Search Documents

By Schoeman L., K. C. Sole

Evaluation and measurement of the influence of changes in conditions and electrolyte composition during early stages of a growing metal electrodeposit are crucial to predict changes in developing morphology. A galvanodynamic polarization technique was developed to reliably measure overpotentials for nickel electrodeposition from sulfate electrolyte. The validity of these polarization parameters as indicators of the relationships between changes in the electrolyte and resulting deposit morphology was evaluated for electrolytes of varying composition. Findings indicate that nucleation and plating overpotentials measured by the described technique can be used as indicative tools for monitoring, evaluating and ultimately improving control of the electrodeposition of nickel from sulfate electrolytes. The results predict that nickel deposits of desirable quality and morphology are obtained when plating overpotentials are higher than 700 mV vs. Ag/AgCl and nucleation overpotential is less negative than plating overpotential.

Jan 1, 2017

By Oberlando Gonzalez, Claudia Serna, Andrea Alzate, Esperanza López, Maria Holuszko

This paper presents a systematic approach on gold recovery from electronic waste (e-waste) using ammonium persulfate. This process was developed as a response to the lack of hydrometallurgical systems capable of separating gold from its metallic substrate without material grinding, with minimum formation of pollutants, and achieving a lower reaction time. Computer memory boards, electronic processors and electronic pins and contacts were analyzed to determinate base metals (Ni, Fe, Cu) and gold (Au) using microwave plasma atomic emission spectroscopy (MP-AES). An aqueous commercial grade ammonium persulfate with oxygen and pressure was used to produce the persulfate anion (S2O82-) and the oxidative sulfate ion (SO42-), which partially oxidized and leached the base metals breaking the Au-Ni-Fe-Cu bonds and allowing gold to be recovered in its original non-leaching state. The influence of the oxidative parameters was evaluated using full factorial (FF) and central composite designs (CCD) with response surface methodology (RSM) and first and second order models were developed. Using RSM allowed to obtain a faster recovery of gold, minimizing the agent consumption. The findings presented suggest that optimized quantities of ammonium persulfate, oxygen, pressure, temperature and liquid solid ratio could be used for selective oxidization of the base metals and to extract more than 96% of gold from e-waste.

Jan 1, 2017

By C. Ayora

The Iberian Pyrite Belt (SW Spain and Portugal) contains one of the largest reserves of pyrite in the world with mining activities dating back to prehistoric times. About one hundred abandoned mine wastes and galleries release a huge acidity and metal load to the Tinto and Odiel rivers. Once the mining activity is over, polluting discharges can persists for decades or even centuries with no specific responsible entity. In-situ passive remediation technologies are especially suitable for these orphan sites. The concept is to insert a reactive porous material in the natural flow path of contaminated surface and ground waters, and it is implemented through infiltration ponds and reactive barriers, respectively. Calcium carbonate pea-size gravel is the common alkalinity supplier to neutralize acidity and precipitate metals. These remediation systems have been traditionally implemented in coal mines. However, the acid drainages from the Iberian Pyrite Belt contain metal concentrations one to two orders of magnitude higher than those from coal mines and require special designs to avoid quick clogging or passivation (coating) of the grains of reactive material. To overcome these problems, a Dispersed Alkaline Substrate (DAS) mixed from fine-grained limestone sand and a coarse inert matrix (e.g. wood chips) was developed. The small grains provide a large reactive surface and dissolve almost completely before the growing layer of precipitates passivates the substrate. The high porosity and the dispersion of nuclei for precipitation on the inert surfaces retard clogging. However, limestone dissolution only raises pH to values around 6.5, which is sufficient to precipitate the hydroxides of trivalent metals (Al, Fe), but it is not alkaline enough to remove divalent metals. Magnesium oxide, which hydrates to Mg hydroxide upon contact with water, buffers the solution pH between 8.5 and 10. A DAS system replacing limestone with caustic magnesium oxide has been tested to be very efficient to remove divalent metals (Zn, Cd, Mn, Cu, Co, Ni, Pb) from drainage previously treated with limestone.

Aug 1, 2013

By Maria D. Mastalerz, Wei Wang, Maria E. Holuszko, Amit Kumar

In this study, the micro-FTIR analysis was used to investigate in-situ surface properties of coal and its components (macerals) and these were directly correlated to the coal hydrophobicity as measured by the contact angle before and after reagent addition to understand the suitability of the reagent for flotation. The micro-FTIR technique can provide a semi-quantitative analysis of the chemical functional groups on coal surface, exactly where the contact angle is being measured. Selected functional groups and their ratios that provide information about aromaticity, the contribution of oxygenated groups, and aliphaticity are used to evaluate the reactivity between reagents and various coal components. The observations made in relation to the susceptibility of some reagents towards certain coal components should lead the way to a smarter way of using process design in terms of reagents selection for coal flotation.

Jan 1, 2017

By Pingchao Ke, Zhihong Liu

Fe(III)-As(V) precipitates were synthesized from the Fe(II)-As(V)-SO42--H2O system at 90°C in initial Fe(II)/As(V) molar ratios of 4.0 and 5.0, respectively. The synthesis were carried out by introducing oxygen gas into the system to oxidize Fe(II) ions into Fe (III) ions, and at the same time, adding aqueous sodium carbonate solution into the system to neutralize the acid released by the hydrolysis reactions, with the purpose of keeping the pH constant at 1.5±0.05. The precipitates obtained were characterized by XRD, chemical composition analysis, SEM, XPS, and Raman spectrum. The results indicated that the particles in the precipitates were in the morphology of irregular aggregation with their sizes in the range of about 1–4 µm. The precipitates consisted of scorodite, ferric arsenate and amorphous hydrated ferric oxide, of which amorphous hydrated ferric oxide formulated as Fe(OH)x(SO42-)y. The characteristic XPS peaks of Fe-AsO43- and Fe-O in the precipitates located at 711.8 and 713.3 eV, separately, and the existence of amorphous hydrated ferric oxide led to two series of shake off lines developed over the end of high binding energy of Fe2p XPS. The precipitates were stable in TCLP tests at pH 4.93 for 60 hours with the arsenic concentrations in the leaching solutions being 0.27 mg/L and 0.59 mg/L for the precipitates prepared in the initial Fe(II)/As(V) molar ratios of 4.0 and 5.0, respectively. The tests for the long-term stability of the precipitates were carried out by leaching them for 40 days at 25°C under various media in the pH range from 9.50 to 10.57, and the results showed that the precipitates synthesized in this study were much more stable than those by previous researchers.

Jan 1, 2017

By S. W. Asihene, K. Osseo-Asare

The thermodynamic data necessary for the quantitative treatment of Metal-NH3- H2O systems at elevated temperatures are lacking in the literature. As a result discussions of the chemical basis of high temperature processes, such as leaching and hydrogen reduction, have tended to rely on low temperature thermodynamic data. In this paper a critical review is presented of the available high temperature data for metal ammine formation in aqueous systems, and methods are suggested to enable extrapolation of elevated temperature stability constants from low temperature thermodynamic data. Predictions of the Van't Hoff Lsobar, the simple cation Correspondence Principle (whereby metal ammine complexes are treated as simple cations) and Helgeson's Electrostatic-Nonelectrostatic Model are compared with the available high temperature stability constants for nickel ammines. Up to 80 °C all three estimation methods yield results which are in agreement with experimental data. However, serious deviations occur at higher temperatures; the various models overestimate the stability constants in the order Van't Hoff Isobar > electrostatic-nonelectrostatic model > simple cation Correspondence Principle. Using the experimental nickel data as a basis, a method is presented which permits reasonable estimates to be made of the stability constants of metal ammine complexes for temperatures above 80 °C.

Jan 1, 2004

By Derek Perkins

"Brenda Mines Ltd. operates an open pit copper and molybdenum mine located in south central British Columbia. The main economic mineralization is chalcopyrite and molybdenite. Pyrite, galena and sphalerite are also present in varying quantities. The mineralization is present in small veins and fractures in a porphyritic quartz diorite host rock.The mill processes approximately 30,000 tonnes of ore daily. The ore is crushed in three stages and then ground in conventional rod mill - ball mill circuits with cyclone classification. The cyclone overflow is fed to the bulk flotation circuit as a pulp with a density of 50% solids. The particle size distribution is approximately 35% plus 65 mesh. Bulk rougher and cleaning flotation produce a concentrate grading approximately 20% copper and 4% molybdenum. This concentrate is fed to the separation circuit, where the copper is depressed with sodium hydrosulphide and the molybdenum is floated. These products are further ground and then upgraded by column flotation. The molybdenum concentrate is pumped to the leach plant to reduce concentration of lead and copper. It is then washed, filtered, dried and packed for shipment to Europe. The copper concentrate is filtered, dried and subsequently shipped to Japan.Prior to November 1977, the mill flotation control was carried out by the assay laboratory using a Philips PW 1540 sequential x-ray spectrograph. The assay set consisted of twelve samples, analysed on a two hourly basis for copper, molybdenum, lead, iron and silica.In order to provide elemental composition information on a much shorter sampling interval and to produce speedier control analysis for automating process control, an Applied Research Laboratories PCXQ on stream analyser was purchased. The installation of this analyser, reduced the turnaround time of the control analyses from (2) hours to (20) minutes. At Brenda, the following assays are used in the mill control strategies."

Jan 1, 1989

By A. Carbonari

In order to gain competitiveness and compete at a global level, construction companies should improve their efficiency. The problem is even more relevant in the construction field, whose work processes find it hard to evolve towards new automated methods and techniques in the management field. For that reason, this paper suggests how construction companies could apply new technologies to implement automated management of environmental hazards. Based on a survey regarding the environmental risks presently experienced in construction sites, noise and dust were considered two of the main hazards. So in this paper a networked system for real time remote monitoring of the spatial distribution of dust in construction sites was developed. Such a system would relieve builders from the commitment of on-site surveys, allowing for a continuous monitoring of the site conditions and of the real exposure of each worker and pass-by to the pollutants generated by construction works. The main system requirements considered are: easy to deploy, reliable, as accurate as needed to be able to send real-time warnings and store a good estimation of the real exposure to which involved people have been subject to. So far the research produced a prototypical hardware for dust monitoring made up of wireless sensors which can be easily deployed on site. The sensors were calibrated by means of laboratory tests, where their measurements were compared with those collected by means of highly accurate instruments, which were taken as a reference. Thanks to these experiments, calibration curves for the sensors were worked out, showing also the measurement range of the sensors.

Aug 1, 2013

By G. T. Lapidus, R. Zárate-Gutiérrez

Selective leaching of lead from a Pb-Ag-Zn concentrate with hydrogen peroxide in citrate solutions was studied at room temperature. Leaching tests were performed, varying the H2O2 concentration and the solid-liquid ratio, holding the solution pH constant at 7, and the citrate concentration at 1 M. Lead extractions of 100 % were achieved with 4 and 5 times the stoichiometric quantity needed to form elemental sulfur, with only a small amount of metal impurities dissolved (Ag, Zn and Fe). The lead solubility limit at those conditions was found to be ~21 g L-1. X-ray diffraction analyses of the leach residues were free of galena (PbS), while other metal sulfides, such as sphalerite (ZnS), chalcopyrite (CuFeS2) and pyrite (FeS2), were basically unaffected.

Jan 1, 2014

By A. W. Lovett

"THE last two years have been years of recession or, perhaps, years of marking time, depending upon whether the observer is a pessimist or an optimist. There has been a slackening in the industrial tempo that has been reflected in many ways in the national economy. As one of the chief barometers of economic health, the consumption and supply of energy reflect this slowing up.These same two years have also seen significant changes in the relation between the sources of energy. In periods of declining demand, it has happened in the past that coal, as the basic or residual source of energy, has shown the effects to a greater extent than the other energies. In these two years, however, in addition to this usual effect, there has been the acceleration in the Joss of market to diesels in the railway consumption category and the continuing decline in domestic consumption. The story of these years is presented in the statistical tables that form the foundation of this paper. Statistics, particularly in the form of tables, are rather dry and are sometimes difficult to follow but the overall developments are illustrated by graphs which present a more striking picture."

Jan 1, 1959

By Joachim von Scheele

An oxyfuel-based technology - OXYFINES - has been introduced for in-plant recycling. It provides fines, dust, sludge (without any drying-step) and other by-products arising in the steel and metal producing industries to be recycled directly back into existing processes or a separate unit on-site. Results from full-scale installation (20,000 tpy) for dust treatment, full-scale and pilot-scale trials with dry and wet materials in the steel and ferroalloy industries are presented. Processing rates at 3.5 t/h have been demonstrated. The product is agglomerates or lumpy pieces, the latter if the product has passed an all-liquid stage and thereafter been crushed. The technology does not only provide a solution to the problems connected to dust and sludge generated in metal production. It also turns these materials into a low-cost raw material useful for the production in question, thus replacing part of the raw material input in electric arc furnaces, blast furnaces, etc. Elements harmful to re-use of the processed dust or sludge, e.g., zinc and alkaline components in steel production, are removed as secondary dust, and material yield of main components for re-use is very high, about 98%. The paper reviews the concept, the results obtained and its status; its use for sludge recycling is emphasized.

Jan 1, 2004

By H. J. McQueen

The modeling of the extrusion of 6061 alloy and its composites with 10 to 20 vol% Al203 or SiC by two techniques. The uniaxial finite element method FEM (DEFORM" ) provided force-stroke curves and temperature rise over the range 450-500 °C, 2.6-5mm/s and extrusion ratios of 31 and 64. The traditional technique considers ideal work and redundant work as well as friction and uses average temperatures and strain rates. The two techniques are used to clarify each other and to extend the analysis to 400 and 350 °C. The calculated efficiencies are compared to measured values in extrusion trials and to values derived for 7075 extrusion analyses. The analyses are based on constitutive equations determined by torsion testing tests.

Jan 1, 2004

By Apoorva Bajaj

Iron ore mines of Steel Authority of India Limited (SAIL) have to comply with strict chemical composition norms laid down for iron ore lumps supplied to its steel plants. This requires a careful planning of the overall ore excavation operation. In general terms, the problem can be stated as: Given the chemical composition of ore for all excavation sites, excavation capacity of each shovel, distance of each excavation site from the crushing plant and the number of dumpers available for transport of the ore, find out the percentage of ore to be excavated from each excavation site such that the production rate is maximized and the chemical composition norm is satisfied to the best possible extent. This paper presents an approach to solve this problem using Branch and Bound method. The specification for r.o.m. quality has been modified by incorporating a new parameter, ?Al2O3 / SiO2? ratio, which has a significant effect on the performance of iron blast furnace.

Oct 1, 2009

By L. M. Ame, W. D. Harwood

"This paper outlines a management philosophy aimed at promoting employee involvement, quality and process improvement at Inco 's Thompson operations. It describes the use of statistical process control techniques, lessons learned and examples of progress.IntroductionThis paper provides an overview of the Manitoba Division's performance through the promotion of greater employee involvement, quality and process improvement. Having learned from other practitioners o f quality management, the Manitoba Division believes its experiences are applicable to all mining and other businesses.The Thompson operation consists of two underground mines, an open pit, a mill, a smelter and an electrolytic refinery. The workforce consists of 2000 members. The main products are electrolytic nickel slab and proprietary nickel rounds. Production levels are currently at capacity in response to heavy market demand.Paralleling much of the mining industry the corporation was faced with six years of decreasing nickel prices (Fig. I). Inco Limited survived by focusing on productivity and cost improvement. Manitoba Division productivity improved 32070 over three years beginning in 1982-the worst financial year in the company's history (Fig. 2). A real unit cost reduction of 20%, net of inflation, was also achieved (Fig . 3)."

Jan 1, 1990

By P. Lostritto, G. E. Agar, G. Labonte, M. Cherevaty

"A locked cycle flotation test was done on a sample from the ovoid portion of the Voisey 's Bay copper-nickel sulphide ore. The chemical conditions for this test were generated by prior independent testing. In this test work the time in each of the five separation stages was optimized prior to executing the locked cycle test. A numerical simulation of the continuous circuit material balance was done prior to the locked cycle test. The test results were not fully satisfactory because the flotation of pyrrhotite in the bulk rougher and cleaner stages was not consistent. The preliminary indication was that the samples had oxidized to varying degrees during storage.INTRODUCTIONINCO has performed batch laboratory flotation testing on ore from Voisey's Bay which is a mixture of chalcopyrite, pentlandite and pyrrhotite. Earlier, Lakefield Research was contracted by Diamond Field Resources to test the ""flotability"" of the ore, which included a pilot plant trial. INCO's J. Roy Gordon Research Laboratory has repeated many of the batch tests that Lakefield did to verify their results. Based on their own work, INCO has modified the circuit proposed by Lakefield Research. The modified circuit is based on batch test work, but no locked cycle test (LCT) was done. It is believed that this circuit will produce a copper concentrate at 29-30% copper and a primary nickel concentrate at 15-20% with recoveries of 80% or above.For several years the University of Toronto has been working with INCO to provide ""hands on"" experience for undergraduate students as an Industrial Research Project (IRP). This year, the objective for IRP was to optimize the time for each of the five separation stages for the Voisey's Bay ore then to numerically and experimentally simulate the material balance for a continuous circuit."

Jan 1, 1998

By S. C. Livanou, S. P. Tampouris, E. N. Zevgolis

In ferronickel (Fe-Ni) production from oxidized nickeliferous ores, mechanical losses of ferronickel in the slag are reduced by magnetic separation. Slag from the electric furnaces (E/Fs) contains 0.16% Ni. Its magnetic separation gave a pre-concentrate with 0.76% Ni, weighing approximately 6.5% of the feed. Nickel recovery was 29.7%. This pre-concentrate was then treated in a second (concentration) plant. Concentration treatment involves screening, crushing and magnetic separation. A pre-concentrate with 0.76% Ni gave a magnetic concentrate with 2.58% Ni and a non¬magnetic part with 0.35% Ni. Smelting of the non-magnetic part without the addition of a reduction agent in a laboratory electric arc furnace, gave a ferronickel alloy with approximately 20% Ni and a slag with 0.16% Ni.

Jan 1, 2005

By A. Hosseini

Full-scale rupture tests were conducted on 508 mm (20 in) diameter API X-60 5.7 mm wall thickness pipes containing either axial semi-elliptical cracks or simulated corrosion defects with equivalent depths ranging from 20 to 60 percent thickness. In the case of the cracks, the failure pressures were predicted with reasonable accuracy when considering a level 3 failure assessment diagram (FAD) procedure based on API 579, as compared to level 2 FAD, since the mechanical properties were known. In both cases, the accuracy improved for shallower cracks. Considering simulated corrosion defects, the RSTRENG approach provided more reliable results on predicting the collapse pressure. For a similar depth and profile, the cracked pipes failed at a lower pressure than those containing simulated corrosion defects of equivalent depth.

Jan 1, 2010

By Magdy Ibrahim

Detailed as-built project schedules are necessary to close out construction projects, benchmarking, forecasting, dispute resolution, and improving cost estimates of future projects. Manual procedures for developments of as-built documentation is time consuming, involves numerous interfaces and human interventions. This paper presents computational framework that encompasses automated site data acquisition and generates schedule updates utilizing commercially available project scheduling software. The work is carried out collaboratively with a Hydro Quebec team. The site data is captured employing mobile computing using iPad® type computers and Wi-Fi. The information is directly compiled in a centralized database server. The synchronization tool is a bi-directional application and is used on servers to communicate with iPad® computers deployed onsite. The captured data is stored in Microsoft SQL® relation database that consists of 63 entities. Computer software application has been developed in Microsoft Visual Basic® (vb.net) environment for extracting the collected site data, linking the database to the as planned schedule, and generating the actual, also known as as-built schedule. The development can be utilized in automated progress reporting, evaluating future bids, generating master schedules and a wide range of efficient EVM applications.

Aug 1, 2013

By L. J. Cabri

A gold sample assaying 11.4 g Ault was selected for this study. Approximately 99% of the gold in this sample occurs as discrete gold minerals; the balance occurring as invisible gold in pyrite (determined by SIMS analysis). The sample was coarsely ground and sieved, yielding -38, 17, 22 and 22 wt.% in the -400+160 um, -160+80 um, -80+40 µm and -40 µm size fractions. Assays of the size fractions gave a gold distribution of -32, 20, 21, and 27% respectively. Processing with the hydroseparator (model HS-02) gave two tailings products and one concentrate from each size fraction. Assays of the concentrate from each size fraction gave gold recoveries of -7, 7, 24, 19%, respectively. Polished sections were prepared from each hydroseparation product and studied by image analysis to automatically search for gold minerals. Calculations were done using the surface area of the grains of gold minerals found on the polished sections.

Jan 1, 2005

By P. M. Tyroler, W. J. Thoburn, M. R. Alberty

"An initial test of this unique application demonstrated that hot gunned refractory would adhere satisfactorily. Subsequently, it was found that the proportion of material sticking during application increased with increased vessel temperature and when a mix containing pitch was used. About 75 per cent of the latter type adhered when it was applied at 1600°C.TBRC availability increased from an historical average of 62.5 per cent to 64.7 per cent during four campaigns when hot gunning was routinely practiced. Refractory cost was about 20 per cent less than that anticipated without gunning. Average parameters per campaign with gunning ranged as follows: 90 to 108 heats, 10 to 37 applications and 1.4 to 2. 7 hours per application. Prior to gunning, the average number of heats per campaign was 73.IntroductionThe Top Blown Rotary Converter process at Inco's Copper Cliff Nickel Refinery converts copper-nickel-sulphur concentrates to a material suitable for carbonyl refining (1),(2).Operating conditions are particularly hard on refractory. Batch cycles finish at temperatures up to 1650°C, with occasional excursions over 1700°C. New heats are then usually initiated immediately and the refractory is subjected to intense thermal shock from the cold feed. Temperature cycles are also introduced three to four times during a heat when the process is interrupted for scrap charging, temperature measurement or sampling.Abrasion wear results from rotation of the converters at speeds up to 15 RPM and from agitation of the bath with supersonic-velocity oxygen. Mechanical damage also occurs when chunks of scrap or solid matte are processed. Chemical corrosion is also present, as we know from our own laboratory work(2) and reports of operations elsewhere. As a consequence, refractory material and installation form a very large proportion of the converter plant costs. Equally important is the loss of converter availability during rebricking; this significantly reduces plant capacity."

Jan 1, 1981