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By László Guczi1

Nanosize model gold particles with varying size were fabricated by deposition of a 10 nm thick gold film onto SiO2/Si(100) substrate by electron beam evaporation followed by modification using low energy Ar+ ion bombardment. The change in particle size were monitored by the Au 5d valence band states determined by ultraviolet photoelectron spectroscopy (UPS). The gold/iron oxide interface was studied by iron oxide deposition on gold. It was found that the energy profile of Au 5d valence band states are strongly redistributed with decreasing the gold particle size mostly affecting at the lowest and at the highest binding energies. The size effect in the UPS spectra can be interpreted by the energy redistribution rather, than by narrowing the 5d states. The iron oxide deposition increases the catalytic activity in CO oxidation whether it is on gold nanoparticles or on a continuous 80 nm thick gold film. The activity enhancement is significantly larger in case of gold nanoparticles. The interface interaction is operative in enlargement of the catalytic activity even if gold particles are not exposed to the surface, but they are located below the iron oxide layer.

Oct 1, 2003

By Blair Hrabi

Introduction; ?Risks Associated with the Resource Estimation Process; ?Limitations of Available Data; ?Geological and Structural Control of Mineralization Trends; ?Recognizing Multiple Mineralization Controls and Complex Trends; ?Accurate Geodomaining; ?Conclusions.

May 1, 2013

By Tao Cheng

Previous research and applications in construction resource optimization have focused on tracking the location of material and equipment. There is a lack of studies on automated monitoring of the interaction between workers and equipment for safety purposes. This paper presents a new approach for measuring the safety performance of construction personnel particularly when they work in very close proximity to moving equipment as well as static hazards such as chemical and flammable substances. A method of generating hazardous zones according to the geometric and kinematic characteristics of the considered hazard is introduced. The spatio-temporal relationships between the hazardous zones and workers? positioning data collected by real-time location sensing technology are automatically analyzed. This approach has been validated in a controlled test bed environment that simulates a construction site. Results indicate that worker?s safety performance of selected activities can be automatically and reliably measured using the developed approach. Furthermore, a heat map is generated for visualizing proximity related issues in the test bed using the computed results.

Aug 1, 2013

By S. M. J. Mirazimi, F. Rashchi

Recovery of vanadium from LD (Linz-Donawits) converter slag was evaluated by means of microbial leaching. Vanadium leaching was performed in two stages. In the first stage, the bacteria were grown in a culture medium and in the second stage; vanadium containing slag was added to the metabolites produced by bacteria. Bioleaching was performed using heterotrophic bacteria Pseudomonas Putída. Control tests without bacteria inoculation were also performed and the results were compared with bioleaching outcomes. Optimal conditions for the bioleaching of vanadium containing slag were determined.

Jan 1, 2011

By D. R. Wright

"The modest thermal efficiency of the steam turbine cycle essentially determines the heat required and, therefore, the coal consumption and ash production of pulverized-coal-fired powerplants. This paper emphasizes how some properties of coal and its ash can crucially affect the operation of a steam generator and its flue gas cleaning equipment. A brief reference to some siting factors and economics reaffirms the all-pervasive influence of the properties of coal and ash and establishes the importance of a firm supply of cooling water. The economics of scale remains a compelling factor in selecting the size of units, despite disappointing performances by some of the larger units. Environmental considerations suggest that smaller units still have a role to play. IntroductionCoal fuelled one industrial and economic revolution, beginning two hundred year s ago . It was the precursor of competing fuels, notably natural gas, oil and uranium, which eclipsed it in terms of convenience and rate of growth.The turmoil that now exists because of rapidly dwindling supplies of no-longer-cheap oil and the concerns about nuclear energy-justified or unjustified-exacerbated by an operating incident at the Three Mile Island Nuclear Powerplant, prompt speculation for a resurgence of coal, especially where it cangenerate electricity to replace energy from imported oil.The world's reserves of coal are not inexhaustible, although they are ample for several decades. Of greater import is the fact that the world's coal reserve s are more widely distributed than its oil reserves, and they appear less convenient as instruments of economic and political persuasion by opportunist powers. The crux is whether or not the world will accept all that a massive, if temporary, return to coal implies.Combustion of pulverized coal in steam generators to pro duce electricity is a 50-year-old, well-understood technique; it is undergoing continuous refinement to meet evolving environmental and economic criteria and is not found wanting. It is certainly the only technique available and technologically advanced enough to replace oil immediately on a large scale. Although it may take a decade to bring a new coal-fired powerplant into service, this delay is a reflection on nontechnical and administrative processes. Capital and operating costs of coal-fired powerplants are significant and subject to inflation, but, because of the accumulated experience in this field, the ability to control costs is better than for those energy processes which are less mature or still in embryo form. More exotic, soft energy systems, touted as the panacea for world energy problems, have still to prove themselves on the scale they are needed and under the stringent climatic and operating conditions coal-fired powerplants have already mastered."

Jan 1, 1980

By Osvaldo A. Bascur

Industrial complexes rely on measurements of flow rates, qualities, and concentrations for monitoring and optimizing their operation. Corporations use the data from the various sensors and measurements to make business decisions, which affect the profitability of the operation. However, gross errors, due to a variety of reasons like faulty sensors, bad instrument calibration, or incorrect process models may corrupt the actionable information supplied to operations, quality managers, and maintenance personnel. The solution is to use the sophisticated new tools to model the process, sift through the available data to locate the gross errors, and use statistical data reconciliation to validate the sensors and instruments. In this way the data are unified to give the most accurate plant information for use by the monitoring and decision making processes. Most mining and metallurgical plants use predictive maintenance policies based on statistical analysis and special techniques, like vibration analysis, and oil and lube analysis for critical equipment. Process control strategies are installed in several metallurgical sites. All of these depend on reliable and accurate data. The data unification methods validate the individual measurements by using the concept of balances and statistical techniques where each instrument is no longer independent of the other measurements in the facility. This paper refers to the data unification and analysis methods required for profitable plant operations. Continuous improvement and monitoring of the measurement system at the plant and analysis of the reconciled data provide the best information for the decision-making process. On-line gross error detection and elimination methods are required to ensure efficient evaluation of process performance and process optimization. An open discussion of the new methods for gross error detection and data unification will be presented.

May 1, 2001

By J. C. Moreno, G. Rios, M. Palacios

The Huelva smelter was commissioned in 1970 coinciding with the shutdown of the old smelter in the Rio Tinto mine site. That new smelter consisted of two Momoda blast furnaces with a capacity of 500 dmtpd of concentrate. Nevertheless, soon after their start-up, it was clear that an increase in the smelting capacity was needed. After an analysis of the existing alternatives at that time, the flash smelting technology was chosen. The new Outokumpu Flash Smelting Furnace (FSF) came into operation on 18 September1975, with an initial capacity of 900 dmtpd of concentrate, using four Venturi-type burners and preheated atmospheric air. Since that date the Huelva Smelter team, together with Outokumpu (now called Outotec), have continuously improved our FSF design, process conditions and operational practices, leading to a present capacity of 3,500 dmtpd of concentrate. Since 1975, five smelting campaigns have been completed, the last ending in November 2013 with the rebuilding of the original FSF hearth. This paper describes the history of these improvements and the lessons learned.

Jan 1, 2014

By André Bérubé

"IntroductionSince the disappearance of Les Forges du Saint-Maurice at the end of the last century, many historians have taken an interest in the lengthy past of this enterprise. They considered the political, socio-economic, administrative and anecdotal aspects of the industry, but barely dealt with the elements of technology. The purpose of this article is to try to fill this gapru.Les Forges du Saint-Maurice was an integrated industrial concern, specializing in the production of semi-finished wrought iron and finished cast iron, that operated almost without interruption between 1734 and 1883. Les Forges first came into being in 1729, when Montreal merchant Francois Poulin de Francheville submitted to the king of France a request for the right to exploit the bog iron ore deposits on his seigneury of Saint-Maurice. This request, agreed to in 1730, was one of a long series of attempts, previously unsuccessful, to establish a local iron industry in the colony. Several such proposals were held up by a lack of capital from promoters or a too rigid application of the mercantilist policy by the metropolis. In 1730, however, the French minister Maurepas favoured a more liberal policy which would encourage private enterprise. The benefits of an iron industry to the naval construction industry was a factor that caught the attention of administrators. The choice of the site for Les Forges was based on the following factors:• the abundance of surface deposits of bog iron ore in the Saint-Maurice region;• the presence of a vast supply of hardwood and conifers needed in large quantities by this industry;• the proximity of sandstone and limestone deposits, indispensable materials for the construction and operation of the blast furnace;• the presence of a water stream, with sufficient flow to provide the hydraulic power needed for the operation of the machinery."

Jan 1, 1983

By Louis R. Bernier

Most systematic studies carried out on passive treatment systems incorporating the use of limestone drains, under aerobic or anaerobic conditions, essentially deal with the treatment of effluents from mines in the USA. A limestone drain typically comprises a trench filled with crushed limestone rocks surrounded by impervious materials. In the case of anoxic drains, the trench is generally isolated under a geomembrane liner covered with soil. Contaminated mine effluents flow by gravity towards these limestone drains where the passive treatment consists in bringing the carbonates into solution, thus increasing the pH and alkalinity. Factors to be considered in the design are: chemistry of the contaminated mining effluent ([metals, [Al], [sulfates], dissolved oxygen, acidity, pH), desired residence time, nature of the rock, grain size, density, void ratio and mass of the limestone rock used, alkalinity, life span and hydraulic behaviour of the drain. Certain secondary effects (saturation by sulfates, co-precipitation, adsorption) may either be beneficial (lowering the sulphate and metal load) or harmful (armoring the limestone rock and clogging of the drain). This paper gives a brief status report on the available knowledge on the use of limestone drains for passive treatment of mining effluents heavily loaded with metals. Examples given include the old Lorraine mine (Ni-Cu), Témiscamingue, where limestone and dolomite rock drains were installed in 1998 when a cover with capillary barrier effects was placed over the tailings site.

Nov 1, 2002

By L. Mercier, R. Narendrula, F. Desmarais, L. Amaratunga, A. Aledresse

Thiosulfate is recognized as a promising alternative lixiviant to cyanide for the extraction of gold from ore bodies. Gold thiosulfate ([Au(S2O3)2]2), however, is not well-adsorbed by activated charcoal, making industrial scale use of thiosulfate for gold leaching impractical at present. Because of their high specific surface areas (500-1000 m2g-1) and uniform open-framework nanoporosity (pore channel diameters in the range 3-10 nm), functionalized mesoporous silicas are widely recognized as highly effective materials for the selective, rapid and high capacity uptake of mercury, gold and platinum group ions. In the present work, the efficient and rapid adsorption of gold thiosulfate by thiol-functionalized mesoporous silica (hereafter designated MP-HMS) is demonstrated, whereby the thiol groups in the materials bind with the gold complexes by ligand displacement. The adsorbed gold could be leached out using cyanide, regenerating the adsorbent for further uptake cycles. Functionalized mesoporous silica is thus a promising candidate for the preconcentration of gold from thiosulfate leachate solutions.

Jan 1, 2011

By G. Riveros

A new, continuous fire refining process for copper has been developed and tested at the 5 tph pilot scale. During oxidation, the blister copper flows through a packed bed of crushed refractory bricks counter-current to a hot oxygen containing gas. The resulting desulphurized copper flows then directly into a packed bed of charcoal for deoxidation. By controlling the air to natural gas ratio, both temperature and reducing conditions can be controlled. Based on extensive laboratory scale measurements of the rate of copper oxidation and reduction, the process concept was developed aided by process modeling and simulation. The industrial-pilot scale installation built at the ENAMI Paipote smelter in Chile, consists of two cylindrical, compact reactors, operating in line, with a designed capacity of 5 t/h of blister copper. The results of the industrial-pilot tests confirmed the feasibility of the new process. The blister copper processing capacity was increased to 10 t/h with satisfactory sulphur removal. The degree of oxidation as well the copper temperature was controlled with relative ease. The specially designed siphon block allowed for smooth tapping of the oxidized copper and separation of refining slag. The reduction of oxidized copper in the packed bed of charcoal appeared to be very effective while control of the degree of reduction according to the height of the bed ensured control of the oxygen content in the refined copper at the required level.

Jan 1, 2007

By A. Jafarnia

Aluminum alloys are frequently grain refined during solidification in order to promote the formation of an equiaxed grain structure in the casting. The application of Ti-based grain refiners and/or Ti containing master alloys for improving mechanical properties may result in formation of Al-Ti based intermetallics. Although the grain refinement produces many desirable qualities in aluminum castings such as improved castability and mechanical properties, the addition of Ti to Al-Si foundry alloys may lead to the formation of some undesirable intermetallic particles such as AlTiSi and cause a number of operational problems such as nozzle blockage due to segregation and agglomeration of aluminide particles within the nozzle. There are several questions to be clarified when minor amount of Ti is added to Al-Si alloys. They include nucleation and growth of AlTiSi particles, their morphologies and orientation relationships with aluminum matrix and the dissolution of these intermetallics during the course of solidification and/or post solidification treatments. The current study was initiated to study the process and possible mechanism of aluminide dissolution and the related phenomena such as segregation and agglomeration. It reports the results found during reheating of laboratory prepared Ti-added A356 alloy at three temperature ranges of below solidus, mushy zone and above liquidus.

Jan 1, 2004

By D. V. Krefting, D. R. Bennett

"The Cyprus Anvil Mining Corporation established a lead-zinc mine and concentrating plant at Faro in Yukon Territory in 1969. Following some 12 years of continuous operation from a single pit adjacent to the concentrator, the company decided to expand operations into two additional areas on the Vangorda Plateau. The two new deposits, known as Grum and Vangorda, are located some 15 kilometres from the existing concentrator.Confirmation of mining feasibility was followed by determination of the most practical and economical method of transporting the raw ore from the new mine sites to the existing concentrator. This analysis was carried out in two phases. The first phase reviewed the feasibility of alternative transportation systems on an 'order-of-magnitude' cost basis. This work identified systems worthy of more detailed examination. The second phase examined the preferred alternatives in greater detail.Initially, operating principles and parameters were established and catalogued. Then, based on these criteria, complete systems were developed utilizing alternative modes of transportation . In the overview analysis, some transportation modes were judged impractical and discarded, 'order-o f-magnitude' costs were developed for other systems and the most costly were eliminated . In the detailed study, the favourable systems were examined in depth which required development of accurate capital and operating costs, consideration of environ- mental impacts and an assessment of intangibles associated with the operation of a new development."

Jan 1, 1984

By E. Larsen

Marine tailings disposal may in some cases be the best solution to one of mining’s major environmental problems. The public standing of this solution is poor, partly because of past bad practices. Among the tailings problems spreading of super-fines and toxic substances stand out. The two are often interrelated as heavy metals, insoluble to sea water, tend to adsorb on fines and spread piggyback on them. Only one paper seen, has addressed the mineralogy of fine particles in suspension. The topic was a secondary tailings deposit. Studies on the sedimentation of fines in large river estuaries show that different minerals sediment sequentially as the salinity of the river increase. Mineralogy in the particle size range where particle separation takes place, has so far, naturally been in focus for the mineral processors. Next to nothing is known about the fines which may cause environmental problems. Tailings disposal has, due to its complexity, to a large extent been taken over by specialists in other fields, biologists, engineering geologists, chemists. The basics of the subject ought also to be given more input by the mineral processing community. A drawn out battle about tailings discharge into some fjords has taken place in Norway. The detractors focus at fine particles (could be dangerous nanoparticles) spreading and emphasize the effects. Calculation is simple: 5 million tonnes tailings annually discharged, containing 1 wt. % < 1µm determined by laser diffraction, results in 50 000 tonnes of nanoparticles let loose in the environment. The industry`s difficulty to answer, is lack of basic research on this topic. Test work to develop a methodology to address the problem is described. One thing the mineral processors know is that final tailings may be comprised of tailings from separate separation processes, with different properties, some of which may require special treatment. One tailings stream from a Norwegian mine is investigated in such a context.

Jan 1, 2016

By S. H. Castro

Molybdenite depression by shear degraded polyacrylamide solutions has been investigated. Aqueous solutions of polyacrylamide-type flocculants were subjected to shear degradation under a range of high-speed stirring conditions. Settling tests, carried out with quartz slurries and sheared polyacrylamides, showed reduced flocculant performance with increased degradation. As the sedimentation rate is strongly dependent on the polymer&apos;s molecular weight, these results fit well with the shear degradation theory, which predicts the production of shorter chain segments due to breakage of the polymer macromolecules. Microflotation tests on natural molybdenite showed that the depressing ability of a commercial polyacrylamide flocculant remained unaltered after shear degradation, even when the flocculating ability was entirely lost. Practical implications of shear degradation on molybdenite flotation are discussed.

Jan 1, 2004

By A. J. Hyett, R. D. Reichert

"A laboratory and field research program was conducted to investigate the major factors influencing bond capacity of grouted cable bolts. The results indicate that cable bolt capacity most critically depends on the grout uniaxial compressive strength (UCS), the radial confinement, and the embedment length.In the laboratory &apos;split-pipe&apos; tests were conducted using P VC, aluminum and steel pipes to provide radial confinement, and field test sites were chosen in granite, limestone and shale rock masses. For both datasets higher capacities were obtained under conditions of higher radial confinement. A correlation between the two was obtained through a comparison of the radial wall stiffness of the laboratory pipes with that of the field boreholes as measured using a high pressure dilatometer. Cable bolt capacity was found to increase with embedment length though not in direct proportionality.The use of low water cement ratio grouts (<0.40) can increase cable bolt capacities by 50% to 75%. This effect is maximized under conditions of high radial confinement. However, the use of super thick grout paste (0.30 and less) may be both impractical and undesirable, first because of their limited pumpability and second because of their inconsistency in strength. Grouts with a water cement ratio of between 0.35 and 0.40 are recommended for practical cable bolt applications."

Jan 1, 1992

By Bruce K. McKnight

"The new H-W orebody was evaluated by considering its production at three technically feasible rates. Capital and operating costs were estimated f or each rate and production sequences were established using mining cutoff limits generated by an ore value algorithm. The viability of the project was then examined by conducting economic and financial analyses of each of the three production cases under various world economic scenarios. These analyses employing standard profitability measures demonstrated all three cases would be economically viable; the production case which maximized the Net Present Value of the project was the one selected for development and production.IntroductionWestmin Resources Limited and its predecessor company, Western Mines Ltd., has been continuously carrying out mining operations near Myra Falls in Central Vancouver Island since December 1966. The mining operation, whose current production rate is approximately 830 tonnes / day (t/d), based on ore derived from the Myra and Lynx Mines, produces copper, lead and zinc concentrates which contain significant quantities of gold and silver in addition to the base metals.In the late 1970s, with Lynx and Myra ore reserves slipping to unacceptably low levels, a major increase in mine-site exploration was initiated, with outside geological staff brought in to complement the efforts of the mine&apos;s geological staff. By the end of 1979, this program had resulted in the discovery of a significant new orebody on a deeper horizon some 300 metres below the one which hosts the Lynx and Myra deposits. Throughout the period 1980-1982, major drilling was carried out to evaluate the new H-W deposit and by the end of 1982, drill-indicated mineral inventory for the deposit compared with Myra, Lynx and Price ore reserves was as shown in Table I. During this same three-year period, a major development and evaluation program was underway comprising environmental monitoring and control programs, shaft sinking test mining, bulk sampling and mill testing, rock mechanics studies and preparation of the Stage I and II reports for the multidisciplinary Environmental Land Use Committee (ELUC).As a result of the preliminary engineering work and exploration drilling, it became rapidly apparent that the H-W deposit could support a considerably higher production rate than the current one. Accordingly, engineering studies including scheduling of development and production as well as capital and operating cost estimates, were focused on three possible production rates: 1350, 1800 and 2700 t/d. Our task was to select the optimum one of these three rates."

Jan 1, 1987

By Barton G. Stone

The mining and exploration industries have been using Geostatistics (Matheron, 1963) for the past forty years. It has been extensively incorporated into three dimensional block modeling software whose usage has reflected the growth in the use of personal computers since 1980. Because of the utility of geostatistical models in mining and production planning, much of the modern reserve and resource modeling is done by mining engineers, geostatisticians and geological engineers. Explorationists are initially less concerned with three dimensional models until such time as a deposit has been roughly delineated. However, the concept of regionalized variables in ore deposits deals with the effect of spatial correlations between data points in a three dimensional sample space and should be useful for optimizing the spacing of drill holes to allow maximum bang-for-the-buck in drilling programs. This paper examines three common deposit types (porphyry copper, VMS and intrusive gold) to examine whether geostatistical methods have been used to minimize drilling costs because of better understanding of spatial correlations. The three model types were chosen from publicly available corporate websites of Canadian based Junior Mining Companies. They include the Wolverine polymetallic zinc deposit of Yukon Zinc in Yukon, Canada; the El Morro Deposit in Chile (30 percent ownership by New Gold Mining Company, and the Fort Knox Gold deposit in Alaska and 50 percent ownership by Nova Gold Resources). Typically, individual mining corporations post their technical reports as CNI 43-101 reports on their corporate website as indications of the favorability or progress on their more exciting properties. Data considered for this paper was not collected or generated by the author, but the information was extracted from these publicly available sites and had a variety of authorship.

Oct 1, 2009

By J. Stachulak, M. Scobie

"This paper addresses the occurrence and indicated causes of conveyor fires in North American and European underground mines. Some significant convey or fires which have been experienced in recent years in Canadian hardrock mines are then reviewed. The nature of existing conveyor monitoring technology is considered in the context of such fire hazards. Experiences with new monitoring technology recently installed at several conveyor sites at Inca Ltd. mines are then reviewed.IntroductionFires associated with conveyors have long been recognized as a serious hazard in underground coal mines. Recently, however, there have been some significant conveyor fires in Canadian underground hardrock mines. These offer important evidence as to the nature and causes of potential hardrock mine fifes. They also warrant attention with a view to improving over-all mine design, ventilation and emergency preparedness.In addition, a new era in mine communications and monitoring technology has been entered which should offer improved capability to protect against such fires. This paper was motivated by the need to understand the causes and mechanisms of conveyor fires in order to improve their safety. This should be possible through implementing more effective monitoring systems, as well as improving conveyor design. Underground mines are becoming more intensively mechanized, with less human surveillance of equipment and a greater dependency on remote monitoring systems."

Jan 1, 1992

By R. A. Mantz, V. N. Balbyshev, A. N. Khramov, N. N. Voevodin

Corrosion protection properties of the hybrid organo-silicate coatings on aluminum substrate can be significantly improved by means of encapsulation of organic corrosion inhibitors within the coating material. In order to achieve sustained release of corrosion inhibitor and long-term corrosion protection, a secondary chemical equilibrium of either ion-exchange interaction with the coating matrix or cyclodextrin-assisted molecular encapsulation of the inhibitor has been employed. Several organic corrosion inhibitors, such as mercaptobenzothiazole, mercaptobenzimidazole, mercaptobenzimi¬dazolesulfonate, and thiosalicylic acid have been examined by a group of electrochemical methods including potentiodynamic scan, electrochemical impedance spectroscopy, and scanning vibrating electrode technique. It has been found that the formulations that contain ß-cyclodextrin demonstrate superior corrosion protection capabilities as the complexation equilibrium results in a continuing delivery of inhibitor to corrosion sites. The approach is considered a promising way for active corrosion protection of high-strength aluminum alloys when integrity of barrier coating is compromised.

Jan 1, 2004