.0-23.02 %. Researches on flotation beneficiation of oxidized lead-bearing ore are conducted. Sulfidizator gave to grinding, on flotations there were used the collector (butyl xanthogenate of sodium) and frother (T-80). Experiments were conducted with a new sulphidizator – calcium polysulphide. The latter is obtained by interaction of CaO calcium oxide with sulfur and water at high temperature with component mass the following ratio S:CaO:H2O =10:5:85. Extent of mill initial ore was optimised (88.42 % of - 0.071 mm grade). For the optimum mill mode the studies on matching of an optimized consumption of sulphidizators are performed. On basic technology with application of sulphide of sodium as a sulphidizator at optimum mill, the lead concentrate with the content of lead 64.4 % at extraction of 86.6 % was received. The content of cerussite in a concentrate was about 14.9 % at extraction of 82.1 %. With application of calcium polysulphide as a sulphidizator the lead concentrate with the content of lead 68.0 % at extraction of 88.0 % was received. The content of cerussite has made 16.0 % at extraction of 85.0 %. Application of a new sulphidizator allows to increase extraction of lead in a concentrate from 64.4% to 68% and cerussite extraction – from 82.1 % to 85.0 %. The possibility of application of calcium polysulphide as a sulphidizator instead of conventional sulphurous sodium was established.

Jan 1, 2018

By P. Oliveira, A. Peres, A. Silva

"The decrease in iron content and increase in contaminants grade, associated with greater participation of compact and semi-compact materials, has impacted the recovery of a mechanical cells flotation circuit in the Iron Quadrangle, Brazil. The recovery decrease in the flotation stage motivated the current conventional flotation circuit reevaluation seeking alternatives to restore the recovery, without affecting the final concentrate quality parameters, with low investment. Sampling, chemical characterization of samples, bench scale flotation experiments, and mass balances were conducted. Analysis of the results showed opportunities to improve the circuit performance. The stages prior to the flotation circuit changes were: rougher, cleaner, recleaner and scavenger. In the previous configuration, recleaner was operated as cleaner scavenger and the iron grade in the scavenger concentrate was 23%, representing 38% of the new feed. After the circuit change, the circulating load was reduced from 38% to 15% and the iron content was upgraded to 42%, resulting in increased residence time. The iron content in the global tailings of the concentrator was decreased from 10.9% (year of 2013 average) to 10.2%, representing gains in both mass and metallurgical recoveries.INTRODUCTIONRegarding plant practice, the year 1972 represents a landmark for the concentration of iron ores in Brazil. VALE started up 28 units of WHIMS (wet high intensity magnetic separators) at the Cauê plant in Itabira, each one producing 1x106 t/year of concentrate. Later 17 WHIMS machines were commissioned at Conceição. During the 80’s decade of last century, changes in the ROM required the addition of a cleaner flotation stage to decrease the silica content in the pellet feed.The first company to use reverse cationic flotation as the only concentration operation of iron ore was SAMARCO (start up in 1977). Since 2015 flotation has been utilized at VALE in Itabira as major concentration process, magnetic separation acting as scavenger stage.The Jones matrix type WHIMS were manufactured for decades under patent by KHD Humboldt Wedag. After the expiration of the Jones patent, Eriez Magnetics took the world leadership regarding WHIMS manufacturing. The Brazilian branch of Eriez is Inbras. Based on plant practice experience at the Fabrica concentrator, the Brazilian company Gaustec was established (RIBEIRO and RIBEIRO, 2010) and is now present in different countries. The mega sized WHIMS GHX-1400 (18.000 Gauss, gaps smaller than 1.5 mm) were developed to face the challenge of huge throughput required by iron ore processing (Ribeiro et al, 2017)."

Jan 1, 2018

By Alexander V. Epiforov, Stanislav V. Balikov

This paper describes of processing tests of 8 flotation concentrates containing precious and base metals by pressure oxidation (POX) method. Concentrates 1 and 2 were gold-copper concentrates. Zinc and silver were by-products in these concentrates. These concentrates were processed by POX with following cyanidation of POX solid residues, copper solvent extraction and zinc carbonate precipitation. The recoveries of gold, copper, silver and zinc from these concentrate were 98, 99, 30 and 99%, respectively. Concentrates 3 and 4 were lead-zinc concentrates. Silver was by-product in concentrate 3. Gold, silver and copper were by-products in concentrate 4. Concentrate 3 was processed by POX with following reduction smelting of POX cakes for primary lead recovery and zinc carbonate precipitation from POX solution. The recoveries of lead and silver into ingot were 96 and 98%, respectively. The recovery of zinc was 99%. Concentrate 4 was processed by POX with following zinc carbonate precipitation and reduction smelting of POX cakes. Copper was precipitated from the POX solution using sodium sulphide prior zinc precipitation. The recovery of zinc into carbonate concentrate was 99%. The recoveries of lead, gold and silver into lead bullion were 95, 99 and 98% respectively. The recovery of copper into sulphide concentrate was 99%. Concentrate 5 was gold-pyrite concentrate, and concentrates 6-8 were double refractory gold-arsenopyrite concentrates. Silver was by-product in these concentrates. These concentrates processed by POX and CIL. The recovery of gold from concentrate 5 was 98%, and from concentrates 6-8 was 85-90. Low gold recovery from concentrates 6-8 was associated with preg-robbing factor. The recovery of silver from gold-sulphide concentrates did not exceed 10-20%. The low silver recovery was associated with argentojarosite formation that is resistant to cyanidation. The flowsheets for complex processing of precious and base metals sulphide flotation concentrates based on this test work results were proposed.

Jan 1, 2018