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By R. Kumar, A. K. Verma

"In this paper, an anisotropic shear behavior of rock joints is investigated under constant normal load condition (CNL). The natural rock joint roughness is transferred to artificial rock samples using room temperature vulcanizing (RTV) silicon rubber. Artificial cylindrical rock joint samples (90 mm diameter and 50 mm height) are made by mixture of cement, sand, and water in the ratio of 1:1.5:0.45 (by weight). Direct shear tests are conducted on these samples in twelve directions at 30º apart at four different normal stresses (250kPa, 500kPa, 1000kPa, and 1500kPa). Thus, 48 samples are tested in laboratory. Test results shows that the peak shear strength (?) of rock joints is anisotropic in nature due to change in morphological features in particular shearing direction. Joint roughness coefficient (JRC) is determined in each shearing direction by trial and error method using Barton’s model (1973). Further, cohesion ( c) and angle of friction ( ? )of joint surface in each direction is determined. Finally, a relationship between angle of friction ( ? ) and joint roughness coefficient (JRC) is developed. Experimental shear strength and Barton’s shear strength is compared and it is found that effect of anisotropic decreases with increasing normal stress. INTRODUCTIONRock mass is generally composed of discontinuity which refers collectively to joints, faults, bedding plane and folds etc. ISRM (1978) defined joint as a line of break of geological origin along which there is no visible displacement. Joint is three dimensional discontinuity which composed of two matched/mismatched surfaces. The presence of joints in rock mass plays an important role to define its overall shear strength, deformability behavior, in-situ stresses and hydro-geological properties. The shear strength of rock joints is important in the design of near surface/ deep geotechnical works (mining excavation, dam foundation, power plants, underground caverns, and slopes).In last 40 years, many constitutive models are developed to predict shear strength of rock joints under CNL conditions (Patton 1966; Landanyi and Archambault 1969; Barton 1973; Goodman 1976; Barton and Choubey 1977; Plesha 1987; Desai ad Fishman 1991; Amadei and Saeb 1992; Maksimovic 1992; Wibowo et al. 1993; Huang et al. 1993; Amadei et al. 1998; Indraratna 2000; Homand et al. 2001; Wang et. al. 2003; Samadhiya et. al. 2008; Asadollahi and Tonon 2010; Ghazvinian et al. 2012). These constitutive models have limitations to predict shear strength of rock joints in one direction. Till date, among all constitutive models, Barton (1973) model is widely used in practice due its simplicity. It includes parameters such as joint roughness and joint compressive strength (JCS) to quantify joint surfaces."

Jan 1, 2015

By L. E. C. Pignatari

Mine reconciliation is seen, for many, as a test of the quality of model estimates, while in fact it should be seen as a powerful tool for detecting and correcting problems in each step of mining operations, from resource estimation to metal production. Adequate reconciliation practices allow a more efficient control of the mining processes; however, its results can be illusory unless all parties involved have been in compliance with the principles of sampling correctness. This paper presents a new, segmented reconciliation matrix, which is based on the Theory of Sampling (TOS), developed to monitor gold operations and reserve estimation.

Jan 1, 2011

By S. Steinlechner, S. Wegscheider

"In the past, the metallurgical industry was most of the time dedicated on their main commodity, recovering base metals like zinc, copper or lead but leaving other valuable side elements in the generated residues. As a result, these accompanying minor elements, like gold, silver, indium or also PGMs can be found in the dumps of the corresponding industry. Because of political unrest, strikes, economic reasons or decreasing primary resources leading to a high supply risk, also those mentioned minor elements moved into the focus of the recycling industry. Therefore, beside the base metals, first of all the recovery of those minor metals would be of high interest contributing to the economic viability of recycling processes, although they occur in much smaller quantities in materials. In this context, residues from zinc industry, like leaching residues or precipitation residues show high potential to carry silver as well as indium next to lead and zinc. Therefore, the paper summarizes carried out thermochemical calculations investigating a possible recovery of silver as well as indium by volatilization and the influence of zinc and lead on this process. Based on these theoretical investigations with HSC, trials in lab scale were done verifying the obtained results.INTRODUCTIONHuge amounts of iron precipitate, mainly jarosite get landfilled every year although there is a high content of valuable metals in this residue beside iron. Nevertheless, jarosite has to be dumped due to the presence of contaminating heavy metals. The accumulation of these residues takes up massive land on the one hand but also causes a series of environmental problems in ecosystems on the other. Moreover, some toxic ingredients such as arsenic and cadmium can be dissolved in rain water and are therefore harmful to the health of the aquatic systems. (Erdem & Özverdi, 2011; ÖzverdI & Erdem, 2010) Approximately 0.5 t of dry jarosite accumulate in the production of 1 t of zinc by the hydrometallurgical zinc-winning route (Svens, 2010). Jarosite is a precipitation residue formed during the iron removal. In general, the iron already exists in the zinc ore which is why zinc ferrite builds up during the roasting step of the zinc ore. Zinc ferrite is only soluble in strongly acidic solutions and during the hot acid leaching step it gets dissolved while zinc and iron enter the solution. It is necessary to get rid of the iron because otherwise it would deposit on the cathode first due to its precious character which would be harmful in the zinc-winning electrolysis. Nevertheless successful investigations were done by adding chlorine to the jarosite to recover silver. These findings leads to another residue which occurs in huge amounts – electric arc furnace dust (abbreviated with EAFD) from the iron and steel industry. In 2013 the annual electric steel production reached about 451 million tons. Around 15-20 kg of EAFD is produced per ton of steel in an electric arc furnace (EAF), creating approximately up to 9 million tons of dust per year. (Grabda, Oleszek, Shibata, & Nakamura, 2014; World Steel Association) Next to elements like zinc, lead and iron, chlorine and fluorine are present in this dust. While galvanized steel plates in the scrap act as a source for zinc, casting powders, flame retardants and synthetic coatings are responsible for the chlorine and fluorine contents in the dust."

Jan 1, 2016

By W. L. Ott, C. L. Lewis

"AbstractA technique is described for preparation of palladium sponge and for spectrochemical analysis of the metal in this form. The precision and accuracy of the method are discussed. Analyses are compared with previous spectrochemical analyses of palladium in the black form. Good agreement was found in the two sets •of results and it is concluded that they are more reliable than wet chemical .analyses of the same material.IntroductionFOR SEVERAL YEARS the problem of platinum metal analysis by spectrochemical methods has been under investigation at the Spedtrographic Laboratory, Department of Geological Sciences, Queen's University. The problem, briefly -stated, is as follows: Samples of platinum, palladium,-rhodium, ruthenium, and iridium are received as fine metal powders, called sponge. Direct spectrographic analysis of this material has not been found satisfactory due to its heterogeneity •as regards contaminant metals, which may be present up to a total of one per •cent or more. Further-more, spectrographic standards are difficult to obtain and difficult to prepare accurately by adding weighed portions of contaminant metals to the sponge. The fact that •contaminant metals in original samples are probably alloyed with the major constituent is a further difficulty since complete fusion of these refractory metals proved impractical in the present case as a means of standard preparation. It •has, therefore, been found most satisfactory to dissolve the metals, prepare standards by addition of solutions of contaminant metals, and to reduce both standards and samples to a homogeneous form. A previous paper, by Hawley, Wark, Lewis and Ott (2) dealt with a method for spectrochemical analysis of platinum and palladium in their black form. Since completion of research on the black technique, the possibility of analyzing palladium accurately in its sponge form has• been investigated."

Jan 1, 1953

By E. C. Sanford

A laboratory-scale batch extraction unit and operating procedure for studying the hot-water separation of bitumen from Athabasca tar sands are described. The extractor evolved from earlier units and has been in use by Syncrude Research for the past 10 years. By using a unit such as this, it is possible to study tar sand feed quality and the effects of chemicals on the hot-water extraction process, while process variables are held constant. Data are presented to demonstrate the importance of surfactants to the process and the interrelated role of inorganic bases and surfactants.

Jan 1, 1979

By Franc R. Joubin

"Gold has been found in many parts of the Bridge River district of British Columbia; but it is from a relatively small area in the valley of Cadwallader creek that most production has come. The ore-bearing area measures 1/2 mile in width by 3 miles in length; and for convenience it is called the Cadwallader gold belt in this paper. In this belt are found the Bralorne and Pioneer mines and in addition several prospects under development.The gold of the Cadwallader gold belt occurs in quartz veins averaging about 3 feet in width and containing about ½ oz. of gold a ton. Except for a relatively small amount of silver, no other metals are produced from these veins. The ore-bearing veins occur in a variety of rocks. They occupy reverse faults and tension fractures belonging to a distinctive fracture system. Some of these structures are ore-bearing over lengths exceeding 5,000 feet and depths exceeding 3,700 feet. The production of the Bralorne mine (1932-1945) is 996,383 oz. gold and 190,709 oz. silver; that of the Pioneer mine (1930-1945) is 777,588 oz. gold and 135,698 oz. silver. These two mines have together distributed about $25,000,000 in dividends.The Bridge River district first attracted attention in 1863* when prospectors were attracted by its small but rich placer gold deposits. Most of the important lode deposits of the Cadwallader gold belt were discovered in 1897 (11). Many years of desultory development followed and it was not until 1928 and 1932 that the Pioneer and Bralorne mines, respectivdy, entered into profitable production."

Jan 1, 1954

By Schrade F. Radtke

THE law of our present industrial society is the law of the jungle. By this I mean survival of the fittest. I do not refer to man or animal or the development of superior genetic strain. Rather do I refer to one's product, one's process, or one's material of construction. Each must perform in a superior manner or it is doomed to extinction; it must be steadily improved so that it can meet the competition of ether materials, of other equipment, or other processes. We have before us the classic examples of the horse and buggy vs the automo-bile, cf silk vs nylon, of the steam locomotive vs the diesel engine; in each case, a superior product has virtually wiped out its predecessor. Furthermore, a product, process, or piece of equipment is sold on its performance, together with engineering data which define its •characteristics and performance. For the most part, the present day sales-man must deal in terms of engineering performance of his product; he must know competitive materials -their strength and limitations as well N either old fashioned salesmanship, tradition, nor custom could have saved the horse and buggy from extinction; a superior product which has been steadily and con-sistently improved won out, 'and in turn, this change-over caused a dramatic• change in our whole way of life.

Jan 1, 1960

By Yan-Jun Shen

The rock mass classification system, BQ (basic quality), is the only national system that is suitable to most kinds of rock engineering in China. It uses two main aspects of the rock mass, the intact uniaxial compressive strength (UCS) and the rock intactness index (KV), to obtain the rock mass BQ. The index KV could be measured by the acoustic wave method. However, because this method is an indirect approach to characterize the rock mass structure, misfits often occur between the test results and the actual rock mass characteristics. Therefore, a new parameter KGSI expressed by the geological strength index is proposed to replace the original KV, and a new method is presented to express the value of BQ as a function of the UCS and the KGSI. Then, the underground excavations at five hydropower stations were chosen as examples to study the relationship between the revised BQ and the each of the international systems (RMR, Q or RMi). In addition, the applicability of the RMR, Q, or RMi system is discussed for China?s rock characteristics and geological conditions, and suggestions are given for improving the revised BQ system.

Aug 1, 2013

By K. Kryst, K. Elkayar

The increasing need to process lower grade contaminated copper concentrates and simultaneously produce higher purity copper cathodes necessitates a more diligent control in the electrorefining process. Ion exchange processes can be a powerful tool in controlling electrolyte impurities to ensure trouble free operation within the tankhouse and to help maintain cathode purity. In addition, some impurities can be recovered as a value added product. The use of a short bed ion exchange process provides a unique opportunity for impurity management in copper refineries. Several metals are discussed in this paper, including Sb, Bi, As and Ni and their methods of control and recovery within the copper electrolyte circuit. INTRODUCTION To produce a high purity copper product by electro-refining a copper electrolyte, it is important to control the concentration of impurities such as arsenic (As), bismuth (Bi), antimony (Sb), and nickel (Ni). These impurities are introduced into the electrolyte from the copper anode and can affect the copper product and the production operation. The presence of As in the copper product results in a lower electric conductivity and reduced workability of the copper. High levels of Bi in the electrolyte will result in a copper cathode product containing Bi. High Sb concentration will cause undesired floating slimes. A variety of methods have been developed to control the level of these impurities in the copper electrolyte including precipitation, liquid extraction, and ion exchange. These impurities can be recovered and used. This paper discusses novel methods that utilize short bed ion exchange technology to control these impurities. Also, the use of ion exchange to recover acid from the liberator cells bleed for reuse in the tankhouse is reviewed. SHORT BED ION EXCHANGE Short bed ion exchange technology has been employed extensively in the metal finishing industries for over forty years. Unlike conventional ion exchange, short beds are fixed beds without freeboard space. The application of short bed technology results in significant benefits when compared to conventional ion exchange. The resin used in this technology has a significantly smaller diameter than conventional ion exchange resin. As a result of the smaller resin size, exchange kinetics improves dramatically. This facilitates operation at higher flow rates and the use of smaller beds with a small mass transfer zone length. Smaller beds are especially important for applications that use chelating resins due to the high cost of the resin.

Jan 1, 2019

By J. G. Stevens, S. W. Colley

"Selective separations of metals and ions in mineral extraction and refining are becoming more challenging as ore bodies become more complex and environmental pressures increase. The separation and containment of mercury produced in gold mining are a factor in the profitability and operability of mines. This paper will discuss the development and implementation of the Johnson Matthey HgFree selective mercury removal process. The process is designed to selectively recover co-leached mercury from either heap leach pregnant solutions at ambient temperature and low mercury concentrations, or electrowinning pregnant solutions at elevated temperature and high mercury concentration, without affecting gold or silver recovery. The process utilizes a highly selective adsorption-desorption step in which mercury is removed quantitatively by the HgFree adsorbent without adsorption of gold, silver or other metals present. Development of the original HgFree adsorbent has resulted in a process whereby mercury can be recovered as an inert salt and is never present as the free metal. The HgFree adsorbent can be regenerated and recycled in situ, and is capable of being reused multiple times. The overall process is compatible with existing gold mining and recovery practices and offers significant environmental and sustainability benefits, including reduction or elimination of the need to retort mercury with a subsequent reduction in potential mercury air emissions. Development of the HgFree adsorbent and process will be discussed along with a pilot operation at two operating mines.INTRODUCTIONMany gold ore bodies contain high concentrations of mercury which when extracted with cyanide, co-extract with the gold and other metals. This mercury is carried through the process with the gold, posing environmental and technical issues when it is separated from the doré. This paper describes a method to selectively adsorb mercury from the gold recovery circuit while it is in a soluble form, leaving gold to be processed as normal. The removal of mercury from the circuit eliminates the need for mercury retorting of doré and so reduces the potential environmental impact of fugitive emissions of elemental mercury."

Jan 1, 2016

By G. A. McGuffin

"IntroductionWITH the increase in quantity of sour gas reserves in the Province of Alberta, and the wider market for sulphur brought about by mounting world demand and restrictions placed on the principal supply, it was inevitable that this important source of sulphur would be .developed. In the light of these facts, it seems timely that a general paper on sulphur recovery from petroleum gases be presented. This, then, is the purpose of the following text. A short discussion of each of the following subjects is presented:(1) Properties and uses of sulphur(2) Existing sources(3) Market research(4) The recovery process in Turner Valley(5) Hazards of sulphur productionNo pretext of originality of material is made since innumerable reports have been prepared on this and related topics and information contained in these has been used quite liberally.Properties and uses of SulphurSulphur is a non-metallic element having an atomic weight of 32.06. The stable crystalline form at atmospheric temperature is referred to as 'rhombic' sulphur. It is bright yellow and has a specific gravity of 2.05, equivalent to 129.2 lb./cu. Ft. Above 204°F. sulphur has another stable crystalline form, referred to as 'monoclinic'. This is reddish-brown and is slightly less dense than the rhombic variety (122.4 lb./cu. Ft.). Sulphur in bulk form weighs 84 to 90 lb. per cu. Ft. Sulphur melts at approximately 240°F. to a straw coloured liquid which is quite viscous."

Jan 1, 1952

By T. Xue

429 As part of Inco's S02 abatement project for its Sudbury operations, a weak acid treatment plant (W ATP) was commissioned at the Copper Cliff smelter in August of 2004 to treat the weak acid streams generated by the flash furnaces, the MK reactor and the fluidized bed roaster (FBR) gas cleaning plants. The W ATP process was developed by Inco Technical Services Limited (ITSL) by means of laboratory and mini-pilot plant programs. In the W ATP process, the feed solution containing arsenic, sulphur dioxide, iron and other impurities is treated by oxidation and neutralization to form a stable precipitate for disposal in Inco's tailings impoundment area. During the commissioning of the WATP, a team of operations, maintenance, engineering, project and R&D personnel was formed, and the designed capacity was achieved in less than a month. Since then, the W A TP has been operating smoothly and the impurities, specifically arsenic, in the Copper Cliff smelting process have been effectively removed.

Jan 1, 2006

By D. Bouchard, M. Forté, A. Charette

A transparent replica of a casting die was built to achieve a better understanding of the filling mechanisms of aluminum in high pressure die casting. Water and tomato paste were respectively used as analogues for the Newtonian liquid aluminum and the non-Newtonian semi-solid aluminum. The transparent die was installed on an industrial casting press and filling was filmed with a high-speed camera. Differences between the Newtonian and non-Newtonian fluids are presented and discussed.

Jan 1, 2006

By M. J. Latva-Kokko

This paper describes the behaviour of iron and the methods used for iron control in the nickel matte leaching process. OMG Harjavalta Nickel Oy processes approximately 10 000 t/y of iron, which enters the process with the nickel matte raw material. Iron dissolves and precipitates in several different stages of the leaching process. Compounds like ferric hydroxide, parabutlerite, goethite, hematite and jarosite are found. Iron removal is done within the leaching process, and this means that the dissolution of nickel sets the limiting conditions for iron precipitation. A leach residue consisting mainly of the iron precipitates is neutralized and stacked in the waste pond. When iron is precipitated from concentrated nickel sulphate solution, some nickel is lost by co-precipitation. Recent studies have shown that Ni-Fe ratios less than 1%, attributed to co-precipitation, can be obtained with jarosite precipitates, compared to 2-3% ratios typically found with hematite precipitates. Iron can be precipitated as jarosite under the optimal nickel leaching conditions by adding ammonium sulphate to the feed slurry of the autoclave.

Jan 1, 2006

By Y. Béliveau

Emission of perfluorocarbon gases, CF4 and C2F6, produced during anode effects from aluminum electrolytic cells are a significant part of the total equivalent CO2 emitted by aluminum plants. With the current concerns about global warming, the reduction of these PFC gases is a key issue in reducing greenhouse gases for a smelter and achieving GHG emission agreement goals. This paper will present the approach taken by the Alcoa vertical-stud Soderberg plant in Baie-Comeau to reduce GHG emissions generated during anode effects and close emission gaps with other Alcoa Soderberg plants. The approach has been to adapt the existing technology in place at the Baie-Comeau Soderberg plant. PFC emissions were lowered by reducing both the anode effect duration and frequency through different methods. Examples of change include: implementing skimming practices and wider side crust break area for better alumina dissolution in bath, increasing the ratio between reacted and pure alumina, reducing the time to declare anode effects in the potrooms, implementing best work practices and finally educating the workforce on the importance of reducing PFC emissions.

Jan 1, 2007

By S. Vaidya, R. C. McKellar, N. K. Sinha

Nominally [001]-oriented nickel-base single crystal (SX) superalloy CMSX-10 was investigated at 900°C under constant load, equivalent to an initial stress of 700 MPa, for creep strains from 7% to fracture strain (18.2%). The cross-sectional dimensions of initially uniform cylindrical specimens were measured along their entire length after the tests. The cross-section changed from circular to near elliptical shape. The anisotropic deformation, measured in terms of eccentricity, increased with the increasing strain level, but for a given strain level, it remained constant along the entire length of the initially uniform gauge section. The results are discussed in terms of diameter, eccentricity, area, local stress and microstructural observations. The most striking observation was the fact that all the specimens displayed a yoke-like shape, or the reduction of cross sectional area, at two locations within the originally uniform gauge section. Such observations have not been reported in the literature for single crystal superalloys.

Jan 1, 2006

By K. E. Waters, E. R. L. Espiritu, G. R. da Silva

"Rare earth (RE) elements are essential components of emerging green technologies. The increase in demand for these applications have driven the search and development of new rare earth deposits such as the Niobec project in Quebec, Canada. This deposit consists primarily of dolomite with significant amount of RE minerals bastnäsite and monazite, the primary sources of RE elements. Due to the minerals’ fine liberation sizes, flotation is commonly used as a concentration method. To develop an efficient process, the electrokinetic properties of the minerals must be understood. In this study, the surface properties of bastnäsite, monazite (RE minerals) and dolomite (a common gangue mineral) were investigated by zeta potential measurements. These measurements are affected by various ions present in solution; for bastnäsite, monazite and dolomite, some of these ions are H+, OH-, PO43- and CO32-. Dolomite, being a sparingly soluble mineral and a primary component of the ore, may be the greatest contributor of these ions in solution in the form of CO32- ions. Thus, different sources of CO32- ions (from dolomite dissolution and from Na2CO3) were investigated. The research work aims at elucidating how these reagents may influence the minerals’ surfaces. The results have shown that dolomite supernatant and sodium carbonate greatly affect the electrokinetic properties of each minerals. The addition of dolomite supernatant have resulted to relatively similar zeta potential of the minerals; while, sodium carbonate have affected them differently. These observations could be useful in efficient flotation of bastnäsite and/or monazite from bastnäsite-monazite-dolomite system.INTRODUCTIONThe increase in the demand for rare earth (RE) elements has driven the search and development of new deposits. Out of 53 rare earth projects in the world, 19 can be found in Canada (Hatch, 2015). These include the Niobec project of Magris Resources Company in Quebec. This deposit contains a significant amount of rare earth minerals (such as bastnäsite and monazite), with carbonates (such as dolomite) as the primary gangue minerals."

Jan 1, 2016

By Chris Harris, Kamal Adham

The use of HCl acid is gaining momentum among hydrometallurgical processes. However, the issue of environmentally efficient and economically viable ways to regenerate HCl acid (from various metal chloride intermediate products) remains a technology and operational challenge. The authors provide a state-of-technology review based on Hatch’s years of testing, design and commissioning experience with high-temperature units (fluid bed and spray roasters), plus the recent efforts in the area of low-temperature HCl regeneration.

Jan 1, 2014

By N. Dobrin, R. Sheinman, Y. V. Kokotov, L. N. Braginsky

Increasing the production of a Mixer-Settler unit requires either increasing flow rates or increasing extractant concentration. The mixers still have to ensure complete emulsification and to maintain high values of specific interface surface area in order to provide a high rate of mass transfer. Theoretically, an increase in mixing intensity can support increased flow rates without reducing extraction efficiency. Unfortunately, conventional pump mixers and mixing systems create small droplets that do not separate easily. As pumping action and mixing intensities are increased, the quantity of small droplets increases. We describe the development and industrial application of a novel mixing system for efficient mass transfer without forming significant quantities of small droplets, targeting both high mass transfer rate and low entrainment values.

Jan 1, 2014

By M. Reda

Because of the adverse environmental effect of Chromate, Molybdate ions had been investigated as replacement for Chromate and the results had shown not to be encouraging. Film deposited from peroxopolymolybdate (from reaction of Molybdenum meta, with excess Hydrogen Peroxide), are more robust than that deposited from molybdate solutions. This was shown to be due to higher fraction of Mo (IV) and Mo (V) that form from Mo (VI) in the peroxopolymolybdate deposited film than the film deposited from Molybdate solutions. The peroxopolymolybdate film contains 40% un-hydrated molybdic acid, tetraperoxodimolybdate and tetra peroxo tetra molybdate. The protective properties of peroxopolymolybdate were shown to be due to the effectiveness of the un-hydrated molybdic acid.

Jan 1, 2010