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By Zhigang Liang

Investigation into the mixing of 150t ladle furnace by two-nozzle jetting was performed by a water model simulation of 1:4. The effects of nozzle arrangements including separation angle, radial position and asymmetry as well as tracer adding position on the mixing time were studied. The most favorable mixing is achieved when the two nozzles are symmetrically arranged at half radii in the ladle, with 45o separation angle. The empirical relationship between the mixing time and stirring power intensity has been established for two-nozzle jetting based on the present experimental results. In addition, the swelling above bath surface is also investigated with two-nozzle jetting.

Jan 1, 2009

By C. A. Young, J. D. Miller

Adsorption isotherms previously determined by in-situ Fourier transform infrared/internal reflection spectroscopy (FT-IR/IRS) for oleate adsorption at calcite and fluorite surfaces near pH 9 and at various temperatures are compared. Results indicate that, at both mineral surfaces, chemisorption occurs at equilibrium concentrations below approximately l x l0-5 M oleate while calcium dioleate surface precipitation occurs at higher equilibrium oleate concentrations. The extent of chemisorption at the calcite surface is 3 to 5 times less than that at the fluorite surface while the extent of calcium dioleate surface precipitation on calcite is nearly a magnitude larger than that on fluorite. However, for both minerals, surface precipitation decreases with increasing chemisorption. Contact angle measurements and flotation recoveries show the hydrophobicity of fluorite to be greater than that of calcite at each of the temperatures and oleate concentrations studied. Significant differences are noted only in the chemisorption region. Unlike calcite, the hydrophobicity of fluorite was sensitive to the presence of oxygen in the system. Multichannel Laser Raman Spectroscopy (MLRS) showed this behavior was caused by the double-bond reactivity of adjacent chemisorbed oleate molecules and subsequent formation of an epoxide/polyether complex at the fluorite surface. Such a reaction product could not be detected at the calcite surface. These differences in adsorption density, hydrophobicity, and polymerization behavior are discussed in terms of the intrinsic surface properties of the minerals.

Jan 1, 1999

By Michael J. Nicol

Growing environmental and occupational safety concerns about the use of cyanide in gold processing has increased the interest in more acceptable alternatives. The most likely of these is thiosulfate. However, the thiosulfate process lacks a proven in-pulp method of recovering the dissolved gold, because activated carbon is not effective for the absorption of the gold thiosulfate complex .. Anion exchange resins do offer a possible route for in-pulp recovery. This paper describes work aimed at the evaluation of the effectiveness of commercially available anion exchange resins for the recovery of gold from thiosulfate leach liquors? and pulps. It has been found that strong-base resins are superior to weak-base resins in that they have a larger capacity, which assists in reducing the competition from other anions within a leach solution. Further studies with a selected commercial strong-base resin have shown that competing polythionateanions (particularly tri-and tetrathionate). Lower the maximum possible gold loading but that gold is selectively recovered over other base metal anions in solution. Kinetic experiments found that while? competilig anibns did not affect the initial rate? of gold loading it was important to minimise the contact time of the resin in solution so to prevent displacement of loaded gold by competing anions over longer times. A small-scale resin-in-pulp plant investigation showed gold can be recovered from a leach pulp by a strong-base resin to yield gold loadings of 3000 mg/L, barren pulp containing less than 0.05 mg/L of dissolved gold and. copper loadings of 500 mg/L. Loaded copper was displaced gold and at a loading of 2000 mg/L gold the copper loading was minimal «500 mg/L). The resin was found to recover gold adsorbed on the solids that would, otherwise have. reported to tails if a solid/liquid separation method were used. A patented two-step elution process in which copper and then gold are separately eluted from the resin is also discussed.

Jan 1, 1998

By Valentine A. Chanturiya

The aim of this paper is basically to show progress in the study of nanosecond processes involved in the disintegration and breaking-up of mineral complexes with fine noble metals. We studied the influence of nanosecond High-Power Electromagnetic Pulses (HPEMP) on the physical and technological properties of refractory gold-containing ores and beneficiation products. Experimental data are presented to confirm the formation of breakdown channels and selective disintegration of mineral complexes as a result of pulse irradiation, which makes for efficient access of lixiviant solutions to precious metal grains and enhanced precious metal recovery into lixivia during leaching. Preliminary processing of gravity concentrate with a HPEMP resulted in significant increase of gold and silver extraction into lixivia during the cyanidation stage, with gold recovery increased by ~31% (from 51.2% in a blank test to 82.3% after irradiation). Gold recovery from stale gold-containing dressing tailings products increased after pulses-irradiation from 8-12% to 80-90%.

Jan 1, 2006

By Eulogio Velasco, Jose Nino, Marcos Cardoso

"Recycling of aluminum scrap for production of secondary alloys used for automotive applications is increasing continuously. Automotive alloys require a strict control to remove alloy impurities, inclusions and excess of magnesium. The advantage of aluminum is its recyclability with large energy and emission savings with minimal loss in material properties. The aim of this work is to study the magnesium removal from recycled aluminum by chlorine injection in a reverberatory furnace, and removal by an oxidation process at high temperature in an industrial rotary furnace.The magnesium removal by gas injection is carried out by the reaction between chlorine and magnesium, with its efficiency associated to kinetic factors. In the rotary rapid oxidation of aluminum and magnesium elements at high temperature is characterized by the formation of surface films composed of magnesium oxide. Additionally this work reviews the benefits of an efficient demagging process.IntroductionThe advantages of using light alloys for automotive applications include fuel economy improvement, greenhouse gas reductions and polluting emissions. These characteristics makes the aluminum alloys an attractive option for automotive components such as powertrain products and other critical parts like cylinder heads and blocks. [1]Aluminum alloys coming from recycled automotive components, used beverage cans (UBC) and wrought alloys have positive effects in the energy savings and current environmental trends. Producing a scrap recycled aluminum ingot consumes approximately 5% of the energy required to produce a primary aluminum ingot from bauxite ore. [2]"

Jan 1, 2011

By P. Klut, D. Groult, R. Marechalle, B. T. H. Bonnema

In the past 5 years, Compagnie Europeenne de Dezingage (CED) has developed a successful dezincing process and the St. Saulve pilot plant has evolved into a commercially successful production plant. Currently the plant meets all the required standards for scrap and zinc quality, output capacity, availability, and meets the prescribed environmental emissions standards. The initial process problems relating to zinc recovery, uncontrollable explosions and sodium hydroxide aerosol emissions have all been solved. Presntly, the yearly production of dezinced scrap is around 50.000 tonnes/year; this capacity is enough to supply the local market. This capacity can be increased easily to 65.000 tonnes/year or more. The market for dezinced material is growing due to the increased consumption of galvanized material on one hand and on the other hand the higher demand for high quality scrap. The proven technology of CED is currently patented worldwide, but CED is inviting licensees to implement the dezincing technology in other parts of the world.

Jan 1, 2000

By J. Kevin Cotchen

The results of "submerged arc" electric furnace processing of a variety of materials is discussed with respect to the process and products, including the characteristics of the products (e.g. TCLP or Toxicity Characteristics Leaching Procedure). The materials melted include slags and wastes containing various metal oxides including copper, tin, lead, zinc, chrome, nickel and other associated elements. The findings of these tests are compared to those reported in the literature for other operations treating similar "wastes".

Jan 1, 1992

By Marco V. Ginatta

Current world production, 60'000 ton/y, is exceedingly too small for titanium's extraordinary combination of favorable properties; it should be 1,000,000 ton/y (7% of stainless-steel). Prices that competitively sustain that sales volume are achievable only with electrolytic production, as it is for all other commercial nonferrous metals. But titanium does not have its commercial electrolytic plants yet, because of producers decisions and strategies, scientists works, industrial problems with chloride process, lack of consumers sponsors. Fluoride high temperature process has the advantages of aluminum electrolysis, plus other favorable characteristics specific to titanium and its feed material. One electrolytic titanium potroom replaces several different plants used for sponge production. Production of titanium ingots with zero defect is achieved. The solidified cathode rectangular slabs are suitable for direct rolling.

Jan 1, 2001

By Kathryn Hindmarsh

The most common method for the concentration of cyanide in gold leach circuits is based on the titration of cyanide ions with silver ions. This can either be done manually as a titration with a visual end-point or by using one of several commercial cyanide analysers which are 'based on the same titration but use a potentiometric end point This method has 'its limitations in the case of some ores such as those containing high amounts of soluble copper and those that are treated at low (less than pH 9) pH values in that the titration results do not accurately reflect the concentration of cyanide which is available for the dissolution of gold. This paper will present the results of the development of a novel "active" cyanide analyser which is based on the rate, of the reaction between gold colloids and cyanide. Gold colloids have a deep red colour and can be very simply prepared and stored for extended periods of time when stabilized. t has been shown that colloidal gold behaves similarly to metallic gold, dissolving in aerated sodium cyanide solutions to give the colourless Au(CNh-ion, This allows the reaction between the colloids and cyanide to be monitored spectrophotometrically at 520 nm. An automated instrument has been developed around this concept which can analyse a filtered pulp stream every few minutes with periodic calibration using standard cyanide solutions, Results of test work on synthetic solutions and solutions derived from several Australian gold plants will be presented as will the results of a comparative evaluation with a commercial titration analyser on a local gold plant

Jan 1, 1998

By R. Mehta, M. Misra, X. Su

"The conventional methods to assess Acid Mine Drainage (AMD) potential of the waste rocks and tailings are based on wet chemistry and leachability tests. These methods are time consuming and expensive. There is a growing interest to develop alternate techniques to establish the reactivity of acid mine tailings and stability of treated waste forms. The Electrochemical Impedance Spectroscopy (EIS) is a reliable non-invasive technique which can be used for quick estimation of reactivity of the potential acid generating tailings. In this paper the utilization of the EIS technique for the estimation of reactivity of tailings is discussed. EIS can also be used to predict the long term stability of different stabilized waste forms.IntroductionMetal contaminated mine drainage is one of the most persistent environmental problems facing the mining and mineral processing industries today. Of all the mine drainage pollutants, acid mine drainage has become a substantial concern because of the potential long-term environmental implications and the accompanying liabilities. The main source of acid mine drainage is the tailings containing sulfide-ores which are generated during the ore processing. When these sulfide minerals, particularly pyrite and pyrrhotite, are exposed to oxygen and water they begin to oxidize. The initial chemical reactions produce acid and the acid dissolves heavy metals present in the tailings. Rainfall and snow-melt flush the toxic solutions from the waste sites into the downstream environment [1-2]. In addition to mining tailings, several Department of Energy (DOE) sites contain wastes which are contaminated with radionuclides and heavy metals."

Jan 1, 1999

By G. A. Irons, D. Guo, D. Angheiina

To produce low-carbon (<30 ppm) steel in the tank degassing process, a ladle of steel with an oxidizing slag is placed in a vacuum tank equipped with bottom bubbling. The kinetics of this process are slow compared to the more prevalent RH degassing process, providing the impetus for the present work. There are several aspects to this work: water models of the fluid flow in the ladle; simulation of the decarburization (CO evolution) with C02 desorption in water; pilot-plant (60 kg) studies of the decarburization kinetics; mathematical modelling of the fluid flow in the ladle; mathematical models for each of the kinetic sites (plume, top slag and auto-nucleation); and full-scale trials. The results show that during the refining cycle the contribution from each reaction site changes, suggesting avenues for reducing cycling time and final carbon contents.

Jan 1, 2000

By Richard J. Abitz

Thennodynamic geochemical models have been applied to assess the relative effectiveness of a variety of reagents added to aqueous waste streams for the removal of radioactive elements. Two aqueous waste streams were examined: effluent derived from the processing of uranium ore and irradiated uranium fuel rods. Simulations of the treatment train were performed to estimate the mass of reagents needed per kilogram of solution, identify pH regions corresponding to solubility minimums, and predict the identity and quantity of precipitated solids. Results generated by the simulations include figures that chart the chemical evolution of the waste stream as reagents are added and summary tables that list mass balances for all reagents and radioactive elements of concern. Model results were used to set initial reagent levels for the treatment trains, minimizing the number of bench-scale tests required to bring the treatment train up to full-scale operation. Additionally, presentation of modeling results at public meetings helps to establish good faith between the federal government, industry, concerned citizens, and media groups.

Jan 1, 1996

By Jr. Napolitano, Jr. Sanders

"Morphological evolution of a dendritic growth front in a binary alloy is simulated using a cellular automaton approach to establish the feasibility of modeling such growth with a local rule-based scheme. The motivation for this work is derived from the need to predict the development of solidification structures within real components of complex geometry, where significant constraint of the thermal and solutal fields may exist. Such cases present complex boundaries and large domain sizes, which may preclude the effective use of more conventional methods. In this work, a model is presented which couples a two-dimensional alternate-direction-implicit finite-difference diffusion solution with a cellular automaton growth algorithm to simulate morphological evolution in alloys solidifying under directional growth conditions. Temperature, composition, and interface curvature are incorporated into a local growth potential which is used by the automaton, allowing the interface to evolve. Alloy solidification is simulated over a range of experimental conditions, producing various structures. Issues addressed include morphological instability, primary spacing selection, interface curvature, microsegregation, and tip conditions.IntroductionThe development of dendritic structure plays an essential role in alloy solidification. Virtually every microstructural feature, within a cast alloy component, is related to the interface morphology present during solidification. Conventional solidification theory, describing dendrite tip kinetics and mushy zone phenomena, provides a means for estimating overall microstructural parameters for an alloy solidified under steady-state conditions. Microstructural prediction for actual components, which are finite in size and complex in geometry, requires a description of the evolution of the interface morphology under transient conditions and geometrical constraint and an understanding of how the structure propagates through the mold. Any useful simulation tool must be equipped to handle these circumstances within the limits of computational feasibility."

Jan 1, 1998

By C. O. Bounds

Management of emission control dust from electric? arc furnace (EAF) steelmaking as an RCRA-EPA listed hazardous waste places economic and environmental pressures on the steelmaking industry. Horsehead Resource Development Company, Inc. (HRD) serves the industry by recovering nonferrous metals from the dust in rotary kiln plants in Palmerton, PA and Chicago, IL, and has demonstrated the commercial viability of its patented coal-fired FLAME REACTOR Process. However, because of location and/or regulation, many steelmakers could be more economically served via on-site processing of its dust. Therefore, in 198-7, through a contract with the Gas Research Institute, HRD embarked on a program to develop a gas-fired reactor and test a prototype unit. The development program has successfully proven the environmental, technical and economic performance of the concept. Consistently high zinc, lead and cadmium recovery to an oxide concentrate as well as production of a nonhazardous, delistable slag have routinely been achieved. The gas-fired FLAME REACTOR field experiment results and the economic performance of on-site or smaller regional plants will be highlighted.

Jan 1, 1990

By Arthur E. Morris

Process modeling software is used extensively in process engineering, but there is a notable lack of affordable software for educational uses. This paper describes two educationally oriented software programs for thermochemical modeling of processes involving metals, minerals, and ceramic materials. Both programs run as Excel@ spreadsheet files. The first is FREED, a thermodynamic database program containing datafiles for 2500 species. It contains the entire U. S. Bureau of Mines and most of the U. S. Geological Survey database, plus data for scores of other species drawn from various sources. Several modules are available for manipulating and viewing the data. The second program is THERBAL, for making thermodynamic calculations using FREED data. Equilibrium calculations can be made for systems with non-ideal solutions, for a specified set of pressure, temperature, and input amounts of reactants. An optional heat balance is also calculated. The results are displayed as tables or charts in Excel worksheets. Examples of the use of THERBAL will be given for the reforming of natural gas for DRI production, DRI production, and EAF steelmaking. Some observations will be made on its use in the classroom. The development of FREED and THERBAL was initially carried out at the Department of Metallurgical Engineering, University of Missouri - Rolla as part of a project to preserve and enhance the Bureau of Mines database. The current versions were developed privately by the authors.

Jan 1, 2002

By Y. W. Chung, W. I. Chia

"The interaction of water vapor with single crystal Ni3(Al,Ti) and polycrystalline Ni3Fe, with and without the presence of oxygen, has been studied with Auger electron spectroscopy, photoemission spectroscopy, thermal desorption and isotope exchange. Water dissociates to produce atomic hydrogen above 200 K on both Ni3(Al,Ti) and Ni3Fe surfaces. For Ni3(Al, Ti), the reaction is structure-sensitive. Pre-adsorbed or co-adsorbed oxygen on Ni3(Al,Ti) and Ni3Fe significantly suppresses hydrogen production due to water dissociation. This suppression process occurs more efficiently on Ni3Fe than Ni3(Al, Ti).IntroductionOrdered intermetallic compounds such as aluminides, silicides and titanides are very attractive for structural applications at high temperatures. This is because these intermetallics tend to form adherent oxides in oxidizing environments which protect the base materials from excessive oxidation and corrosion. In addition, they have low density, relatively high melting points and good high-temperature strength. However, the moisture in air severely embrittles many ordered intermetallics such as FeAl [1-3], Fe3A1 [4,5], C03Ti [6,7], (Co,Fe)) V [8], Ni3Si [9], Ni3(Si,Ti) [10], Ni3(AI,Mn) [Ill, and Ni3A1 [12-14], resulting in low 'ductility and brittle fracture at room temperature. Recent studies by Liu and coworkers (see review by George and Liu [15]) provide a qualitative description of the mechanism for this moisture-induced embrittlement. During elongation testing, cracks are formed, thus exposing fresh alloy surfaces. One or more active components of the alloy react with water vapor in the environment to produce atomic hydrogen which penetrates into crack tips and causes hydrogen embrittlement. This is similar to that proposed for moisture-induced embrittlement of aluminum alloys [16]."

Jan 1, 1996

By A. P. Pavia

Investigation on profitable ways to recover significant quantities of silver remaining dissolved in highly concentrated chloride solutions frequently pass through the development of solvent extraction (SX) routes. In this work, the general pathways involving Ag(I) extraction by dibutylthiourea (DBT) or tetraethylthiuram disulfide (disulfiram, DSF), from concentrated acidic chloride solutions, are investigated. With this purpose, the dependence of Ag(I) distribution coefficient on ligand and chloride concentrations has been analysed. Furthermore, in order to check whether there is some protonation at any site of DBT or DSF after contact with adequate chloride phases, lH NMR has also been used. The collected spectroscopic data suggest that anionic Ag(I) extraction reactions are not likely to occur. Based on the overall results achieved, proposals for the most probable Ag(I) extraction reactions are made.

Jan 1, 2001

By Michael J. Nicol

This paper summarizes some of the results of a study of the reactions involved in the Caron leaching process and identifies the roles of the major dissolved species in the kinetics of dissolution of iron alloy particles formed during reductive roasting. Using rotating disk electrodes and synthetic leach solutions, the reduction of water with the evolution of hydrogen was found not to occur on a dissolving iron surface under typical leach conditions. It has been established that the oxidative dissolution is governed primarily by a reaction involving reduction of Co(III) to Co(II) ions. The reduction of oxygen was also found to make a significant but largely indirect contribution to the kinetics of the dissolution process. The dissolution rates of various iron-nickel-cobalt-copper alloys which simulate the dissolving alloy particles in a Caron plant were measured in synthetic leach solutions under aerobic and anaerobic conditions. The initial dissolution rates of iron, nickel and the iron alloys were found to increase in the presence of thiosulphate, whereas the thiosulphate had a negative effect on the dissolution rates of cobalt and copper. It is shown that the eventual passivation of the iron occurs sooner in solutions rich in Co(II) ions. Whilst these conditions are present in the quench slurry, on-site measurements have shown that due to the very high concentration of reduced dissolved species, passivation does not occur until the slurry is strongly aerated. In the light of these fundamental findings, options for optimizing the rate of dissolution and minimizing the extent of passivation of the iron and iron alloys are discussed. Keywords: Ammonia, leaching, alloy, kinetics, passivation.

Jan 1, 2004

By H. Kamarudin

The behaviour of cassiterite-sulphosuccinamate flotation system was examined in the light of zeta potentials measured by micro-electrophoresis method. It was observed that sulphosuccinamate substantially affects the zeta potentials of cassiterite, lowering its i.e.p. to pH 2.5 and indicating a specific adsorption and/or chemical interaction. The optimum concentration for flotation, as seen in micro-flotation tests, was found to be associated with the most effective lowering of the zeta potentials, the optimum pH being 3.0. The effect of cations in the pulp was examined for the presence of ferrous, ferric, aluminium and lead ions. The ions ferric and aluminium were observed to create an intense effect of increasing the potentials to positive side, possibly due to adsorption of cation hydroxy complexes, as indicated by their respective species distribution diagrams.

Jan 1, 1994

By Ben Hogg

Since the development of the top-submerged lance (TSL) technology for copper and lead smelting by the cooperation of Mount Isa Mines (MIM), now owned by Glencore, and the Commonwealth Scientific Industrial Research Organisation (CSIRO) the core of the ISASMELT™technology has always resided in the lance system. Through continuous innovation and operation of our own smelters, first at MIM, subsequently at Mopani, and also at both the Kazzinc Copper and Kazzinc Lead smelters, Glencore Technology have expanded the core equipment supply to enhance the plant operability. The success of Glencore Technology’s expertise can be directly measured by the success of the Kansanshi Copper Smelter plant, which achieved 100% nameplate capacity within three months of start-up. This paper describes the ISASMELT™ core equipment and how it is applied to smelt sulfide materials. It highlights the strength of the ISASMELT™: continuous innovation to facilitate the versatility and continued increased capacity with every plant implementation.