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By Y Wan, L Liao

Organo-montmorillonites were synthesised by intercalating different amounts of dodecyl trimethylammonium bromide, cetyl trimethyl- ammonium bromide and stear trimethylammonium bromide into montmorillonite layers, and were used for the adsorption of 17b-estradiol in aqueous solution. The adsorption kinetics and thermodynamic of 17b-estradiol onto organo-montmorillonites and the effect of pH on the adsorption capacity of organo-montmorillonites for 17b-estradiol were studied. The adsorption isotherms at 20¦C, 35¦C and 50¦C were measured. Results show that organo-montmorillonite has a high affinity for 17b-estradiol. More 17b-estradiol can be adsorbed on to organo-montmorillonite and the adsorption is more rapid at a lower temperature. The montmorillonite intercalated with cetyltrimethyl- ammonium bromide with the amount equivalent to one times of its CEC has the highest adsorption capacity. For all organo-montmorillonites synthesised in this study, an optimum pH (around nine) for the adsorption of 17b-estradiol exists. Before this pH 17b-estradiol uptake increased with increasing pH. After that the 17b-estradiol uptake decreased with increasing pH. Simulation of the isotherms indicated that the adsorption of 17b-estradiol onto organo-montmorillonites is a spontaneous and exothermic process. Endocrine-disrupting chemicals (EDCs) are the focus of current environmental concern, as they can cause adverse health effects in an intact organism, or its progeny, subsequent to endocrine function. Most EDCs are man-made organic chemicals (industrial chemicals, crop protection products, antifouling compounds, pharmaceuticals and personal care products). In addition, EDCs can be naturally occurring in the environment (eg the natural female hormones estrone and 17b-estradiol). Therefore EDCs, especially estrone and 17b-estradiol, are ubiquitous in the aquatic environment receiving sewage inputs. Estrogen and 17b-estradiol are among the most potent of all EDCs and are sufficiently stable to survive present sewage treatment processes and are reactivated during those processes through deconjugation (Clara, Strenn and Saracevic, 2004; Zhang and Zhou, 2005; Fukuhara et al, 2006; Butler and Guilbault, 2006; Volpe et al, 2006; Ren et al, 2007; Zeng and Li, 2007). In comparison to traditional contaminants such as pesticides, the concentrations of the most potent EDCs are low, generally within ng/one range. The current sewage treatment processes have limited capacity in removing certain EDCs (eg 17b-estradiol, C18H24O2) It is therefore essential to install additional treatment processes to remove them from wastewater before discharge (Zhang and Zhou, 2005; Fukuhara et al, 2006; Lee, Jung and Kim, 2006). Adsorption is considered to be a possible way to remove EDCs from aqueous solution. Various adsorbents have been studied, including chitin, chitosan, ion-exchange resin, activated sludge, activated carbon (Clara, Strenn and Saracevic, 2004; Yoona and Westerhoffa, 2003; Zhang and Zhou, 2005; Fukuhara et al, 2006; Ren et al, 2007). Studies have shown that organo-montmorillonite has a high affinity for organic pollutants (Li, 1997; Zhu et al, 1998; Han et al, 2001). The aim of this work is to investigate the feasibility of removing 17b-estradiol from aqueous solution by adsorption onto organo-montmorillonite.

Jan 1, 2008

Before the arrival of the first Europeans, Aborigines living in the northern Flinders Ranges mined ochre - an earthy form of haematite used for pigment.The discovery of copper ore at Kapunda and Burra in the 1840s stimulated the early settlers to prospect further north along the ranges. Many of the new discoveries were not properly evaluated and companies were floated on the most tenuous evidence.

Jan 1, 1993

By Millett R

In January 1989, Western Mining Corporation (WMC) acquired the Perseverance and Rocky's Reward orebodies and associated infrastructure from the Agnew Mining Company (AMC). AMC had closed the operation in August 1986 and it had been on care and maintenance since that time. To return the operation to full production as quickly as possible it was planned to mine the Rocky's Reward orebody by opencut mining and treat this ore whilst the underground Perseverance workings were rehabilitated. Removal of overburden from Rocky's Reward thus commenced immediately with a target of April 1989 for delivery of the first ore to the concentrator. Extensive rehabilitation and upgrading of the concentrator commenced in late January, and continued in stages for an 18 month period. The first stage consisted of overhauling all existing equipment and completing a crusher upgrade commenced by AMC prior to the mine closure. During this period, it was necessary to recruit a workforce and re-establish all the required support structure. In late April the plant commenced commissioning trials on mullock. The first ore was crushed on the 11th May 1989 and concentrate produced the following day. From May 1989 to June 1990 the plant was producing nickel concentrate whilst further upgrading continued. During this period, the flotation capacity was tripled by installation of a bank of eight Wemco 144L flotation cells in rougher-scavenger duties and two 12 metre by 2 metre diameter columns in cleaning duties. The existing vacuum drum filters were replaced by two Larox PF32 pressure filters, eliminating the need for solar drying and allowing the flash drier to be fed direct from the filters. These, along with a major borefield expansion and further work to the crusher increased the nominal plant capacity from 600,000 to 1,000,000 t/yr. The plant achieved the 1,000,000 t/yr rate in April 1990.

Jan 1, 1991

The recent installation of top gas temperature probes in blast furnaces at Australian Iron & Steel Pty. Ltd. - Port Kembla, has provided the means for studying radial gas flow distribution in blast furnace shafts. This paper describes the top gas temperature probes and outlines their development and results of initial studies aimed at obtaining a suitable relationships between temperature profiles and furnace parameters. The effects of various combinations of burden materials have been outlined by the results reported. The use of probes has also helped to clarify the effect of casting cycles on furnace operation leading to increased emphasis on the reduction of the interval between gun-up and drill-out. Areas for future studies are also broadly Outlined.

Jan 1, 1975

By D Hart

In 1944 some ten or so pieces of legislation impacted on the mining industry. Today in excess of 80 in one way or another apply to the Northern Territory miner. This paper will look at the nature of the legislation that has been introduced and the reasons for its introduction. During the Second World War the mining of resources such as iron, tin etc for the war effort set the platform for the subsequent expansion of the industry in the post-war years. Thereafter, the change in attitudes over the years that have resulted from a more conscious public and more responsible governments and developers associated with the recognition of the legal rights of others and the threat of litigation, will be traced. With a major review of the Northern Territory Mining Act currently in progress, this paper will view ANZMEC's foreshadowed preference for a National Code and the NT's intent of drawing some commonalities with other states of Australia to achieve this aim. Finally, the questions of over-regulation and whether existing legislation is complete will be addressed. From this it is foreshadowed how legislation may develop during the lead into the 21st century.

Jan 1, 1994

To enable AN-FO .tòo' be used on an equal .weight basis wish Nitro Gl reerin.e expl3oòsives r smaller diameter bore holes became necessary With consequent modifications to drill steel and burden on holes, De't'onation of AN-FO "in small diameter holes proved successful' both with 'and without primer charges but some altorat-ions were required to. adopt Anolodeòr.s to the smaller -holes, Important factors in training all operators In the new charging method were the retention of imp-,cved, fragmentat'ion, avoidance of excel ive ove:break and keeping wall rock dilution 'to an absoluato mi. iArurle ò The ò successful storage of Ammonium 14t-rate in c"!ime.tic conditions 'with daily'.-' temperature fluctuationc above and below the critical' 90¦F, has. been "achieved,

Jan 1, 1964

Companies involved in the mining industry are exposed to risks, referred to as corporate risks, as part of the business process. Directors and management should be aware of these risks and make appropriate business decisions to address each risk. If business risks are not addressed on a timely basis the consequences are likely to be serious and will adversely impact the ultimate success of the business.The key corporate risks are:Poor cash flow and treasury management. ò Incompetent or unmotivated staff.ò Poor product quality.ò Accounting systems that do not provide meaningful and timely information.ò Computer system deficiencies. ò Ineffective credit screening.ò Assets not adequately protected.ò New ventures undertaken that are either inappropriate or not adequately researched.Exposures to corporate risk should be dealt with by Directors and management by systematically identifying major risk areas and implementing appropriate internal and management controls to deal with such risk areas. Proper management controls and procedures include the setting of overall corporate objectives and policy, monitoring adherence to such policy, establishing early warning systems to highlight problem areas and maintaining security over assets.

Jan 1, 1990

By Sillet R, Corin P. J, Wilson G

Zinc Corporation of Broken Hi11 had some long hole stopes coming into use which could not be mined using diesel loaders, because of ventilation restrictions. In preference to use of pneumatic loaders, and because there were no field proven electric loaders in Australia, Horwood Bagshaw Ltd., were commissioned to repower a diesel loader with an electric motor, within the confines of the existing machine

Jan 1, 1977

By Just J, Nguyen G, Dunn J. G, Graham J

A sample of pyritic gold concentrate was investigated by wet chemical and electron optical techniques. Sub-samples were roasted in a laboratory scale fluidized bed roaster in the temperature range 400-700¦C. The calcine was characterised, and cyanide-leached using a standard bottle rolling test. Gold extraction efficiencies varied with roasting temperature. At temperatures of 400 and 450¦C gold ex- tractions of less than 40% were achieved, but between 500-700¦C the extraction had increased to 93--98Z. The surface area of the calcine varied with roasting temperature, reaching a maximum at 500¦C. There was no correlation between the surface area of the calcine and the efficiency of gold extraction.

Jan 1, 1987

Diagnostic Monitoring of Concentrator Circuits with Random Forest Models

Sep 13, 2010

The Koongarra uranium deposit was discovered in August 1970 by Noranda Australia Limited. Denison Mines Limited acquired the rights of ownership in October 1980 and has continued the 'struggle' to bring the proposed mine, containing approximately 13 300 tonnes of U308 of Indicated ore and having a value of $1 billion (1984 dollars), into operation. During the 14 years that have passed, the owners have found it necessary to deal with numerous Federal, State and Territory government departments, aboriginal representatives, handle thousands of communications, attend and convene countless meetings and spend millions of dollars. This paper addresses the history, the requirements, the problems and the costs to date for what - no return.

Jan 1, 1984

By Brasnett TC

A wide variety of problems are encountered on a day to day operating basis in the Isa Mine Concentrators. These vary from complex textural problems in the lead-zinc concentrator and their subsequent effect on grinding and flotation to scheduling of converter slag treatment in a chalcopyrite concentrator. With the advent of process control, metallurgists need to specialise and keep up to date with technology improvements. This paper will attempt to describe the significant problems'faced by a Metallurgist û Control.

Jan 1, 1978

Integrated chemical thermodynamic software and computerised databank systems have evolved over the last 15 years. The extent to which these systems have automated thermodynamic calculations relevant to extractive metallurgy is examined. The scope for further automation and the role of the expert consultant is discussed.

Jan 1, 1991

I must tell you at the outset that I come to this conference deeply disturbed at the `role of Government in international dealings in mineral and energy resources'. I am disturbed by the confusion that now passes for policy. I am disturbed by the short- range view of critical problems taken by a majority of Governments. I am equally disturbed by the even shorter range of view taken by a growing army of industries. Many of them clamour for Governments to solve their problems in a specific way, with little regard for any other sector but their own-and with even less regard for the fact that every time a Government takes over some of their responsibilities they surrender some of their freedom. I would not say that longer range views don't exist. But I would say that they don't prevail at the present time. Instead, we are seeing the con- stant development of many policies for individual problems which don't tackle the fundamental causes. We must get back to basics without delay.

Jan 1, 1978

By Yang RL, Bailey ML

During overburden blasting operations in dragline pits, coal edge losses along the lowwall edge of the new pit are often experienced. In tonnage terms, losses can be significant. With the thick seams at Callide Mine, 20,000 tonnes of coal can be lost along a 600 metre pit. In addition to the immediate dollar value of the coal, replacement of this coal (from which overburden has been removed) will be from higher ratio and higher cost pits in the future. Unit costs of production for the remainder of the coal uncovered in the current pit increase. Experiments involving variation of blasthole inclination and/or amount of standoff on the front row of blastholes have given no significant improvement in the coal edge loss control.

Jan 1, 1988

By S F. Simmons, A McOnie, J L. Mauk

Three cross sections, 200 m apart, display the distribution of indicator hydrothermal minerals across the Empire zone of the Golden Cross epithermal Au-Ag deposit, Waihi, New Zealand. These minerals are used to interpret the temperature and composition of hydrothermal fluids. The distribution of interstratified illite-montmorillonite and illite indicate that temperatures ranged from 140 to >220¦C, with temperatures above 220¦C predominating. The mineral assemblage of quartz-adularia-chlorite-illite-calcite-pyrite envelops the Empire vein system and stockwork, and reflects formation from an alkali chloride water whereas the mineral assemblage of replacement calcite-interstratified illite û montmorillonite-kaolinite forms a carapace and reflects formation from a CO2-rich steam-heated water. Alkali chloride waters appear responsible for the epithermal Au-Ag mineralisation.

Jan 1, 1995

By Richardson F. A

Techniques for flotation optimisation were investigated at Cobar [lines Pty:Ltd., in anticipation of the proposed installation of a computer and on-stream analysis. Successful laboratory and pilot plant tests for flotation performance optimisation using the Simplex Evolutionary Operation Technique (Simplex) lead to a full scale plant test using this method. The index developed for" Simplex response evaluation of flotation performance was based on metallurgical and economic criteria. This index was further modified to minimise the effect of head grade fluctuations. The test program was carried out on one of two parallel copper flotation circuits to allow comparison with normal "manual" operating control, and was conducted for thirty eight shifts. Results from the test section operating under Simplex direction were superior to those obtained using normal "manual" operating techniques and demonstrated the use of the Simplex Evolutionary Operation Technique as a method of reducing reagent consumption in flotation but, at the same time, maintaining satisfactory metallurgical performance. Experience in the use of the technique indicated the need for modifications to the rules of Simplex operations. Modifications were proposed, tested and appeared satisfactory.

Jan 1, 1973

By Smitham J. B

A selection of Australian washed coal samples was examined to determine the effect of sample hydrophobicity (rank) and particle size on froth stability in the flotation process. The results indicate distinct rank-based variations in froth volume and stability for flotation tests conducted without the use of collector, over a series of particle size distributions.High-rank coals showed a greater tendency to generate stable, high-volume froths than coals of lower rank. Implications for circuit design and operation are outlined.

Jan 1, 1988

By N F. Glenn, S Thiruchittampalam, B P. Banerjee, S Raval

The determination of shear strength parameters for the spoil material plays a crucial role in the assessment of a dump’s stability; nevertheless, their evaluation necessitates laborious laboratory experiments. In order to address this issue, Simmons and McManus (2004) formulated a framework that serves as a foundation for categorising spoils according to their distinctive shear strength parameters based on observable and tactile characteristics. This framework, previously identified as the ‘BHP Mitsubishi Alliance Coal (BMAC) Spoil Shear Strength Framework’, is now recognised as the ‘CoalSpoil’ framework. The spoil characterisation provided by the CoalSpoil framework offers benefits but is not without limitations. The examination of these attributes in the field is a time-consuming task that demands expertise. Subjectivity arises in the spoil characterisation when attributes straddle the line between two categories, such as delineating matrix-supported and framework-supported fabric structures. To enhance consistency in the spoil characterisation process, minimising human intervention is crucial to mitigate bias, classification errors, and safety risks. This study seeks to achieve this aim by introducing image-assisted and automated methods for spoil characterisation.

Sep 1, 2024

Almost from the beginning of civilisation the inhabitants hadlearned the art of recovering and working copper to produceitems which were of use to society.From the early beginnings of the use of copper which can betraced back 6000 years and more, there has been an evolutionaryprocess accentuated in more recent times in which the art ofproducing alloys particularly with tin and latterly zinc and otherelements, has given society a wide range of useful alloys for usein industrial, domestic and architectural applications.

Jan 1, 1995