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By R. K. Jonas

"Pressure leaching and pressure oxidation in autoclaves are important alternatives in the extractive processing of gold, copper and nickel ores. The application of advanced control to pressure leach and pressure oxidation autoclaves could achieve significant benefits as has been shown in alumina pressure leaching. This paper compares and contrasts alumina digestion autoclaves to other mining autoclaves with respect to advanced controls. The application of advanced control in alumina with over 30 units controlled worldwide, and its benefits will be reviewed. The design and potential benefits from advanced control for pressure oxidation and leaching will be presented.INTRODUCTIONIt is this author's position and the purpose of this paper to propose that advanced control could be effectively applied to autoclaves in the nickel, gold, and copper mining processes. This is based on the proven effectiveness of advanced control on autoclaves used in the alumina industry for pressure leaching of bauxite ores. Incremental, but significant increases in production could be realized by applying advanced control to autoclaves, as evidenced by the alumina industry, and this not being implemented in other autoclaves in the mining industry.In addition, today the mining industry is being challenged to improve their production methods. In some markets like nickel, there is pressure to improve productivity and reduce the cash cost per ton. While in other markets like copper and gold, demand is vigorous with favourable pricing, and there are advantages to increase production and productivity given limited plant capacity. Advanced control has proven its capability to improve mineral processing operations through increases in throughput, recovery, as well as reducing variability. In today's mines, autoclaves are being used to a much larger scale and with much larger importance, thus it would be beneficial to improve operational performance through the use of advanced control.Accordingly, it is the author supposition that an opportunity exists in the mining industry to use a proven advanced control technology to improve the operations and financial performance of mines using autoclaves."

Jan 1, 2012

By M. A. Creaney

"The Construction Group is responsible for the construction of all of Placer Dome’s major projects and contributes to the development of most major feasibility studies. This group includes an international collection of Placer Dome people who have built mines in Papua New Guinea, Australia, Chile, the United States and Canada. This paper outlines the changing role of the Construction Group from the early days of single projects to today, when several projects are in various phases from feasibility to construction. The projects’ total annual budgets have from time to time exceeded one billion dollars. IntroductionAs the competition increases globally between the major gold mining companies, the impetus continues to build mines at the lowest cost with the shortest construction schedule. Placer Dome has more than met that challenge by building mines around the world at a pace that was not contemplated 15 or 20 years ago. Since 1960, Placer Dome has built 30 mines and expansions at a cost of nearly 4.5 billion dollars.In the last six years alone, Placer Dome has built 14 mines and expansions, worth 2.6 billion dollars. The company’s success is due primarily to Experience, Innovation, People and Standards.The diversity between projects, let alone the pace, has been a challenge. Placer Dome has built mines around the world in a variety of extreme climates and distinctive cultures. The construction experience gained from these projects has allowed Placer Dome to develop an extensive knowledge and data base making it easier to “fast track” projects.Through the years Placer Dome has developed a human resource base. It now has an experienced and adaptable core team of people able to set up construction projects and build mines anywhere in the world. By developing standards and systems to support the projects they can act as soon as a new project is approved, and complete the projects quickly and effectively. The result is that Placer Dome now has the construction expertise to build its own mines, giving them the competitive advantage that allows them to design and construct a mine in the least time at the lowest capital cost. This was demonstrated in March 1997 with the completion of the construction of two new mines in 12 months."

Jan 1, 1998

By Roger J. Higgins

Papua New Guinea is a country on the cusp of development, struggling to find a balance between the demands of national and regional growth, landowner expectations and the maintenance of cultural identity. Ok Tedi Mining Limited is the single largest contributor to PNG?s economy, representing about 10 percent of the country?s GDP. OTML is demonstrating that business and country risk can be managed through effective, respectful partnerships with local communities. OTML?s relationships with the communities of PNG?s Western Province are multifaceted. Communities have borne the brunt of the mine?s environmental impact, yet have benefited enormously from the development that the mine has brought. Importantly, the PNG economy is now the ultimate beneficiary of more than four-fifths of the dividends from the mine, the majority of which are held in trust for long-term sustainable development projects. The paper describes how OTML works with the Western Province communities to create a secure operating environment that recognizes the people?s aspirations for development and self-determination.

May 1, 2002

Reaction between xanthate ions in solution and oxidized compounds present on the surface of galena to form lead xanthate is considered to be a side reaction not contributing to flotation, although accounting for some consumption of reagent. The direct reaction of lead sulphide with xanthate and oxygen to form lead xanthate is the most significant to flotation. Coadsorntion of dixanthogen is also involved. Previous work has shown lead recovery in lead rougher flotation to be a function of m [H+] where: m = concentration of xanthate in solution rHl = hydrogen ion concentration. A plausible explanation for this relationship is suggest-ed. Likewise, the experimental findings that the amount of xanthate adsorbed under certain conditions is a function of m'[H+] are explained in terms of reaction between xanthate ions and soluble basic lead salts such as PbO.PbS04? It is also shown that m[H+] should have a constant value in lead cleaners operating at a higher pH than the roughers. This conclusion is confirmed by plant data, and the value of the constant agrees well with the calculated value. The finding is useful in mill control.

Jan 1, 1965

By D. W. Zandee

"IntroductionHaving mined an economic mineral bearing rock which is of insufficient grade to warrant direct smelting, upgrading or beneficiation is required to make it an economically viable ore. The first step in effecting the concentration process is comminution or sequential breaking of the rock to allow liberation and subsequent recovery of the desired mineral particles. Desirably the ore could be broken down to the point where the valuable mineral is completely liberated to maximize the chance of recovering as much of it and in as pure a form as possible. The number of energy intensive stages of breakage required to attain this goal depends on many physical characteristics of the ore such as hardness, friability, toughness, grain size, existing fracture planes and particle shapes.Commonly the distinct stages are primary, secondary and often tertiary crushing and finally grinding. To increase the efficiency of each stage of size reduction, pre-treatment sizing is common.Crusher feed is commonly scalped of large pieces or screened for reduction crushers and classified for secondary grindingcircuits.Although crushing and screening is employed for many different products, this chapter reviews current practice in larger tonnage metalliferous ore treatment plants.Current practice is to use large gyratory or jaw crushers for primary crushing and some sort of gyrating or cone crushers for additional stages of reduction. For autogenous or semiautogenous grinding circuits only the primary crushing stage is necessary, the balance of the work being performed in the grinding stage. For conventional grinding circuits using ball mills or combinations of rod and ball mills, secondary, tertiary and even quaternary crushing stages are normally required.Older type crushers such as stamp mills, double rolls, sledging mills and hammermills are no longer common but are used for small tonnage special processes.Important to efficient crushing are a variety of sizing devices such as grizzlies and vibrating screens. Products at different stages must be stored to give surge capacity and allow controlled feeding rates through mechanical and gravity feeders. These storage piles, bins and feeders as well as crushers and screens are commonly integrated into a total facility by means of conveyor systems. Most often these are endless rubber belts driven by simple or multiple drive mechanisms usually consisting of electric motors and speed reducers."

Jan 1, 1989

By D. Vanin

"Conventional single heading track drifting in the hard rock mining industry has not shown any significant improvements in advance rates, despite the advent of modern track jumbos and igh speed muck handling systems .This paper presents Kiena 's experience in using a 7 ft 2 in. diameter larva Mark 6 Tunnel-Boring Machine (TBM) for driving 6000ft of drift.IntroductionKiena Gold Mines is located about 5 miles west of the town of Val d'Or, Quebec, approximately 300 miles north of Montreal. The mine commenced production in October 1981 and has gone through various expansions of ore production with 287 916 metric tonnes in 1982 to reach 453 800 metric tonnes in 1986.Due to the majority of claims being covered by a lake, a grassroots exploration drive of remote areas of the property was required to allow diamond drilling on a yearly basis. High speed sequential excavation methods (SEM) of single heading drifting in the mining industry has not progressed much in the past 20 years despite the advent of electric-hydraulic jumbos, Haggloader and Hagglund type cars. Certain examples of record SEM drifting advances have been performed in the past but only under very specific ground and cost conditions."

Jan 1, 1987

"Accelerated expansion of Western Canada's metallurgical coal industry has again stimulated considerable exploration activity in the Rocky Mountain Foothills Belt and influenced much of the R&D related to transportation, processing and carbonization. Preparation R&D has included further pilot-plant work on desulphurization, spherical agglomeration and modified compound cyclones (which are also proving themselves in other mineral beneficiation studies). Combustion research, aside from increasingly stressing control of combustion source pollution, has directed special attention to lignite PF firing and problems arising from lignite ash. Studies directed toward the non-fuel utilization of coal have centered on such diverse topics as active carbons, carbonaceous filter media, plant nutrients and industrial applications of humic acid derivatives. In addition, a number of long-range research projects related to such matters as coal chemistry and pyrolysis have been actively pursued, and further attention has been given to improved sampling techniques and analytical methods."

Jan 1, 1969

By R. H. Beaton

"About 1905, a plant was constructed at C1ayburn, in the Lower Fraser valley, 4'5 miles east of Vancouver, to process shales from Sumas mountain into heavy clay products. In time, mining operations were found to be more favourable on the opposite side of the mountain, and by 1913 a plant, which soon became the centre of activities, was completed at Kilgard. Destroyed by fire in 1949, the plant was rebuilt on modern lines, and a second plant was established at Abbotsford, six miles to the west. The Company, from its beginning, has grown with development of the Province. In recent years, operations have kept abreast of latest developments, particularly in materials handling. Latest innovation has been the complete conversion of fuel from Bunker C oil to natural gas. In 1957 the Company became associated with Harbison Walker Refractories, Limited, a leader in its field in the United States, and its title was changed from Clayburn Company, Limited, to Clayburn-Harbison, Limited. Currently, the Kilgard plant produces sewer pipe, agricultural tile, and flue liner; the Abbotsford plant, refractories and facebrick. Improvement of products and development of new ones are tasks of a recently-completed testing and research laboratory.Almost all ware produced is marketed in Western Canada or Washing-ton State. The Vancouver area absorbs the bulk of structural clay products."

Jan 1, 1959

By Newell G. Alford

COAL companies are definitely becoming conscious of the need for better organization. Mechanized mining and the intricate preparation of coal have brought with them the demand for better trained and more highly skilled mining personnel. Refinement in coal mine management is increasing the demand for young graduate engineers to start in the lower grades of the reorganization and prepare themselves to meet rapidly increasing coal mining responsibilities. The interest is wide in scope and extends from self-helps, extension work, and management study at the mines to stimulation of interest in coal mining amongst undergraduate mining students, leading to their permanent employment after graduation. Data by the United States Bureau of Mines show the total annual value of coal production (bituminous and anthracite in the U.S.) through the past 22 years as being more than 38 per cent of the combined value of all ocher mineral industry products. Natural-gas production has gained rapidly on coal since 1916; petroleum exceeded coal beginning with 1934 (see Figure 1). For this 22-year period, the Committee on Student Interest in Coal Mining, in the A.I.M.E., made a survey of the mining schools in Canada and the United States to show the approximate absorption of young graduate mining engineers by the coal industry. In 1938, 232 mining engineers were graduated as compared with 42 in 1918 (a war year) and 180 in 1923. From 1923 to 1929 the graduates declined to another low of 90, but from there on there was a rapid annual increase in the graduating output, reaching a total of 232 in 1938 and continuing upward to a maximum of over 325 graduating this present month.

Jan 1, 1940

By J. Budac, E. Krause, C. L. Stewart, D. Wrana, S. W. Laundry

"As part of an over-all arsenic management strategy, Inco has developed a novel process that converts a by-product high moisture copper/arsenic sulphide precipitate into a crystalline copper arsenate suitable for the manufacture of wood preservation chemicals.The copper/arsenic sulphide precipitate is atmospherically leached with oxygen and sulphuric acid, producing a crude (blue) copper arsenate precipitate, elemental sulphur, and a copper and nickel containing solution. The blue copper arsenate is dissolved with sulphuric acid, the molar Cu/As ratio is raised to 2, and a crystalline copper arsenate (olivenite) is precipitated by the addition of sodium carbonate. Dissolved copper is recovered using metallic nickel (or matte) and elemental sulphur, to produce a low-moisture (low-arsenic) precipitate suitable for standard nickel-copper processing.The process was successfully piloted at Inco's Manitoba Division between September 1990 and June 1991. The copper arsenate product typically analyzed 43% Cu and 25% As, and the moisture content was about 10%."

Jan 1, 1995

By C. M. Diaz, P. J. Mackey

Since its inception, in 1987, the Copper-Cobre series of conferences has established itself as the prime world forum for discussing advances in copper process metallurgy, in particular copper sulfide smelting, copper recovery by leaching and electrowinning and copper electrorefining. All copper producing countries have actively participated in the pyrometallurgy symposia held in the framework of these conferences. In 1999 and 2003, the close to 100 pyrometallurgy papers that were presented had to be accommodated in two volumes. In the present paper, the authors firstly provide a brief historical sketch of the Copper-Cobre conferences and then focus on providing a retrospective look at the dramatic changes that have taken place in copper smelting in the last few decades, primarily as discussed in the Copper-Cobre and precursor conferences pyrometallurgy proceedings. Topics include: the development of autogenous, increasingly more intensive, environmentally sound and energy efficient smelting processes; significant improvements in Peirce-Smith converting practice and at the same time the commercialization of alternative continuous converting routes; the consequent expansion and modernization of smelters; the increasing compliance with strict government environmental regulations in most copper producing regions of the world; the realignment of the copper smelting industry throughout the world; and trends in copper smelting R&D. A look at the future closes these reflections on the contribution of the Copper-Cobre conferences to the advancement of copper smelting technology.

Jan 1, 2007

By J. C. Underwood

"The wear performance of grinding balls under conditions of impact and abrasion is affected by their chemical composition and structure. The selection of appropriate analyses and heat treatments that will provide both abrasion and impact resistance takes into account the effects of certain elements on structure and harden-ability, as well as the over-all effect of composition and hardness penetration on the residual stress pattern developed through heat treatment. Direct quenching from forging temperatures substantially increases hardenability over that obtained in reheat-quench practices, and can be done without undue risk of damage to the ball provided that the harden-ability bears the correct relationship to ball diameter.Average volumetric hardness and percent hardened volume are convenient parameters for quantitatively expressing the response to heat treatment and indicating anticipated wear properties. A number of factors which can lead to reduced wear life as a result of material or processing problems are reviewed and illustrated."

Jan 1, 1959

By James H. Cobbs

Blind boring of shafts is becoming an increasingly important part of shaft sinking. Blind-bored shafts have reached diameters of 25 It in Europe and 16-1/2 ft in the United States. Much of the technology developed for blind boring has evolved from the technology of drilling wells for oil and gas production. Blind boring offers economic advantage in a number of situations where conventional shaft sinking either is extremely difficult or very expensive by virtue of large-capacity aquifers which must be penetrated, unstable ground or where very rapid sinking is required. In sedimentary rocks, blind boring is cost competitive with conventional sinking, in diameters of about 12 ft or less. Blind boring is not competitive with raise boring where conditions are favourable for raise boring. Blind boring does, however, offer greater flexibility than raise boring and can be performed in situations where raise boring is inefficient or impossible. Combination machinery has been developed to perform both blind boring and raise boring, so that the machine can be used effectively in situations where only the near-surface portions of the shaft are unfavourable for raise boring. Development work is being supported by the United States Bureau of Mines for blind boring equipment capable of boring shafts up to 30 feet in diameter.

Jan 1, 1979

By Magella Pelletier

"IntroductionDepuis une vingtaine d'année, les nombreux travaux de géochimie effectués par l'industrie privée et les milieux gouvemementaux ont permis:• de découvrir de nombreuses zones minéralisées a valeur économique;• d'identifier et de vérifier certains patrons de dispersion géochimique au-dessu s de secteurs minéralises déjà connus;• de favoriser le développernent des techniques analytiques;• de forcer le développement d'une mise en carte des résultats d'analyse, qui soit plus adéquat afin de permettre une meilleure interprétation géochimique.L'une de ces cartes géochimiques qui permet le mieux de mettre en valeur les données analytiques et qui fut instaurée au debut des années 80, est la carte d'interprétation géochimique par pondération.Cette carte numérique semi-quantitative, qui est construite à partir des données de base et de l'importance des éléments indicateurs pour une substance donnée, permet d'identifier et de définir des zones possédants de fortes probabilités pour la recherché de sources minéralisées."

Jan 1, 1987

By Lawrence D. Hoy, Armand Savoie, Pierre Trudel, Ghislaln Tourigny, Robert Crépeau, Lao Kheang

"Recent fluid inclusion and stable isotopic studies in the Bousquet mining district have identified spatial and temporal trends in mineralization temperatures and isotopic compositions of vein forming fluids. These studies indicate that mineralizing temperatures were lower during sterile vein formation (T=200-300°C) than during auriferous vein formation (T = 300-400°C), and that 8 80 values of minerals in sterile veins are lower by 1-3 %o than in associated auriferous veins. In addition to these small differences in 8 80 within individual mineralized zones, a trend of increasing 8 80 values of vein minerals is identified from west to east across the district, with 8 80 of vein minerals increasing by4-6%o. Quantitative evaluation of potential causes of the observed oxygen isotopic shifts suggests that the best explanation for these trends is the derivation of the mineralizing fluids from an isotopically inhomogeneous terrain in which the fluid isotopic compositions are controlled by the isotopic compositions of the host lithologies due to high rock/water ratios in these source terrains. This inhomogeneous source terrain is interpreted as consisting of the Blake River Group volcanics (low 8 80 component) and the adjoining Kewagama and Cadillac Group sediments (high 8 80 component).The genesis of the hydrothermal fluids is attributed to crustal heating during metamorphism, with the fluids representing metamorphic dewatering products and/or fluids incorporated during deposition and burial of the host lithologies. Ductile deformation of the fluid source regions impeded fluid migration during metamorphism; the ultimate release of the mineralizing fluids is attributed to the penetration to depth of vertical structures (fault and shear zones) during brittle deformation of the crust under waning metamorphic conditions. Release of fluids caused by this puncturing of the closed hydrologic source regime produced a localized zone of lowered pressure, drawing fluids from adjacent lithologies toward the fault zones, feeding further hydrothermal fluid upwelling. Au mineralization resulted from chemical processes related to cooling of the hydrothermal fluids and/or interaction with lithologies encountered during fluid migration; the level of crust at which Au deposition occurred likely migrated upward with the thermal anomaly caused by hydrothermal fluid upwelling, eventually reaching the level of current exploitation. Cessation of fluid flow along the vertical structures is attributed to inadequate recharge of the hydrothermal systems as fluid contents were depleted in the lithologies proximal to the vertical structures and/or sealing of the structures by mineral deposition."

Jan 1, 1990

By G. L. Palmer

"Abstract- ln 1986, anomalous sampling results for heavy minerals were obtained at various sites in Namaqualand on the west coast of the Cape Province. Drilling in 1987 at Graauwduinen penetrated up to 35 meters of heavy mineral-bearing Tertiary sands which extend several kilometers inland from the coast. The heavy mineral suite includes ilmenite, rutile, leucoxene, zircon and monazite, along with garnet, pyroxene and amphibole. Three deposits are recognized, two of which comprise the resource to be mined by Namakwa Sands Limited, a recently formed Anglo American Corporation subsidiary company.Mineable reserves in excess of 500 million tonnes have been delineated, sufficient to sustain mining for over 35 years at projected production rates. During the feasibility study, on-site investigations included test mining at various sites to assess mineability and to provide material for metallurgical testing in a pilot plant located at the site. Ilmenite produced at the mine will be smelted at a new facility to be built at Saldanha Bay . Saleable products comprise titania-rich slag, pig iron, zircon and rutile.During the exploration phase, company environmental guidelines were established and monitored. The feasibility study incorporated a Class 1 Environmental Impact Report, the contents of which were made public following the principles of the Integrated Environmental Management legislation."

Jan 1, 1994

By T. Takayama Filho

Votorantim Metais Zinco is a smelting facility which produces SHG zinc, zinc alloys, sulfuric acid, liquid SO2, copper sulfate, cadmium metal and silver concentrate. It is located at Juiz de Fora, Minas Gerais State, Brazil. This facility has been operating since 1980 and its current capacity is 95,000 tonnes of zinc per year, using mostly imported sulfide concentrates.The plant uses the conventional roast-leach electrowinning (RLE) process, in which iron is removed from the circuit as jarosite. The residues generated by the RLE process, which amount to about 200 t/day (dry weight), were until 10 years ago, deposited in tailing ponds having no impervious lining. More recently, jarosite and other wastes have been deposited in a properly built reservoir, but this is reaching its maximum capacity. In order to decommission these disposal operations and to reclaim the sites in an environmentally acceptable manner, Votorantim Metais concluded in 2004 a rehabilitation project for the old tailings pond and prepared detailed plans for managing the current and future disposal of jarosite-bearing residues. This paper describes the procedure for removing iron from the hydrometallurgical circuit and discusses the past and current status of the residue disposal sites, as well as the future challenges related to the environmentally acceptable handling of iron residues.

Jan 1, 2006

By M. F. Lopez, A. J. Mattus, S. B. Magid, D. B. Mobbs

"The use of Caro's acid as a replacement for hydrogen peroxide for the oxidation of vanadium prior to solvent extraction resulted in a 56% reduction in oxidant usage when compared on an equivalent hydrogen peroxide basis. Comparative oxidation tests, using two actual uranium mill raffinates, resulted in premature precipitation of an amorphous ferric vanadate when hydrogen peroxide was used to oxidize one of the raffinates containing a high iron to vanadium ratio. The use of Caro's acid eliminated the precipitation problem, thereby permitting the adjustment of the raffinate pH to a higher, more favourable level prior to solvent extraction.Potentiometric characterization of the raffinates revealed that vanadium is responsible for the inefficiency of hydrogen peroxide compared with Caro's acid, with the oxidation efficiency of iron being the same for both oxidants. A limiting potential between 720 and 740 mV was observed when using hydrogen peroxide, while, when using Care's acid, potentials approaching 1200 mV were achievable.A four-stage, countercurrent extraction performed on the oxidized raffinates did not reveal any operational problems. The extraction efficiency and the extraction coefficient were found to be higher when Caro's acid was used as the oxidant, as opposed to hydrogen peroxide.IntroductionMost vanadium is recovered as a by-product of some other process: leaching of Carnotite uranium ores, oil fly ash, phosphate rock or chromite processing. The major source of vanadium has been from uranium mills incorporating acid leaching of Carnotite ore s at elevated temperatures and pressures. The by-product recovery of vanadium from uranium ores of the Uravan Mineral Belt, located in the Colorado Plateau , is a common occurrence when vanadium recovery is economically viable."

Jan 1, 1983

By R. Khanna, K. Hyun Ko, A. J. Berkovich, J. Hook

"The co-pyrolysis of synthetic polymer polyethylene terephthalate (PET) and agricultural wastes (naturally occurring polymer-macadamia nut shell) was investigated in the temperature range 473K to 1273K using a horizontal furnace with an aim to understand their thermal degradation under isothermal conditions. In-depth characterization of pyrolysis residues was carried out using x-ray diffraction (XRD) and solid state nuclear magnetic resonance (NMR) for carbon structure, and through determination of the concentration of unpaired electrons using electron paramagnetic resonance (EPR). In previous studies, it has been found that PET thermally decomposes ~ 650K-700K, releasing (~80 wt % of initial weight) gaseous products due to random chain scission. In the case of macadamia nut shell, three types of byproduct can be obtained from pyrolysis: char, tar and gaseous products. In the co-pyrolysis of macadamia nut shell with PET in 50-50 wt% ratio, total product weight ratio could be modified with the addition of PET acting as a hydrogen source. This is because a recombination of thermal cracking products of cellulose could be suppressed by hydrogen from PET, which will later lead to an enhancement of tar formation. In addition, pyrolysis around 673K is sufficient for bond cleavage to occur in cellulose and lignin leading to the formation of negatively charged activated carbon with high surface area, providing bonding sites for volatiles evolving from PET. Therefore the co-pyrolysis may be able to enhance the product yield (tar/char/solid carbon residue) along with a reduction in the release of gaseous products. During the co-pyrolysis, temperature was found to have a significant influence on the kinetics of thermal degradation and solid residual by-products after co-pyrolysis.INTRODUCTIONPlastics are being used worldwide in a wide range of applications in the modern society; their usage has resulted in increasingly a massive waste problem. The production of most synthetic plastics requires hydrocarbons that are produced from petrochemicals derived from fossil oil and natural gas, a non-renewable source (Speight 2011). Currently, plastic manufacture utilizes ~4% of world oil and gas production, and it is expected to drive further increases in petroleum demand by 1-2% due to their large volume of manufacture (Hopewell, Dvorak et al. 2009). Landfilling and incineration of plastic waste are the two main routes to plastic waste management (Encinar and González 2008). In Australia, only 10% of waste plastics were recycled in 2006 (White and Hyde 2011). This means that large amount of fossil fuels from plastics has either been simply burned for energy recovery or buried in the ground. There is an urgent need for developing alternative avenues for recycling waste plastics. Our group at UNSW has carried out extensive research on the recycling of waste polymers as carbon resource in steelmaking including slag foaming and carbon dissolution from waste plastics into liquid steel at 1600°C; the effect of basic plastic characteristics such as chemical composition, structure, bonding network etc. was examined (Sahajwalla, Rahman et al. 2009)"

Jan 1, 2012

By H. W. Kasaini, E. Bourricaudy, T. Larochelle

Rare Element Resources Inc., a U.S. based company, has developed a three-stage process for producing a +98% mixed REO powder from hard rock feedstock (-48 mesh, 2.9-4.8% REO) consisting of bastnaesite and ancylite minerals. Firstly, the whole ore is digested in chloride media at low temperature in counter-current flow mode. Secondly, the rare earths (REEs) are selectively precipitated as oxalates directly from an impure pregnant leach solution (PLS). Finally, significant amounts of free acid and water are recovered from the REE-depleted filtrate and subsequently recycled within the process. Excess heat from the oxalate calcination process is captured and reused in the plant. Due to the low leach temperature (45 ºC) and moderate acid dosage (240-297 kg/t, HCl), rare earth oxides (REOs) are preferentially leached out of fine solids leaving most of the base metals (Ba, Fe, and Al ) in the residue. Selective recovery of REEs from the PLS is achieved by mixing dilute oxalic acid (33% H2C2O4) and PLS at elevated temperature (85-95 ºC). The REEs plus thorium are precipitated as oxalates (REE2 (C2O4).xH2O) while the base metals are left behind in the barren filtrate. Multiple batch and pilot test results have confirmed that 50-80% of the oxalic acid can be recovered from the REE-depleted PLS through low-temperature crystallization (10-15 ºC). Typical leach efficiencies of critical rare earths at 45 ºC range from 85-99% (average 93%) while oxalate precipitation at high temperature increases the crystal size of RE oxalates (>450 microns, d80) thereby improving filtration. The economic benefits of this process include elimination of flotation and magnetic separation Capex and driving hydrometallurgical Opex down to $6- 7/kg, REO produced. As part of a comprehensive risk mitigation strategy, Rare Element Resources Inc has operated multiple pilot plants at SGS in Lakefield, Ontario, Canada to optimize counter-current leaching (CCL), REE oxalate precipitation (OXP), and thorium removal circuits. This paper presents pilot testing data from CCL and REE OXP circuits.

Jan 1, 2016