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By Takahiko Okura, Chiharu Tokoro, Shunta Shibuya

Copper concentrates bearing arsenic as enargite (Cu3AsS4) or tennantite (Cu12As4S13) have disadvantage on copper smelting environmentally and economically, so those concentrates should be treated decently. In this paper, some experiments of arsenic removal from several kinds of copper concentrates by heat treatment in an inert atmosphere were discussed. In this study, several samples in which arsenic contents varied 0.18 to 8.3 wt % were heated to the temperature range of 400 °C to 700 °C under argon gas flow during 1 hour. The heat residues and volatilized materials (V.M.) were analyzed by XRD, XRF, ICP-AES, XAFS and MLA to analyze residual concentration of arsenic and residual mineral composition. Experimental results showed that arsenic removal from copper concentrates advanced in 2 steps; at the temperature range of 500 ° C to 550 °C and of 550 °C to 650 °C, respectively. MLA analysis showed that a few of arsenic in enargite was removed by 550 °C heating and a majority of it was still combined with copper and sulfur as tennantite. On the other hand, arsenic in tennantite was removed almost completely by 650 °C heating. Furthermore, a particular type of arsenic mineral, such as Cobaltite (CoAsS) still remained after heating at 700 °C.

Jan 1, 2014

By Donald S. Cameron

By dispersing gold in high surface area form supported on metal oxides, its inert character can be transformed to make economical, effective catalysts. Gold has already been demonstrated in a number of fuel cell applications such as gas phase catalysts, electro-catalysts, and electrical connectors. In this paper, the various types of fuel cell systems are reviewed, and several opportunities for gold identified. Low temperature fuel cells, including alkaline and solid polymer electrolyte types rely on high surface area platinum group metal catalysts which are highly susceptible to poisoning by low concentrations of carbon monoxide in the fuel supply. Hydrogen is frequently obtained by steam reforming hydrocarbons, followed by the water gas shift (WGS) reaction. A promising initial use for supported gold catalysts is in catalysing this WGS reaction. Research has shown that gold supported on iron oxide (Au/a-Fe2O3 ) WGS catalysts are more active than the current commercial copper oxide / zinc oxide catalysts, and effective at temperatures as low as 120oC. Products from reformer/ water gas shift reactors can be further purified by removing traces of carbon monoxide. If a small proportion of oxygen is introduced into the fuel gas stream, carbon monoxide can be preferentially oxidized to carbon dioxide even in the presence of hydrogen. Gold nanoparticle catalysts on iron oxide support (Au/a-Fe2O3 ) have exhibited higher activity than commercially available platinum on alumina (Pt/?- Al2O3 ) preferential oxidation catalysts. The low temperature of this reaction may make it feasible to incorporate these catalysts within the fuel cell itself. Proton exchange fuel cells provide several possible applications for catalytically active gold and its alloys. Carbon supported platinum group metals would benefit greatly from improved electrical conductivity if gold replaced some or all of the carbon support material. As electrode current densities are raised, electrical resistance constitutes an increasing proportion of voltage losses within the fuel cell. Dramatic reductions in cell stack voltage losses have already been demonstrated by reducing inter-cell contact resistance using gold plating. The low temperature oxidation properties of gold catalysts have been investigated in controlling gaseous emissions from direct methanol fuel cells, and gold also provides essential catalysis in building direct borohydride oxidation fuel cells. The prospect of a range of other applications for gold in fuel cells to contribute useful improvements in corrosion resistance and conductivity is assessed. Globally, fuel cells have been developed for a wide range of applications including stationary generators, cars and buses, industrial vehicles and small portable power supplies, each of which represents a substantial market. Hence there are likely to be many and varied opportunities for gold catalysts to contribute to the performance and economics of the systems being commercialized.

Oct 1, 2003

By K. V. Konigsmann

"Concentrate dewatering operations have a significant influence on the economics of base metal beneficiation. The expenditures f or energy and labour per tonne of product are high. The relatively low efficiencies of standard techniques present inducements for process modifications. Development efforts at several Noranda concentrators led to process changes which improved productivity, namely, agitated pulp storage in large vessels, process automation and pressure filtration.IntroductionA program was initiated in 1968 with the aim of improving utilization of manpower and equipment in dewatering operations. The following considerations motivated us in this effort: Firstly, filters and dryers had traditionally been operated continuously and in step with grinding and flotation circuits. The demand for labour and equipment operating time was fixed and was not determined by the rate of concentrate production.Secondly, dewatering equipment had usually been designed to handle the concentrate tonnages which were produced when mill feed grades were high; therefore the equipment operated at less than capacity when treating ores of average metal content. The first goal was the separation of the flotation process from concentrate dewatering by development of a practical storage system for concentrate pulps . A second objective was the gradual introduction of dependable automatic controls. The steep increase in energy costs after 1973 added urgency to the search for dewatering processes which were highly energy efficient."

Jan 1, 1984

By I. M. Marshall

SOME years ago the writer had the opportunity to plumb a number of mine-shafts, each of which presented various conditions and difficulties. This afforded the chance to compare several methods of shaft plumbing in the light of ease and rapidity. This comparison led to the development of an adaption of the Weisbach, or approximate alignment, method, to three wires in a single shaft. Professor Weisbach, some time prior to 1850, introduced his method of shaft plumbing by triangulation on but two wires, and was the first to show that a triangle of very narrow shape is the best for this purpose. THE WEISBACH METHOD The two-wire method, using a Weisbach triangle, is described in several .English text-books on mine surveying and is used frequently in various parts of the world, but in Canada it is almost unknown. The writer has described an example of this two-wire method (1), but a brief resumé here may clarify the explanation of its application to three wires. In this two-wire method, instead of endeavouring accurately to align the instrument with the wires, it is set only in approximate alignment, and the small angle formed at the instrument is measured. This is expressed graphically in Figure l, where C represents the position of the instrument and A and B the positions of the wires. The sides of the triangle are measured as well as the angle ACB, and the angles at B and A are found by applying the Sine Rule or the formula

Jan 1, 1938

By Mohammadreza Jalali

Alberta contains over 400 billion barrels of viscous crude oil in fractured carbonates but there is no viable extraction technology as yet. Petroleum geomechanics has become a vital part of the assessment of such hydrocarbon reserves, especially for naturally fractured cases, which are particularly challenging in terms of accurate recovery prediction because of joint fabric complexity and lithological heterogeneity. As a result of interconnected fractures, transport properties of fractures (mostly permeability issues rather than thermal effects) are affected by production and injection activities that change the pore pressures, temperatures, saturations, and effective stresses. Enhanced oil recovery methods involving massive amounts of fluid injection (hot or cold) at high pressure (pinj) may be used to mobilize and produce the oil; therefore, deeper understanding of the fractured systems is desirable. Pressure and temperature variations in a fractured reservoir change the in situ stresses in the reservoir and surrounding rocks; this affects fracture apertures, radically changing the bulk flow properties because flux rate is highly sensitive to aperture. Hence, coupled pressure, temperature and effective stress changes must be considered for fractured reservoirs under a thermo-hydro-mechanical (THM) coupling approach.A hybrid FDM/DDM coupled method is presented to couple pore pressure and stress around a fracture in an impermeable matrix block. Deformation and stresses are calculated in each time step and then fracture permeability, which is the most sensitive petrophysical parameter in fractured reservoirs, is updated based on the fracture aperture variation. This model is then verified with UDEC (Universal Distinct Element Code) which uses a discrete approach to cope with fractured rock mass behavior.

Jun 1, 2012

By A. V. Corlett

MR. C. S. Gibson: Mr. Chairman, I listened with much interest to Mr. Corlett's paper. Those of us who are directly engaged in mine ventilation and dust control are impressed by the improved atmospheric conditions to be derived from the use of methods of mining such as those in operation at Aldermac, which Mr. Corlett has just described, and those employed at Noranda. It is a well known fact that drilling-dust is one of the most potent factors in the production of silicosis in mines handling ores containing quartz, so that from that angle the use of diamond drills, instead of percussion drills, to drill ore for blasts in stopes is an important development. A second point which I think merits mention is blasting. Blasting, we all know, creates the most dust in a mine and the fact that you can drill ore for a large blast with diamond drills and fire it, say, on Saturday night, and then have all the next day to ventilate the workings, is a great advance in dust control. 1 have wondered if Mr. Corlett, or possibly those at Noranda, can en-vision the use of the diamond drill as a means of advancing cross-cuts and drifts, preparing stopes, etc. I believe it is a matter which is receiving considerable attention at the moment in some parts of the world and J thought it would be interesting to have Mr. Corlett's reaction on that point. MR. A. V. CORLETT: I am not quite so hopeful of using diamond drills as a means of drilling holes in the ordinary drift. Maybe some of the diamond drill men can give us some further information on that point. MR. R. D. LoNGYEAR: The diamond drill manufacturers are working on that problem, but until further work is done we have nothing definite to offer. Drilling holes with a diamond drill to compete with rock drills for advancing drifts and cross-cuts is a desirable objective, because of the elimination of drilling dust and the ability to cut a smooth bore of uniform diameter. To reach this objective, higher rates of penetration are required, which can only be achieved by discovering the optimum bit rotating speed, by reducing vibration, and by further improving the bits and machines. We are optimistic, but the problem is still largely in the research stage.

Jan 1, 1940

By Aalbert Zwijnenburg

One of problems connected with the use of gold/titania-based catalyst systems is the low yield in propene oxide (up to 2 wt %). It is shown that the low propene oxide yield is due to product inhibition. New options for propene epoxidation with hydrogen and oxygen are discussed. INTRODUCTION The direct gas-phase synthesis of propene oxide (PO), by the use of molecular oxygen, is still aimed for. Agbased catalysis is in principle possible, but selectivity at present is not promising. Highly dispersed gold on titanium containing catalysts show an extraordinary selectivity in the oxidation of propene to the corresponding epoxide (> 99 %), using a combination of H2 and O2 as oxidation mixture [1]. Additional studies of the epoxidation reaction have indicated several drawbacks of the Au/TiO2 catalyst. Firstly, the low conversion (1- 2 %) obtained under typical reaction conditions (atmospheric pressure, 323 - 423 K) cannot be increased by increasing the reaction temperature, because this leads to extensive by-product formation. Secondly, the low efficiency of hydrogen (relatively large amounts of water are formed) is hard to prevent. Finally, significant deactivation of Au/TiO2 catalysts within several hours on stream has been observed. Deactivation can be almost completely prevented by using dispersed TiO2 supports, such as TiO2/SiO2 and Titanium-Silicalite-1 (TS-1) [2]. In recent literature [2,3] a hydroperoxide-like intermediate has been proposed to be responsible for the selective epoxidation. This oxidising species is said to be formed over gold and subsequently used for epoxidation over the Ti-containing support. The support is responsible for the slow desorption of PO. One of the problems for future industrial application might be the low yield in propene oxide. Furthermore, the presence of minor amounts of by-products, not detected on lab-scale catalyst testing, might complicate the separation unit in an industrial process. The reason for the low PO yield over Au/TiO2-based catalysts will be discussed in this paper. Temperature Programmed Desorption (TPD) and micro-flow experiments have been carried out to study PO desorption and catalyst performance, respectively. A catalytic cycle is proposed together with its consequences for the maximum yield in PO. Finally, several process and catalyst options are discussed in view of potential future industrial application.

Oct 1, 2003

By Scott Hommema

? Bitumen in the oil sand averages Bitumen 12 wt%; water makes up 4 wt% ? Imperial Oil (operator) and ExxonMobil developing Kearl Leases #6, 36, 87 (~200 sq. km) ? Target resource > 4 Billion Barrels ? 3 Phase development, ~100 kbd per phase High-quality resource ? Surface mineable bitumen ? Average properties (full lease) ? TV:BIP < 8 ? Grade > 12 wt% bitumen ? Ore thickness of 40 m ? Overburden thickness of 20 m Status ? Phase 1 ? Front end engineering and design underway ? Detailed engineering to start 2008

May 1, 2008

By Bo-Hyun Kim

Outline ? Strainburst criteria and hypotheses adapted for this study. ? Influence of excavation method on rock mass properties. ? Excavation disturbance factors vs. deformation modulus, etc. ? Estimation of blasting damage zone around excavation. ? Considerations of energy on burst-prone ground. ? Literature review & closed form solution. ? Numerical simulations. ? Summary and future works.

Oct 1, 2010

By Weldon Li

Outline ?Introduction and Motivation ?Previous Research ?Details ?Findings ?Current Multi-Piece Mining Wheel Research ?Methodology ?Preliminary findings ?Current and Future Activities ?Summary and Closing Remarks

Oct 1, 2010

By T. Nomura, N. Saitoh, K. Tamaoki, Y. Konishi

We have developed new recycling technologies, based upon an eco-friendly biotechnology, in order to extract precious and rare metals sourced from end-of-life products and electronics. We have been focusing on the metal ion-reducing bacteria, Shewanella algae and Shewanella oneidensis, that are able to reduce and deposit gold ions (Au(III)) or PGMs ions (Pd(II), Pt(IV) and Rh(III)) into metal nanoparticles at room temperature within 120 min. When processing the aqua regia leachate of printed circuit boards, Shewanella bacteria were able to rapidly and selectively collect gold ions under acidic conditions in the presence of heavy metal ions, proposing a new bio-recovery system for gold. This biotechnological procedure also has the potential to allow the recovery of PGMs from the leachate of automotive catalysts. Shewanella bacteria were also able to successfully perform the complete reduction and deposition of the PGM ions. The ability to collect the PGM ions suggests that this represents a new process for the biorecovery of PGMs from used automotive catalysts. Our proposed biological method enables the rapid and highly efficient recovery of precious and rare metals via separation and concentration utilizing microbial reactions at room temperature.

Jan 1, 2014

By G. J. Desroches, E. Ozberk, M. J. Collins, B. D. Krysa, I. M. Masters

The zinc refinery of Hudson Bay Mining and Smelting Co., Ltd. went through a major modernization in 1993, when the roaster and the calcine and fume leach circuits were replaced by a new Sherritt zinc pressure leach plant. The HBMS plant, in Flin Ron, Manitoba, represents the first commercial application of the Sherritt two-stage zinc pressure leach process, with /00% of the zinc concentrate feed processed in autoclaves. The process design of the new plant required definition of the deportments of elements such as antimony, arsenic, chlorine, cobalt, fluorine, germanium, magnesium, manganese, selenium, tellurium and thallium. This paper describes the deportment of these elements in the commercial zinc plant during the first nine months of pressure leach operation, and compares these results with operations prior to the introduction of pressure leaching, and with the results of tests carried out in the She"itt laboratory during the process development phase.

Jan 1, 1995

By Patrick Laflamme, Jean-François Boulanger

Les minerais de cuivre sulfurés, qui représentent 80% de la production mondiale de cuivre, imposent une étape de concentration des minéraux, premièrement pour atteindre une teneur en cuivre minimale qui permette le traitement pyrométallurgique, mais aussi pour limiter la présence d’élément pénalisants (délétères). Cette introduction offre un survol des principes, limites et pistes d’améliorations touchant la concentration des minéraux de cuivre.

May 2, 2024

By T. S. Wanne

Tunnel sealing experiment (TSX) was conducted between 1997 and 2004 in the Canadian URL located in Manitoba. In the experiment, a tunnel was excavated parallel to the maximum principal stress direction, filled with sand and sealed with bulkheads at both ends. It was then pressurized and heated by injecting hot water. The rock mass response was monitored with seismic methods. The main interest in the numerical simulation was the damage formed during the heating phase. The large-scale PFC2D models replicated a central plane- strain section of the TSX chamber. The models captured the first-order phenomena observed in-situ displaying the difference in the damage in the roof and floor regions, respectively. This difference was due to the filling material confinement of about 100 kPa on the tunnel floor, which occurred in the course of the heated experiment.

May 1, 2009

By P. R. Stephenson

Mining projects depend on the amount and quality of the mineral reserves, which in turn depend on the amount and quality of the mineral resources. Only Measured and Indicated Resources may be converted to mineral reserves and Inferred Resources may not, with certain exceptions, be used in economic studies. Responsibility for the estimation of mineral resources rests with the Qualified Person (QP) and there is a wealth of literature, text books and case studies to guide the QP. Responsibility for the classification of the mineral resources also rests with the QP. While there is some industry guidance and common practice on approaches to resource classification on which the QP can draw, the process is (or should be) heavily dependent on the exercise of judgement by the QP. However, this inevitably leads to situations where, for example, one QP?s Inferred Resource is another QP?s Indicated Resource. If the QP?s judgement is poorly reasoned or illogical (as is sometimes the case), it can have a major impact on the project, often with substantial cost or value implications. Project managers and company executives should not unquestioningly accept QP?s classification decisions and should apply the same intensity of due diligence that they apply to other critical elements of the project.

May 1, 2011

By E. You

Kennecott Utah Copper Refinery and Outokumpu Technology have developed a wireless Electrolytic Cell Monitor (CellSensor) system to monitor cell voltage and temperature. The system is based on a robust self-organizing and self-healing wireless network with a very reliable redundant structure. The microprocessor controlled CellSensor device operates off a small amount of energy harvested from the cell bus and requires no external power source. The radio works in the 2.4 GHz international ISM band using robust Spread Spectrum technology. The CellSensor does not require end user calibration of either the voltage or temperature sensors and accuracy is superior to previous systems. The on-board computation power allows digital filtering of the cell voltage signal which results in very high quality data. The system requires much less maintenance than conventional hardwired systems and is intrinsically safer since no high voltage isolation is required. The advanced diagnostic functions allow the device to determine if the bus tap contact is degrading. The CellSensor can also be used for monitoring electrowinning (EW) cells for a variety of metals. CellSensor have been tested for over two years at the Kennecott Utah Copper and Boliden Harjavalta Pori refineries. The CellSensor system is now commercially available through Outokumpu Technology.

Jan 1, 2007

Presentation Plan Hoist ropes ?Importance ?Mandatory and routine Inspections Continuous monitoring of wire ropes for mine hoisting ?Why a continuous monitoring of mine hoisting ropes.? ?Description of the ??Contiscan?? monitoring system ?Information data gathering Advantages of the ??Contiscan?? monitoring system ?Visual rope inspection on daily basis ?Monthly inspection ?Payload capacity flexibility and potential increase for deep mining operations. ?Periodical inspections by external experts ?Importance of the costs associated with hoisting production shutdowns. Commercialization and availability

Aug 1, 2013

By Louise Laverdure

Outline ?Background ?Issues and considerations ?Why do we need to innovate ?Green Mining Initiative ?Footprint reduction ?Innovation in waste management ?Ecosystem risk management ?Mine closure and rehabilitation ?The Future

May 1, 2011

By Vern Evans

Saskatchewan has historically been recognized for farming, but in 1943 while drilling for oil, potash was discovered. The initial attempt to gain access to the potash beds was unsuccessful, however, subsequent attempts were successful and today there are ten operating potash mines in Saskatchewan. In this paper we will provide a brief overview of the historical and current Potash industry in Saskatchewan.

May 1, 2011

By M. G. Lipsett

General Challenges for Mining & Mineral Processing Operations ? Capital-intensive industry ? Ongoing cost pressures ? Remote locations ? Workforce demographics ? Dynamic, unstructured, rugged environment

May 1, 2008