Search Documents

By John S. Stevenson

THE Twin "J" Mine, operated by Twin "J" Mines, Limited, represents an amalgamation of the old Lenora, Tyee, and Richard III mines (see Figure 1) on mount Sicker, eight miles by road, northwesterly, from the city of Duncan, on Vancouver island. These mines produced 253,000 tons of copper-gold ore between 1898 and 1909 (see Table I). During the more recent period of production from these properties, July, 1943, to May, 1944, Twin ?J? Mines, Limited, mined and milled ore with values mainly in copper and zinc, and minor values in gold, silver, and lead. Figures are not available for this later production. Field work at the property was started by the writer in 1941 and continued in 1943 and 1944.

Jan 1, 1945

By Louise Grondin

Laronde Mine has been working for a number of years to identify substances that could contribute to process water toxicity and to find an effective way of removing these contaminants from the water. Initial studies have identified ammonia, nitrite, cyanide, thiocyanate, cyanate, dissolved organic carbon, copper and zinc as potential toxicants. Bench-scale tests were carried out with Lakefield Research to find a water treatment process that could effectively remove the suspected toxicants. Nine treatment processes were evaluated: 1) granular activated carbon (GAC) filtration followed by zeolite, 2) zeolite filtration followed by GAC filtration, 3) aeration followed by GAC filtration, 4) multi-stage GAC filtration, 5) chlorination followed by dechlorination, 6) addition of clay based polymer, 7) treatment with peroxide and ultra-violet light, 8) bulk addition of GAC and zeolite powder, 9) treatment with bacteria. This article presents a summary of the test results and of the problems associated with the evaluation of technologies for the treatment of toxicity.

Nov 1, 2002

By Getu F. Biftu

There is general agreement among scientists that global surface temperatures have been increasing during the past decades. The increase in temperature is postulated to be the result of either an increase in greenhouse gases emission or climate variability (i.e., due to variations in sun or volcanic activity or El Nino and La Nina events) during past decades and may continue to increase. The effects of a predicted rise in the Earth?s surface temperature include an increase in average global evaporation and increase or decrease in precipitation (Bloomfield, 1992; Mann et al., 1991; Vinnikov et al., 1990; Gan 1995; Zhang et al., 2000a). The general circulation models (GCMs) project a global warming due to greenhouse effects of 1.5-4.5°C by the mid 2050s, with the most pronounced changes taking place in northern latitudes (Nicholls et al., 1996). However, similar predictions at a watershed scale or even a regional scale using GCMs are mot possible yet (Arnell et. al., 1996; Georgievskii et. al., 1996; Zhang et al., 2000a). Detection of historic trends, changes and variability in climatic variables is another indirect means of understanding potential future changes or variability at regional and local scales. The main objective of this paper is to review studies related to climatic change or variability and associated hydrologic changes at a regional scale and local scale, particularly those studies applicable to the Oil Sands Region (OSR) of Alberta. This paper identifies gaps in our current understanding of the hydrologic processes that may be affected by climate change; it discusses potential implications to developments in the OSR; and it explores mitigation opportunities including several that have already been implemented.

May 1, 2004

By Joey R. Kish, Shooka Mahboubi, Hatem S. Zurob, Gianluigi A. Botton

The kinetics of the Cr2O3-based scale oxidation and volatilization were studied in the presence of water vapour (H2O). A commercial Cr2O3-based scale forming Type 310S stainless steel was examined at the ambient pressure (0.1 MPa) and 550ºC in relatively low and high H2O containing environments of air- 10% H2O and air- 70% H2O, respectively. The increase in the partial pressure of H2O (pH2O) from 10% to 70% resulted in transition of the oxidation and volatilization kinetics from the parabolic rate law for air-10% H2O to the paralinear rate law for air-70% H2O. The kinetics transition was attributed to the increase in the Cr loss rate from the base scale after coupons exposure in air- 70% H2O. The significant role of the Mn alloying element in the base scale protectiveness was also discussed in the context of the Cr2O3-based scale stability.

Jan 1, 2017

By K. Ilankoon, I. M. Saman, S. J. Neethling

In heap leaching the transport of the acid from the drippers to the surface of the ore particles is a major factor in the overall performance of a heap. This flow behaviour is complex as the flow is unsaturated and occurs along a tortuous set of inter-particle channels and connections. The particle properties such as size, shape and porosity are very important when modelling the liquid holdup and flow within heaps, since the dominant mechanisms at work are quite different. This paper investigates the effect of these particle properties experimentally on heap flow behaviour using a 1-D column leaching system consisting of non-porous glass beads with a system of actual ore particles. The similarities and differences between the two systems on flow behaviour are described using an inter-particle flow model. In addition, the applicability of positron emission particle tracking (PEPT) for laboratory column leaching will be detailed to calculate hydrodynamic dispersion in packed beds compared to more conventional residence time distribution (RTD) tests and also to obtain the time averaged rivulet flow paths through the particles of the bed for the better understanding of heap hydrodynamics.

Jan 1, 2014

By Y. S. Sun, Northeastern University, W. B. Li, P. Gao, Z. Y. Zhang, J. W. Yu

"The boron-bearing iron concentrate was extracted from ludwigite ore by the process of magnetic-gravity separation. In order to fully utilize the refractory ore and meet the boron consumption of China, a novel process for separation of boron from iron in boron-bearing iron concentrate was proposed in this paper. In particular, laboratory scale experiments of improving boron reactivity were performed. Fine boron-bearing iron concentrate briquettes were reduced by bituminous coal completely at 1125 °C for 150 min. The effect of sodium carbonate, which was used as an additive in the roasting process, was investigated. The addition of sodium carbonate decreased the boron reactivity and facilitated the volatilization of boron. The influence of diverse cooling methods of the reduced samples on the boron reactivity was studied. The results indicated that boron reactivity could reach up to 80.76% when the reduced samples were cooled by rapid water quenching. In addition, the magnetic material containing 92.71 % Fe with a recovery of 95.11 % and boron-rich non-magnetic material containing 14.51% B2O3 with a recovery 88.85% could be obtained by low-intensity magnetic separation. The magnetic material and boron-rich non-magnetic material were good raw materials for steel-making and borax production, respectively.INTRODUCTION Ludwigite ore is abundant in Liaoning province of China, with 28.43 Mt B2O3 accounting for 57% of the boron resources of the country (Liu et al., 2006). However, it has not yet been utilized on an industrial scale due to its complex mineralogy and fine mineral dissemination (Wang, Wang, Ding, Ma & Xue, 2012). At present, boron-bearing iron concentrate and boron concentrate can be obtained from ludwigite ore using magnetic-gravity separation. The boron concentrate contains B2O3 12%~16%, which can be used as a high-quality raw material for the boron chemical industry after activated roasting, but the B2O3 content in the iron concentrate reaches up to 4%~6%. In order to further separate boron and iron from boron-bearing iron concentrate, a blast furnace and a solid pre-reduction followed by electric arc furnace melting have been proposed (Liu, Cui & Zhang, 1998; Wang et al., 2012). However, both of these two current routes face the same crucial problem that molten boron-rich slag has to be cooled slowly to obtain the alkali-dissolution activity of boron, which affects the yield of boron resource."

Jan 1, 2016

By R. O. Burt

The original flowsheet of the TANCO mill consisted of a simple two-stage gravity circuit for the recovery of the tantalum concentrates. With decreasing grade and grain size of the tantalum minerals, considerable modifications to the circuit have been required. This paper discusses the various recent improvements carried out 011 all stages of the flowsheet, which have resulted in a 10% increase in recovery. Future improvements, including on stream analysis, and the possibility of tantalum flotation , are also discussed.

Jan 1, 1979

By V. G. Papangelakis, M. Cheung, M. Dry

The high pressure acid leaching of laterite was modelled and simulated using a combination of two commercially available software packages, namely Aspen Plus 11.1 and the OLI Stream Analyzer. New kinetic parameters for the acid-controlled metal dissolution and precipitation reactions at temperature were first determined from previous experimental data on the leaching of limonite. A grain model with cylindrical pellets was used to model the solid-liquid dissolution reactions. Precipitation reactions were modeled via aqueous equilibrium chemistry. A dedicated thermodynamic database previously developed at the University of Toronto was used in conjunction with the OLI software to model the solution chemistry and calculate the concentration of hydrogen ions in solution at the leaching temperature. Mass balances were handled by Aspen Plus. The simulation gave good predictions of nickel dissolution under industrial and laboratory conditions, for the dissolution of limonite and limonite/saprolite blends. Computational

Jan 1, 2005

By J. E. Dutrizac

Mercury balances have been obtained for the flotation circuits at Pamour Porcupine Mines, Timmins, Ontario, and at Brunswick Mining and Smelting Corporation, Bathurst, New Brunswick. The mineral form of mercury in both deposits has been ascertained. At Pamour Porcupine, the mercury is approximately evenly divided among sphalerite, native silverelectrum and tetrahedrite-tennantite; at Brunswick Mining, this element is contained mostly in the sphalerite, although tetrahedrite (and possibly pyrite) also contains minor quantities.

Jan 1, 1979

By F. Khomamizadeh

In this study the effect of solidification rate, T6 and T7 heat treatments on thermal fatigue resistance of A319 aluminum was investigated. Increasing of the solidification rate improved the thermal fatigue resistance of the alloy by refinement of the microstructure. The most sensible areas for thermal fatigue crack growth were the eutectic zones, T6 and T7 heat treatments improved the thermal fatigue resistance of the alloy by enhancing of the matrix resistance against the crack propagation. The slight reduction of the thermal fatigue resistance after T7 heat treatment is attributed to coarsening of the precipitates which reduces the matrix resistance.

Jan 1, 2005

By Niraj Bala

Boiler tubes of coal-fired boilers suffer severe erosion-corrosion (E-C). One method to counteract this problem is by the use of therma, spray protective coatings. Cold spray coating process was used to deposit Ni-20Cr powder on SA 516 (Grade 70) boiler steel. The bare as wel, as the coated steels were subjected to cyclic experimenta, studies, in the superheater zone of a coa, fired boiler. The weight change technique was used to establish kinetics of the erosion-corrosion. XRD, FE-SEM/EDS and X-ray mapping techniques were used to analyse the as-sprayed and corroded specimens.

Jan 1, 2010

By E. Dernedde

A few studies have suggested that the rate of adsorption of hydrogen fluoride on smelter grade alumina is determined by kinetic factors. However, no performance equation for dry scrubbers has appeared in the literature so far. Experimental data from a pilot dry scrubber with co-current flow were compared with results of kinetic models of adsorption, film diffusion and pore diffusion. The pore diffusion model was deemed the most appropriate. It was transformed into a performance equation for steady-state operations of dry scrubbers by the inclusion of the alumina recirculation. Operating results of industrial dry scrubbers with co-current flow were successfully evaluated by means of the performance equation. The average fluoride content of the alumina was also estimated by using the pore diffusion model.

Jan 1, 2011

By M. Mezbahul-Islam

Thermodynamic modeling of the Mg-Cu-Ni system is carried out as a part of multi component thermodynamic database for Mg alloys. This system is being modeled for the first time using the modified quasichemical model, which considers the presence of short range ordering in the liquid. The thermodynamic descriptions of the binaries Mg-Cu, Cu-Ni and Mg-Ni have been extrapolated to the ternary Mg-Cu-Ni system using Toop geometric model. The constructed database has been used to calculate and predict thermodynamic properties, isothermal sections and liquidus projections of the Mg¬Cu-Ni system, which showed very good consistency with the experimental data.

Jan 1, 2011

We describe a new method of characterising the effect of dissolved materials on the rate of coalescence of bubbles in aqueous media. Single bubbles were allowed to rise to meet the surface of an aqueous solution, and the time of persistence between arrival and bursting of bubble was measured as a function of solute concentration. A laser beam was placed just above the surface of the liquid, with a detector in the light path, so that any disturbance at the surface could be seen as a break in the beam. The arrival of a bubble at the surface could be detected from the behaviour of the trace on an oscilloscope, and when the bubble broke, another significant change in the signal could easily be seen. The time between disruptions was reported as the persistence time. The effect of a homologous series of n-alcohols (C1 to C8) on the persistence time was measured, in aqueous solution. It was found that with increasing concentration of a particular solute, the persistence time increased up to a point, and then declined. However the magnitude of the persistence time was found to increase with increasing numbers of carbon atoms in the molecule. Bubbles of 1, 2 and 3 mm diameter were used. Persistence time increased with increasing bubble diameter, the maximum values observed being of order 100 secs. For a given solute, the persistence (drainage) time increased with increasing bubble diameter. The concentration Cmax at which the maximum persistence time was observed, was found to be independent of the bubble size. It decreased uniformly as the carbon number increased, and was well correlated by the function y1/2 (dy /dc) -2 I dc)-2 . There was no apparent correlation with the surface excess at maximum persistence time.

Jan 1, 2006

By Raj K. Rajamani, Nikhil Dhawan

"Agglomeration has become common pre-treatment step to improve heap leach percolation thereby recovery, the fundamental understanding of the agglomeration process for crushed ores is still lacking. Agglomeration is required for ores which either contain excessive amounts of clay or an excessive quantity of fines generated during mining and crushing. Numerous experiments have been carried out in laboratory scale batch drums using different ores. It has been found out that experimental agglomerate size distributions exhibit self-preserving spectra. The self-preserving/ similarity distribution of the agglomerates is found to be independent of operating conditions and is uniquely determined by the size enlargement mechanism. An empirical model based on the absolute difference between moisture applied and optimum moisture was developed. This model uses self-preserving spectra in the form of a Rosin-Rammler distribution function to predict size distribution at different operating conditions. The empirical model was considerably easier to work with plant scale agglomeration drums. Also, a test known as dip test is developed which improves fundamental understanding of the agglomerate formation and growth mechanisms. This test also provides the progeny size distribution of each agglomerate size. The progeny size distribution was analyzed with a model that partitions the particles into a host and guest category. The ensuing partition coefficient identifies the behaviour of a particle as a host for other particles or a guest layering on other particles. This concept helps in identifying the type of agglomerate that would result for a specific feed size distribution. INTRODUCTIONHeap leaching is one of the hydrometallurgical processes that have served as a green and economically viable process for the treatment of low grade complex ores of copper, uranium, nickel, silver and gold (Dhawan et al., 2013). Heap leaching appears to be a favorable candidate for the least energy consuming process for low grade ores. In heap leach operations nowadays a pretreatment step known as crushed ore agglomeration has been implemented (Dhawan et al., 2013). A bed of agglomerates improves the uniform percolation of solution through the heaps of ore. Therefore, it was possible to treat wastes and mill tailings via agglomeration and heap leaching. Agglomeration pretreatment is required for ores which either contain excessive amounts of clay or an excessive quantity of fines generated during mining and crushing (Bouffard, 2005; Dhawan et al., 2013).While agglomeration has become common practice pretreatment step in heap leach operations, the fundamental understanding of the crushed ore agglomeration process is still lacking. The author reviewed publications up to 2012 on the crushed ore agglomeration process and did not come up with modeling studies on the topic (Dhawan et al., 2013). Some of the possible reasons can be the stochastic nature of the process, experimental difficulties, and lack of instrumentation for fundamental studies."

Jan 1, 2016

By D. M. Muir

The mineralogy of residues formed during the pressure acid leaching of arid region nickel laterite ore varies according to the salinity of the process water, alkali cation additives and the overall acid loading. In fresh water, hematite is the main iron-bearing leach residue component, together with amorphous silica and hydronium or sodium alunite/jarosite [(H3O,Na)(Fe,Al)3(SO4)2(OH)6]. As the process water salinity increases, or as NH4+ or K salts are added, alunite/jarosite is the kinetically favoured iron-bearing phase accompanied by an increase in acid consumption. The alunite/jarosite appears as two XRD distinct phases with different Fe:Al molar ratios. In weakly saline water, iron-rich alunite/jarosite slowly transforms to hematite and an aluminium-rich alunite/jarosite together with the release of acid. The addition of potassium salts forms a more stable alunite/jarosite whilst the addition of ammonium salts leads to greater transformation of alunite/jarosite at 250°C. Weakly saline process water gives enhanced nickel recoveries, whilst strongly saline process water gives lower nickel recoveries but higher soluble iron because of chloro-complexation. SEM and microprobe analysis shows very little nickel is associated with the alunite/jarosite and hematite phases. Nickel losses to the residues are attributed to adsorption on amorphous silica and to a lesser extent on alunite/jarosite.

Jan 1, 2006

By D. Virely, M. Gasc-Barbier, J. Guittard

"The valleys of the Dordogne and the Vézère (France) have been inhabited since prehistoric times, as evidenced by the famous site of Lascaux. A few miles away, the village of La Roque-Gageac is also a very popular tourist destination (about 1.5 million tourists per year): The village is sandwiched between a massive limestone cliff and the Dordogne river. The collapse of a cave roof high above the village in January 2010 led us to characterize instability together for the cave and the whole cliff and propose a adapted instrumentation to monitor the fracture openings in the rock mass that are linked to climatic variations. Measurements have been going on and been recorded for nearly 4 years. They point out the role of thermal stress fatigue in the breakdown of the rock mass. In this paper we describe the site under study, the instrumentation and its main results. INTRODUCTIONThe phenomenon of thermal fatigue has been very little studied as far as rocks are concerned, whereas it is rather well characterized for other types of materials: Elsevier published a journal dedicated to fatigue (International Journal of fatigue). In the case of rocks, thermal phenomena and their impacts on mechanical behavior have been analyzed from a micro-structural point of view, and it is now well-known that an increase in temperature causes a dilatation of crystals (Arnould et al., 2004; Berest & Weber, 1998). This dilatation may lead to the development of inter-granular traction and compression stresses, and if those stresses are greater than fracture strength, inter-granular and intra-granular cracks may take place. On the other hand, the fatigue phenomenon (cyclic repetition of a temperature variation which is less extreme than the one that may lead to this inter-granular or intra-granular fracture) is a phenomenon which has not been much studied.The principal studies on thermal fatigue on rocks come mainly from the field of geomorphology, particularly in connection with the analysis of the evolutions of past climate that can explain the present shapes of those landforms: those studies remained essentially qualitative and not quantitative. Le Ber & Oter Duthoit (1987) proposed a thermal and thermodynamic approach to analyse the disaggregation of rock masses. This analysis is dedicated to the study of paleoclimates and was implemented to better understand the formation of slope deposits in order to propose transfer models permitting the reconstruction of the climactic conditions contemporary to their appearance. Since deterioration in the cliff only appears after several cycles, it means that it is a gradual and irreversible deterioration which leads to an increase of the « disorder ». Seen from a macroscopic system point of view, this irreversible evolution is quantified by the internal creation of entropy."

Jan 1, 2015

By H. Abdollahi

Cold rolling is one of the most important techniques in metal forming since the cold rolling products are almost finished product, The product quality of this process is widely influenced by friction in the roll gap; therefore, controlling the friction and other parameters affecting the cold rolling is very important in order to have a product with high quality, Among the cold rolling parameters, the pressure distribution or friction hill within the roll gap is known as the most significant one, In this study, a new software (Matroll), is introduced which can determine the coefficient of friction (COF) and plot the friction hills for an industrial mill, Besides, based on rolling equations, it offers about 25 rolling parameters as outputs. To verify the software operation, the real industrial rolling data was used as inputs, The results (outputs) are in good agreements with the findings of other researchers, The COF values are very reasonable, The friction hill shows that COF is not constant over the whole arc of contact.

Jan 1, 2005

By B. Lafrance, C. J. Beaumont-Smith, L. R. Jones

"Abstract - The Burnt Timber gold deposit is located in the Paleoproterozoic Lynn Lake greenstone belt of the Trans-Hudson Orogen, Manitoba. The deposit occurs along the Johnson shear zone, and is hosted by enriched and depleted tholeiitic volcanic arc basalts cut by feldspar porphyry dikes. The Johnson shear zone is a regional, belt-parallel structure characterized by the intensification of the regional S2 foliation. At the Burnt Timber deposit, S2 is folded by centimeter- to meter-scale, Z-shaped, F3 chevron folds that have an axial planar S3 crenulation cleavage. Within the 20 to 30 m-wide core zone of the shear zone, S2 and F3 are transposed parallel to S3 and the volcanic rocks are strongly sheared parallel to S3. The presence of a steeply plunging stretching lineation, together with dextral shear sense indicators along both S2 and S3 on horizontal surfaces, suggest that the Johnson shear zone is a dextral transpression zone. Gold was introduced in pyritic, biotitic, and carbonatized mafic volcanic rocks along the core of the shear zone. Mylonitic mafic volcanic rocks contain localized high-grade zones (=10 g/t Au) that differ from wider carbonatized, low-grade zones (<3 g/t Au) by the presence of deformed gold-bearing quartz-pyrite veins. High-grade zones are also associated with swarms of quartz-pyrite veins that cut across sericitized and carbonatized feldspar porphyry dikes, which acted as brittle, competent bodies during shearing. Gold deposition in the high-grade zones was controlled by the channeling of hydrothermal fluid along the core of the shear zone during shearing of the volcanic rocks, and brittle fracturing of the porphyry dikes. Sommaire - Le gîte aurifère de Burnt Timber est situé dans la ceinture de roches vertes Paléoprotérozoïque de Lynn Lake dans l’orogène Trans-Hudsonien, au Manitoba. Ce gîte est situé le long de la zone de cisaillement de Johnson et est encaissé dans des basaltes tholéiitiques d’arc enrichis et appauvris recoupés par des dykes porphyriques. La zone de cisaillement de Johnson est une structure régionale parallèle à la ceinture de Lynn Lake caractérisée par une intensité accrue de la foliation régionale S2. Au gîte de Burnt Timber, S2 est affectée par un plissement F3 en chevrons en Z d’échelle centimétrique à métrique associé à un clivage de crénulation de plan axial S3. Dans la zone centrale de 20 à 30 m de largeur au sein de la zone de cisaillement, S2 et F3 sont transposés parallèlement à S3 et les roches volcaniques sont fortement cisaillées le long de S3. La présence conjointe d’une linéation d’étirement à forte plongée et d’indicateurs cinématiques dextres sur les surfaces horizontales S2 et S3 suggère que la zone de cisaillement de Johnson est une zone transpressive dextre. L’or a été mis en place dans des volcanites mafiques altérées en pyrite, en biotite, et en carbonate au coeur de la zone de cisaillement. Les roches volcaniques mylonitiques présentent des zones aurifères locales à haute teneur (=10 g/t Au) qui diffèrent des zones à basse teneur (<3 g/t Au) par la présence de veines de quartz et de pyrite aurifère. Des zones à haute teneur associées à des essaims de veinules de quartz et de pyrite sont aussi notées dans des dykes porphyriques à plagioclase altérés en séricite et en carbonates; ces dykes se sont comportés comme des corps compétents durant le cisaillement. La déposition de l’or dans le zones à haute teneur a été contrôlée par la circulation du fluide hydrothermal au coeur de la zone de cisaillement durant la déformation des roches volcaniques et la fracturation des dykes porphyriques."

Jan 1, 2006

By H. J. McQueen

Friction stir welding (FSW) generates complex microstructures in the nugget and thermomechamically affected zones (TMAZ) that have led to diverse explanations. However, consideration as an extension of microstructure development in piercing/extrusion can lead to a better understanding of flow patterns and microstructures during FSW. Furthermore, the intense strains in the nugget/TMAZ can be interpreted by comparison with ultra-high strains in torsion that exhibit dynamic recovery as extending into regions with high angle boundaries strongly serrated with spacing near the subgrain size defined by the high temperature. The subgrain diameter and extrusion pressure have been shown to be dependent on the Zener-Hollomon parameter Z (=t exp(Q/RT), Q activation energy, R gas constant) combining temperature T and strain rate E in the same mariner as for torsion and compression. Moreover, such tests exhibited steady state stress os above a certain strain Es (rising as Z increases) in which T, , subgrain diameter and dislocation spacing remain constant. Due to the subgrain boundaries (SGB, low angle <5°, i.e.,LAB), continually rearranging by migration, decomposition and reformation, the subgrains remain equiaxed in elongating grains, whose boundaries (GB) become serrated as they migrate to absorb SGB. As confirmed by straining in torsion at constant T and Z. , more subgrains bordering the greater GB area have several high-angle facets (HAB) ; these small cellular regions with a mixture of HAB and LAB facets are designated HAB-subgrains. As serrations in neighboring grain boundaries impinge, the grains pinch off becoming shorter; this occurs at higher strains as subgrain size decreases with rising Z. The pinching-off makes the neighbors thicker so the grains never become thinner than about two subgrain diameters. In conjunction with such geometric dynamic recrystallization (gDRX), GB&apos;s undergo a net migration into grains with denser substructure, enlarging those with larger subgrains. Consequently a better name has been proposed: grain dimensioning dynamic recovery (gDRV).

Jan 1, 2007