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The status quo of ecological rehabilitation in metal mine in China and progress in the technology for ecological rehabilitation are presented, including soil reconstruction, soil improvement, plant selection. The present and future research fields are suggested: basic theory of ecological rehabilitation, operative technology of ecological rehabilitation, new technology application research and ecological rehabilitation plan, management and policy.

Jan 1, 2014

By B. Y. Tuo

This article presents results of studies performed to determine the feasibility of using low-grade limonite ores from Yunnan deposit. Laboratory tests and commercial trials have shown that the magnetic separation can be performed with a high high-grade concentrates. The quality of the preparation concentration meets the requirements for blast-furnace smelting. The results as a whole demonstrate the feasibility of utilizing bank limonite ore. Yunnan limonite?s magnetic separation, roasting magnetic separation and flotation experimental study shows that grade of the ore grade can been from 32.91% heighten to 58.64%, a recovery of iron is 90.87%, productive rate is 51% through orthogonal test optimization; roasting magnetic separation can obtain that the grade of iron preparation concentrate is 61.16%, recovery is 67.39%, productive rate is 36%. As far as economy and enviormental protection is concerned, strong mag-netic suggested a more appropriate process. Keywords: Limonite; Roast; Magnetic separation

Jan 1, 2014

By Liu Yong

A complex rare metal ore, containing various valuable elements is used in this study. The mineralogy results indicate that the mineral composition of the raw ore is complex, and there are more than thirty-eight kinds of minerals in the raw ore, and the elements, such as Nb, Ti, Fe, REO, Be etc, always form isomorphism relationship. The REO content of the raw ore is 0.45%, and the contents of other rare metals Nb, Ta, Ti and Zr are 0.33%, 0.02%, 0.93% and 2.00% respectively, and the main gangue elements are Si and Al, and their contents are 71.84% and 8.5% respectively. The beneficiation-metallurgy combination process of ?preconcentration-reduction and magnetic separation-acidification and leaching-precipitation? is used to treat the raw ore. The preconcentration of raw ore is realized through high intensity magnetic separation, and the magnetic field intensity is 1.0T, and the rough concentrate with 2.88% REO and 1.95% Nbresidue can be obtained, and the iron recovery is 92.83%, and the REO recovery is 95.87%, and the Nbresidue is treated by hydrometallurgy process of ?acidification-leaching-precipitation?, then the rare earth oxide, niobium concentrate and zircon-bearing residue can be obtained, and the REO recovery is 80.10% and the Nbresidue and the gangue obtained from the high intensity magnetic separation process is separated by gravity separation, and then the zirconium concentrate can be obtained. The indexes of the beneficiation-metallurgy combination process used to treat the complex rare metal ore are as follows. The REO content of the rare earth oxide is 92.58% and the recovery is 58.44%. The Nb2O5 and 27.42% TFe can be obtained. Iron in rough concentrates is removed after reduction and low intensity magnetic separation, then the iron powder with Fe content over 88% and nonmagnetic rare-metal 2O5 recovery is 94.77%. The rare-metal 2O5 recovery is 80.04%. The mixture of the zircon-bearing 2O5 content of niobium concentrate is 28.34% and the recovery is 54.02%. The ZrO2 content of zirconium concentrate is 28.43% and the recovery is 52.35%. The TFe of iron powder is 89.53% and the recovery is 78.13%. Keywords: rare metal ore, separation and extraction, beneficiation-metallurgy combination, comprehensive utilization

Sep 1, 2012

By W. Z. Yin

With increasing of mining depth, many iron ores in Liaoning Province contain carbonates such as siderite and ankerite. The emergence of these carbonates in ores creates a fatal impact on the running producing process of anionic reverse flotation in Dong Anshan Sintering Plant, which leads to ?concentrate and tailing no separated?. And its reason is still unknown. Moreover, siderite, despite that its ferric theoretic grade is only 48.2%, however, do not affect the blast furnace utilization factor, therefore, can be used as raw materials in ironmaking. In order to solve the separate problem of iron ore containing carbonates, five pure minerals, martite, magnetite, quartz, siderite and ankerite, were selected for a series single flotation experiment. The aim was to discover the flotation difference of these minerals, furthermore, to explore a new flow sheet for the iron ore containing carbonates. The results of single mineral flotation experiment reveal that the combination regulators, starch and CaCl2, in different pH extent, can make these minerals taking on obvious flotation difference, which make it possible to process the iron ore containing carbonates. A new flow sheet, step-flotation, to process iron ore containing carbonates is explored, that is, first step, direct-flotation processing, is to eliminate the bad effect that the carbonates bring in flotation system by collecting carbonates under neutral condition; the second step, reverse?flotation processing, is to get qualified iron concentrate by collecting quartz under alkaline condition. Manual mixed ore sample were processed successfully through this new flowsheet under proper reagent system, which has absolute advantage compared with routine flowsheet. Actual ore sample of compound magnetic separation concentrate were processed successfully both open and closed circuit experiment through this new flowsheet. SEM and EDS were used to probe the reason why carbonates affect the regular processing. It is analyzed that moderate floatability of siderite and its coating on the surface of hematite and quartz make the phenomenon ?concentrate and tailing no separated?. This research provides a reasonable processing scheme for iron ores containing carbonates and can be used for reference in processing other complicated, refractory iron ore.

Jan 1, 2014

By Ritva Tuunila, Antti Häkkinen

"Wet stirred milling is one of the most effective grinding methods in producing very fine powders in large scale production, but it is a very energy-intensive process, especially when pigments or even nanosize particles are produced. Therefore, optimization of the process parameters is important. The specific energy consumption is a function of stress energy, which describes the effect of tip speed and media characteristics on grinding, and is related to the number of stress events during milling. In effective grinding, a large number of stress events are necessary. The stirrer configuration influences the number of stress events and their intensity, because the motion of the media and the suspension are caused by a rotating stirrer. The effect of three different stirrer types: a pin, disc and blade stirrer, on the grinding rate, i.e. product fineness and specific energy were investigated in this study with a batch laboratory stirred mill with two tip speeds. The material used in the experiments was calcium carbonate. The results obtained with the smaller tip speed showed approximately similar grinding rates and energy consumption for all stirrer types. When looking in closer detail, the blade stirrer seemed to give the finest product with all grinding times compared to the pin and disc stirrers, which both produced almost the same product fineness with the same grinding times. The specific energy consumption was the smallest with the disc stirrer, but not very big differences were obtained. With a higher tip speed, greater differences occurred both in grinding rates and specific energy consumption. The blade stirrer was the most effective in grinding, and the pin stirrer the next. The net energy consumption for the blade and pin stirrers was almost the same, but it was slightly higher for the disc stirrer."

Jan 1, 2014

By R. Singh

The present paper deals with the development of flotation based process for enrichment of a lead-zinc sulphide ore from Ganesh-Himal region of Nepal. Detailed characterisation and flotation studies were carried out under varying process conditions. The sample assayed 2.47% Pb with 13.6% Zn. The ore was predominantly made up of spahlerite and pyrite in association with subordinate amounts of galena, minor amounts of pyrrhotite and chalcopyrite. Dolomite was the main gangue. The modal analysis showed the probability of fair liberation of sulphides from gangues around 210 microns but the locking of galena with sphalerite and other sulphides continued to finer sizes. Under the optimum process conditions the rougher lead and zinc recoveries were 96.3% and 90% respectively. Multistage cleanings of rougher products proved helpful in improving the concentrate grade, meeting the required specification. Based on the studies undertake a process flow-sheet for the concentration of the ore to individual lead and zinc concentrates was developed.

Jan 1, 2014

This study examines the surface alteration and flotation behaviour of synthetic moncheite, PtPd(BiTe)2, in the presence of pentlandite. The telluride minerals contribute around 20% ~ 30% and up to 45% of the PGM present in the Platreef ore and are considered to be slow floating as there is evidence of these minerals reporting to the tailings. It was proposed that oxidation products from other minerals and grinding media would affect the mineral surface composition and floatability thereby causing inadvertent depression of moncheite due to precipitating ions. ToF-SIMS analyses (time of flight secondary ion mass spectrometry) was used to characterise the mineral surface as well as the extent of surface alteration. Microflotation was used to deter-mine the hydrophobicity of the synthetic minerals. Conditioning of moncheite in the presence of pentlandite reduced the flotation response of the + 38 -106µm size fraction from > 99% to 56%. This was due to pentlandite dissolution products (iron and nickel hydroxy species) which formed overlayers on the mineral surfaces thereby inhibiting the adsorption of collector. In addition, further grinding of these samples, with and without pentlandite conditioning showed a negative effect on recovery due to the fineness of the particle size distribution and there was no advantage gained from any possible exposure of fresh sites in the sample.

Jan 1, 2014

By J. Quinteros-Riquelme

Despite increasing demand, the supply of silver is limited by its inadequate recovery from ores. Due to its scarcity in nature, its high ore variability and complex mineralogy of current silver deposits, its recovery by mineral froth flotation presents a real challenge for process engineers. A silver ore often contains significant amounts of five to ten different silver minerals and knowledge of the mineralogy is a necessary precursor to flotation testing. In this work, a complex silver ore was treated by using batch laboratory flotation, in an effort to find the best experimental conditions to obtain the optimal silver recovery. Mineralogical characterization of feed samples was conducted using a combination of tools, namely the mineral liberation analyzer (MLA) and inductively-coupled plasma mass spectrometry (LA-ICP-MS), which indicated that most of the silver occurred as ?invisible? silver in pyrite. The pyrite assay of the ore was approximately 4%. The ore was processed in two flotation stages. The first stage, sulphide flotation, aimed to collect a sulphide mineral rich concentrate; then a non-sulphide flotation stage was performed by adding sodium sulphide and collectors to the remaining material in the cell, with the objective of obtaining a pyrite rich concentrate. To reach the target recovery of silver from this ore, various variables were altered. In the first stage: mixed collectors, activators, dispersants, and mainstream inert grinding were assessed. In the second stage, the conditions for sulphidization and subsequent flotation were both investigated. From the grade recovery curves for silver and sulphur it was possible to observe a similar metallurgical behavior for both elements, supporting the results given by the mineralogical characterization. Keywords: silver oxide, froth flotation, sulphidization, mig

Sep 1, 2012

By V. I. Ryaboy, I. V. Ryaboy, E. D. Shepeta

"The problem of separation of copper minerals and arsenopyrite remains relevant because of environmental requirements. The selective action of reagents with the thioamide group (thioamides) is known in iron sulfide’s flotation of pyrite and pyrrhotite. The aim of this study was to reduce the arsenic content in the copper concentrate when using thioamides by reducing the flotation of arsenopyrite in the flotation of the sulfide part of the skarn scheelite-sulfide ores. We have chosen the most widely used thioamides for the study, such as Z-200. We also synthesized new reagents with the thioamide group. The most selective and the most powerful thioamide copper collector were used for further studies. Reduction of arsenic content in copper concentrates is achieved in the following way: You need to apply a strong thioamide collector with a selective but weak dialkyldithiophosphate collector, or vice-versa, a selective, but a weak thioamide collector should be used with the dialkyldithiophosphate reagent with strong collective properties. The proposed combination presents industrial interest because of its accessibility. The application of thioamides in copper minerals and arsenopyrite selection has showed that these reagents have fewer selective properties than dialkyldithiophosphates. To achieve the comparable recovery of copper using dialkyldithiophosphates requires markedly greater consumption of thioamides, due to their lower hydrophobic ability. The application of a composition of thioamides and dialkyldithiophosphates allows to increase the recovery of copper and to obtain a lower arsenic content in copper concentrates compared to their individual use. The lowest arsenic content in the copper concentrate is obtained in the composition consisting of the newly synthesized thioamide with strong collective properties and selective dialkyldithiophosphate. The addition of even small amounts of xanthate to the composition of thioamides and dialkyldithiophosphates causes a sharp increase in the arsenic content in the copper concentrate without a notable increase in copper recovery."

Jan 1, 2018

By Y. M. Zhu, G. C. Gong

"The influences of citric acid (CA) on the flotation behavior of cassiterite using styrene phosphonic acid (SPA) as the collector were studied via single mineral flotation tests, contact angle measurements, zeta potential determinations and solution chemistry calculations in this paper. The results of single mineral flotation tests revealed under the conditions that pH=4 and the dosage of SPA 100 mg/L, the recovery of cassiterite reached 76.78%. The addition of 20 mg/L AC decreased the recovery by 12.42% at pH=4. Contact angle measurements demonstrated the adsorption of CA prior to SPA made the cassiterite more hydrophilic. The results of zeta potential determinations and solution chemistry calculations indicated the chemisorption of C6H7O7- and C6H6O72- filled parts of the Sn site on cassiterite surface and prevented the SPA from getting adsorbed. The hydrophilic effect of AC was stronger than the hydrophobic effect of SPA and the flotation of cassiterite was crippled. INTRODUCTION Tin is an important metal which is widely used in medical instruments, marine engineering materials, electronic and electrical devices, welding, weapon manufacturing and organotin compounds industries (Angadi et al., 2015). Cassiterite is the only mineral from which the tin can be extracted, thus it is of great importance to efficiently exploit the cassiterite mineral. Flotation is an indispensable method for the recovery of cassiterite (Li et al., 2015). However, cassiterite is usually in association with many other gangue minerals which are of similar floatability, such as quartz, calcite, fluorite, iron oxide, wolframite, scheelite and tourmaline (Sreevinas, 1997). So some modifiers are necessary in the cassiterite flotation process. The amounts of the modifiers used in the flotation must be judicious and the overmuch modifiers may cripple the recovery of cassiterite (Parsonage et al., 1987). Nevertheless, the research about the effects of the modifiers on the flotation behavior of cassiterite has been rarely reported. In this paper, the influences of citric acid (CA) on the flotation of cassiterite using styrene phosphonic acid (SPA) as the collector were investigated by flotation tests, contact angle measurements, zeta potential determinations and solution chemistry calculations."

Jan 1, 2018

By D. W. Lui

Tangdan copper oxide deposit, the largest independent copper oxide deposit in China so far, is located in the northeast of Yunnan province, southwest of China. The ore from this deposit is characterized by: low grade, high oxidation ratio, and fine-grained disseminated, resulting in poor flotation recovery. The analysis of plant flotation data reveals that the loss of copper minerals into tailings is mainly with coarse size fraction due to insufficient liberation and fine size fractions, especially minus 10 microns fraction, which proved to be very difficult-to-float with conventional flotation. In order to improve the performances of plant flotation of this ore, laboratory flotation tests were conducted with the pure malachite, which was the principle copper oxide mineral in Tangdan copper ore deposit. The results obtained suggested that a finer grinding (up to -325 mesh or even -400 mesh) be needed to decrease the loss with coarse size fraction, and vacuum flotation is a promising way for the recovery of the fine malachite effectively.

Jan 1, 2014

By Jaeheon Lee, Jae-Chun Lee, Doyun Shin, Minseuk Kim, Hyunsik Park

"The appropriate treatment of cyanide waste water is becoming an emerging issue because of the toxic residue and large quantity produced from gold processing plants. In the present article, we designed and operated a continuous biological cyanide treatment system using domestic sewage sludge and various microorganisms including a cyanide-producing and degrading bacterium, Chromobacterium violaceum. The synthetic wastewater containing 50 mg/L of cyanide was pumped continuously into the reactor at a flow rate of 500 mL/d for 21 days. When 50 mg/L of cyanide was fed, the cyanide concentration in the effluent of the reactor inoculated with activated sludge (S-50) decreased by 7.5 mg/L in the effluent. The other reactors did not show significant cyanide degradation and the reactor inoculated with C. violaceum showed increased cyanide concentration in the effluent. The microbial community in the reactors was analyzed by 16S rRNA-gene based pyrosequencing technique to investigate microbial response to cyanide addition and operation time. The microbial community analysis shows that the phylum Proteobacteria was detected in the reactors showing significant cyanide degradation (S-50), while Firmicutes and Bacteroidetes was dominant in the other reactors with very low cyanide degradation. Proteobacteria could not compete when the other phyla Firmicutes or Bacteroidetes were inoculated. This study shows the feasibility of the biological cyanide treatment system for gold processing plants and contributes new fundamental knowledge about the microbial community in the biological cyanide treatment system. INTRODUCTION Cyanidation has been widely used to recover gold from ores or secondary resources since first proposed by MacArthur and Forrest in 1888 (MacArthur et al., 1888) and it is used in many states of the USA, including Nevada, Arizona, California, Colorado, and Idaho (Laitos, 2012). Cyanide compounds are highly toxic and create serious problems for wildlife and water management (Solomonson, 1981; Donato et al., 2007). Furthermore, because many countries have imposed strict standards for cyanide discharge (USEPA, 1985), it is essential to develop a cost-effective and environmentally friendly technology for treating cyanide-containing wastewater."

Jan 1, 2018

By Y. G. Sun

This paper mainly reported separation manganese silver oxidized ores process by amylum de-gradation reduction and its influencing factors. When dosage is given according to nMn : nH2SO4 : n(C6H10O5)n : nH2O=1:k21.8: k116.66:30, the amount of up to 95.93% Mn leach rate and less than 2% silver loss can be obtained. Cyanidation process was used to extracted silver from leaching Mn residues. Silver leach rate could reach 94.15% at consumed amount of 1kg/t NaCN for 1h. Silver leach recovery rate was more than 92.27% by leaching Mn and cyanidation two-step processes so manganese and silver were separated effectively.

Jan 1, 2014

By B. Csoke

As opposed to large household appliances, in the processing of which dissambling has an important role, this possibility is pushed into the background as the size decreases. The practicable solution is physical liberation of the used small electronic household devices (by comminution) and separation of the liberated components according to their physical properties. In the first phase of the experimental work the structural/material composition of the typical products (mixer, kitchen robot, hair dryer, coffee machine, iron, bread toaster, vacuum cleaner, oil fryer) was determined. In the second phase a physical liberability test for each appliance using a rotary shear/shredder for crushing and a hammer shredder for milling was carried out. In the third phase the experimental separability tests using an air classifier and a shaking air table, as well as an eddy-current and an electrostatic separator were performed. In the present paper the results obtained using the air classifier and the electrostatic separator, are reported. To follow the life of a grain a new methodological procedure was elaborated. The particle size fractions after comminution were sorted into material fractions (copper, aluminium, plastics, etc.), then separated, and finally the recovery of the material components in the products were determined. Furthermore, the joint separability was investigated from two points of view: 1) for grain fractions and 2) for each waste appliance. According to the tests carried out so far, it was established that it is reasonable to form appliance groups by selection (e.g. mixer, iron, bread toaster and similar appliances form the first group, while the sandwich oven,

Jan 1, 2014

By A. Shibayama

Soil contamination by organic compounds is one of the most concerned issues on polluted soil. It is well known that there are limited methods to remediate the contaminated soil on site. Especially, the in-situ method for contaminated soil is too difficult to de-contaminate the organic pollutant. In this study, the fundamental ability of soil remediation, which aimed to decrease oil concentration in, in-situ process, have been researched by using a high pressure gas generated from ?crush composition? on artificially oil contaminated soil. The n-hexadecane (n-C16H34) and other organic compounds were selected as soil oil contaminators, gravimetric analysis by soxhlet extraction and GC-MS were used as qualitative and quantitative analysing methods. For the experimental examination, the influences on the difference in the concentration of n-hexadecane (and other organics), the tamping amount, position and repetition of crush composition in soil, and scale (size) of experimental model were investigated. The n-hexadecane concentration reduced by the explosive effect of crush composition showed a reasonable decrease of about 30 wt%~60 wt% compared to the initial n-hexadecane. The removed amount of n-hexadecane and distance from explosion point of the crush composition was related in scale and model of contaminated soil.

Jan 1, 2014

By A. A. Rogozhin, E. G. Likhnikevich, S. I. Anufrieva, A. V. Kurkov

"Russia is among the nations holding the world's largest lithium ore reserves. Lithium is of key importance for the global economy. Therefore, it is important to review the current state of technology research aimed at finding the most effective solutions for the recovery of lithium from promising reserves in Russia. In Russia, a number of process solutions for the flotation of spodumene into salable concentrate (5% Li2O) have been implemented at the earlier existing complex low-grade ore concentration project. By applying these solutions, a sample of high-grade spodumene ore (4.7% Li2O) of the Greenbushes deposit was processed into a spodumene concentrate (7.5% Li2O) at a high recovery (~93%) of lithium. In Australia and Canada, new processes have been developed for the recovery of high-grade spodumene concentrates from high-grade ores using dense medium separation and flotation. For the recovery of mica lithium concentrates from low-grade ore, a flotation process was developed in Russia using the cationic collector ANP-2 and Oxifos-B as an additional collector. Low-grade ore containing 0.14% of lithium oxide was processed into a 2.7% Li2O concentrate. New hydrometallurgical lithium concentrate and ore processes are developed to avoid high-temperature (>1000 °C) roasting. The Sileach process (Australia) includes leaching of lithium ore with sulfuric acid in the presence of a halogen-containing component at a temperature of 95-115 °C. In the Russian process, lithium is recovered into an alkaline solution from low-grade spodumene ore in a pressure alkaline leaching environment (250 °C, NaOH concentration > 300 g/l). The developed concentration and hydrometallurgical methods will allow to design on their basis efficient processes for recovering salable products for hi-tech industries from lithium ores.INTRODUCTION Lithium has many unique and important properties. It is the least dense hard metal. Its alloys have some of the highest strength-to-weight ratios. Lithium has the lowest melting point of all known solid elements and is used as a highly-effective heat transfer medium. The high demand for lithium is due primarily to its unique electrochemical potential and low thermal expansion coefficient. It is used in the production of glass and ceramics, in petrochemicals, metals, medical and other industries. Since the late 20th century, the electronics industry has been the largest consumer of lithium. In recent years, lithium has attracted much attention also as an important component of ultra-lightweight electronic devices. It is also the preferred metal for electric batteries used in mobile electronic devices, vehicles, household power generators, making it an important resource for the development of environmentally friendly technology. Leading automotive brands have ambitious plans for the production of electric cars — Tesla Motors, VW, Toyota, GM, BYD Auto. It is expected that the production of electric vehicles alone will triple the demand for lithium by 2025. A sharp increase in the production of lithium is expected. Lithium has all the prerequisites to become a strategic resource of the 21st century. (Deutsche Bank, 2016; Bradley et al, 2017)"

Jan 1, 2018

By Zhangm Zeqiang, Manman Lu, Hanquan Zhang, Hong Yu, Jintao Fu

"Pelletizing is an important technique in the ironmaking industry. Artificial and natural magnetites are materials that are widely utilized in the iron ore pelletizing process. In this work, the pelletizing characteristics of these two types of magnetite have been investigated in detail. The obtained results shown that in contrast to natural magnetite, the artificial magnetite concentrate exhibits stronger hydrophilicity, lower electronegativity, larger specific surface area, and rougher surface. In addition, the green pellets produced from the artificial magnetite concentrate are characterized by a higher compressive strength as compared to that of the pellets obtained from the natural magnetite concentrate. However, the shock temperature of the artificial magnetite pellets around 255 C is significantly lower than the threshold specified by the industry. The balling characteristics of the material obtained by mixing 20% of the artificial magnetite concentrate with 80% of the natural magnetite concentrate are considerably improved with respect to those of the individual components.INTRODUCTION Pelletization is an essential process of the ironmaking industry in China. Since the pellets produced from iron ore exhibit high mechanical strength, good particle granularity, and uniform shapes, pelletizing high-grade iron ores with good metallurgical reducibility can lower the coke ratio, improve their technico-economic index, and reduce the cost of processing pig iron in blast furnaces[1, 2]. Presently, high-grade magnetite is a material utilized for pelletizing various iron ores across the globe. However, its natural deposits have been depleting rapidly in recent years; as a result[3], China’s dependence on the foreign high-grade iron ores exceeded 70% in 2009 and reached the level of 87% in 2016. Hence, possible methods for the efficient cultivation of limonite, siderite, hematite, and other refractory minerals that correspond to low-grade, finely sized, inhomogeneous, and scattered iron ores have attracted significant attention [4, 5]. In particular, magnetization reduction roasting and magnetic separation techniques, which are widely utilized for obtaining high-grade artificial magnetite, represent effective ways of processing iron ores that can alleviate the scarcity of natural magnetite resources [6, 7]. The artificial magnetite produced by magnetization reduction roasting exhibits different characteristics as compared with those of natural magnetite (including the degree of hydrophilicity, surface potential, specific surface area, and other surface physicochemical properties[8-11], which significantly affect its pelletizing behavior. In this work, the surface characteristics of artificial and natural magnetites are investigated in detail, and their effect on their pelletizing properties (such as green ball strength, heat stability, and pelletization rate) are examined."

Jan 1, 2018

By Y. Y. Li, T. T. Yang, R. X. Zhou, Z. H. Shen

"Wetting theory is one of the basic theories of flotation. The effects of concentrations, carbon chain length and pH values of saturated fatty acid collectors (lauric acid, myristic acid, palmitic acid and stearic acid) on the surface wettability of collophanite and dolomite were investigated by measuring the contact angle with dynamic captive-bubble technique and calculating adhesion work of bubble-mineral. The results show that the contact angles both of collophanite and dolomite are higher with enhancement of hydrophobicity when pH value of 5~9. The contact angles both of collophanite and dolomite are reduced with improvement of surface hydrophilicity. When strong acid pH value of 2~4 or strong alkaline pH value of 10~13. The reasons for this are that the fatty acids mainly exist with insoluble RCOOH molecules in strong acid condition, and competitive adsorption of OH- and RCOO- in the mineral surface is formed in strong alkaline condition. With the increase of the collector concentration, the contact angles of the collophanite and the dolomite all first increase then decrease. The formation of hydrophilic micelles results in the decreasing of contact angles and enhancement of surface hydrophilicity opposite when the collector concentration exceeds CMC. The contact angles of the collophanite and dolomite and the WSG of the bubble adhesion increase, the hydrophobicity enhance with the increasing of carbon chains of saturated fatty acid from 12 to 18. The variation tendency for the adsorption quantity of collectors and floatability of collophanite and dolomite are in line with the change trend of contact angle basically. It shows that the wettability of solid-liquid-gas interface can be well characterized by the dynamic captive-bubble technique.INTRODUCTIONPhosphorite resources are the main raw material for producing phosphate fertilizer and producing phosphoric acid (Cao et al.,2005), which is an important strategic mineral resource. The useful minerals in calcareous-magnesium phosphate ore are collophanite, and the main gangue minerals are dolomite (SISH et al.,2003). The lattice ions of the phosphorite and dolomite are both Ca2+, their similar surface properties and similar floatability are the main reason for the flotation of calcareous-magnesium phosphate ore difficultly (Fang et al.,2011). Usually, fatty acid collectors are used for the flotation of calcareous-magnesium phosphate ore under acidic conditions by reversing flotation method to remove dolomite (ABOUZEID et al.,2009), or direct flotation is used to gather collophanite in the alkaline conditions (Gong et al.,2017). The flotation behavior of collophanite and dolomite affects the indexes of concentrate and flotation efficiency directly. Therefore, it is necessary to study the action mechanism and the flotation method of the collector with the phosphate rock and dolomite respectively (Moudgil et al.,1988; Hanna, et al.,1990)."

Jan 1, 2018

By H. Q. Peng

The study of synergistic reagents combination of mineral floatation is more and more important with the decreasing of bonanzas now. In order to determine the chemical reaction mechanism, here we present the synergistic reagents combination: amyl-xanthate, butyl-dithiophosphate and N,N-diethyldithiocarbamate ester, which dissolved by different organic solvents. The reagents were applied by an Anhui mine to float low-grade covellite as a substitute for ethyl-xanthate. One reaction products Na2HPSO3?5H2O (disodium hydrogen-thiophosphate pentahydrate) which was re-crystalized and measured by X-ray diffraction analysis. In its crystal structure, the two crystallo-graphically different Na ions are six-coordinated and are bridged by two covalent bonds with the O atoms of water molecules to give a basket unit. However, we can?t get Na2HPSO3?5 H2O by combining butyl-dithiophosphate and N,N-diethyldithiocarbamate ester under the same condition. This discovery may provides a intuitionistic evidence that in the process of reaction, the three com-pounds would cooperate with each other, but the decisive reaction may be the hydrolyzation of amyl-xanthate.

Jan 1, 2014

By Herman Mendoza, Luisa Ciriaco

An investigation of the seeding mechanism using heterocoagulation and the Derjaguin - Landau - Verwey - Overbeek (DLVO) theory of two pure minerals is the objective of this study. The seed was silica with modal diameters of 4.529 µm (fine particles) and 5.216 µm (coarse particles) and the test powder was hematite with a modal diameter of 0.883 µm. Parameters included variations in the concentration and particle size of silica. Both particles were first subjected to size determination and settling tests via Stoke’s Law. The silica-hematite system was then suspended in 0.001 M KNO3 electrolyte solutions where pH was adjusted. Afterward, the suspension was agitated and was allowed to settle at different time intervals while obtaining turbidity readings. Results through settling time and turbidity vs. pH graphs indicate that maximum heterocoagulation occurs from pH 2 to 5 while minimum heterocoagulation occurs from pH 6 to 7. At these pH levels the zeta potentials of silica and hematite are negative and positive, respectively. On the contrary, repulsive forces dominate the system from pH 8 to 11 due to the particles’ negative zeta potentials. Furthermore, the attachment of hematite to silica increases when the parameters become larger thereby increasing the effectivity of heterocoagulation at acidic to neutral pH levels.

Jan 1, 2014