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By Don Ibana

The use of solvent extraction (SX) in process metallurgy is particularly attractive as it is applicable to a wide range of solute concentration and pH, and it allows complete separation of chemically similar metals such as nickel and cobalt and the rare earths among others. It is therefore applicable to the processing of low grade and complex ores, which is increasing and expanding owing to the diminishing reserves of quality ores, and this has driven the increasing and expanding use of SX.The current SX technology, however, has inherent limitations owing to the use of mechanical agitation as it induces high shear mixing. Excessive shear produces very fine droplets, and while this favours mass transfer, it also leads to sluggish phase separation. High shear mixing is also known to favour crud formation. All these factors as well as high power and reagents consumptions contribute to poor process efficiency. Electrostatic solvent extraction (ESX) is similar to conventional SX except that mechanical agitation is replaced with electrostatic agitation. In direct contrast to mechanical agitation, it allows the production of very small droplets that can be made to maintain intense motion, which favours mass transfer, without affecting the phase separation. In addition, as it uses an electrostatic field, the power consumption is minimal. Hence, it promises to be a superior alternative to conventional SX mixing although an application of the technique is yet to be achieved.Our work to develop an application of the technique in process metallurgy has now established that electrostatic field has no effect on either the stability of the reagents or the chemistry of the process. A volumetric flowrate that is comparable to that of a conventional sieve plate pulse column is achievable. We have also established that electrostatic fields can be made to yield much narrower droplet size distributions than those of mechanically agitated contactors, and they allow better control of droplet motions, which include oscillation and linear motion and hence, mass transfer. These are significant advancements toward our goal and shall be discussed in this presentation.

By J. Paquin, P. Doiron, G. Proulx, P. Champoux

After nine years on a 36 hour schedule and two programs of creeping, the Alcoa Deschambault Potroom of faced the necessity of changing its organization for many reasons: the anodes butts were too small, the anode schedule was unbalanced, the iron content in the metal trends had increased, the metal tapping volume did not convene with crucible capacity and the liquid measurement task was delayed by tapping activities. A kaizen activity inspired the Potroom department to improve the organization. A team of 15 people including the process engineer, the process technician, team supervisors and Potroom operators developed a scenario, which would permit flexibility to creep pots if energy is available and an increase of added value production.This paper will describe the systematic approach, the communication method, the trials, the changes, and our success, along with the problems experienced by the team during the adaptation of Alcoa Deschambault Potroom organization over a 20 month period. Aluminium 2006 45th Annual Conference of Metallurgists ofCIM Montreal, Quebec, Canada Edited by

Jan 1, 2006

By Hojat Naderi

In this research assisted leaching of chalcopyrite using sodium peroxodisulfate was studied. Electrochemical techniques such as Tafel analysis and electrochemical impedance spectroscopy (EIS) were used to investigate the surface reactions of a chalcopyrite electrode in the presence and absence of Na2S2O8. According to the results, addition of sodium peroxodisulfate increases the current exchange of the corrosion process and prevents the formation of a passive layer on the surface of the electrode. EIS tests show the trans-passive dissolution of the passive layer on the chalcopyrite electrode in presence of Na2S2O8. Equivalent electrochemical circuits were modeled for Na2S2O8-free and -containing solutions and the model parameters were compared to determine the effect of S2O8 2− on chalcopyrite dissolution. Copper dissolution from pure chalcopyrite mineral and chalcopyrite concentrate was carried out using 15 g/L sulfuric acid solution with and without Na2S2O8. Simultaneous presence of 10 g/L ferric ion and 40 g/L peroxodisulfate salt results in about 40 and 18% of Cu extraction from chalcopyrite concentrate and pure chalcopyrite mineral, after 96 h, respectively.

By B. Ndlovu

The world mineral industry has over the years experienced growth in the production of nickel (Ni) due to its use not only in the catalytic industry but mainly also to its demand in the stainless steel production industry. Hence there is a need to produce more pure and marketable grades of Ni through the use of efficient purification routes such as solvent extraction. The V10-LIX®84-IC system resulted in nickel (Ni) extraction isotherm shifting to lower pH levels. The pH window of opportunity for the extraction of Ni subsequently increased in solution containing magnesium (Mg) and calcium (Ca) even though the system also resulted in slight shifts to less positive pH values for Mg and Ca curves. Results showed a synergistic effect of LIX®84-IC when added to V10 for all elements, Ni, Mg and Ca. The pH50 values for elements Ni, Mg and Ca in the V10-LIX®84-IC system were 2.95, 8.10 and 7.70 respectively. Comparing results obtained when using V10 alone produced ?pH50 for Ni, Mg and Ca being 3.35, 0.15 and 0.70 respectively, which was a confirmation of the synergistic shifts for all the elements. The ?pH50 (Mg-Ni)value was 1.95 with no synergism and 5.15 with synergism and that for ?pH50 (Ca-Ni)was 2.10 with no synergism and 4.75 with synergism. This showed that the Ni-Mg separation factor was relatively larger than the Ni-Ca. Improved loading and stripping kinetics were also observed. Keywords: Nickel solvent extraction separation, magnesium, calcium, versatic 10 acid and LIX®84-IC.

Jan 1, 2008

By Dean E. Matthews

The concept of a pile for construction is credited to a Neolithic tribe called the "Swiss Lake Dwellers" who lived in what is now Switzerland about 6,000 years ago. They used piling, not for supporting heavy loads as we do today, but for elevation to protect themselves from wildlife. The Romans often used piles, and built many structures, including buildings, homes, bridges, roads and viaducts on piling. The Romans built the first bridge across the Tiber River in Rome on timber piles in B.C. 1620. Homes in the cities of Venice and Ravenna were built on piles from B.C. 100 to A.D. 400. The Romans also built the first bridge across the Thames River in London in A.D. 60 on timber piling.

Jan 1, 2003

By Conny Postupack

The first principle one usually learns about blasting is that competence in this field is best gained by experience in making blasts rather than by reading a book or by listening to a lecture. The reason for this is that there are a large number of variables affecting blasting results and not all of these can be accounted for by a few rules or a few sets of equations. Even an experienced in a new area, may have co make one or two himself to the new conditions with which he blaster when operating shots just to acclimate is faced.

Jan 1, 1991

By Madan M. Singh

Hydraulic mining has been practiced in the United States since 1852 and many mineral commodities, such as gilsonite, phosphates, lead-zinc, silver ores and St. Peter Sandstone can be mined in this manner. In 1958, the U. S. Bureau of Mines initiated research into the mining of coal using these techniques.1-4 These early investigations were conducted in the 5000 psi pressure range. The large nozzle diameters used in this pressure range produced extremely high flow rates which created visibility problems at the coal face, and required removal of large amounts of water from the mining area. Besides, the production rates were not much better than with mechanical methods. This indicated that with higher pressures the water quantities might be reduced using the same or higher horsepowers but enhanced breakage. For this reason intensive investigation in material removal using fine water jets at extremely high pressures (50,000 psi to 100,000 psi) has been undertaken. This was not the entire reason for this contract from the Bureau of Mines, however. The contract objective is outlined later. IIT Research Institute has done pioneering work in high pressure jet development in the United States.5-8 Similar schemes have been investigated abroad. 9-13 Hydraulic mining of coal at relatively low pressures is successfully being done in the Soviet Union, Japan, Canada, and most recently, in Germany.

Jan 1, 1973

By William Gleason

"It is safe to say that the coal industry, in the United States and globally, is currently suffering through one of the hardest times in its history.A perfect storm of competition, changing energy demands, politics and public perceptions have collided, inflicting significant harm to the industry that many say is irreparable. This, in turn, has led to massive job losses in some regions, heavy cuts in production and even bankruptcy filings from two of the largest coal mining companies in the nation.Cheaper natural gas can certainly take a large share of the blame for the struggle of coal, as utility companies switch from coal to natural gas for power generation. According to the U.S. Energy Information Administration (EIA) the amount of coal used for electricity generation in the United States is at a 45-year low.November 2015 marked the fifth consecutive month that natural gas was the leading source of power generation in the United States. EIA said generators produced 101,866 thousand megawatt hours (MWh) of electricity with gas in November versus just 87,789 thousand MWh with coal, the lowest monthly level since May 1980 when monthly coal use was 84,884 thousand MWh.According to Robert Godby, director of the Center for Energy Economics and Public Policy at the University of Wyoming, there are a number of factors playing a role in the decline of coal, but he points to the advances in fracking as the tipping point.“A lot of people will argue that regulation is the cause of the decline, and it has played a part, for sure, but the story of the recent past is more about what competition has done to the energy market,” Godby told Mining Engineering. “The war on coal was originally declared by natural gas in 2008.”The price of natural gas, which was at $13 per million Btu before the gas fracking boom, has fallen to as low as $1.68 in December 2015. Likewise, Godby said the cost of wind generation is now lower than the cost of generation from coal and the cost of solar generation is coming down as well. In addition to that, the demand for energy has changed in the past five years with more efficiencies in everything from building design to lightbulbs."

Jan 1, 2015

By S. Chander, S. W. Musselman

The molecular structure of hydrophobic and hydrophilic groups in nonionic surfactants has been related to the wetting and dispersion of selected pigments. The nonionic surfactants included in this study are acetylenic diol based surfactants and ethoxylated alkyl phenols. The Langmuir model could be used to fit adsorption data. Further analysis of the data showed that the free energy of adsorption was a function of adsorption density of the surfactants at the interface. The change in free energy with adsorption density could be interpreted by considering a change in the orientation of the adsorbed molecules. Acetylenic diol based surfatants were found to have an area per molecule of 2-3 times that of similarly ethoxylated alkyl phenols. The wetting and dispersion properties of lamp black, a model hydrophobic surface, by these surfactants were investigated by contact angle measurements and particle size analysis. Acetylenic diol based surfactants with ethylene oxide contents between3.5 and 10 moles per molecule and alkyl phenol based surfactants with approximately 9 moles of ethylene oxide per molecule were found to provide superior wetting abilities. Longer ethylene oxide chains were required for superior dispersion capabilities within each family of surfactants. Complete wetting and dispersion was found to occur above the critical micelle concentration of the surfactants.

Jan 1, 2000

By P. Dhar, H. R. Kota, M. Thornhill

Precipitated calcium carbonate is used as a filler and coating material in the manufacturing of paper because of its high brightness and light scattering characteristics. However, beneficiated calcite has similar potential, given the fact that the industrial specifications are already achieved. For paper industries, the requirement is that the desired product should be pure and have a brightness of 93 to 95 percent. A very-high-grade calcite deposit of around 92 percent is located in the north of Norway, which is used as the raw material for ground calcium carbonate (GCC) feed for the paper industries. There is a substantial amount of calcite resource, which has pyrite and pyrrhotite as major impurities. These sulfides, even when present in minor concentrations, impart color to the end product (paper). Removing these minerals is estimated to increase utilization of the deposit by 10  percent, which represents several million tonnes of calcite marble. Due to the requirement for environmentally friendly reagents and chemicals by the mineral industry, fatty di-amines are being tested for pyrite and pyrrhotite flotation. The interaction mechanism of diamine with the main components of the ore were studied and optimum conditions for removal of sulfide impurities are outlined.

By Floyd C. Bossard

In underground mining operations, the over- riding issue has to be protection of worker health and safety. The employees underground, making a living in a dangerous occupation, know these are major issues. These men bargain their lives and health on the presumption that the operating management knows its business, and they, the underground employees, can pursue their occupation with the assurance that management has provided a safe and healthy ambient underground environment. When management assumes the mantle of protection of underground workers, it has to be positive that qualified engineers have designed the project, and that capable operating personnel are in charge and always available. Those persons with these responsibilities must be knowledgeable in the engineering and occupational health aspects of sine ventilation. The ultimate function of a mine ventilation system is to provide a comfortable, healthy and safe ambient environment for the underground workers. The attainment of these objectives has been complicated with the increased application of electrical equipment and diesel-powered mechanized mining equipment underground (discharging toxic diesel emissions); increased production rates with the attendant increased production of airborne dust; and mine development in increasingly hostile mineral formations containing combustible strata gases, radon gas emissions, along with high heat and humidity. In general, the modern mechanization of present mining operations has resulted in a sore complex set of problems for the engineer planning the underground ambient environment.

Jan 1, 1983

By S. K. Singh, P. R. Sheorey

To meet increasing demand of coal, underground mining is largely being replaced by the exploitation at deeper horizons and with greater complexities. The exploitation-proposition may be below not-to-be-disturbed surface properties or below water-bodies, posing a constant threat of inundation. Also, the mounting pressures to limit the adverse impacts on the environment bring the extraction-undertaking to face more challenges. An understanding of subsidence-mechanism and a rational quantification of subsidence parameters is a requisite herein. This paper presents such pragmatic quantification, validated at mine-sites in India. In comparison, better productivity, conservation and safety is ensured in this approach.

Jan 1, 1999

This report has been prepared in response to a request by the Bureau of Land Management (BLM) Fairbanks Alaska District Office that the Bureau of Mines quantitatively assess the potential supply of minerals from undiscovered deposits in the White Mountains National Recreation Area (WMNRA) and the western part of the North Steese National Conservation Area (SNCA) in Alaska. The assessment will be used to assist in future land-use decision-making. Resource Management Plans (RMPs) for the WMNRA and the SNCA were approved by the BLM in 1986. These plans imposed significant restrictions on new mineral development in the two areas. The level of public concern regarding these actions, especially on the part of the mining industry, has spurred BLM to seek additional information about the potential supply of minerals from the two areas with assistance from the Bureau of Mines. The assessment focuses on an area within the WMNRA and the SNCA which has been administratively closed to mineral entry. The study area encompassed approximately 1.24 million acres and included all of the WMNRA and the western portion of the North SNCA (fig. ES-1). Three quantitative estimates of the potential supply of minerals from the study area were developed: 1) For all lands in the study area, assuming that they are open to mineral entry-the baseline analysis; 2) For those lands which have been closed to mineral entry; and 3) For eleven prospective mineral activity areas, assuming that all are open to mineral entry.

Jan 1, 1989

By Juno Gallego

A soldagem de peças de aço por arco submerso é um dos processos mais tradicionalmente usados na fabricação de componentes estruturais. A microestrutura do metal de solda é importante na definição das suas propriedades mecânicas, sendo a ferrita acicular um microconstituinte capaz de conferir à solda altos níveis de resistência mecânica e tenacidade. A nucleação da ferrita acicular depende da presença de inclusões não metálicas no metal de solda. No presente trabalho fez-se a caracterização microestrutural do metal de solda preparados com diferentes aportes térmicos. Lâminas finas foram observadas por microscopia eletrônica de transmissão, que possibilitou determinar alguns parâmetros morfológicos e químicos das partículas e a sua relação com a nucleação das ripas de ferrita acicular. Verificou-se que partículas irregulares com maior tamanho, mais ricas em titânio quando formadas com maior energia de soldagem, apresentam maior probabilidade de servirem como sítio preferencial para nucleação da ferrita acicular, se comparadas às partículas mais lisas e menores.

Aug 7, 2018

By Earl G. Hoover

For most geologists and miners the term "asbestos" refers to a group of highly fibrous silicate minerals that readily separate into long, thin, strong fibers of sufficient flexibility to be woven, are heat resistant and chemically inert, and possess a high electric insulation and therefore are suitable for? uses where incombustible, nonconductive or chemically resistant material is required. The United States Mining Enforcement and Safety Administration (MESA) specifically refers to the naturally occurring minerals chrysotile. amosite, crocidolite, termolite asbestos, anthophyllite asbestos, and actinolite asbestos as "asbestos" if the individual crystal fragments have the following dimensions; length -greater than 5 micrometers, maximum diameter -less than 5 micrometers, and a length to diameter ratio of 3 or greater. Since asbestos has been identified as one of the ten most carcinogenic substances (a cancer causing agent) it has become, for many government regulatory agencies, a major issue concerning banning emissions to the environment.

Jan 1, 1978

By Ahmed Alghamdi, Salem AlGharbi, Aisha AlHarbi, Owain Morton, Norah AlMuhaisen

This paper addresses the challenges in optimizing the phosphate flotation process, specifically focusing on the variability in P2O5 recovery. An artificial intelligence (AI) driven Flotation Prediction Model was developed to accurately forecast P2O5 grades. Leveraging real-time data from various operational sources, the model provides insights into how operators can opstimize key flotation parameters to enhance product quality and recovery rates. The results demonstrate the effectiveness of AI predictive modeling in addressing operational variability, marking a crucial step toward intelligent operations in the phosphate flotation process.

Feb 1, 2025

By Robert E. Murray

The title of my paper, "A Company's Response to Federal Coal Leasing," brings to mind a picture of a dog chasing its tail. This is what the coal industry, has been doing since the Federal coal leasing moratorium went into effect in 1971. We've gone around in many circles, but we are only very slowly, if at all, getting closer to catching our tails, i.e., efficient, economical, and rational Federal coal leasing. My companies, The North American Coal Corporation and its four Subsidiaries, The Falkirk and Western Plains Mining Companies and The Coteau and Missouri Valley Properties Companies, together hold in excess of 4.5 billion tons of lignite reserves in North Dakota. Some of our North Dakota properties are substantially interspersed with Federal coal, with the government holding title to the minerals in every other section. This checkerboard pattern of Federal ownership has made it difficult to develop and market some of our reserves, and, as a result, it has become imperative that we be familiar with and active in the Federal Coal Leasing Program.

Jan 1, 1982

By George S. Rice

"It is well known that the lost coal left in the ground in mining, under such conditions that recovery is practically impossible, constitutes a large proportion of the coal in the beds worked. A recent estimate, in a paper on ""The World's Fuel Supply"" presented by Prof. L. P. Breckinridge, of Yale University, before the Annual Meeting of the. American Society of Mechanical Engineers, places the average loss in bituminous coal mining as one-third left in the ground.The bald statement that there is a loss of one ton of coal for every two recovered may seem to those not familiar with coal mining to imply inexcusable and wanton waste. Perhaps a better way of expression is in terms of total recovery rather than in terms of losses. Many mine superintendents and mine owners will readily concede that their total recovery may be only 60 to 75 per cent, but to state that they are wasting 25 to 40 per cent arouses antagonism. The suggestion is of willful waste, whereas the majority of the operators try to the best of their ability to get a high recovery under the adverse and complex conditions that confront them. These involve natural, commercial, and labor conditions, and the requirement in many cases of boundary pillars under railroads and buildings, which may be called for in the deed or lease, or in the absence of specific exemption in the deed or lease, the common law requirement that a surface owner is entitled to the support of the surface."

Apr 1, 1921

By Parry. V. F., John B. Goodman

"INTRODUCTION The Denver region coal field, covering an area of approximately 7,640 square miles, extends from the Wyoming State line to the middle of El Paso County, Colo. The coal in this region is subbituminous in rank. Much of it is used as domestic fuel. During the last decade the production of coal in this field has remained fairly constant at an average of 2,600,000 tons per year. This production has come from 50 to 60 mines, 88 to 90 percent of the production being from the section of the field north of Denver.According to the Standard Specifications for Classification of Coal by Bank of the American Society for Testing Materials 4/ the coals in this region are classified in the Subbituminous B and C group. On the as—mined basis, they contain about 22 percent moisture and average 9,600 B.t.u. per pound. They are noncoking and slack to a variable extent when exposed to the weather. This is characteristic of subbituminous coals."

Aug 1, 1939

Bubble Load Measurements in Flotation - A Critical Review of Current Practice

Sep 13, 2010