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By S. Yano, S. Takagi, Y. Nagaya, T. Akai, T. Ishida, Z. Bennour, T. Suzuki

"It is often reported that the concept of single-plane-fracture is not sufficient to account for the productivity from shale gas/oil wells. Many researchers introduce the concept of the stimulated reservoir volume to describe observed production behaviour. However, the characteristics of the stimulated reservoir volume are not well understood. In this study, to investigate the characteristics of fractures and surrounding region induced by the hydraulic fracturing, a devised hydraulic fracturing experiment was conducted using the cylindrical shale specimens in the laboratory.Two resins were prepared as the fracturing fluid for the experiments: cyanoacrylate, an instant glue, mixed with a fluorescent paint (resin A), and methyl metaacrylate, a thermosetting acrylic resin, mixed with a fluorescent paint (resin B). These resins were able to fix within the specimen after fracturing. This is because the present study aimed to only detect fractures induced by hydraulic fracturing. Cut sections of the specimens were observed under ultraviolet light irradiation. It is expected that the hydraulically induced fractures and the surrounding regions will be detected because the induced fractures filled with the resin should emit light, while the other parts will not.The specimens, which were collected from the Kushiro Coal Mine in Hokkaido, Japan at the depth around 275 m, were roughly 85 mm in diameter, 170 mm in length, and cored normal to the sedimentary planes. An injection hole with a 10-mm diameter was drilled onto the center of the specimen parallel to the sedimentary plane to simulate hydraulic fracturing in shale gas development. The experiment was conducted under a uniaxial loading condition of 3 MPa and the fracturing fluid was injected into the sealed injection hole at a constant flow rate using a syringe pump.After the fracturing experiment, the resins were fixed in the specimens and then the cut sections were observed under ultraviolet light irradiation. As a result, the hydraulically induced fractures, which were filled with the resin, are clearly observed. Detailed microscopic observations show that the main fractures are tortuous and are accompanied by many thinner ramified fractures. Additionally, fractured regions where the resin penetrates significantly are observed around the main fractures in the specimens fractured by the resin B. These induced fractures and fractured regions are considered to be the stimulated region in which permeability is improved. The necessity of estimation on the features of fracture tortuosity and ramified fractures is indicated for more accurate understanding of the well production and the stimulated reservoir volume."

Jan 1, 2015

By T. Gonzales, M. Maleki, M. Caçador, B. Climenhaga, H. Ghorbani

The campaign life of furnaces in the copper making industry is greatly affected by damage caused by normal operation cycling and abnormal conditions. Proper monitoring and assessment of the existing conditions and safe remaining life of the vessels and their refractory lining is key to prevent an unplanned early replacement. This paper presents an industry-proven refractory management program as well as a typical fitness-for-service assessment of a rotary vessel shell in order to extend the campaign life of copper making furnaces and enhance safety. The furnace refractory management system involves a comprehensive audit and monitoring program which has been successfully applied to several copper flash smelting furnaces over the past 15 years. The fitness for service assessment provides a methodology to estimate the remaining life of the steel components by evaluating the existing damage and future damage rate based on the historical survey data. The above practices can provide the operator with cost savings by extending the vessel campaign life in lieu of implementing more rigorous refractory lining and shell audits. INTRODUCTION Primary copper smelting is generally divided into two categories of flash smelting and open bath smelting. There are many different types of vessels that can be used to convert the copper concentrate to blister copper including, flash, Mitsubishi process, TSL (ISA/Ausmelt), SKS Bottom Blowing, Anode and Teniente/Noranda furnaces, reactors, and Peirce Smith converters. Each vessel has its own complex and intense environment which requires careful refractory and steel design to withstand the severe thermomechanical and thermochemical attacks within its campaign life. The campaign life of furnaces is greatly affected by damage caused by normal operation cycling and abnormal conditions. Proper assessment of the existing conditions and safe remaining life of the vessels and/or refractory lining is key to prevent an unplanned early replacement. This paper presents an industry-proven refractory management program as well as a fitness-for- service assessment methodology to estimate the remaining campaign life of copper making furnaces resulting in cost savings and enhanced safety of the operating vessels.

Jan 1, 2019

By Naizhong Xu

During the past 30 years, fully mechanized caving mining has played a positive role in the improvement of the efficiency of coal production, but which has also had a great influence on the mining environment, especially to environment damage of shallow mining areas in the central and western regions of China. The surface subsidence parameters are the basis of the surface environment evaluation and governance. During 1980~1990s of the last century in China, fully mechanized mining subsidence laws were researched more fully, however, since coal caving technology is affected by many factors, and researches on its mining subsidence laws (parameters) were found to be grossly inadequate. Through actually observed in recent years, it is considered that coal caving mining subsidence laws (parameters) can use fully mechanized mining law (parameters) for reference. Based on fully mechanized mining laws (parameters), this paper reveals the similarities and differences of the surface subsidence laws between fully mechanized caving mining and fully mechanized coal mining, which can guide the work of coal mining under buildings, water bodies and railways in new mine area and mine collapse governance.

Aug 1, 2013

By W. Almdal

"To compete in the ever expanding global market, companies must continuously improve. Benchmarking, a tool that can help determine where the best areas for improvement are, is more than comparing measures, it is comparing how business is carried out and how decisions are made. The key to success is in integrating benchmarking results into the organization, so that those most affected by the results own them and are empowered to use them as a positive change agent. This is a necessary step to achieving substantive change to practices and achieving optimum performance improvement. IntroductionBenchmarking is a powerful tool that can assist in the continuous goal of improvement. Benchmarking is more than comparing productivity rates or unit costs, it is seeking out best practices and assimilating them into a business to provide a positive change agent.Benchmarking is a continuous process - is time consuming, labour intensive, and requires a lot of discipline. There are no easy answers and no easy solutions, just a lot of work. The results, however, are nothing short of spectacular. More and more companies are adopting benchmarking practices because it is a key tool of the learning organization and will become part of the way business is done, part of the way it is managed. Business must change to stay ahead or to get ahead and benchmarking can accelerate the process of business change. Improvements in an organization can happen faster and more effectively with a benchmarking approach."

Jan 1, 1994

By A. S. MacNeil

In the operation of any colliery, a factor of prime importance is power, of which there are three sources available--man, horse, and mechanical. It is obvious that man-power is by far the most expensive, .and that animal-power, also, is more costly than mechanical. In recognition of this fact, mine owners must, for economical ?reasons, reduce the use of man-and horse-power to the minimum by the increased use of machinery. In other words, they must aim at as complete mechanization as conditions will permit, taking advantage of existing physical factors that are favourable and making the necessary adjustments and modifications to meet the less favourable conditions. Intensive coal-mining, or the concentrated production of coal, has two distinct objectives: First, the maximum production from a limited area, in a given time, thereby reducing the pit-room to be maintained; and second, reduction in cost. To this end the coal should be mined, loaded and delivered to the surface by mechanical means wherever possible. To do this, however, requires the solution of many problems arising out of the varying conditions that obtain underground. The system of longwall mining lends itself to a more efficient scheme of mechanization than does pillar-and-room, as, in the former, the first step has already been taken by the removal of all the coal in one operation, and the opening-out of one face, the equivalent in mining area of fifteen or more rooms. Much has been clone of late towards mechanization in the longwall mines of the Sydney coal-field, and with gratifying results, but not without great difficulties and frequent disappointments. In 1923, an attempt was made with shaker conveyors. The introduction of conveying was a step to bridge the gap between the face, where the coal is produced, and the main transportation arteries leading to the slope or shaft. The receiving of the coal at the faces and its delivery to main loading points on main haulage-ways was the part allotted to the conveyors.

Jan 1, 1932

By D. W. Euler, B. J. Clauzier

"Implementation of an effective energy management system will reduce energy costs without impacting negatively on production.The energy management system must be designed to complement the operation and be integrated with the organization. It must be reliable and easy to use but most important, it must have an accurate and timely feedback reporting system to allow the operation to take appropriate action.Falconbridge Limited was one of the first three companies to be awarded the energy monitoring demonstration program in May 1987. The program is sponsored jointly by the Ontario Ministry of Energy and Ontario Hydro.This paper describes the approach taken by Falconbridge Limited to implement the Onaping Area Energy Management System.IntroductionThe objective of the project was to implement an effective energy management system, capable of reducing energy costs without impacting negatively on production.Energy management systems must be designed to complement the operation and to be integrated with the organization. The system must be reliable and easy to use, but most importantly, it must have an accurate and timely feedback reporting system to allow the operation to take appropriate action."

Jan 1, 1990

By Michael J. Sapko, Ellsworth R. Spencer, Frank J. Perzak

"The fire resistance of several mine conveyor belts is evaluated using a new belt-flammability apparatus developed by the U.S. Bureau of Mines. The test apparatus, experimental details and a calculated flammability index (FI) are described.The FI values are useful for ranking the fir e resistance of mine conveyor belts. Values are determined using parameters readily measured with thermocouples, high-temperature flow probes and a methane-oxygen torch, all of which are components of the Bureau's new test apparatus. The FI varies directly with the flame-spread rate and the rate of heat release during burning and varies inversely with the critical (minimum) ignitor energy output.The fire-resistance ranking of nine different belt types using this moderately scaled apparatus is compared with available full-scale data on belt fires. This comparison shows that the ranking based on the FI is consistent with the full-scale data.IntroductionFull-scale fire hazard evaluations of mine conveyor belts are not easily related to the properties usually measured in small-scale flammability tests. The inadequacy of small-scale belt fire tests has been demonstrated in works by Mitchell, Warner and Reinke.Mitchell and Warner showed that certain neoprene (NP) and polyvinyl chloride (PVC) belts, which had been approved by the Code of Federal Regulations 30 CFR 18.65, were nevertheless capable of propagating flame over their entire length when full-scale fire conditions were simulated. Comparable results were also observed by Reinke at the Tremonia experimental mine in Dortmund, West Germany, where all belts burned in full-scale tests even though they passed the small-scale tests. Only by reducing the severity of the full-scale test could these fire-resistant belts be grouped on a pass-fail basis."

Jan 1, 1982

Shafts are the most important workings in the underground mines. Their technical state to a large extent determines the safety and efficiency of mining operations. However, in many cases periodically performed inspections show unsatisfactory technical state of the shaft lining (local defects, cracks, cavities, losses of the outer surface of the lining or, in case of the bricks, losses of the masonry). The most common cause of these types of damage is progressive deterioration of the lining material, impact of aggressive mine waters, impact of mining operations, deformation of the lining due to the rock mass saturation, seismic activity or periodic freezing of the lining in the upper part of a shaft. The paper presents legal requirements associated with the use of mine shafts in Polish coal mines as well as the ways and range of their control. Furthermore, examples of typical damage to shaft lining and ways to repair it, such as additional bolting, filling cavities or a wire mesh and shotcrete installation, are shown. In the final part, the paper presents a short example of a shaft, in which damage to the lining was one of the main causes of the shaft's failure. Due to the damage to the shaft lining, at the depth of approx. 65.0 m, the shaft was spontaneously filled with overburdened soil material. It resulted in a large crater to come to the surface, which, in turn, caused damage to the buildings and facilities present in the impact zone. On the surface the diameter of the crater was approx. 60.0 m, its depth approx. 11 m and the estimated volume was of about 30,000 m³. The disaster also caused disturbance in the ventilation of two neighbouring mines and the increase in methane hazard. Given the size of the crater, the measures to eliminate consequences of the catastrophe were undertaken in several stages.

Aug 1, 2013

By Q. J. Xu

In blasting sensitive areas, the use of traditional blasting for rock fracture is restricted. Soundless cracking technology has been presented to achieve rock fracture instead of blasting. However, when the diameter of a borehole is larger than 50 mm, it is very dangerous that the soundless cracking agent (SCA) will have a tendency to gush from the borehole, which also leads to cracking failure. In this paper, a new large scale borehole soundless cracking technology is presented, using a new enlarged drill bit and mechanical plugging, which could solve the hole gush problem. Experiments were made to measure the expansive pressure of the SCA working in boreholes of F40 mm and F100 mm. The difference between two sizes of cracking phenomenon was compared and analyzed to show that large scale borehole soundless cracking has larger expansion pressure and faster reaction speed than traditional soundless cracking. Based on the experimental data, finite element analysis was utilized to study the stress concentration and stress distribution between two neighboring large boreholes in several media during the cracking process. Using the data from experiments with finite element numerical simulation, the brittle material fracture condition was analyzed to design the parameters of the borehole mesh. With the theoretical analysis, the technological process and reference parameters of large scale borehole soundless cracking were proposed, including the borehole spacing, burden distance, depth of the borehole and so on. Then a single rock was cracked with the new enlarged drill bit and new plugging, and the results proved the feasibility of the new large scale borehole soundless cracking technology, which achieved the expected goal of improving the cracking ability and reducing the cracking time. This paper presents a new efficient rock cracking method for blasting sensitive areas, and which could apply to mining engineering, demolition engineering, excavation engineering and other engineering applications where there is a demand soundless and non-vibration fracturing of rock.

Aug 1, 2013

By Ken Musgrave

"What Most Effective Management Does?It must satisfy the demands, of three groups of people: owners, employees and the public.OwnersOwners want profitable operations that will pay them a return on their investment, plus operations managed for long life. Many owners are also concerned with employee's well being and their company's public image.EmployeesJob security and a good income are probably still the most important demands, however, as time goes by, employees are also demanding more involvement in safety issues, working conditions, and even how work is done.The PublicThe public requires acceptable environmental standards, as well as enjoying the prosperity supplied by a successful operation.How are Mines Managed?Most mines are managed very traditionally. The basic credo is that the managers make the decisions, and the hourly, and junior salaried employees do what they are told. Clearly this is the extreme case, epitomized by the long service shift boss who might say ""It took twenty-years to become a shift boss, and no miner is going to tell me what to do"" .There are some exceptions, two notable ones being Campbell-Chibougamau, and T.G.S. (now Kidd Creek Mines) which, in very different circumstances, decided on a more participative style.Campbell-Chibougamau, having closed down due to unprofitable operations, reopened, using a team structure with working leaders, and a system for sharing gains against cost targets with employees. Although the system has some problems, and development miners are bonused conventionally, this has been a basically successful program.Texasgulf Sulphur, a company with a history of non-union operations, and a participative management style, made a corporate decision to operate their Kidd Creek Mine in the same way. The orebody was rich enough to allow them the luxury to do this, but they have never had a strike, so perhaps they have more than saved the cost of the benefits and salaries they needed to pay. They also reward employees with a stock distribution scheme based on service and earnings."

Jan 1, 1985

"The gravimetric dust sampler is one of the tools now available to the industrial hygienists for determining the worker 's exposure to the numerous types of particulate matter that may be present in the workplace. The paper ' reviews the different sampling trains that can be used for the two major criteria for respirable dust and some of the sources of error in this dust assessment technique.IntroductionIt may be stated simply that the measurement of airborne dust in the working environment is done for one or two reasons: namely, for engineering control purposes and! or to evaluate the potential for toxicological insult arising from the inhalation of dust particles.This paper reviews the progress made in the development of dust-assessing instruments, particularly the gravimetric types designed to meet British and U.S. dust criteria , and discusses the limitations in their use for this purpose."

Jan 1, 1981

By Hammenm R., J. Hammen, C. Hammen

"The production of salable Rare Earth Element (REE) products necessitates a sequence of chemical separation steps between the mine and market commodities. The effectiveness of the chemical separations that purify REE salts is critical to the success of the producer, as the purity of REE salt products affects their market price. This is due to the fact that impurities in REE salts, even at low levels, can be deleterious to the function and usability of the end product. The purification of REE by removal of low levels of contaminant has been referred to as "product polishing". The technologies commonly in use for product polishing, solvent extraction (SX) and ion exchange (IEX) are challenged by the availability of separation chemistries to separate the contaminant from the desired REE salt. In simple terms, if a product specification is 99.9% purity, the SX or IEX separation reagents need to have at least a 999:1 selectivity ratio. Significant testing has been carried out on the use of solid phase extraction (SPE) columns to extract low-level impurities such as aluminum or zinc from REE product streams. The SPE columns are nano-composite materials that have rapid equilibration kinetics with the solutes being processed by the columns. The SPE matrices have been modified with chelating ion exchange ligands that bind the contaminating ion with great selectivity in residence times of a few seconds. Thus, REE streams with 1 to 2% of contaminating aluminum ions, have been polished to >99.99% purity. In this paper, results are presented on the removal of aluminum impurity from a didymium (neodymium+praseodymium) product stream using SPE technology. The selection of the SPE medium and the process steps to treat the feed solution for aluminum removal and ultimate stripping and recycle of the solid phase extractant are discussed."

Jan 1, 2014

By Samantha A. Beeson, Colin Poole

"A selective flocculation-floe flotation technique is already in use in the Canadian potash industry for the removal of water-insoluble slimes, but the process is currently limited in its application and reagent consumption is high. The work described in this paper details investigations into the separation of sylvite and halite from water-insoluble slimes by selective flocculation utilising other commercially available polymers.Preliminary flocculation performance tests were undertaken on pure sylvite, halite and water-insoluble minerals to establish the importance of a number of experimental parameters. The data from these single mineral tests was then used to establish optimum parameters for the separation of sylvite and halite from a synthetic mixture similar in composition to a typical potash ore. Under optimum conditions, separation was achieved with high recoveries using dispersant and flocculant dosages significantly lower than those currently used in plant practice.IntroductionAlthough solar evaporation and solution mining are used in some operations, most potash is extracted by conventional underground techniques and is then processed by froth flotation, in order to separate the valuable sylvite (KCI) from halite (NaCl) and water-insoluble gangue minerals. Flotation is usually preceded by a desliming stage to remove water-insoluble fines, but this also results in high potash losses and affects process brine requirements. To overcome these problems, one plant operated by Cominco in Saskatchewan uses a selective flocculation -floe flotation process (Banks, 1979/1980), in which a polyacrylamide flocculant is added to produce floes of water-insoluble material with minimal incorporation of halides. A collector is then added to render the floes hydrophobic and suitable for removal by froth flotation.A number of workers have also investigated the use of selective flocculation in potash processing, but these too have been concerned with developments in the removal of water-insoluble slimes (Williams, 1960; Brogiotti et al, 1974; Chan et al, 1986; Thompson et al, 1979; etc.). This paper provides results of novel investigations into the selective flocculation of sylvite and halite from water-insoluble minerals and discusses the possible mechanisms involved."

Jan 1, 1995

By Robert B. Parsons

"The Canadian Exploration Incentive Program (CEIP), which was announced by the federal government on May 3, 1988, promises to maintain the viability of flow-through shares as a financing mechanism which has proven to be so crucial to the health of the junior exploration sector. This month, Tax Notes examines, the main features of CEIP, which will come into play on January J, 1989. IntroductionOn May 3,1988, the Honourable Marcel Masse, Minister of Energy Mines & Resources, and the Honourable Gerald Merrithew, Minister of State (Forestry and Mines) announced the Canadian Exploration Incentive Program (CEIP). Under CEIP, the federal government will make cash payments to eligible applicants equal to 30% of eligible exploration expenses. CEIP payments will be available with respect to both mineral, and oil and gas, exploration. In essence, the program will replace the ""mining exploration depletion allowance"" (MEDA) presently applicable to mineral exploration, and the Canadian Exploration and Development Incentive Program (CEDIP) which is presently available to the oil and gas exploration sector.This paper discusses briefly the main features of CEIP insofar as the program will affect mineral exploration. The comments herein are based on the Canadian Exploration Incentive Program Act which received Royal Assent on July 21, 1988, and on a discussion paper which was released by EM&R in May 1988. The bulk of the rules relating to the program will be in the form of regulations which have yet to be finalized. It is understood that EM&R would like to have the regulations in force by October I, 1988, when the oil and gas portion of CEIP becomes effective. (The rules relating to mineral exploration will become effective January I, 1989)."

Jan 1, 1988

By S. Pietruszczak, G. Su, T. S. Nguyen, E. Haghighat

"In this paper, the mechanical properties of Tournemire argillite are modeled using a mathematical framework which employs the microstructure tensor approach (Pietruszczak & Mroz, 2000). The experimental data incorporates the results of a series of triaxial tests (Abdi & Evgin, 2013) conducted at different orientation of bedding planes relative to the direction of loading. First, a plasticity framework is presented which involves the specification of the conditions at failure as well as the description of the irreversible deformation process. Later, a systematic procedure is outlined for identification of material functions/parameters involved. The paper is concluded by presenting the results of numerical simulations of the triaxial tests. It is demonstrated that the model can adequately reproduce the primary effects of anisotropy in the stable deformation regime as well as the onset of fracture.INTRODUCTIONThe understanding of the mechanical behaviour of argillaceous rocks is important in many types of geotechnical projects, including petroleum extraction, carbon dioxide sequestration as well as deep geological disposal of radioactive waste. In all these cases, the primary concern is the onset and propagation of damage due to excavation, transport of pore fluids and/or elevated temperature. The Canadian Nuclear Safety Commission (CNSC), Canada’s nuclear regulator, will be responsible for the licensing of future deep geological repositories. In order to evaluate the safety of deep geological repositories, CNSC staff keep abreast of scientific developments by collaborating with national and international partners on experimental and theoretical research on the long-term performance of those engineered and natural barriers. Through that collaboration, the CNSC has access to data resulting from experiments performed at different Underground Research Laboratories (URL). Such an URL is situated in Tournemire, France, in an argillaceous rock formation, the Tournemire argillite. The Tournemire argillite is characterized by the presence of closely spaced bedding planes and exhibits a strong anisotropic behaviour, so that its strength as well as deformation properties are directionally dependent."

Jan 1, 2015

By N. Razavinia

Most mining and metallurgical industries produce relatively large quantities of low grade waste heat which they vent, for the most part, to the environment. To date, little is being done to recover some of this heat and transform it from low grade to a high grade energy form such as electricity. A few decades back this was also true of paper, plastics and metals. Recycling was not a prominent activity. Today, we all know that it is and that recycling is a must for sustainable development. To this end, we feel that we are now at that point in time when the recycling of waste heat to electricity must be given serious consideration. By recycling waste heat one can achieve at least one if not two of the following benefits: 1) reduction in the carbon footprint ? by improving the overall energy efficiency of a process, and 2) production of electricity at an economically viable cost. We have developed a process that captures, concentrates and converts (3 C?s) waste heat to electricity. The process comprises 3 distinct interacting units. The first unit captures and concentrates waste heat using heat pipe technology. The second unit converts some of the concentrated heat to mechanical work which can then be readily converted to electricity. This unit is based on the classical piston/cylinder engine arrangement that is widely used by consumers to power systems with compressed air, for example. The third unit of the process dissipates the heat that the engine cannot convert to high grade energy. It also uses heat pipe technology to achieve this. The combination of the 3 units forms a unique system for recycling waste heat. This paper describes the system and it presents some results that show how the system can be made to be economically viable.

Aug 1, 2013

By Rodrigo Serna, Nora Schreithofer, Zoltan Javor, Kari Heiskanen

"Mineral floatability is a function of mineral properties such as size, liberation, shape, surface composition, reagent coverage on the surface, level of oxidation on the surface, etc.; pulp chemistry: Eh, pH, temperature, DO, reagent type, etc. and hydrodynamic conditions: turbulence, gas dispersion, D32, etc. The biggest challenge with predicting the floatability of an ore is finding a measurement method that would take into account the effect of all of the variables on the floatability of the minerals. The particle-bubble attachment time measurement is considered as an alternative way to predict the floatability of minerals instead of using expensive and time consuming flotation tests because it takes into considerations both surface chemistry and hydrodynamic parameters present in the froth flotation. The existing particle-bubble attachment time method is suitable for studying some significant flotation variables such as pH, temperature, particle size, reagent type and concentration. Nevertheless, measuring the attachment time as a function of collector coverage or surface oxidation is much more challenging. This paper introduces a new induction timer designed to measure the effect of galvanic interaction on the attachment time of particles. The new setup employs an array of needles to create 6 bubbles with the average size of 2.1 mm. Imaging system is used to set the initial distance between the particle bed and the array of bubbles. The attached particles are collected and sent for further analysis. One of the main benefits of the new experimental setup is that the attached particles can be physically separated from the unattached particles therefore many of the particle properties can be analysed and evaluated.INTRODUCTIONSchumann (1942), and Tomlinson and Fleming (1963) proposed that the flotation rate constant is dependent on four probabilities: particle-bubble collision (PC), particle-bubble attachment (PA), particlebubble aggregate stability in turbulent environment (PE), and particle-bubble aggregate stability in froth phase (PF). Any change in any of these probabilities will affect the overall flotation rate constant. All of the above-introduced probabilities are influenced by stream- variables and mechanical variables but their extent of influence vary. The stream variables are particle properties that have been shown to affect flotation rate constant such as size, shape, liberation, mineralogical composition, reagent surface coverage, surface oxidation, etc. The mechanical variables are the direct and indirect properties of the flotation unit affecting flotation rate constant such as cell and impeller geometry, air rate, impeller speed, air holdup, bubble size, residence time, hydrodynamics, froth depth, etc. For instance, the probability of collision is affected by many mechanical variables (bubble size, hydrodynamics, bubbles holdup etc.) but only one stream variable (particle size) has a major effect on it. On the other hand the probability of attachment is affected by much more stream variables: particle size, shape, liberation, surface composition, particle surface oxidation and collector coverage, Eh, pH, etc."

Jan 1, 2016

By L. Li

Iron removal is a common procedure in hydrometallurgy of non-ferrous metallic ores. Chemical precipitation and solvent extraction are currently the main methods employed for separation of iron from copper leach solution. However, chemical precipitation methods have the problem of producing large amounts of iron precipitates, and/or requiring high temperature and high pressure conditions for precipitation. The precipitates are difficult to separate from the solution. Emulsification is a general problem for solvent extraction, which causes loss of extractants and contamination of the electrolyte. A common problem for solvent extraction and chelating ion exchange processes is the difficult iron stripping process. Therefore, finding an efficient and environmentally friendly method for iron removal is of great significance. In this paper, new processes of using ion exchange resins to remove iron from copper leach solution have been investigated. Salicylic acid, amino carboxylic acid, amino phosphonic acid and hydroxy-oxime resins were employed to adsorb iron from a simulated copper leach solution containing 40 g/L of Cu2+ and 36 g/L of Fe3+. It was found that a hydroxy-oxime resin, named Z-Fe, has excellent adsorption selectivity on Fe3+. Desorption behavior of the resin was studied by two step elution using dilute H2SO4 and oxalic acid solution, respectively. After optimizing the adsorption-elution processes, the extent of removal of iron from the simulated copper leach solution using resin Z-Fe was 90%, while copper recovery could reach 100% in closed circuit processing.

Jan 1, 2016

By F. Habashi

"Extractive metallurgy was divided into the three sectors pyro-, hydro-, and electrometallurgy in 1959 when Professor Joseph Newton at the Idaho School of Mines in Moscow mentioned this in his book Extractive Metallurgy. Pioneer hydrometallurgists who built this discipline can be traced to the alchemists in the ninth century. It is now a mature subject of great importance in which pressure plays a vital role. Short biographies of some hydrometallurgists and the processes they invented are briefly outlined.INTRODUCTIONHydrometallurgy is the use of aqueous solutions to recover metals from ores. It is a relatively new discipline when compared with pyrometallurgy the use of fire to melt ores and recover metals which was practiced in ancient times. Hydrometallurgy can be traced to the time of alchemists whose concern was the transmutation of base metals into gold. Although alchemists did not succeed in their venture yet they described many reagents that are useful today. For example, they prepared sulfuric acid by distillation of iron vitriol, muriatic acid by distillation of sulfuric acid with salt, and nitric acid by reaction of sulfuric acid by reaction of sulfuric acid with salpeter. Jabir Ibn Hayyan the Muslim alchemist who lived in the ninth century (Figure 1) described aqua regia a mixture of nitric and hydrochloric acid that can dissolve gold although either acid has no action on gold. THE MIDDLE AGESIn the Middle Ages, it was reported that copper was recovered at Rio Tinto in Spain by allowing copper-containing pyrite to be exposed in piles to the action of air and rain. Copper sulfate solution obtained was treated with pieces of iron to precipitate metallic copper—a process that was called cementation. Georgius Agricola (1494–1555) (Figure 2) a medical doctor in Saxony who used to visit mines and smelters to examine miners and metal workers, described in his book De Re Metallica the parting of gold, i.e., separating of silver from gold by acids."

Jan 1, 2016

By F. Andrieux

"Extruded aluminum profiles are increasingly used for lightweight vehicle construction. Since fracture strains of aluminum profiles are relatively low, damage modeling is crucial for reliable crash simulation. For aluminum profiles, not only the stress state but also the orientation influenced both the deformation and damage behavior. For the material characterization smooth tensile tests were performed in six orientations, both stress-strain curves and r-values were registered. Moreover notched tensile and shear-tension tests were performed in three directions. Finally punch specimens were tested to investigate biaxial loading. Digital image correlation (DIC) analyses were performed to determine local strain values such as critical values at failure. Numerical investigations were conducted with the strain based damage model GISSMO, which is well suited and widely applied for crash simulation. For a strain based failure model the choice of the deformation model is crucial. Deformation models with increasing complexity were investigated to find the best compromise over all experiments. It was found that there is still a great requirement on development of a material model which describes the orientation dependence of the hardening behavior over all stress states in order to be able to use a strain based failure model reliably.INTRODUCTION Weight reduction is an important step for less energy consumption and as a consequence aluminium is increasingly used in automotive parts. An important field of application is the well-established aluminium extrusion which allows the realisation of quite complex shapes of profiles required for an innovative lightweight design with integrated functions. Typical applications are chassis parts, bumpers, crash elements, air bags, etc. Especially the Al–Mg–Si medium strength alloys of the 6000 series can be easily extruded to form complex profiles and prevail for extrusion. Since fracture strains of aluminum profiles are relatively low, damage modeling is crucial for reliable crash simulation. For aluminum profiles not only the influence of the stress state but also the orientation with respect to the extrusion direction have an influence on both the deformation and damage behavior and need to be characterized. The effect of orientation on deformation behavior has been intensively investigated in the last decades and material models haves been proposed (e.g. Barlat & Lian, 1989; Barlat, Lege, & Brem, 1991; Barlat et al., 2003) to describe accurately anisotropic behavior. However it can be noticed that the parameters of anisotropic material models often rely on the yield stress in different directions, which means that the effect of strain hardening is not automatically accounted for. The accuracy of the models at large deformation is not guaranteed and has to be verified. In contrast to deformation models both the characterisation and the modeling of anisotropic damage behavior are not systematically studied. Isotropic failure models based on a critical strain as function of stress triaxiality (ratio of the hydrostatic stress to von Mises equivalent stress) are widely used for crash application (e.g., Bai & Wierzbicki, 2010; Sun, Andrieux & Feucht, 2009; Sun et al., 2013). The mechanisms of failure are manifold and not fully understood; to develop an anisotropic failure model it is mandatory to also have experimental data in different orientations for loading scenarios other than uniaxial tension, e. g. shear, biaxial tension, which implies an extensive experiment plan. This makes the development of failure models more challenging than deformation models for which it is possible to develop a reasonable anisotropic model using the framework of yield function and calibrate the material parameters based on results of tensile tests in different directions. Moreover the development of deformation and failure models are intricate as the variables governing the damage evolution are predicted by the def"

Jan 1, 2018