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By D. S. Salonine

Aluminum alloys are widely used in modern industry. Tubes and hollow shapes give great opportunities for structural purposes as well as fluid transport due to their stiffness and lightness, Extrusions on a mandrel or through a bridge die, that requires splitting of the billet with re-welding, produce hollow shapes with varied contours, fins and multiple cavities. Moving and stationary mandrels, mandrel lubrication, tooling for ribbed-tube heat exchangers, and for drilling pipes are considered. Bridge dies can be classified by the bridge position relative to the die face, by mandrel support structure, and by assembly type, The main parameters influencing the quality of the die-welded seams are considered, The difficulties of extruding various alloys through bridge dies are discussed in terms of metallurgical factors, Some approaches to the calculation of the stresses in a bridge are presented.

Jan 1, 2005

By T. Y. Chong, J. A. Folinsbee

Since milling began in 1909, the PJV Dome mill has been expanded several times, to the current throughput of 11,500 tonnes per day. PJV recovers free gold using crushing and grinding followed by gravity concentration. The remaining gold in the gravity tails is recovered by cyanide leaching followed by Carbon-In -Pulp processing. Prior to 1993, cyanide tailings were impounded in the tailings pond where cyanide was allowed to degrade naturally. Effluent was discharged seasonally during the summer and early autumn to maintain the water balance. In 1993, an Effluent Treatment Plant (ETP) was designed and constructed for the purpose of removing dissolved metals and suspended solids. In 1997, an INCO SO2/Air cyanide destruction process was added to the ETP. Even though the ETP was successful in meeting the cyanide, metals and total suspended solids (TSS) discharge limits, often the treated effluent failed to pass toxicity tests. Following successful laboratory and plant scale testing, the addition of the chelant EDTA (ethylene diamine-tetra-acetic-acid) was commenced in the 1999 operating season. To date, discharged effluent has passed all toxicity tests. This paper describes the evolution of the ETP from its early conception to the various phases of upgrade needed to meet the MISA discharge limits.

Jan 1, 2005

By Andrew Barnes

The adsorption capacity of peat collected from a proposed mine development in northern Sweden has been determined using laboratory column experiments in which peat was irrigated with a simulated (acidic) waste rock dump leachate. The simulated leachate was made using a hydrogen peroxide leach of composite waste rock from the proposed mine development. The waste rock samples were composited in proportion to their predicted extractable tonnage for the mine development in order to generate a more representative leachate solution for the waste rock facility. As expected the test revealed that the peat material shows a very high affinity for attenuation with greater than 70% of Co, 90% of Ni and 95% of Cu removed from influent solutions through the majority of the tests demonstrating the potential benefits in mine water treatment. In contrast, it was found that Fe is initially released from the peat at concentrations up to 100 mg/L and can mean potential problems for the water released depending on the receiving environment. The exact mechanisms for Fe release is uncertain, though it is suspected that ion exchange / competitive desorption is responsible. Inspection of the laboratory results and drainage data from the natural peat wetland receiving drainage during overburden prestriping and mine development at the mine site are comparable, confirm the validity of the experiments, and further emphasize the potential for future use of pre-stripped peat material in managing water quality.

Aug 1, 2013

By Georgy A. Cherkashov, Andrey V. Efimov, Yury S. Borodaev, Nadezhda N. Mozgova, Sergey G. Krasnov, Tamara V. Stepanova, Alexander M. Ashadze

"Abstract - A horizontal mineralogical-geochemical ore zonation with a southeast to northwest trending succession of Cu and Fe (Zn) main zones has been discovered in the Logatchev hydrothermal field (14°45??N Mid-Atlantic Ridge). The major minerals are pyrite, chalcopyrite, bornite, isocubanite, digenite and chalcocite. Zn-sulfide, marcasite and covellite are less abundant. Rare minerals are native copper, zincian copper and cobalt pentlandite (first found in oceanic massive sulfides), Cu and Cu-Co-bearing Fe-disulfides. Two groups of the main sulfide assemblages with different copper contents are recognized: Group I comprises assemblages with primary sulfides (isocubanite, chalcopyrite, pyrite and Zn-sulfide; Cu up to 35 wt% in Cu-bearing minerals); Group II contains assemblages with secondary Cu-rich sulfides (bornite, digenite, chalcocite; Cu ~60 wt%) as well as rare minerals (cobalt pentlandite, native copper and zincian copper). The assemblages of Group I formed at a temperature of about 300°C; the sulfur fugacity (log fs2 atm) at 300°C is probably 9.9. Relations between minerals of this group are contradictory, attributed to non-equilibrium environments, and no unified sequence of crystallization of minerals has been determined. Minerals of Group II replace, rim or cross the assemblages of Group I. Group II minerals crystallized in a distinct sequence (cobalt pentlandite-bornite-digenite- chalcocite-native copper), with increasing copper content from the start to the end of the depositional sequence. This may correspond to pH from 7 to 8 near Eh = -0.2 at 250°C. Minerals of this group were generally formed under hypergene alteration processes. Compositions of ore minerals were studied by means of electron microprobe analysis (EMPA) (150 analyses). Narrow composition fields were revealed in all main sulfides, which comprised known experimental data. ZnS contains 6.0 to 28.0 mol.% FeS, which is close to data known for other hydrothermal massive sulfides from the Mid-Atlantic Ridge (MAR). A common admixture in ZnS is Cu (0.16 to 1.32 wt%). Rare grains of unusual anisotropic Fe-disulfides, (Fe0.95Cu0.05)S2 and Cu(Fe,Co)9S20, were found among the ore minerals."

Jan 1, 1999

By S. M. Bradshaw, E. Charikinya

"Microwave induced cracks have the potential to enhance metal recovery from coarse sphalerite particles in heap leaching operations by creating new crack surface areas for lixiviant and enhancing value mineral exposure. The mode of fracture and the extent of mineral exposure due to microwave induced cracks have not yet been investigated. The objective of this study was to determine the extent of particle damage and mineral exposure in microwave treated particles. This was done using X-ray computed tomography (XCT) and image analysis techniques. XCT analysis was conducted on small (–5+4.75 mm), medium (–16+9.5 mm), and large (–25+19 mm) sphalerite ore particles before and after microwave treatment (MT). Geometrical properties, such as volume and surface area of each mineral phase in each particle was determined from the XCT reconstructed images using VGStudioMax image analysis software. These geometrical properties were used to calculate the interfacial areas of sulphide mineral grains in microwave treated particles before and after MT. The ratio of specific interfacial area after MT to specific interfacial area before treatment was used as an indicator of the degree of preferential grain boundary fracture. The results showed significant grain boundary fracture after MT at all sizes. For small sized particles, about 31% of the interfacial area was lost compared to 23 and 16% for medium and large particles, respectively. The results also showed an increase in the degree of mineral grain exposure of 28, 26, and 15% for small, medium, and large particles, respectively, after MT. These results provide experimental evidence supporting improved mineral exposure due to MT. INTRODUCTIONFor some years it has been suggested that microwave treatment (MT) of ores might result in preferential grain boundary fracture that would have benefits such as improved grain exposure and particle weakening. (Kingman, 2006). Most of the experimental work investigating the application of microwaves to mineral processing flow sheets has focused on assessing the benefits of applying microwave technology to flow sheets consisting of size reduction and mechanical flotation cells (Kingman et al., 2004). Experimental studies have shown that coarse crushing during tertiary grinding of microwave treated ore resulted in a better liberated coarser flotation feed (Scott, Bradshaw, & Eksteen, 2008). It has been suggested that improved liberation in milled flotation feed, was due to the presence of grain boundary fracture in microwave treated particles. However, this improvement in coarse particle liberation does not necessarily translate to a significant improvement in downstream flotation recovery (Kobusheshe, 2010). This is as a result of the size limit to the flotation of coarse material, due to detachment forces acting on particle-bubble aggregates, which increase as the particle size increases (Jameson, 2012). Current conventional, mechanically agitated flotation cells are not designed to float coarse material (Jameson, 2012). Hence it has been difficult to show the downstream processing benefits of applying microwaves to ores processed by comminution followed by flotation (Kobusheshe, 2010). It is clear from investigations carried out so far that inappropriate downstream exploitation of microwave treated ore would fail to realise a meaningful process benefit (Kobusheshe, 2010; Ali & Bradshaw, 2011)."

Jan 1, 2016

By H. Itou

A mechanism of scorodite formation at ambient pressure was investigated using transmission electron microscopy (TEM). Several types of iron arsenate were obtained from Fe/As solutions (Fe/As = 1.0 and 1.5) at pH values of 1.0, 1.25 and 1.5 at 95°C. Amorphous FeAsO4.xH2O was precipitated from solutions having a higher mole ratio of Fe/As at pH l.5, even after 9 hours. A few micron sized particles were observed by SEM, but these proved to be agglomerates of 10-50 nm amorphous FeAsarxH2O particles when observed by TEM. This means that supersaturation of the solution causes the acceleration of nucleation of iron arsenate hydrate. Crystalline scorodite was obtained from a solution in which the Fe/As mole ratio was unity, at pH l.0 and pH 1.5, after 3 hours. Almond-type crystalline scorodite particles were observed by TEM and most of them showed high crystallinity. The addition of scorodite seed material enhanced the crystallization. Amorphous FeAsO4.xH2O, however, was observed at the surface of the seeds during the early stages of precipitation. It is postulated that crystalline scorodite is not directly precipitated even on crystalline scorodite seeds, but requires a certain time to crystallize on the seed material.

Jan 1, 2006

By W. T. Irvine

"The Britannia ore deposits are approximately 20 miles north of Vancouver; and occur in a prominent ridge facing Howe sound. A large ironstained bluff first attracted the serious attention of early prospectors. This; upon investigation; proved to be the outcrop of a large copper orebody. The highest outcrops were 4; 300 feet above sea-level.The original discovery was made in 1888, but no real development took place until 1902. The first mining was done in what came to be known as the Jane orebody, and some production was obtained from this in 1905. Underground exploration led to the discovery of several other orebodies. The first main adit, the 1,050-foot level, was driven to tap the ore at an elevation of 3,300 feet above sea-level. During succeeding years, however, long adits were driven from points lower down on the mountain side. These, with connecting shafts, followed the ore to horizons well below sea-level. The lowest working has now reached to 880 feet below sea-level. The property has been in almost continuous operation since its original exploitation in 1905. Until the end of 1944, 732,414,420 pounds of copper and 261,125 ounces of gold had been produced from the mine."

Jan 1, 1954

By Bob A. Hamaguchi

The Trojan Tailings Pond at Highland Valley Copper developed in only 15 years from a biologically inactive water body into a productive lake with a well established aquatic ecosystem. This process was assisted by a few simple and inexpensive procedures including fertilization and introduction of essential organisms. The success at the Trojan Pond has encouraged the use of similar techniques in other water bodies on the mine site. This paper details: ??The history, water quality and thermal behavior of Trojan Tailings Pond ?Techniques used in fertilization; introduction of micro-flora (algae etc.), large aquatic plants, zooplankton and invertebrates ??Selection and sources of suitable transplant materials ??Rate and extent of vegetation establishment ??Biomass production ??Rates of organic sediment accumulation over tailings ??Bacterial activity in the sediments ??Improved water quality through the bioaccumulation of aqueous metals in plants and the subsequent bacterial binding or precipitation of that metal during decomposition in the tailings sediment. Robert A. Hamaguchi graduated with a Mining Diploma from the British Columbia Institute of Technology in 1971, followed with a Bachelor of Applied Science in Mineral Engineering from the University of British Columbia in 1975. Since graduation, he has worked for numerous open pit mining operations throughout British Columbia. In 1991, he joined Highland Valley Copper working as an Environmental Engineer responsible for government liaison, reclamation, decommissioning and other environmental duties. Heather M. Larratt graduated from the University of Calgary in 1978 with a B.Sc. in Environmental Biology (First Class Honors). She has provided drinking water management and reservoir design for numerous cities and irrigation districts in British Columbia for 20 years. Heather has also worked for 12 years in reclamation of mine water, including passive SRB water treatment systems. Mark R. Freberg joined Highland Valley Copper in 1991 after working at number of mining operations in British Columbia and the Northwest Territories. He graduated in 1979 with a Bachelor of Applied Science degree in Mineral Engineering from the University of British Columbia.

May 1, 2001

By J. P. Nicoud

"The Frog's Leg project is located in the Kundana mining centre 22 kms West of Kalgoorlie, in Western Australia. The Mines and Resources Australia (MRA) Dioro Exploration Joint Venture has had considerable exploration success centred on the high grade Frog's Leg discovery. A gold resource of 930,000 ounces has been defined. At Frog's Leg there have been three discrete resource domains recognised - Supergene, Contact, and Quartz Lodes. This paper describes the metallurgical test work undertaken.The selection of the drill core was a joint effort by the MRA Senior Geologist and Mineral Engineering Technical Services (METS) to ensure the samples were representative of the ore body. Optimisation of gold recovery was essential as both the Contact and Quartz Lodes have exceptionally high percentages of free gold as well as significantly higher grades than the typical open pit ores found in Western Australia. The metallurgical scope of work included documenting all of the metallurgical test results, establishing the comminution characteristics, determining the percentage of gravity recoverable gold, evaluating the cyanide leach characteristics and determining the tailings characteristics. These studies were used as the basis of flow sheet design to treat both ores and to discuss the advantages and disadvantages of alternative flowsheets. Investigations also included toll milling options at various plants as well as second hand and transportable plants. Considerable technical effort has been put into ore characterisation by way of test work aimed at managing the process risk at each stage of project development, including mitigation. MRA also carried out detailed mineralogical analysis of the ores."

Jan 1, 2005

By Paul Bedard, Réal Daigneault, Guy Perrault

"La mine Lamaque est située a Val d'Or, Québec; les roches hônes appartiennent au groupe de Malartic, partie supérieure, et sont des andésites et des pyroclastites. On y retrouve deux formes d'intrusifs; des petites cheminées (ca. 150 m D) et des dykes (ca. 10 m d'epaisseur). Les petit es cheminées contiennent:1 - des diorites et des tonalites (cheminées principale, est et ouest) d'affinité calco-alcaline: Zr 140 ppm, Sr 761 ppm, P2O5 0.31% et (La/Sm)n 3.0;2 - des diorites (cheminée 4) d'affinités tholéiitique: Zr 32 ppm, Sr 181 ppm, P2O5 0.27% et (La/SM)n 1.5.La diorite de la cheminée no 5 contient deux fractions, une de chacune de ces deux affinités. Les dykes tant de porphyre feldspathique quartzifére que ceux de prophyre feldspathique sont d'affinité calco-alcaline: Zr 83 ppm, Sr 500 ppm et P2O5j 0.10%.Le gisement de 10 mine 2 est filonien: veines subhorizontales (""flats "") surtout et veines sub-verticales dans des zones de cisaillement. Le dernier réajustement structural de direction de compression nord-sud a broyé le quartz des veines existant es et rendu possible leur minéralisation. Les veines minéralisées contiennent du quartz, de la tourmaline, de la calcite avec des traces de scheelite, de pyrite et d'or; elles sont bordées par de minces (2 à 20 cm) bordures d'altération où l'on retrouve un enrichissement en carbonate, paragonite, apatite, rutile, saphène et zircon et où les phases ferromagnésiennes sont disparues. On a documenté le migrations géochimiques suivantes:I - de la bordure d'altération vers l'éponte, K2O, Rb et MgO;2 - de l'éponte vers la bordure d'altération, Na2O;3 - de l'éponte vers la veine, SiO2.P2O5, TiO2, Zr, Y, Nb et CaO sont enrichis dans la bordure d'altération."

Jan 1, 1983

By Tom Dettweiler

Who We Are A global pioneer in discovery, development and recovery of deep-ocean assets Shipwrecks Deep-sea Minerals Company Overview Founded 1994 HQ ?Tampa, Florida USA Employees 45 Tampa + 150 Abroad Publicly Traded: NASDAQ:OMEX Requires Specific Financial Controls and Reporting

May 1, 2013

By Frank S. Palkovits

Over the past 30 years, underground paste backfill systems have been implemented across the globe in many configurations, each with a primary focus of providing high quality backfill to enhance mine operations. However, a number of key design drivers are not always well understood within design engineering firms that occasionally undertake this work, leaving opportunities on the table. Perhaps not always obvious to those newly embracing paste technology, identifying key drivers and opportunities attainable through a paste backfill system is generally not straightforward, requiring innovative approaches to securing higher productivity, availability, performance, maintainability, and operator health and safety. This paper describes a number of applications and audits of paste backfill systems for several challenging mine operations. Key challenges include iterative design aspects of availability of good backfill materials, plant location and configuration, general arrangement, and binder receiving/storage systems.

Oct 1, 2010

By Matthew Janes

Advantages: Clean samples Low sample disturbance Very low spoil Versatile Fast Penetrates all formations Resonant Drill 100 or 150 kW Self tuning to resonance Rotation to 100 rpm Increased depth in dense soil Increased productivity Reduce water use Reduce casing plugging

May 1, 2013

By J. E. Dutrizac

The dissolution of low-iron sphalerite, (Zn,Fe)S containing 0.08% Fe, in ferric sulphate-sulphuric acid media was investigated using closely sized fractions of crushed sphalerite crystals and sintered disks made from the crushed crystals. Linear kinetics are observed, and the predominant reaction products are ZnSO4, FeSO4 and elemental sulphur. The leaching rate increases systematically with increasing temperature, and the calculated apparent activation energy is 56 kJ/mol for the sized sphalerite and 54 kJ/mol for the sintered disks. The relatively high apparent activation energy suggests that the rate is chemically controlled, a conclusion supported by the insensitivity of the rate to the disk rotation speed. The rate increases as the 0.22 power of the Fe(SO4)1.5 concentration, and as the 0.22 power of the H2SO4 concentration. However, in the absence of ferric ions, the rate increases more significantly with increasing H2SO4 concentrations, and relatively rapid rates are observed in solutions containing >0.5 M H2SO4. In 0.1 M Fe(SO4)1.5-0.3 M H2SO4 media, the measured rate decreases with increasing sulphate concentrations, added as Li2SO4. The rate of dissolution of low-iron sphalerite is promoted by dissolved copper concentrations as high as 800 mg/L. In contrast, dissolved silver, even in the 0-2 mg/L concentration range, significantly retards the dissolution of the low-iron sphalerite.

Jan 1, 2008

By Zhiye Zhao, Jianping Sun, Zhipeng Xu

"The subsea rock cavern project is an underground storage facility. For cost-effective and safe excavation, the risk caused by the groundwater seepage into the rock cavern must be addressed. As one of the essential steps of the assessment work, the hydraulic conductivities of the fractured rock masses should be reliably determined based on the limited measured data and geological information from the few boreholes. On the basis of site investigation data and monitored water flow and water pressure data during excavation, this paper presents an estimation method for hydraulic conductivities of the rock masses containing water bearing zones.INTRODUCTIONIn the development of underground rock caverns/tunnels, the uncertainty of hydro-geological conditions plays a critical role in terms of construction cost and construction safety. Excessive groundwater seepage has been identified as one of the key safety factors which always lead to vast loss, such as the Seikan Tunnel in Japan which encountered sudden water inflow and then catastrophic face collapsing, tunnel flood during excavation (Xu et al., 2013). As a key factor in the risk management associated with the groundwater leakage into rock cavern, the hydraulic conductivity determination is very important for cost estimation, reliable water control and construction management.The case presented in this paper is an underground project consisted of a cluster of rock caverns/tunnels for storage of hydrocarbon products. These caverns are located in heterogeneous sedimentary bedrock, at a depth of 130 m beneath a basin, and the crowns of caverns are located at about 100 m below the sea bottom. The caverns/tunnels are designed at two levels, the water curtain tunnels are at the upper level, and oil storage caverns are at the lower level, as shown in Figure 1. A number of horizontal and vertical water injection holes drilled from the upper water curtain gallery tunnel will establish continuous horizontal and vertical water curtains for providing a stable pressure distribution around the caverns, to keep oil/gas inside the lower storage caverns. As the hydrostatic pressure of groundwater around the storage caverns is higher than the pressure of stored oil and gas, the stored oil and gas will not leak out of the cavern (Lu, 2010; Xu et al., 2015). Groundwater pressure gauges are installed in the water curtain gallery tunnels, and water from the operational and access tunnels is injected continuously into the curtains to maintain the pressure. Some monitoring data are recorded at different construction stages. This paper proposes suitable methods to predict the hydraulic conductivity in rock mass and to determine the hydraulic conductivity in the water bearing zones."

Jan 1, 2015

By R. R. Song, Q. Li, H. Xing, X. C. Wei

Geomechanical modelling of fault stability is an important part of CO2 capture and storage (CCS) research program to ensure its viability and long-term safety. Storage of CO2 in deep subsurface reservoirs requires estimates of sustainable fluid pressures that will not induce fracturing or fault reactivation which could cause fault slip. More importantly, fault slip gives rise to seismic waves, which inflict severe damage to the cap rock of the reservoirs and may result in leakage pathways for the buoyant plume and thus compromise the integrity of seal formations. In this study, we generated a numerical model tuned towards conditions usually encountered in the Shenhua CCS demonstration project in Ordos basin. In particular, with the purpose of evaluating the sensitivity of the parameters as well as their relationships with the moment magnitude of the seismicity, a variance-based sensitivity analysis was adopted for importance ranking of the uncertain input parameters of the given model. However, such flow models could involve one or several spatial inputs, for instance, fault dip, distance between fault and the injection well, friction angle of fault, permeability of fault, Young's Modulus of fault, injecting pore pressure and the stress field. Studying the sensitivity to each of these spatial inputs motivated the present work. The results led to the following conclusions: fault depth and fault dip significantly affect the behavior of the fault and the fault slip becomes violent with the fault depth increasing and fault dip decreasing. Furthermore, the results indicate that slip time increases with the fault dip decreasing and decreases with permeability of fault increasing. In addition, the calculation of seismic moment and moment magnitude of an earthquake demonstrates that it rises significantly with the decrease of fault dip and the increase of fault depth, and it decreases with the rising stress field. The results show that variations of the only controllable parameter injection pressure do not show great influence to the fault behavior compared with other geological factors, which imply site selection is extremely important for the CCS projects.

Jan 1, 2015

By F. D. Aaring

"IntroductionTHE PINCHER CREEK gas condensate field, in Township 3, Range 28, and Townships 3 and 4, Range 29, West of the Fourth Meridian, was discovered in 1947 by the Canadian Gulf Oil Company with the completion of Pincher Creek No. 1 well in the Madison lime-stone of Mississippian age.This discovery was the result of a great deal of detailed seismic work in the area and is a credit to the geophysical personnel of the Company. The depth of the reservoir varies from 7,400 feet to 8,200 feet subsea, with the established water level at -8,200 feet. The predicted depth was but a scant 100 feet from that found in the discovery well, at 11, 705 feet. Since the discovery of the reservoir, three additional wells have penetrated the Madison limestone and have further verified the original •seismic interpretation of the limits of this reservoir.To date, •only a very small amount of gas has been produced from this field. Consequently, the reservoir studies that have been made so far are predominantly based on investigations of the phase behaviour of the fluid and physical characteristics of the reservoir rock. In view of the above limitations, it has been necessary to set up and perform model reservoir studies with the fluids and to recover as much core from the productive Madison limestone as possible in order that it might be analysed by conventional laboratory technique and be subjected to detailed microscopic geological examination."

Jan 1, 1952

By M. Sanchez

In the last decades, the Chilean copper mining and metallurgical industry have had to modify their technological processes to meet the environmental regulations implemented by the Chilean government, and also to support the pressure of the public opinion. Thus, air quality standards for sulfur dioxide and particulate matter (primary and secondary), plans for reducing emission of arsenic by the Chilean copper smelters, effluents discharge limits, among others regulations were applied by the environmental agency. Additionally, agreements on cleaner production were carried out by mining sector and government. Now, a draft law on mine closure, and another on environmental mining wastes (abandoned mines) are being discussed by the authorities and the mining sector. In the context, production and environmental impacts in different ways to produce copper in the Chilean mining industry are reviewed and regulatory tendencies as well as abatement technologies today used are exposed and discussed in this presentation. Pyro, hydro and electrometallurgical processes employed and their current effluent and contaminants are presented showing various alternatives of treatment in the copper industry. An update of regulations established in Chile vis a vis copper production, with an especial attention to mine closure are also presented.

Jan 1, 2007

By E. Wolmarans

The selection of the main mineralised zone (MMZ) concentrator milling circuit has followed a comprehensive route over the preceding 10 years. Many knowledgeable parties have contributed and assisted in developing the milling circuit according to the best available information. The final selection of the flow sheet was completed after DRA conducted a techno-economic study on four possible comminution circuits ranging from conventional crushing and ball milling to fully autogenous (AG) milling. The results from all the above mentioned work indicated that it is possible to treat the MMZ ore at the desired throughputs to the desired grind sizes in a fully autogenous grinding circuit. The flow sheet was designed to treat the main mineralised zone (MMZ) arising?s from both underground and open cast operations and incorporates a fully autogenous grinding (AG) circuit. Commissioning of the 375ktpm concentrator at Nkomati Nickel began in August 2009 with the first ore reporting to the mill on the 15th of September 2009.

Jan 1, 2012

By K. Turgeon, D. Larivière, L. Whitty-Léveillé, J. -F. Boulanger, C. Bazin

"The processing of ore containing rare earth elements leads to the production of an impure solution of these elements. The separation of the rare earths from the impurities and the production of individual elements is usually carried out by solvent extraction. The effectiveness of the extraction conditions and of the reagents is generally tested in the laboratory. This paper deals with the processing of results from solvent extraction laboratory tests planned to generate data redundancy. A method is proposed to take advantage of the data redundancy by accounting for the pH variation during the extraction. The parallel processing of several tests also allows estimating the equilibrium constants for the extraction. The proposed method produces equilibrium constants that are more reproducible than values estimated using conventional approaches. The method is illustrated with solvent extraction tests conducted on synthetic solutions of rare earth elements.INTRODUCTIONThe processing of ores containing rare earth elements (REE) usually includes the production of a concentrate of the minerals carrying the REE. These minerals, for instance monazite and bastnäsite, contain the 14 elements from La to Lu plus yttrium and scandium. As an example monazite has the general formula of (La,Ce,Pr,Nd,Sm,Eu,Gd,Tb,Dy…Lu)PO4 with a typical lanthanum content of 20-26%, cerium content of 40-50%, praseodymium of 4-6%, neodymium of 16 to 20%, and decreasing concentrations of heavier elements (Gupta & Krishnamurthy, 2005). During the processing of a REE mineral, it is generally not possible to isolate and separate a single REE from all the rest. The mineral molecules need to be broken (usually via a heat treatment followed by leaching with a base and/or an acid) to produce an aqueous solution of the REE of the ore. After purification of the solution, the REE can be precipitated as a bulk concentrate and sold to a refinery that separates the REE into particular groups of REE such as the light versus heavy REE or into individual elements such as lanthanum, neodymium, or europium oxides to yield value-added products."

Jan 1, 2016