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By Shun Myung Shin, Kang Jeong, Kyoungkeun Yoo, Jin Koo, Dong Hyo Yang, Soo Sohn

"The optimum discharging condition to dismantle the batteries without explosion was investigated to recycle the lithium primary batteries, which could be exploded by heating too much or crushing. The 3 waste lithium primary battery cells were discharged with 500 cm3 of 0.5 kmol·m-3 sulfuric acid. Fe concentration and pH increased rapidly after 3 days at 35? and after 1 day at 50?. Chromium concentration increased by 4 days at 35? and 2 day at 50?and then decreased, and nickel concentration was very low. Because Li concentration increased gradually, Li became dissolved after the dissolution of cover material. When the discharged batteries were shredded, the batteries discharged at 50°C were not exploded and those discharged during 3 days at 35°C were exploded. This result shows that the waste batteries could be stabilized within 1 day at 50°C and 4 days at 35°C. Introduction Lithium has some advantages for battery e.g. it is the lightest metals and also has the highest electrochemical potential at 3.04V[1]. For over thirty years lithium primary batteries became famous for their performance in various applications such as IT, medical, and military[2,3]. They gained a reputation for their long shelf life, constant voltage, wide operating temperature range, and low self-discharge characteristics[3-5]. World primary lithium battery market was expected to grow from $820.6 million in 2003 to $1,1355.3 million in 2010 (http://www.frost.com, Frost & Sullivan)[2-4]. The lithium primary batteries have very various sizes and components. Lithium batteries are made with lithium metal as anode active material and non-aqueous solvent as electrolyte. As cathode active material, various kinds of materials were used such as manganese dioxide (nominal voltage, 3.5V), thionyl chloride (3.6V), and carbon monofluoride (3.0V). In Korea, 50 % of the spent lithium primary batteries must be recycled because spent lithium primary batteries have been listed in EPR (Extended Producer Responsibility) of the enforcement degree of the act on the promotion of saving and recycling of resources. However, the batteries have been landfilled since there is no economic method to recycle the batteries in Korea[2,3]. When the batteries were heated too much, charged, pierced, over discharged, or short-circuited, the batteries explode because lithium reacts violently with water or air and because contents such as lithium, electrolyte, and sulfur become flammable by high temperature[4]. Therefore, it is so difficult to recycle safely the spent lithium primary batteries."

Jan 1, 2008

1. In 2002, a total of 763 nonmetal mining operations reported employment to the Mine Safety and Health Administration (MSHA). Examples of nonmetal mining operations include the mining of clay, trona, barite, phosphate rock, gypsum, talc, gemstones, and pumice. Nonmetal mines comprised 5.3% of all mining operations. • Nonmetal mining operations are located in all but nine states or territories (Alaska, Delaware, Maine, New Hampshire, Rhode Island, Vermont, Wisconsin, Puerto Rico, and the Virgin Islands). • Mines producing common clay comprised 29.2% (n = 223) of all nonmetal mining operations.

Jan 1, 2004

By P. Rosario

During the last few years high-tonnage plants have been designed with comminution circuits using semiautogenous grinding (SAG) mills, high pressure grinding rolls (HPGR), or both, followed by ball mills in different configurations. A strong interest in improved energy efficiency and reduction of carbon footprint, along with the recent launch of new high-capacity crushers and stirred grinding mills, has driven the industry to investigate the development of novel flowsheets. This paper presents work based on recent projects that include modeling and simulation of two innovative circuits recently considered for current projects. One circuit uses autogenous (AG) mills and parallel trains of crusher-HPGR and the other is a modified three-stage crushing circuit with the use of HPGRs and pebble mills. The paper indicates the potential savings in operating costs provided by the HPGR-pebble mill circuit when compared to a more conventional SAG-mill-based circuit.

Jan 1, 2010

By HARRINCTON EMERSON

UNEMPLOYMENT is the most ominous shadow ahead of the industrial nations today. Only two great industrial countries are free from unemployment, France and the Soviet Commonwealth. In France the social unit is the family, not the individual. This has saved France. In the Soviet Commonwealth, development is proceeding so rapidly from agricultural to industrial that there is still a dearth of muscle workers in the non-agricultural enterprises. In the other industrial countries unemployment results both from acute temporary recession in industrial activities and from the rapidly increasing substitution of the machine for the man. Temporary recessions can be mitigated, alleviated by makeshifts, often ill considered. Secular recessions due to a fundamental change in the way of accomplishing physical, chemical results cannot be cured by any makeshift. There must be a period of transition. There is therefore before us the three- fold problem, immediate, prosimate and ultimate.

Jan 1, 1930

By M. Ramulu, A. Raina, A. Chakraborty, Jethwa Choudhury, Dudhankar

Application of digital image analysis technique for assessment of blast fragmentation is gaining grounds in India, very recently. Central Mining Research Institute, India made its maiden attempt to optimize blast design based on fragmentation assessment of one of the biggest opencast mines of Singareni Collieries Company Limited, India. Indigenously developed photoanalysis software called ‘FRAGALYST’ was used for measurement of blast fragmentation A series of trial blasts were carried out in overburden benches with ongoing blast parameters and pictures of muck pile were taken by video camera for image analysis. Cycle time study of loaders and dumpers was done to determine machinery performance for each and every blast. Optimization of pre-blast parameters like specific charge, specific drilling and post-blast results like shovel cycle time and dumper cycle time, was done to determine optimum range of fragmentation. Interpreting the mean fragment size (K50) obtained by image analysis the blast design parameters were modified.

Jan 1, 2001

By Merwin H. Howes

In constructing the NORAD Combat Operations Center, controlled blasting techniques were employed to achieve smooth walls and to avoid shattering the rock beyond excavation lines. Extraordinary measures were taken to stabilize the rock to permanently preserve the openings. Rock stabilization was accomplished by means of reinforced concrete and gunite linings, rock boltings, installation of chain-link fabric, and epoxy resin and cement grouting. A particular zone of weakness at B vital location was supported by exceptionally thick reinforced concrete lining, rock bolts, and cement grout.

Jan 1, 1966

By S Hapugoda, H Han, L Lu

Charcoal produced from Syzygium Zeylanicum trees was widely used in ancient Sri Lankan iron smelting practices. Charcoal made from Syzygium Zeylanicum tree trunks, branches and leaves were analysed by optical mineralogy and SEM and found to contain unusually high concentrations of calcium oxalate (CaC2O4.H2O – CaOx) crystals in plant cells. Partial and full reduction tests of a high-P Brockman ore were conducted at several temperatures with coke and coke doped with CaOx and CaCO3. It was observed that CaOx promoted reduction and generated comparatively more metallic iron in reduced samples. Furthermore, CaOx encouraged phosphorous partition into slag phases than into the metallic iron, suggesting CaOx can a potential alternative fluxing material to calcium carbonate for treating high-P iron ores in ironmaking processes.

Sep 18, 2023

By Gregory Rumbaugh, Christopher Mark

Recent pillar collapses have caused five large airblasts in underground U.S. limestone mines. One of these events injured three miners, but all of them put many other miners at risk. To better understand the hazards, Mine Safety and Health Administration (MSHA) conducted a comprehensive review of the international literature on airblasts. More than 40 airblast cases have been documented, in a wide variety of minerals. Experience shows that miners that are in the direct path of the air as it moves towards the mine exits are at the greatest risk. The paper describes a risk management methodology that can be used to evaluate the level of hazard throughout the mine and aid in the selection of controls to reduce the risk. The paper concludes with a detailed case history of an actual pillar collapse and airblast.

By K. Duckworth

"AbstractA new electromagnetic depth sounding technique was applied to the measurement of salt thickness above the workings in the Central Canada Potash Mine at Colonsay, Saskatchewan. The initial tests indicate that this new technique can measure salt thickness and that the technique possesses operational feature s which make it possible to monitor trends in salt thickness throughout the mine. The technique can be applied using existing equipment, but the tests do indicate the desirability of developing equipment with features specially suited to the mine environment.IntroductionTESTS were conducted in the Central Canada Potash Mine at Colonsay, Saskatchewan during 1974 and 1975 to determine if a new technique in electromagnetic depth sounding could provide a convenient means of measuring salt thickness above the workings. This new technique, which was described by Duckworth (1975), offers operational features which appear to be advantageous in this particular situation.The problem requires that soundings be made upward from the mine workings to the base of the second red shale. This shale forms an impermeable seal on top of the Prairie Evaporite. A knowledge of this salt thickness is of interest due to the need to avoid any possibility of the workings rising to cut the red shale. Another desirable objective is the detection of any disruptions of the red shale. Ideally, this should be done ahead of the workings in order that such areas of disruption may be avoided."

Jan 1, 1977

By Ronnie Melker, Joel Webster, Daniel Belardo, Thomas Hyatt

Quality assurance of drilled shafts is highly dependent upon the construction practices used during the excavation and concrete placement process. When performed under slurry, challenges are presented in maintaining borehole stability and placing a uniform and continuous concrete column. An integral part of the construction operation is to evaluate the as-built integrity to verify the drilled shaft is capable of safely transferring the required loads to the subsurface. One such case is exemplified by a project involving the expansion of an existing public transit rail line. The expansion required the construction of a new bridge bent supported by seven 5-ft diameter drilled shafts of various lengths. The specifications for the project required both Cross-Hole Sonic Logging (CSL) and Thermal Integrity Profiling (TIP) for drilled shaft integrity evaluation. Both of these post-construction non-destructive tests (NDT) are designed to detect anomalies or the presence of regions with reduced concrete quality. However, the implementation and methodologies of performing each of these NDT methods are significantly different. Cross-Hole Sonic Logging uses ultrasonic signals emitted from a transmitter in one access tube to a receiver in another access tube. Thermal Integrity Profiling measures elevated concrete temperatures during the curing process using embedded thermal wires. Both test methods require different access details and therefore have different costs associated to the contractor or owner to perform. This paper provides a detailed comparison of these NDT methods as performed on these seven drilled shafts. The associated financial and time costs to perform each method are compared and the results are discussed in detail. INTRODUCTION Drilled shafts are a fundamental deep foundation element that can be designed to resist large bending moments as well as to transfer large compressive axial loads through weaker upper soils to competent soils or rock below. Often times when the upper soils are very soft, lateral support by casing or slurry, or a combination of both, may be used to hold back the softer soils from collapsing into the hole before concrete has been placed. Due to the blind nature of drilled shaft construction and the qualities issues that may arise during the placement process, it is essential for design engineers to specify non-destructive testing (NDT) to assess the quality of the as-built drilled shaft. CSL and TIP testing are two NDT methods designed to detect areas of lower quality concrete or soil inclusions throughout the length of the drilled shaft and determine its overall quality. Each method uses different technologies and methods to achieve the results required to determine the as-built condition of the drilled shaft.

Jan 1, 2019

By John J. Barakso

A summary of geochemical dispersion processes is presented. Secondary and tertiary dispersion of uranium was examined at several uranium prospects in British Columbia. The vertical migration of uranium from bedrock (primary dispersion) through overburden into the various soil horizons, and into snow and plants, was studied, and relationships were sought to explain the dispersion patterns in the secondary and tertiary environments. Soil developments were examined to obtain information on factors affecting the dispersion of uranium in soil profiles and tertiary substances; samples were analyzed for a number of elements. Biogeochemical data indicate that plant geochemistry is a possible exploration aid in areas of heavy overburden owing to the high selectivity of certain plants for specific elements. Some new data on the geochemistry of snow are discussed as a matter of research interest in the tertiary dispersion of uranium. Analytical techniques and problems are discussed, particularly extraction techniques, which must be carefully chosen to give reliable information on uranium dispersion.

Jan 1, 1979

When solid pillar is not left to separate different mining levels in underground mine with high dip angle deposit, waste rock in the backfilled stope could be a safety hazard to future mining activities on levels above or below the backfill. Different backfill methods can be used to eliminate this hazard according to the deposit shape and mining method. Building concrete pillar in ore drift of each mining level is one of them. Concrete pillar had been constructed in underground mines based on operational experience. Little design literature and pillar performance data can be found. At Great Basin Gold Hollister Mine, over two thousand feet of concrete pillar had been constructed. The project started with engineering design which combined civil engineering concrete design and the specialties of underground construction. Time Domain Reflectometry technique was installed to monitor the pillar movement and concrete cylinder samples were collected and tested for quality control. Engineering design, underground construction, quality control and concrete pillar monitoring, as well as precious concrete mixing data from years of experience are fully covered in this paper to give a general frame of concrete pillar method.

Jan 1, 2010

By John R. McWilliams

The technological and economic pattern of the U. S. mining industry has undergone a rapid and continuing change since World War II. To provide realistic up-to-date cost data and to disseminate knowledge of technical developments, the Federal Bureau of Mines, with the cooperation of individual mining companies, is presenting a series of mining methods and costs reports similar to those it issued before 1939. Shaft sinking has always played an important part in mine development and [ration] and is an appropriate subject for this series of reports. Shafts [are] especially important in areas such as the Coeur d'Alene district of Idaho, where every major mine is served by one or more shafts and shaft sinking is in progress at one mine or and her almost continuously.

Jan 1, 1960

On the 26th of June 2000 a hydraulic fill retaining barricade failed at the Bronzewing mine in Western Australia. The barricade failure resulted in the release of 19,000 m3 of saturated hydraulic fill into the mine and caused the deaths of three miners. Following this tragic accident, the practices and procedures of mines using hydraulic fills came under intense scrutiny by regulatory bodies and mining companies. At this time, the use of hydraulic fill at Normandy?s zinc/copper Scuddles mine was suspended and waste rock became the sole backfill material in use underground. By 2003, development of the adjacent Gossan Hill mine had progressed to a point where a self supporting fill material was required to enable full recovery of high grade ore. Cemented hydraulic fill (CHF) was identified as the optimal fill type and work began on designing appropriate management procedures and controls to ensure the safe implementation. This work included definition of the fill properties, plant design and construction, reticulation system design, design of stope barricades and drainage systems and fill placement control and monitoring practices. CHF placement began on 16th July 2004 and has continued to date. Significant operational experience has since been gained in areas including plant performance, fill product quality assurance, barricade construction, stope drainage and in-situ performance.

May 1, 2007

By P. Favreau

"This paper describes the progress accomplished at the Noranda Technology Centre in the field of three-dimensional computer-aided underground blast design. Traditional methods of laying out underground blasts are reviewed, and the new computer-aided approach is described. Time savings achieved through the use of BLASTCAD can be advantageously used to better engineer blasts, using models and blast vibration analysis. Future work involving the attachment of blast models directly to the system is also addressed.IntroductionThe Noranda Technology Centre's (NTC) Environment and Mining Laboratory, in cooperation with the mining operations of the Noranda Group, is committed to the development and implementation of new technologies in the field of mineral extraction . Within the frame of its research program, the Blasting Technology Program is developing computer "" tools"" designed to assist the blasting engineer or technician. These computer "" tools"" are regrouped under a global software system called BLASTCAD.The BLASTCAD project started in 1990 at NTC. At that time computer programs designed to calculate and model various blasting parameters had been accumulated. These programs cam e from different sources and were mutually incompatible. Furthermore, they were developed as research programs with tittle effort spent on user interface. These programs are very useful, but are highly specialized, need large input files and can be quite tedious to use as ""standalone"" packages .Therefore, the situation being faced was one where all these programs were available at the Noranda Technology Centre, but not a t the operations. The two following options were then considered: 1. continue to run all the models and programs at the Noranda Technology Centre, and present results through reports to the mines, or2. regroup all the different programs under a single one that would make them share the same data base and be transported to the user. This second option is the one that was adopted; the result is BLASTCAD."

Jan 1, 1993

By C Jacobsen, N Harries

Assessing and managing instability hazards is an essential activity when working with unstable natural slopes and excavated open pit mining slopes. Slope monitoring has become the standard technique for the management of geotechnical risks associated with mine slope instability hazards. In recent decades, a proliferation of new monitoring techniques such as terrestrial radar, satellite InSAR and LIDAR have become standard operational tools, complementing conventional survey-based monitoring solutions. A reliable monitoring system should identify and record incipient anomalous slope movement. Although the most obvious purpose of a monitoring system is safety related, slope deformation and performance monitoring also enhance the understanding of slope behaviour and assists in improving system design and implementation. For a monitoring system to be considered an effective early warning tool, it needs to operate in real-time and should be linked to the mine’s emergency communication systems. Terrestrial radar systems have been developed that can provide near real-time measurements, at a high level of precision and covering broad areas in all weather conditions. This has had a positive impact on the management of geotechnical risks in operational conditions. The technology adoption of RADAR in mine monitoring has significantly progressed in the last 20 years from technology enthusiasts, to visionaries, to pragmatists to conservative users. However, the increasing adoption of RADAR cannot reduce or remove other monitoring techniques that often have important benefits; even if these technologies cannot be used as a real-time operational tool. An increasing awareness on the importance of combining data from different monitoring techniques to develop a holistic picture of all possible geotechnical hazards is a current industry trend. This is proving to be an excellent foundation for managing hazards associated with slope instability in open pit mines, and is only expected to improve with time with the adoption of new technologies based on big data and Artificial Intelligence (AI).

Nov 29, 2022

By Harry Schnabel

A 6200 m² cement deep soil mixed (CDSM) wall was constructed for an addition to the Museum of Fine Arts in Boston, Massachusetts. The addition was located along the east side of the existing museum within an existing courtyard and in the area of a recently demolished structure. The basement for the new addition extended up to 9.1 m below the floor slabs of the adjacent buildings. The adjacent buildings are supported on a variety of foundations including; shallow spread footings on alluvial sand deposits, low capacity piles bearing in the alluvial sands and Boston blue clay, and caissons bearing on the alluvial sands and clay. Groundwater was less than one meter below the top of the CDSM wall. The new addition was founded on shallow foundations in the desiccated crust of the Boston Blue Clay. The CDSM wall was selected as the most economical means to control deep seated ground movements, limit movements of adjacent structures, and inhibit groundwater flow into the excavation. Braces and a continuous wale were used to support the CDSM wall where it was located adjacent to structures. Tiebacks were used where there were no structures. Other geotechnical construction at the site included: ? Jet grouting (JG) to improve the ground and provide an impervious subgrade layer at the west end of the addition, ? Concrete pier underpinning was used to support an existing structure on the west end of the site, and ? A secant pile wall using alternating drilled shafts and jet grout columns was used for earth support and a barrier to groundwater flow to allow for the installation of a storage tank at the south end of the site. Inclinometers, total station surveying, vibrating wire strain gauges on the braces and wales and load cells on the tiebacks were used to monitor performance of the excavation support system. The excavation support system performed better than required limiting lateral movements of the adjacent structures to less than 13 mm and vertical settlement to less than 8 mm. No settlements or movement were detected during the construction of the wall. Lateral movement of the CDSM wall was typically below 15 mm with the maximum movement occurring near subgrade.

Jan 1, 2011

By Kunihiko Takahashi, Gjergj Dodbiba, Hisayoshi Umeda, Toyohisa Fujita

"An increasing number of mobile phones is increasing the number of the discarded mobile phones. Many efforts are thus being made to collect and recycle these devices. This paper is a short introduction of the recycling system of precious metals from the discarded mobile phone, currently available in Japan. Moreover, an attempt has been made to compare the energy recovery and the mechanical recycling of plastic wastes from the discarded mobile phone. The assessment has been carried out in the context of the life cycle assessment methodology (LCA). The environmental impact of each option was assessed by calculating the following impact indicators: depletion of abiotic resources (ADP), and global warming potential (GWP). 1. Introduction In 2003, the demand for mobile phones was increased since the camera was included in a mobile phone and the 3rd generation of mobile phones was introduced. In turn, the number of discarded mobile phone is rising sharply. Generally speaking, all the metallic parts of mobile phones can be recovered and recycled by using smelting and purification techniques. The recycled materials are then used to fabricate other new products."

Jan 1, 2008

Jan 1, 2004

By M I. Pownceby, N A. S Webster, R Pattel, N Ware

The decrease in quality of Australian iron ore, coupled with the demand for more efficient energy use, necessitates closer monitoring and optimisation of process conditions for iron ore sinter production. Sinter properties are correlated with the mineralogical content and traditionally, quality control has relied on methods such as Fe2+ determination, point counting via optical microscopy and automated electron beam techniques such as QEMSCAN; these can have a typical turnaround time of several days between sampling and reporting of results. As well, there is additional uncertainty around quantifying some of the complex mineralogical phases in sinter such as silico-ferrite of calcium and aluminium (SFCA) and SFCA-I, which are key phases influencing sinter quality. There is a clear need for the implementation of alternative analytical methodologies that offer a turnaround in hours or even minutes to provide information to accurately maintain production conditions.X-ray diffraction (XRD) is a technique widely used for the quantitative mineralogical phase analysis (QPA) of ores and processed materials in the iron ore industry. Partial least squares regression (PLSR) analysis methods have recently been suggested as an indicator of sinter Fe2+ content from powder XRD data without the need for rigorous and often time-consuming mineralogical analysis by the operator. In this study we provide results from the implementation of PLSR to predict the strength of iron ore sinter. Results are sourced from a well-constrained data set comprising strength properties (as quantified by a tumble index (TI)) from a series of compact laboratory test samples. Using this data set it was determined that PLSR has potential to be used as a method for calculation of sinter TI from powder XRD data and, therefore, process control.CITATION:Webster, N A S, Pownceby, M I, Ware, N and Pattel, R, 2017. Predicting iron ore sinter strength through X-ray diffraction analysis, in Proceedings Iron Ore 2017, pp 331–334 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 24, 2017