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By M S. Henderson, R D. Alorro, L G. Dyer

An alternative leaching system for rare earth element recovery from monazite is under development. The initial stage utilises oxalic acid to convert the rare earth phosphate into an oxalate salt through dissolution and reprecipitation and it is the efficiency of this stage that governs the overall recovery achieved. It has previously been proposed that lixiviant consumption is the primary limitation in this process. This work further investigates a range of conditions in an attempt to further elucidate the factors influencing the achievable conversion in this stage. It has been shown that the pH may be governed by multiple reactions both consuming and producing acid (thus the mild change over time). The importance of proper mixing and potential to operate at lower temperature with only moderate impact on kinetics has also been demonstrated. Staged/sequential leaching is more effective in fresh solution as opposed to restoring the lixiviant concentration with subsequent reagent addition, suggesting some impact of solution composition. However, contrary to previous findings, subjecting the leach residue to fresh solution resulted in significant decline in leach rate and overall dissolution. This may be because a greater proportion of conversion was achieved in stage 1 in this work than in previous investigation. This may indicate that eventual passivation or the presence of some more refractory REE minerals limits dissolution. Iron dissolution was relatively consistent upon exposure to fresh solution, displaying the ability of the solution to continue to leach the goethite component of the concentrate.

Aug 24, 2022

By Espi J

The Nena high sulphidation deposit, located in the Sandaun Province, PNG, contains a measured and indicated resource of 51 Mt of copper ore grading 0.5% Cu and 0.6 g/t Au at a 0.5% Cu cut-off. The copper orebody is overlain by an 18Mt oxide gold resource grading 0.1 % Cu and 1.4 g/t Au at a 0.6 g/t Au cut-off. The deposit is hosted in advanced argillic altered pyroclastics interstratified with lavas, volcanoclastics, epiclastics and sediments of the Debom Volcanics within the Frieda River Intrusive Complex. Foraminiferal sediments indicate the Debom Volcanics to be Early-Middle Miocene in age. Alteration is elongated along, and concentric about a northwest trending structure (Nena Structural Corridor) which is about 7km in length. The inner two alteration types, residual and massive silica-alunite are strongly brecciated and host the bulk of later hypogene Cu-Au mineralisation. Weakly mineralised weak silica- alunite and barren peripherally zoned clay alteration surround the inner mineralised alterations. The hypogene sulphide deposition was polyphasal, episodic and is zoned from north to south from covellite-enargite ¦ chalcocite (5600N to 5200N) to a mixed enargite-luzonite (5200N to 4700N) to luzonite-stibioluzonite (4700N to 4400N) in the south within a 1200m long by 300m diameter sub horizontal pipe like body. Paragenesis studies indicate that pyrite ¦ marcasite were introduced early with barite and black native sulphur before deposition of banded pyrite (melnicovite) with barite during a period of brecciation. Continued brecciation allowed bladed covellite ¦ chalcocite followed by enargite-luzonite-stibioluzonite ¦ pyrite (brassy) and minor acicular covellite deposition. Yellow native sulphur and trace amounts of galena were deposited in remaining pores. Pre-acid alteration intrusives domed the mainly volcanic stratigraphy in the southwest and post-mineralisation porphyries in the northeast truncate mineralisation. Supergene processes and erosion have modified the top of the deposit, creating a 45m thick goethitic-scoroditic-haematitic gold cap above a 40m thick (on average) chalcocite rich supergene blanket. Lesser amounts of digenite, covellite native copper and rarely seen malachite occur in the supergene copper zone.

Jan 1, 1997

By van der Walt TJ, van Deventer JSJ, Reuter MA

Owing to their complexity, many metallurgical processes are difficult to model fundamentally, and as a result more attention has been focused on the use of artificial intelligence techniques to simulate these processes. In this paper recent advances in the use of neural nets to model processes not amenable to conventional methods are discussed. These include the application of a new modelling methodology based on the use of neural nets for the dynamic simulation of metallurgical processes, the use of conventional techniques in conjunction with neural nets to simulate gravity separation circuits, as well as the detection of gross errors in variable measurements by means of a neural net representation of the relation between measurement and constraint residuals.

Jan 1, 1993

By J J. Plumb, P D. Franzmann

A study was conducted to describe the microbiology of the MICCL Monywa chalcocite heap bioleaching operation. Microorganisms were detected in the heap using culture-based techniques and cultureindependent PCR-DGGE analysis of the 16S rRNA gene. The metabolic requirements, temperature and pH optima were determined for selected strains isolated from the heap material. Six strains (BH1-BH6) were enriched and isolated from heap solids and leachate samples. Phylogenetic analysis of the 16S rRNA genes showed that strains BH3 and BH4 were closely related to the acidophilic bacterium Acidithiobacillus caldus and strains BH5 and BH6 were closely related to Leptospirillum ferriphilum. The optimum growth temperature for L. ferriphilum was 41.3¦C and the optimum pH range was 1.1 to 1.5. A new species of Archaea was isolated from the heap samples. Cells of the proposed species, Ferroplasma cyprexacervatum (æcyprusÆ L.n. meaning copper; æexacervoÆ L.v. meaning æto heap upÆ), are non-motile pleomorphic cocci, capable of chemomixotrophic growth with ferrous sulfate and yeast extract. Cells grow anaerobically on ferric iron in the presence of potassium tetrathionate and yeast extract as electron donors. Growth occurs from 14¦C to 63¦C, with an optimum temperature of 55.2¦C. The optimal pH for growth was 1.0 - 1.2. The species was phylogenetically most closely related to Ferroplasma acidiphilum with a 16S rRNA gene sequence similarity of 95 per cent. Molecular analysis of mine samples (16S rRNA PCR-DGGE) detected the above-mentioned cultured strains of microorganisms as well as species of Sulfobacillus and other unknown Proteobacteria. The microbial community of the Myanmar bioleach heaps contained similar levels of diversity to a dump bioleach operation in Chile, but contained greater amounts of biomass than another heap bioleach operation in Australia. The operating parameters of the Myanmar heaps (low pH and moderate temperature) have selected for the growth of moderately thermophilic microorganisms that are more commonly found in extremely low pH acidic mine drainage sites than in heap systems. The novel species of Ferroplasma is thought to be involved in the aerobic and anaerobic cycling of iron within the heap bioleaching environment.

Jan 1, 2004

By J Pan, G Qiu

In this paper, an analysis is made of the present situation in the Chinese steel industry and its demand for iron ores. It is shown that the demand for iron ores has been growing substantially with the rapid development of the steel industry all over the world, especially in China. However, the iron ore market is currently in the situation where supply exceeds demand due to the economic crisis, with more investment in mines and less output of steel for several years ahead all over the world. Gigantic pressure is confronting the Chinese steel mills due to the too high and irrational price of iron ores. It is time to return the price of iron ores to a normal position much closer to their value. More attention has therefore been paid to developing low-grade and complex iron ore resources in China due to the irrational price of imported iron ores. More innovative mineral processing processes have been developed to tackle these complex resources. A systematic introduction to the development of beneficiation processes for low-grade iron ores is provided, including upgrading low-grade siderite, limonite, micron sized haematite and magnetite resources.

Jan 1, 2009

By Moritz P

Thiourea has been recognised for a long time as an acid-stable complexant for gold. Generally, the use of thiourea has been shown to exhibit enhanced leaching kinetics compared to cyanide but suffers the disadvantage of excessive reagent consumption. Thiourea leaching is particularly com- patible with the extraction of gold from refractory ores. This is due to the need for an oxidative pretreatment to liberate the gold. Such pretreatments typically result in the production of an acidic residue. The application of novel thiourea leaching technologies to the extraction of gold from a bioleached pyrite concentrate was investigated. The interac- tion of leach variables with thiourea consumption and gold extraction was established. An economic assessment of thiourea leaching was compared with conventional cyanidation. The results indicated that gold leaching of the bioleached residue using thiourea compared very favourably with cyanidation.

Jan 1, 1991

Sample preparation for gold samples, where the distribution and size of gold particles is often irregular, usually demands that a relatively large sample weight is taken to produce a representative sample for analysis. Traditional sample preparation of gold samples incorporated multiple stages of coarse particle size reduction followed by subdivision of the sample prior to final fine pulverising. This technique developed because of the limited equipment options available to laboratories. As a result significant errors are introduced and the final sample size being pulverised is a small fraction of the original sample weight. Three significant developments have occurred in the last 25 years to significantly improve sample preparation of gold samples: 1.  large capacity fine pulverising,2.  fine jaw crushing, and3.  whole sample coarse pulverising. In the mid-1980s an Australian manufacturer developed large capacity pulverising bowls which had the ability to reduce samples with a mass of 1.5 - 3.5 kg to a nominal 0.075 mm product in approximately three to five minutes. Laboratories were able to produce a large homogeneous pulverised sample which significantly reduced the error in sampling. However, exploration and mine samples are usually 7 to 10 kg and the sample requires a subdivision stage following crushing to produce the 3.5 kg for the pulverising step, thus introducing potential for significant error. The development of fine jaw crushing allowed particle size reduction to -2 mm which reduced the subdivision error of the bulk sample prior to fine pulverising. Subdivision of the crushed sample at -2 mm still results in potential sampling errors, where the gold particles are not sufficiently liberated to be representatively sampled. Clearly the best option would be to reduce the particle size small enough to ensure a representative sample prior to final pulverising. Continuous mills offer a partial solution but are relatively slow and subject the sample to differential pulverising prior to subdivision. Clearly this does not provide the best solution for routine laboratory applications where high volumes of samples are to be processed. The recent development of a large capacity coarse pulverising system allows samples of up to 10 kg to be reduced to -0.25 mm prior to subdivision, and fine pulverised to -0.075 mm. Laboratories now have the necessary equipment to perform reliable large capacity sample preparation of gold samples. The exact choice of a sample preparation scheme may still depend on particular ore types but the need for multiple crushing and subdivision stages is redundant.

Jan 1, 2008

Byproduct coking is practised in three of the major Australian ironmaking centres, the Newcastle and Whyalla works of the Broken Hill Proprietary Co. Ltd. and the Port Kembla works of Australian Iron & Steel Pty. Ltd. Coking first commenced at Newcastle in 1915 and at Port Kembla in 1938. The installations established at these centres include coal cleaning facilities and com- plete byproduct streams. The Whyalla plant, because of its location is somewhat less extensive, having no coal cleaning plant and a comparatively restricted byproduct section. As new batteries have been built every opportunity has been taken to incorporate modern design features and improved operat- ing techniques. This has included the provision of equipment to reduce atmospheric and water pollution. A marked reduction of markets for byproducts has had serious repercussions on the profitability of this section of the Industry.

Jan 1, 1972

By N TassT, J Cyr

At the East Sullivan site, wood wastes covering the abandoned mine tailings impoundment prevent sulfide oxidation by creating an anoxic environment. The addition of coarse ligneous wastes and their high permeability favour infiltration, resulting in a water table rise that maintains most tailings under water saturation and thus provides an additional protection against sulfide oxidation. Moreover, high infiltration allows a more rapid flushing of acid prone groundwater generated prior to the cover placement, which could cause acid mine drainage over a long period of time. Finally, the pore-waters under the cover are characterised by a strong reducing potential, high alkalinity, and near neutral pHs. These conditions favour sulfate reduction and base metal precipitation as sulfides and as carbonates. Pore-water composition monitored from 1992 to 1998 showed a significant Fe2+ decrease, following cover placement. Thereafter, the restoration strategy capitalised on the alkaline and reductive properties of the waters underlying the wood-waste cover. An original treatment of acid effluents, based on the recirculation of water discharging around the impoundment through the organic cover, was implemented. In 2002, the recirculated water from May to October had a mean pumping rate of 240 m3/h, for a total volume of 800 000 m3. Data gathered near the dispersal zone from 2000 to 2002 show that despite the recirculation of acid water (pH ÿ3), the pH decreases by only one unit from 7 to 6, during the recirculation period, ie from May to November. However, alkalinity decreases from 800 to 100 mg/L-CaCO3. Despite this decrease, the alkalinity is back up to 800 mg/L-CaCO3 the following May, thanks to sulfate reduction. From 2000 to 2002, Fe2+ concentration in the pore waters near the dispersal zone is maintained below 2 mg/L. Evolution of surface water quality suggests that the contaminated groundwater flush is completed in the north and north-west area of the impoundment; the east sector is under recovery, while the south sector remains the most problematic. A wood-waste cover, besides limiting sulfide oxidation, can fill the role of alkaline reducing barrier for the treatment of these acidogenic waters, until a balance between acidity and alkalinity in the effluent is reached.

Jan 1, 2003

By D Giddings, S A. Silvester, S Pickerin

Underground fires represent a constant threat to the safety of underground personnel. Miners in the immediate vicinity may face intense heat, blinding smoke, toxic fumes, fall of ground and other direct effects of a fire. However, the vast majority of victims never actually see the fire, and are overcome either by deadly fumes in the ventilating current or by asphyxiation. The mine ventilation system, which maintains a sustainable atmosphere to the working places, can transport products of combustion with equal efficiency. Miners who are remotely situated from a fire may be forced to evacuate considerable distances, through dense smoke and fumes, or even become cut-off from escape. Additionally, miners may become confused by unfamiliar ventilation characteristics caused by fires. Conveyor belts are widely used for transporting minerals in mines as well as in many other industrial situations. Because they contain large amounts of polymeric materials their use in certain environments, especially coal mines, but also in steel works, power stations and other enclosed areas must be controlled to minimise the fire risk. Over last nine years there have been 60 fires in underground mines in the UK alone and that of these, half have been associated with conveyors. This paper summarises the results obtained from a recent research project that has developed a preliminary computational thermal and fluid dynamic model to represent the spread of flame along a typical conveyor belt used in UK deep coal mines. The results of these models have been calibrated against a series of experimental tests performed within a surface fire test gallery. An improved knowledge of the burn characteristics and rate of release of the products of combustion from conveyor belt fires will assist in the development of better fire detection and fire fighting techniques.

Jan 1, 2005

By L Huang

"Successful rehabilitation of tailings landforms of tens to thousands of hectares in size at base metal mines is critical to mining companies’ ‘social licence to operate’. Rehabilitation technology used is closely related to both the economic sustainability of the mining company and the ecological sustainability of the mined environment. Conventional technology to rehabilitate mine waste landforms is costly and constrained by the availability of soil (to reconstruct root zones) and clay materials (to reconstruct compressed layer). Depending on mine waste properties and site-specific resource availability, it is not uncommon to cost A$0.1–0.5 M/ha for the establishment of conventional cover systems over mine waste domains, which often accounts for large proportion of the total closure costs. This can lead to costs approaching several hundred millions dollars for rehabilitating larger tailings and acidic waste rock using conventional cover systems.The present extended abstract proposes a suite of new technologies to tackle the problems outlined above and discusses critical factors in successful rehabilitation from substrate levels to the whole landform performance, in two key aspects:in situ engineering of tailings soil to offset/reduce materials requiredin situ chemical engineering of massive hardpan layer through alkali-activation and mineral gel cross-linking network mechanisms to encapsulate reactive tailings and achieving sustainable hydro-geochemical stability in root zones.This aims at functionally replacing the roles of the compressed clay layer and capillary breaks in conventional covers. These technologies would improve both the economic and ecological sustainability of mine waste rehabilitation, thus addressing the triple-bottom line of mining and mineral processing industries not only in Australia but other countries.CITATION:Huang, L, 2016. Emerging technology for economic and ecological sustainability in the rehabilitation of metal mine tailings, in Proceedings Life-of-Mine 2016 Conference, pp 128–131 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Jun 28, 2016

By F T. Suorineni

Empirical methods are deeply rooted in geomechanics. This is a consequence of the recognised complexity of the nature of the rock mass. The usual assumptions of material continuity, homogeneity, isotropicity and linear elasticity often assumed for soil, concrete and steel are difficult to justify in a rock mass except for mathematical convenience. These assumptions form the bases for most mechanistic, analytical and numerical methods in geomechanics. Believers in empirical methods argue that the complexity of the rock mass and its interaction with structures developed in it is adequately accounted for in empirical methods, which compensate for our ignorance.Franklin (1993) defines empirical design as quantified judgement based on experience. He further states that empirical methods often prove ‘closer’ to the ‘truth’ than the apparently more precise predictions of theoretical analysis, adding that based on real data empirical methods provide a standard against which theoretical predictions are measured and can be judged. This paper takes a critical look at the common empirical methods in geomechanics – rock mass classification systems (Bieniawski, 1973; Barton, Lien and Lunde, 1974; Hoek, 1994a), Laubscher block caving design rules (Laubscher, 1994), the stability graph (Mathews et al, 1981), pillar design equations (Salamon and Munro, 1967; Hedley and Grant, 1972; and their derivatives), pillar design chart (Lunder and Pakalnis, 1997) and failure criteria (Hoek and Brown, 1980; and its derivatives). The common thread in the application of these methods is that in most cases they are often applied blindly without an understanding of the underlying assumptions and database limits. This paper emphasises that users of these methods need to know the underlying assumptions, database limits and inherent hidden risks that are often unmentionable for their satisfactory use. Finally, suggestions are provided for the efficient use of empirical methods and how they can be improved.CITATION:Suorineni, F T, 2014. Reflections on empirical methods in geomechanics – the unmentionables and hidden risks, in Proceedings AusRock 2014: Third Australasian Ground Control in Mining Conference , pp 143–156 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 5, 2014

By E R. Ramanaidou, M A. Wells

Asian steel mills are demanding iron ore with specific chemical, mineralogical, metallurgical and environmental properties to warrant that the ore is of the greatest quality. As a result, a toolkit of analytical techniques becomes important. Hyperspectral analyses of iron ore cores and chips using a HyLogging™ system are now routinely undertaken by BHP Billiton Iron Ore in Western Australia for banded iron formation-hosted iron ores and channel iron deposits to better characterise their iron ores. Objective information can now be expanded by adding new sensors. The current HyLogging™ system provides point analysis reflectance spectra and a red–green–blue high-resolution image, while recent developments, such as hyperspectral imaging using the Corescan system, now provide full spectral image and surface topography. The addition of Raman spectroscopy provides the ability to detect and quantify quartz and magnetite (or maghemite) and cross validate hyperspectral information on hematite and goethite and aluminium substitution in the iron oxides. Micro-X-ray fluorescence mapping also adds chemical information appropriate for cross validation with the aforementioned methods. This paper demonstrates the value of combining these techniques for an optimum characterisation of iron ore.CITATION:Ramanaidou, E R and Wells, M A, 2015. A new toolkit for iron ore characterisation, in Proceedings Iron Ore 2015, pp 587–590 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 13, 2015

By M Ruhrberg, J Grassmann, C Bauer

Within the context of acid mine drainage (AMD) associated with mining activities worldwide there has been a tremendous research effort to determine the extent of AMD and assess the influencing factors controlling this process. However, the majority of the current approaches focus on local and regional scale case studies and do not provide a global scale picture of AMD potentials. This study attempts to develop a method aiming at a global environmental impact assessment related to AMD. To confine the complex topic this study concentrates on acidic emissions from heaps in consequence of copper mining processes. In order to pursue this approach two factors are of significant advantage: a comprehensive environmental data base of more then 600 copper sites worldwide and a method which has been developed and proven to be successful in assessing environmental impacts related to land use. Current and future research efforts focus on using this background knowledge to enable both a comparison between sites and a categorisation of sites according to emission estimates.

Jan 1, 2003

A broker relies heavily on mineral valuations and independent experts' reports to provide the fundamental information, both technical and commercial, which provides the basis of estimating the sharemarket value of securities and underlying assets. It is important to appreciate the significant variance that can occur between the market value and other types of valuation at a particular point in time. In general, most experts' reports and valuations seek to provide estimates of technical/fundamental or ""fair"" value which correspond to the Corporations Law and accounting standards requirements. They do not usually attempt to estimate (stock) market values and it is usually and quite correctly the broker's task to estimate market values on the basis of a technical appraisal and consideration of all other commercial, market and financial influences. Therefore ideally, an independent experts' report or information memorandum will include material relating to commercial and management aspects of a company as well as detailed technical reviews and fundamental valuations. Wherever sensible cash flow projections can be made, cash flow-derived valuations, usually based on discounted cash flow (DCF) calculations, remain the preferred valuation methodology. Brokers in general would not argue with this preference. However, there is a paucity of examples of valuations where alternative methods are applied as a check on the reasonableness of a DCF-based estimate.

Jan 1, 1994

During the 1950's there was a flurry of activity on the design of main ventilation shafts for mines. More recently, a new ana- lysis was commissioned in relation to the multi-shaft, nuclear waste isolation facili- ties currently under design in the United States. This paper presents the major find- ings of that study and should prove of value as a reference in the design of proposed new shafts. An overview of mine shaft resistance introduces the effects of the shaft walls, fittings, conveyances and shaft stations. Each of these is analyzed in turn. A com- pletely new technique is described, which facilitates the estimation of wall resis- tance. The effect of size of a conveyance is quantified and shown to be dominant when the cage occupies more than 30 per cent of the shaft cross-section. The dynamic effects of a moving conveyance are also analyzed.

Jan 1, 1988

By S Servant, T J. Bidwell

Paste backfill technology is gaining rapid acceptance in the Canadian mining industry. The authors were able to work on four different mining sites employing paste technology in their operation. In each site the paste backfill is prepared with very fine tailings containing significant amounts of sulphur minerals. The research program involved laboratory testing on samples prepared in the laboratory, on control samples obtained at the backfilll plant during pouring into the stopes and on core samples obtained from drilling in backfilled stopes. The laboratory testing provided detailed knowledge of the mechanical behavior of the paste backfill. The need for a means of measuring the in-situ mechanical properties of the backfill became clear. A review of various trials published in literature and an evaluation of available technology suggested the Cambridge Self-boring Pressuremeter. A first field campaign confirmed the efficiency and dependability of this instrument leading to the conclusion that it offers a very good method for the in situ measurement of paste backfill properties.

Jan 1, 1998

By G Showers, R Triglavcanin

The complexity of understanding the whole thickening process to achieve real performance improvements cannot be underestimated. The last significant change in feedwell design was more than 15 years ago with the introduction of self-dilution systems û firstly with OutotecÆs Autodil, followed by FLSmidthÆs E-Duc. Now, following many years of extensive in-house research, including close collaboration with AMIRA and the CSIRO, Outotec has launched the next generation Vane Feedwell. The Vane Feedwell has been globally patented and installed at various sites. This paper briefly outlines the feedwellÆs development using CFD modelling and its subsequent performance in a æreal lifeÆ site installation. Plant results of the first commercial Vane Feedwell, in a mineral sands application, are discussed. The Vane Feedwell was retrofitted so comparative data of pre- and post-installation is shown.

Jan 1, 2009

By Rowe J

The case study is based on the largest ore deposit at Mt. Lyell; the Prince Lyell deposit, comprising a regular lensoid mass of dissemina- ted and vein pyrite-chalcopyrite mineralisation. Reserve estimation employs conventional techniques, based on diamond drill hole and relevant development sampling data. Probable ore reserves are estimated using the contouring (isoline) method an longitudinal projections for ore thickness and accumulation (m %Cu) at a '0.8% Cu' cutoff. Final stope and pillar res- erve estimates (proved ore) are derived from designed ring tonnages and contoured accumula- tion for individual mining units, following more intensive sampling. Systematic grade control procedures have been adopted and individual stopes and pillars reconciled against mill production. The proved ore estimates have been found to com- pare favourably with the reconciled production.

Jan 1, 1979

Qualitative measurement of respirable dust in metal mines is limited and an example of this is demonstrated at Northparkes Mine, where operational experience was sought for measuring dust standards and identifying exposure limits. However, relying on operational experience has limited value due to variation in observations from person to person and is based on visible dust (which is larger in size than respirable dust). However, with sophisticated dust measuring equipment, like the real-time aerosol monitor, dust concentrations can be accurately measured and recorded concisely. Research conducted as part of a collaborative agreement on behalf of Northparkes to launch an occupational dust monitoring program was implemented on the mine site. To form the basis of this research, it was hypothesised that no proper dust measuring testing at the mine site had been adequately identified. In addition, existing occupational hygiene monitoring programs did not adequately quantify employee exposures to these hazards. This project will outline the results of an occupational dust monitoring program, hence greatly improving the capacity to quantify the health risks posed to employees.

Jan 1, 2008