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By I Zh Bunin, V A. Chanturia, V G. Minenko, M V. Ryazantseva, A L. Samusev

A promising source for the extraction of rare metals and REEs in Russia is the eudialyte ores of the Lovozero deposit, which do not contain active uranium components. The eudialyte ore reserves of the Lovozero Massif are considered virtually unlimited and therefore have the potential to become a primary source of a number of rare and rare earth metals. The goal of this study was to comprehensively examine the effect of the parameters of high-power nanosecond electromagnetic pulses (HPEMP) and dielectric barrier discharge (DBD) on the leaching performance of eudialyte concentrate and the selective separation of zirconium and REEs from productive solutions. Using scanning electron microscopy and infrared spectroscopy, the mechanism behind the intensification of acidic dissolution of eudialyte as a result of pretreatment with energy impacts was described. During the HPEMP treatment, weakening and destruction of the eudialyte surface was observed, which at the substructural level is expressed in the deformation and local destruction of Si10O27, Si9MO30 resulting in formation of microcracks. During the DBD treatment, the formation of characteristic defects was observed in the form of imprints of dielectric breakdown microchannels and individual mineral fragments. Pretreatment of eudialyte concentrate using HPEMP made it possible to increase the recovery of zirconium into the pregnant solution of leaching by 3.4–4.3 per cent (from 86.6 per cent to 90.9 per cent) and by 4.1 per cent (from 86.6 per cent to 90.6 per cent) when using DBD. The increase in the total recovery of REEs was 1.2–1.8 per cent (from 87.7 per cent to 89.2 per cent). The effect of pH values, solution temperature, initial concentrations of valuable components on the successive recovery performance of zirconium and REEs from the pregnant solutions nitric from the acid leaching of eudialyte concentrate by chemical precipitation was examined. The possibility of selective separation of the zirconium product and rare earth elements with a zirconium recovery of 99.95 per cent and a REE recovery of 87.5 per cent was established. REE loss with the zirconium product was 8.0 per cent and 4.5 per cent with the spent pregnant solution.

Aug 24, 2022

By Clark IH

Numerical modelling is an effective aid for the planning and design of underground coal mines. With funding from the National Energy Research Development and Demonstration Program, CSIRO Division of Geomechanics has produced a workstation environment which will allow the Australian Coal Mining Industry access to a wide range of numerical design models. The emphasis is on usability and simplicity and the long-term aim is that the techniques should be used routinely at the mine site, so that, in the future, design of a new underground mine will routinely involve modelling of each proposed layout.Each of the five numerical analysis programs, FESOFt, FLAC, MNLAY, FEBLK and UDEC has both strengths and weaknesses. Some analyses with each program demonstrate areas when; observed in situ behaviour in underground coal mines has been successfully modelled, and the results of site monitoring provide a basis for comparison with the predictions of numerical models.

Jan 1, 1991

Hamersley Iron Pty. Limited mines and pro cesses iron ore from two orebodies at Tom Price and Paraburdoo, situated in the North West of Western Australia. Conventional open pit mining methods are used at both sites in that material is drilled and blasted in benches, loaded by shovels and hauled to the Primary Crushers or dumped on waste or low grade material stockpiles. The present drilling fleet, consisting of eight high capacity Bucyrus Erie Rotary drills has evolved from an initial fleet of a large number of small percussion rigs. There are significant physical differences between the ore types encountered at both mines which nec- essitate the drilling of smaller diameter blast holes at Paraburdoo than those at Tom Price. The drilling practice at each site is dis- cussed, with examples of performance achieve- ments under varying drilling conditions.

Jan 1, 1978

By B C Tanda, E A. Oraby, J J. Eksteen

"Base metal and precious metal deposits are well known for their significant geometallurgical variation throughout the volume of the proven resource. At the metallurgical level, the plant normally processes an upper oxidised layer, a transition zone and a sulfide zone, often leading to different processing techniques for the different zones. A novel processing approach is presented whereby alkaline leaching with glycine is used to leach base and precious metals, using a copper-gold ore deposit as a case study. Glycine is a cheap, non-toxic, non-volatile, highly water-soluble crystalline solid produced industrially in bulk quantities. As a chelating ligand it forms a number of stable glycinate complexes with Ni, Co, Cu, platinum group metals (PGMs), Au, Ag, Zn, Pb, Hg and Cd, with broad stability regions over an extended temperature-pH-Eh range, allowing dissolution of these metals in the neutral and alkaline regions (pH 7–13). It has been shown that this lixiviant system can leach the metals from their oxide, oxy-halide, basic sulfate, carbonate, native and various sulfide forms, including refractory sulfides such as chalcopyrite. Extraction of the metals from their soluble glycinates is easily achieved using a range of solvent extraction and precipitation processes, and the glycine remains stable in aqueous solution for recycle and reuse. Minerals bearing metals in Groups 1 to 8 of the periodic table are normally unaltered. This technology therefore provides a highly selective leaching environment for the extraction of numerous scarce metals of economic interest, with minimal interaction with gangue minerals, whilst using environmentally benign reagents. Problematic leach residues such as jarosites, elemental sulfur and silica gels are averted through this processing approach. This technology allows hydrometallurgical processing that is much less domain-sensitive in the geometallurgical sense, and utilises essentially the same key reagents for the whole deposit.CITATION:Eksteen, J J, Oraby, E A and Tanda, B C, 2016. Developing Robust Hydrometallurgical Processes to Recover Metals from Deposits with Large Geometallurgical Variation, in Proceedings The Third AusIMM International Geometallurgy Conference (GeoMet) 2016, pp 15–20 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Jun 15, 2016

By J Rayo

Andean countries (Chile, Peru, Bolivia and Argentina) have 42 semi-autogenous mills (SAG) in operation and there are more than 30 projects in the pipeline that consider SAG mills. At the end of the next decade, the total amount of SAG mills in this area will likely be close to 100.There is a lot of reliable operational information collected by JRI Ingenieria Sociedad Anonima, the author’s engineering company, for more than 20 years and processed by statistical software, to be used as a reference for design basis of future projects or to improve operations by comparison. JRI Ingenieria Sociedad Anonima has reliable information related to the performance of more than 50 per cent of the Andean SAG plants.The paper presented considers a set of graphs that summarise the collected and verified SAG plants technical data. The figures will show key parameters as circuits and equipment data, energy consumption, technical availability, utilisation rates, throughput variability, pebble productions, steel consumption and others.The data is compared with typical design basis of several engineering companies and the main differences are analysed and/or commented on.CITATION:Rayo, J, 2014. Comparison of semi-autogenous mills operations in Andean countries, in Proceedings 12th AusIMM Mill Operators’ Conference 2014 , pp 283–296 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 1, 2014

By M Fishwick Tapia

This paper was prepared and translated from the final report of the investigation into the Codelco Chile Salvador DivisionÆs air blast which occurred in the Inca-West area. In this section of the block cave mine, a stable arch formed covering an area of approximately 15 000 m2 . This zone subsequently collapsed producing a massive air blast. The collapse followed a series of planned extraction activities and occurred on 5 December 1999. This paper discusses the cave back arching event and the measures that were taken in order to induce the controlled collapse. This was to minimise risk to personnel, equipment and installations. The results obtained to date are presented.

Jan 1, 2000

By Chunbao Z, Zhenchuan Z

As known to the international mining sectors, Hunan province, called as ' Nonferrous Native Area ', is the main base of nonferrous metals Pro- duction in China. There are over 194 nonferrous mines in this province, most of them distribute over the basin of Xiangjiang River. The state of management of wastewater in Hunan's nonferrous mines is outlined.The experiences and economic benefit in the management and treatment of wa- stewater in Bofang and Mayang copper mines, and at Shizhuyuan polymeta- llic mine, are mainly introduced. It concludes with measures and recommendations for future management and treatment of wastewater in Hunan's nonferrous mines.

Jan 1, 1988

By S H. Sie, R Seetharam, K Naito, T Takagi

Tin-polymetallic vein type deposits are one of the major source of metal producers in the Circum Pacific Belt. This type of deposit is of great importance for the modem electronics and medical industries because of their high content of rare metals (especially indium and bismuth). We have studied two representatives, Tosham of India (Cu-In-Bi-Sn-W-Ag-Au), and Mount Pleasant of Canada (Zn-Cu-In-Bi-Sn-W), using proton and electron microprobes in order to delineate the distribution of medicallhigh-tech rare metals. The electron microprobe study showed that major indium carrier in such type of deposit are roquesite (CulnS2), sphalerite, stannite and a Cu-Zn-Fe-In-Sn-S mineral; and that indium is incorporated in sulfides by coupled substitution like Cu + In = 2(Zn + Fe). The proton microprobe showed that indium at trace levels is also present in chalcopyrite and pyrite. In addition, zinc, copper, arsenic, antimony, selenium, tin, and bismuth are common in chalcopyrite and pyrite. Arsenopyrite contains nickel, copper, zinc, silver, tin, antimony and bismuth. In chalcopyrite and pyrite, zinc, arsenic, indium, bismuth and lead are higher in Mount Pleasant ore, but silver is higher at Tosham. Also thallium and gold were found only in Tosham pyrite. The Tosham deposit is genetically related to S-type magma, while the Mount Pleasant deposit is related to A-type granite. Tosham ore contains zinc-bearing biotites that coexist with chalcopyrite in ore bodies but Mount Pleasant ore lacks such biotite. We propose that the difference in elemental abundance between the two deposits are caused by the different character of source magma and different mineral associations of the ore body.

Jan 1, 1995

By Thatcher R

In areas where undeveloped land represents a scarce resource, an upgraded post mining land use can result in economic benefits to both the mining company and to the community. A study undertaken at Allied Queensland Coalfields Ltd's Aberdare Colliery located between Brisbane and Ipswich during 1986/1987, assessed the costs and benefits of developing the site following mining for grazing, forestry and residential uses. The proposed final land use plan comprised a combination of these uses which can be upgraded to higher valued uses once subsidence monitoring of backfilled opencut areas and dumps indicates that total settlement has reached acceptable levels. The study involved the documentation of existing site environmental parameters and the delineation of site opportunities and constraints. The unpredictable nature of settlement over backfilled opencuts and overburden dumps represents the major constraint to urban development on mined areas.

Jan 1, 1987

The paper continues an account, begun in a previous paper, of experimental work carried out by the author whilst a member of the metallurgical staff at the Cockle Creek Works. The general method of the description of the plant and works practice adopted previously has been followed.The paper is a short account of the methods used in and the results of an investigation of the fume losses from the various parts of the plant.MEASUREMENT OF VOLUMETwo independent methods were used. The first depended on a number of pitot-tube measurements of velocity. These readings were taken in the stacks leading from the various furnaces at a considerable height above the ground so as to obtain as regular conditions as possible at the points where the readings were taken.Three openings were made in each stack and the pitot tube inserted into each opening in turn and readings taken at the centres of imaginary areas of equal size. The average velocity in the stack was thus obtained.After four tests had been made at the smelter stack, which removed the gases from all blast furnaces in use, the centre of velocity of the gases for each test was calculated and was found to be practically constant in position. The previous procedure was varied in subsequent tests on this stack by taking a succession of readings at the centre of velocity instead of at various points...

Jan 1, 1925

By A M. L Smith, W E. Dubbin, K A. Hudson-Edwards

Jarosites (KFe3(SO4)2(OH)6) are examples of minerals that are highly effective scavengers of toxic elements, and are abundant in acid rock drainage systems, acid sulfate soils, metallurgical wastes and other contaminated sites. The K, Fe and S sites can be filled by toxic elements such as Cd, Cu and Zn, but the mechanisms of this incorporation are not well understood.We have used atomistic simulation methods to model the jarosite (102) surface and its interactions with Cd, Zn and Cu, in order to understand the mechanisms by which these potentially toxic elements are incorporated into the K-jarosite structure. Our results suggest that incorporation via a defect complex consisting of an impurity cation at the K site charge balanced by a K vacancy stabilises the (102) surface in the order Cu>Zn>Cd.

Jan 1, 2008

By R Castroviejo, E Pirard, L PTrez-Barnuevo

Process mineralogy provides the mineralogical information required by geometallurgists to address the inherent variation of geological data. The successful beneficiation of ores mostly depends on the ability of mineral processing to be efficiently adapted to the ore characteristics, liberation being one of the most relevant mineralogical parameters. The liberation characteristics of ores are intimately related to mineral texture. Therefore, the characterisation of liberation necessarily requires the identification and quantification of those textural features with a major bearing on mineral liberation. From this point of view, grain size, bonding between mineral grains and intergrowth types are considered the most influential textural attributes. While the quantification of grain size is a usual output of automated current technologies, information about grain boundaries and intergrowth types is usually descriptive and difficult to quantify to be included in the geometallurgical model.Aiming at the systematic and quantitative analysis of the intergrowth type within mineral particles, a new methodology based on digital image analysis has been developed. In this work, the ability of this methodology to achieve a more complete characterisation of liberation is explored by the analysis of chalcopyrite in the rougher concentrate of the Kansanshi copper-gold mine (Zambia). Results obtained show that the method provides valuable textural information to achieve a better understanding of mineral behaviour during concentration processes. The potential of this method is enhanced by the fact that it provides data unavailable using current technologies. This opens up new perspectives to the quantitative analysis of mineral processing performance based on textural attributes.CITATION:PTrez-Barnuevo, L, Castroviejo, R and Pirard, E, 2013. New perspectives on quantitative textural analysis, in Proceedings The Second AusIMM International Geometallurgy Conference (GeoMet) 2013 , pp 191-198 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 29, 2013

By R T. A MacGillivray, S B. Curtis

Bacteriophage (phage) are viruses that infect bacteria. Protein coatings on the surface of the phage particle can be genetically engineered so that they bind to inorganic molecules. The filamentous phage particle is about 930 nanometres in length and 6.5 nanometres in diameter and consists of a single-stranded molecule of DNA surrounded by five different coat protein molecules denoted P3, P6, P7, P8 and P9. Peptide sequences in the P3 coat protein that bind to sphalerite and chalcopyrite have been identified. The binding is selective; phage with specific P3 peptide sequences bind to minerals but do not bind to silica or to pyrite. Two peptide sequences in the P8 coat protein that bind selectively to chalcopyrite and pyrite have also been identified. The amino acids in the P8 binding sequences are hydrophilic and thus a coating of a mineral particle with phage having these peptide sequences may render the particle hydrophilic. Experiments are underway to confirm this. Phage are relatively easy to grow and are not living organisms requiring an energy source to maintain life. Phage can also tolerate a range of pH and temperatures. Given this, and the ability to indentify phage coat proteins that bind selectively to a variety of inorganic molecules, phage have the potential to be useful tools in mineral processing and waste treatment.

Jan 1, 2008

By Yanagase T, Nakamura T, Ueda Y

The possibility of removing the phos phorus and sulphur contained in steelmaking slag has been studied by observing directly through the microscope melts heated on Pt- filaments. After a CaO crystal was placed in the molten slag, distributions of P, S and other elements formed around the CaO crystal were determined with the aid of EPMA. The results indicated that a layer of 2CaO SiO2 is formed on solid CaO in CaO-Si02 melts. Then between CaO and the newly formed compound the molten slag tends to migrate through cracks. For higher Fe 2 03 contents, the layers of the compounds 2CaO.Si02 and 3CaO SiO2 formed around the CaO crystal are not continuous but look more like particles, which promotes the dissolution of CaO. Phosphorus in slag was found to be enriched in the 2CaOòSi02 layer. Phosphorus in the 2CaO SiO2 phase is not related to the primary slag composition, being about 5-7% P205.. Sulphur in slag,as well as the phos- phorus,was concentrated in the 2CaO.Si02 phase. Disintegration due to weathering observed for slags produced in these investigations appeared to be due principally to hydration of lime.

Jan 1, 1980

By Robertson K. S, Hunter T. C

AEG-Elotherm's electromagnetic dosing channel, or Eldomet, is a recent invention enabling the transport and metering of molten metals. The development of a reliable refract- ory lining, and the use of suitable construct- ion and operating techniques has led to the successful application of the Eldomet for casting copper anodes at Copper Refineries Pty. Ltd.

Jan 1, 1974

By J S. Laskowski

Froth flotation process requires the use of frothers. These important flotation agents are commonly characterised as either æselectiveÆ or æpowerfulÆ and are chosen following general guidelines and verification by laboratory and/or pilot plant tests. Fundamental properties of the flotation frothers have been extensively studied over the last few years. These studies have led to the development of standardised procedures to characterise frothers in terms of their ability to reduce bubble size and to increase foam stability. In this research project, the performance of five frothers in flotation of coal is evaluated and related to the fundamental properties of these agents. Since the recovery of water in the concentrate is closely related to the non-selective transport of solid particles by entrainment, the tested frothers are also assessed in terms of their ability to promote the transport of water towards the froth collection zone, both in absence and in presence of solids.

Jan 1, 2005

By L Basnayaka, N Subasinghe, B Albijanic

"It has been recognised that the presence of clay minerals in ores adversely affect flotation performance. In this study, changes in rheological properties of the flotation pulps under normal operating conditions were studied with additions of bentonite and kaolinite clays at various concentrations. Zeta potential measurements were also carried out to determine the changes in surface charge due to adsorption of clay particles. The results showed that bentonite clay adversely affects floatability of pyrite while kaolinite clay had a lesser influence on flotation of pyrite. The addition of Ca2+ ions to the pulp containing bentonite modified the rheological characteristics and in turn improved the pyrite flotation. It was also observed Ca2+ ions suppressed the swelling properties of bentonite and altered surface charge properties of bentonite clay particles. It has been shown that the flow index affected the ultimate recovery and it may provide a means to monitor flotation performance in routine plant operations.Citation:Basnayaka, L, Subasinghe, N and Albijanic, B, 2016. Effect of Clay Rheology on Flotation of a Refractory Gold Ore, in Proceedings 13th AusIMM Mill Operators’ Conference 2016, pp 77–84 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Oct 10, 2016

By E S. Bernard

Toughness testing of fibre reinforced concrete (FRC) at 28 days age is typically undertaken as part of quality control for the many applications where fibres are used in concrete, including shotcrete, tunnel segments, and cast-in-place tunnel linings. The performance achieved at 28 days is usually assumed to be retained with increasing age. However, as the average strength grade of concrete used in most tunnelling applications, including tunnel segments, has steadily increased over the last 20 years, this assumption is becoming increasingly unviable. This is because for some types of fibre the mode of post-crack fibre behaviour depends on the strength of the concrete and can change from a desirable high-energy pull-out mode to a low-energy rupture mode as the strength and age of concrete increases. This paper describes a series of trials performed over two years in which the American Society for Testing and Materials (ASTM) C1609/C1609M beam tests were used to assess the performance of FRC reinforced with two widely used brands of steel and macro-synthetic fibre. The hooked-end steel fibres used for half the beams exhibited a dramatic fall in performance beyond 56 days age as the mode of failure changed from pull-out to rupture. The other fibre did not exhibit a fall in performance with age. This phenomenon highlights the need to quantify performance of FRC at much later ages when long-term performance is required, for example, to resist seismic events or changes in ground stress due to nearby excavations. As an alternative, a reduction factor may be applied to the performance of FRC mixes for which evidence of satisfactory long-term performance is not?available.CITATION:Bernard, E S, 2014. Age-dependent changes in post-cracking performance of fibre-reinforced concrete for tunnel?segments, in Proceedings 15th Australasian Tunnelling Conference 2014, pp 229–236 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 17, 2014

By L O. Filippov, I V. Filippova

Subsea massive sulfide deposits have particular mineralogical compositions and textural features differentiating them from onshore ore. When extracted from salty water and exposed to the air, massive sulfide samples strongly oxidise and soon become covered by thin layers of iron, copper and zinc-rich sulfates and oxides, as well as elemental sulfur. The textural properties vary according to the degree of maturity and the sample position within the hydrothermal deposit. Because of the variation of secondary mineralisation and porosity level, sea floor massive sulfides respond differently from terrestrial ore to processing methods. Froth flotation, commonly applied to separate all types of sulfides from the gangue minerals, is one possible treatment technique to process sea floor ore. Sulfide recovery rate is, in most cases, excellent (>90 per cent). However, separation of the various mineral phases is difficult to obtain even when applying known methods used for onshore ore. Moreover, the flotation behaviour decreases dramatically with time of conservation, even when the samples were stored in a confined environment. High pH range, which is a good way to depress pyrite and therefore to favour the flotation of copper and zinc sulfides, does not have the same effect on subsea ore. Consequently, careful flotation procedure should be elaborated to obtain efficient mineral separation for this specific marine ore.CITATION:Filippov, L O and Filippova, I V, 2015. Processing of subsea massive sulfide ores by flotation – similarity and features with terrestrial ores, in Proceedings Third International Future Mining Conference, pp 239–244 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 4, 2015

By Zichenko ZA, Volkov SV, Shaluhina LM, Emelyanov AF

A method of selective gold recovery from black sands has been elaborated which is based on the liquid phase low temperature chlorination of materials. A liquid agent mixture of sulphur monochloride S2C12 and sulphur dichloride SC12 is used. This method ensures the gold extraction either in the state of AuC13.SC14 complex salt solution or as metal. The kinetics and main physico-chemical parameters of the process (eg density, solid: liquid ratio, temperature) have been investigated. The materials investigated were quartz-insipid ride samples with low sulphur and high iron (up to 70 per cent Fe2O3) contents. Gold recovery is 96 - 99 per cent at temperatures not exceeding 100¦C. Most of the associated minerals remain in the cake. To obtain metallic gold, the resulting solution of the AuC13.SC14 salt after leaching is reduced by hydrazine with subsequent annealing. The elaborated method is remarkable for small energy expenditures owing to low process temperature and a high gold dissolution rate. The solution of sulphur chlorides and other reagents are used in closed cycle.

Jan 1, 1993